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1. 发明授权

US5286874A Process for the production of bismaleinimide derivatives 失效
标题翻译：生产双马来酰亚胺衍生物的方法
公开(公告)号：US5286874A
公开(公告)日：1994-02-15
申请号：US981060
申请日：1992-11-24
申请人： Peter Hardt , Theodor Volker
发明人： Peter Hardt , Theodor Volker
IPC分类号： B01J31/02 , C07B61/00 , C07D207/44 , C07D207/452 , C07D207/24
CPC分类号： C07D207/452
摘要： A process for the production of bismaleinimide derivatives of the formula: ##STR1## In the first step, maleic acid anhydride of the formula: ##STR2## is converted with a methyl-bis-aniline of the formula: ##STR3## in an unhalogenated aromatic hydrocarbon as the solvent, into the corresponding amide acid. In the second step, the amide acid is converted, without isolation, in the presence of an acid catalyst, into the end product of the formula I.
摘要翻译：描述了一种制备式“IMAGE”的双马来酰亚胺的新方法，其中在第一步中，将式“IMAGE”的马来酸酐在式I'的甲基双苯胺转化为未卤化芳烃中，溶剂，得到相应的酰胺酸，并且在酸性催化剂的存在下，在第二步中，不分离而将该酰胺酸转化而得到式I的最终产物。

2. 发明授权

US4950792A Substituted p,p'-methylene-bis-anilines 失效
标题翻译：取代的p，p'-亚甲基双苯胺
公开(公告)号：US4950792A
公开(公告)日：1990-08-21
申请号：US206920
申请日：1988-06-09
申请人： Hans Althaus , Theodor Volker , Andreas Schmidt
发明人： Hans Althaus , Theodor Volker , Andreas Schmidt
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/78 , C07C211/52 , C07C211/56 , C08G18/32 , C08G18/38 , C08G18/65
CPC分类号： C08G18/3814 , C08G2101/00 , Y02P20/582
摘要： New methylenebis(metachloro)anilines which are chain-lenghtening agents or cross-linking agents for polyurethanes.
摘要翻译：作为聚氨酯的链增长剂或交联剂的新亚甲基双（间氯）苯胺。

3. 发明授权

US5026815A Chain-lengthening agents for p-phenylene-methylenediisocyanate-prepolymers for cast polyurethane elastomers 失效
标题翻译：用于铸塑聚氨酯弹性体的对亚苯基 - 亚甲基二异氰酸酯预聚物的延长剂
公开(公告)号：US5026815A
公开(公告)日：1991-06-25
申请号：US493748
申请日：1990-03-15
申请人： Theodor Volker , Hans Althaus , Andreas Schmidt
发明人： Theodor Volker , Hans Althaus , Andreas Schmidt
IPC分类号： C08G18/65 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/76
CPC分类号： C08G18/7671 , C08G18/10 , C08G2101/00 , C08G2380/00
摘要： Chain-lengthening agents based on chlorinated 4,4'-methylenebisanilines for p-phenylene-methylenediisocyanate prepolymer are used for the preparation of cast polyurethane elastomers.
摘要翻译：用于对亚苯基 - 亚甲基二异氰酸酯预聚物的基于氯化的4,4'-亚甲基双胍的链延长剂用于制备流延聚氨酯弹性体。

4. 发明授权

US4048130A Process for the production of self-cross-linking lacquers 失效
标题翻译：自交联漆生产工艺
公开(公告)号：US4048130A
公开(公告)日：1977-09-13
申请号：US557061
申请日：1975-03-10
申请人： Marcel Brunold , Klaus Hering , Paul Wicht , Christian Vonlanthen , Jurg Kislig , Theodor Volker
发明人： Marcel Brunold , Klaus Hering , Paul Wicht , Christian Vonlanthen , Jurg Kislig , Theodor Volker
IPC分类号： C08F2/22 , C08F246/00 , C08L61/20 , C09D133/06 , C09D157/00 , C08L35/02
CPC分类号： C09D133/064 , C08F2/22 , C08F246/00 , C09D157/00 , C08L61/20
摘要： The process for preparing a lacquer utilizing an aqueous dispersion, the lacquer being pigmented or non-pigmented, being self-cross linking upon heat treatment and containing a binder consisting essentially of the following monomers:A. 30 to 70 parts by weight of at least one monomer whose homopolymer has a theoretical glass temperature of less than 10.degree. C., based on the total weight of the binder,B. 30 to 70 parts by weight of at least one monomer whose homopolymer has a theoretical glass temperature of more than 30.degree. C., based upon the total weight of the binder,C. 0.5 and 5 parts by weight of at least one polymerizable acid and/or salt thereof, based upon the total weight of the binder,D. 2 to 35 parts by weight of at least one reactive monomer, based upon the total weight of the binder, andE. 0.5 to 35 parts by weight of at least one alkali or ammonium salt of a polymerizable sulfonic acid compound, based upon the total weight of the binder.The process involves conducting the polymerization in an aqueous dispersion in a reaction vessel at a preselected temperature between 15.degree. and 30.degree. C. and at a starting pH of 3 to 4 in the presence of a redox system consisting of 0.005 to 0.5 percent by weight of at least one alkali and/or ammonium persulfate, based upon the total weight of the monomers, 0.001 to 0.5 percent by weight of ascorbic acid, based upon the total weight of the monomers, and 10 to 30 p.p.m. of at least one iron (II)-salt based upon the total weight of the monomers. No more than 30 percent of the monomers and the majority (at least 50 percent) of the persulfate are inserted into the reaction vessel before the polymerization step starts. After the polymerization step starts, the remaining amount of monomers are dosed into the reaction vessel concurrently and parallel with the iron (II)-salt and the ascorbic acid in such a manner that the preselected polymerization temperature remains almost constant.
摘要翻译：使用水性分散体，着色或未着色的漆制备漆的方法在热处理时自交联并且含有基本上由以下单体组成的粘合剂：

5. 发明授权

US5488163A Process for the production of 4, 4'-(phenylene-diisopropyl)-bis(2, 6-dialkylanilines) 失效
标题翻译：制备4,4' - （亚苯基 - 二异丙基） - 双（2,6-二烷基苯胺）的方法
公开(公告)号：US5488163A
公开(公告)日：1996-01-30
申请号：US360082
申请日：1994-12-20
申请人： Peter Hardt , Ulrich Daum , Theodor Volker
发明人： Peter Hardt , Ulrich Daum , Theodor Volker
IPC分类号： C07B61/00 , C07C209/68 , C07C211/49 , C07C211/50 , C07C211/52 , C08G18/10 , C08G18/65 , C08G59/50 , C08L75/00 , C08L75/04 , C09D7/12
CPC分类号： C09D7/1241 , C07C209/68 , C07C211/50 , C08G18/10 , C08G59/5033 , C08K5/17 , C08K5/18
摘要： A process for the production of 4,4'-(phenylenediisopropyl)bis(2,6-dialkylanilines) of the general formula: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each is a (C.sub.1 -C.sub.4)alkyl group, R.sub.3 is hydrogen or halogen, and the central phenylene function is substituted in the 1,3 or 1,4 position, by reaction of a corresponding diisopropyl benzene with a corresponding aniline in the presence of catalytic amounts of aluminum chloride. The 4,4'-(phenylenediisopropyl)-bis(2,6-dialkylanilines) are used as cross-linking agents for epoxy resins, as chain lengthening agents for polyurethanes, for the production of hydrolysis protective agents for polyurethanes, or for the production of UV stabilizers in varnishes.
摘要翻译：一种制备通式如下的4,4' - （亚苯基二异丙基）双（2,6-二烷基苯胺）的方法，其中R 1和R 2相同或不同，并且各自为（C 1 -C 4）烷基基团，R3是氢或卤素，并且中间亚苯基功能在1,3或1,4位置被相应的二异丙基苯与相应的苯胺在催化量的氯化铝存在下反应取代。 4,4' - （亚苯基二异丙基） - 双（2,6-二烷基苯胺）用作环氧树脂的交联剂，作为聚氨酯的延长剂，用于生产聚氨酯的水解保护剂或生产的UV稳定剂在清漆中。

6. 发明授权

US4978791A Substituted P,P'-methylene-bis-aniline 失效
标题翻译：取代的P，P'-亚甲基双苯胺
公开(公告)号：US4978791A
公开(公告)日：1990-12-18
申请号：US748594
申请日：1985-06-25
申请人： Theodor Volker , Hans Althaus
发明人： Theodor Volker , Hans Althaus
IPC分类号： C08G18/00 , C07C209/78 , C07C211/50 , C07C211/52 , C08G18/32 , C08G18/38 , C08G18/65 , C08G59/00 , C08G59/50 , C08G59/56
CPC分类号： C08G18/3243 , C08G18/3814 , C08G59/5033 , C08G2120/00
摘要： 2,2'-Dichloro-6,6'-diethylmethylene-bis-aniline or mixtures thereof with compounds of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and are straight-chained or branched alkyl radicals having 2 to 4 C atoms, or R.sub.1 and/or R.sub.3 are chlorine and the remaining R's have the above-mentioned significance, as chain-extension means or cross-linkage means for polyurethanes or epoxide resins. Process for the production of 2,2'-dichloro-6,6'-diethylmethylene-bis-aniline or such mixtures. 2-ethyl-6-chloroaniline is condensed with itself or an aniline having the formula: ##STR2## wherein R.sub.5 and R.sub.6 are the same or different and are straight-chained or branched having 2 to 4 C atoms, with the proviso that R.sub.5 can also be chlorine, in acidic medium with formaldehyde or compounds which form formaldehyde. The compounds in the mixture can be condensation products of two molecules of such aniline derivatives.
摘要翻译： 2,2'-二氯-6,6'-二乙基亚甲基双苯胺或其与下式化合物的混合物：其中R 1，R 2，R 3和R 4相同或不同，为直链或支链烷基具有2至4个C原子的基团，或R 1和/或R 3为氯，并且其余R具有上述意义，作为聚氨酯或环氧树脂的链延伸方式或交联方式。制备2,2'-二氯-6,6'-二乙基亚甲基双苯胺或这些混合物的方法。 2-乙基-6-氯苯胺与其本身或具有下式的苯胺缩合：其中R 5和R 6相同或不同，是直链或支链的，具有2至4个C原子，条件是R 5可以也是氯，在酸性介质中与甲醛或形成甲醛的化合物。混合物中的化合物可以是两分子这种苯胺衍生物的缩合产物。

7. 发明授权

US4717747A Stablizer mixtures for vinyl chloride polymer masses 失效
标题翻译：稳定剂氯乙烯聚合物的混合物
公开(公告)号：US4717747A
公开(公告)日：1988-01-05
申请号：US746677
申请日：1985-06-20
申请人： Theodor Volker
发明人： Theodor Volker
IPC分类号： C08L27/00 , C08K5/00 , C08K5/04 , C08K5/09 , C08K5/13 , C08K5/1545 , C08L1/00 , C08L27/06 , C08L33/00 , C08L33/02 , C08K5/15 , C09K15/06
CPC分类号： C08K5/04 , C08K5/1545
摘要： Stabilizer mixtures for vinyl chloride polymerizates for the improvement of the initial clarity and the heat constancy thereof. The stabilizer mixture contains nitrogen-free 3,5-substituted tetrahydropyrane-2,4,6-trione compounds of the formula: ##STR1## wherein R is a substituted or unsubstituted alkyl radical having 1 to 6 C atoms, and a metal salt of an organic acid and/or a metal phenolate.
摘要翻译：用于氯乙烯聚合的稳定剂混合物，用于改善初始透明度和其热稳定性。稳定剂混合物含有下式的无氮3,5-取代四氢吡喃-2,4,6-三酮化合物：其中R是具有1-6个C原子的取代或未取代的烷基，和金属盐有机酸和/或金属酚盐。

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