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    • 6. 发明授权
    • Solid polymer electrolyte composite membrane comprising plasma etched porous support
    • 固体聚合物电解质复合膜,包括等离子蚀刻多孔载体
    • US07807063B2
    • 2010-10-05
    • US10970685
    • 2004-10-21
    • Han LiuAnthony B. LaConti
    • Han LiuAnthony B. LaConti
    • H01M2/14C25B13/00
    • H01M8/1018C25B13/02H01G9/0036H01G9/025H01G9/038H01G11/56H01M8/1023H01M8/1039H01M8/1053H01M8/106H01M8/1062H01M2300/0091Y02E60/13Y02P70/56
    • A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a rigid, non-electrically-conducting support, the support preferably being a sheet of polyimide having a thickness of about 7.5 to 15 microns. The support has a plurality of cylindrical pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores, which preferably have a diameter of about 0.1 to 5 microns, are made by plasma etching and preferably are arranged in a defined pattern, for example, with fewer pores located in areas of high membrane stress and more pores located in areas of low membrane stress. The pores are filled with a first solid polymer electrolyte, such as a perfluorosulfonic acid (PFSA) polymer. A second solid polymer electrolyte, which may be the same as or different than the first solid polymer electrolyte, may be deposited over the top and/or bottom of the first solid polymer electrolyte.
    • 一种固体高分子电解质复合膜及其制造方法。 根据一个实施方案,复合膜包括刚性的非导电载体,所述载体优选为具有约7.5至15微米厚度的聚酰亚胺片。 支撑件具有多个在支撑件的相对的顶部和底部表面之间垂直延伸的圆柱形孔。 优选地具有约0.1至5微米直径的孔通过等离子体蚀刻制成,并且优选以限定的图案排列,例如具有位于高膜应力的区域中的较少的孔和位于低的区域中的更多孔 膜应力。 孔中填充有第一固体聚合物电解质,例如全氟磺酸(PFSA)聚合物。 可以与第一固体聚合物电解质相同或不同的第二固体聚合物电解质沉积在第一固体聚合物电解质的顶部和/或底部。