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    • 4. 发明授权
    • Substituted P,P'-methylene-bis-aniline
    • 取代的P,P'-亚甲基双苯胺
    • US4978791A
    • 1990-12-18
    • US748594
    • 1985-06-25
    • Theodor VolkerHans Althaus
    • Theodor VolkerHans Althaus
    • C08G18/00C07C209/78C07C211/50C07C211/52C08G18/32C08G18/38C08G18/65C08G59/00C08G59/50C08G59/56
    • C08G18/3243C08G18/3814C08G59/5033C08G2120/00
    • 2,2'-Dichloro-6,6'-diethylmethylene-bis-aniline or mixtures thereof with compounds of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and are straight-chained or branched alkyl radicals having 2 to 4 C atoms, or R.sub.1 and/or R.sub.3 are chlorine and the remaining R's have the above-mentioned significance, as chain-extension means or cross-linkage means for polyurethanes or epoxide resins. Process for the production of 2,2'-dichloro-6,6'-diethylmethylene-bis-aniline or such mixtures. 2-ethyl-6-chloroaniline is condensed with itself or an aniline having the formula: ##STR2## wherein R.sub.5 and R.sub.6 are the same or different and are straight-chained or branched having 2 to 4 C atoms, with the proviso that R.sub.5 can also be chlorine, in acidic medium with formaldehyde or compounds which form formaldehyde. The compounds in the mixture can be condensation products of two molecules of such aniline derivatives.
    • 2,2'-二氯-6,6'-二乙基亚甲基双苯胺或其与下式化合物的混合物:其中R 1,R 2,R 3和R 4相同或不同,为直链或支链烷基 具有2至4个C原子的基团,或R 1和/或R 3为氯,并且其余R具有上述意义,作为聚氨酯或环氧树脂的链延伸方式或交联方式。 制备2,2'-二氯-6,6'-二乙基亚甲基双苯胺或这些混合物的方法。 2-乙基-6-氯苯胺与其本身或具有下式的苯胺缩合:其中R 5和R 6相同或不同,是直链或支链的,具有2至4个C原子,条件是R 5可以 也是氯,在酸性介质中与甲醛或形成甲醛的化合物。 混合物中的化合物可以是两分子这种苯胺衍生物的缩合产物。