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1. 发明授权

US4472558A Process for carrying out reactions caused by the transport of substances 失效
标题翻译：进行由物质运输引起的反应的过程
公开(公告)号：US4472558A
公开(公告)日：1984-09-18
申请号：US45028
申请日：1979-06-04
申请人： Clemens Casper , Henning Klussmann , Gunter Lehr , Johannes O. Sajben , Artur Reischl , Rudolf Binsack , Frank Wingler
发明人： Clemens Casper , Henning Klussmann , Gunter Lehr , Johannes O. Sajben , Artur Reischl , Rudolf Binsack , Frank Wingler
IPC分类号： B01D3/28 , B01J3/04 , B01J10/02 , B01J19/24 , C08F2/00 , C08F2/06 , C08G18/00 , C08G18/08
CPC分类号： C08G18/0838 , B01J10/02 , B01J19/243 , B01J3/042 , B01J2219/00085 , B01J2219/00162 , B01J2219/00164
摘要： This invention relates to a process for carrying out reactions which primarily occur during the transport of compounds in the liquid phase or at the liquid-gas interface. Starting components are reacted with one another and/or with gases of the inner space in a multi-phase flow tube having a liquid ring flow which may contain dissolved and/or dispersed constituents. Any necessary heat exchange takes place between the liquid and the wall of the tube or the gases.
摘要翻译：本发明涉及一种进行反应的方法，主要发生在化合物在液相或液 - 液界面输送过程中。起始组分在具有可能含有溶解和/或分散成分的液体环流的多相流动管中彼此反应和/或与内部空间的气体反应。在液体和管壁或气体之间进行任何必要的热交换。

2. 发明授权

US4212963A Polybutylene terephthalates having a low carboxyl content and continuous process for the production thereof 失效
标题翻译：具有低羧基含量的聚对苯二甲酸丁二酯和用于生产的连续方法
公开(公告)号：US4212963A
公开(公告)日：1980-07-15
申请号：US968892
申请日：1978-12-13
申请人： Gunter Lehr , Rudolf Binsack
发明人： Gunter Lehr , Rudolf Binsack
IPC分类号： C08G63/00 , C08G63/78 , C08G63/18
CPC分类号： C08G63/785 , C08G63/78
摘要： Polybutylene terephthalates having a narrow molecular weight distribution, a low carboxyl group content and an intrinsic viscosity of from 0.2 to 1.4 dl/g can be continuously produced by transporting a molten reaction mixture of terephthalic acid mono- and/or bis-(hydroxybutyl) ester or low viscosity polybutylene terephthalate at 160.degree. to 300.degree. C., together with a heated inert gas, in a diphasic annular stream through an externally heated spiral reaction tube (of substantially constant pitch) having a diameter of from 3 to 100 mm and a diameter/length ratio of from 1:400 to 1:2000 by the maintenance of a pressure difference between the beginning and the end of the reaction tube, under conditions such that the absolute pressure, determined at the point of entry of the reaction mixture into the tube, is from 1 to 100 bar and the viscosity of the annular stream is from 1 to 10,000 poises (determined at the reaction temperature), and a circular stream between the surface of the melt and the wall of the tube is produced by the curvature of the tube and a stream of gas flowing at a velocity of from 20 to 300 m/sec to accelerate the transport of material between the melt and the inert gas, whereby the reaction takes place in the liquid phase and/or at the melt/gas interface.
摘要翻译：通过将对苯二甲酸单 - 和/或双 - （羟基丁基）酯的熔融反应混合物输送，可以连续制备具有窄分子量分布，低羧基含量和特性粘度为0.2-1.4dl / g的聚对苯二甲酸丁二醇酯或低粘度聚对苯二甲酸丁二醇酯在160℃至300℃下与加热的惰性气体一起通过直径为3至100mm的外部加热的螺旋反应管（基本上恒定的间距）和二价环状流通过维持反应管的开始和结束之间的压力差，在使反应混合物进入点确定的绝对压力为管子为1至100巴，环形流的粘度为1至10,000泊（在反应温度下确定），并且在熔体表面之间的圆形流 d管的壁由管的曲率和以20-300m / sec的速度流动的气流产生，以加速在熔体和惰性气体之间的材料的输送，从而发生反应在液相和/或在熔体/气体界面处。

3. 发明授权

US4405748A High-impact polyamide moulding compositions 失效
标题翻译：高抗冲聚酰胺成型组合物
公开(公告)号：US4405748A
公开(公告)日：1983-09-20
申请号：US278337
申请日：1981-06-26
申请人： Werner Nielinger , Christian Lindner , Ulrich Grigo , Rudolf Binsack , Friedrich Fahnler , Bert Brassat
发明人： Werner Nielinger , Christian Lindner , Ulrich Grigo , Rudolf Binsack , Friedrich Fahnler , Bert Brassat
IPC分类号： C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L77/00 , C08K3/40
CPC分类号： C08L51/04 , C08L77/00
摘要： Optionally reinforced moulding compositions with high impact strength comprising polyamides and graft products of (co)polymers of butadiene and grafted units of methyl(meth)acrylate.
摘要翻译：任选地，具有高冲击强度的强化模制组合物包括聚酰胺和丁二烯的（共）聚合物和（甲基）丙烯酸甲酯的接枝单元的接枝产物。

4. 发明授权

US4382131A Thermoplastic block copolyesters, a process for their production and their use for the production of mouldings 失效
标题翻译：热塑性嵌段共聚酯，其生产方法及其用于生产模塑品的方法
公开(公告)号：US4382131A
公开(公告)日：1983-05-03
申请号：US329175
申请日：1981-12-10
申请人： Rudolf Binsack , Karl-Heinz Kohler , Leo Morbitzer , Ludwig Bottenbruch , Walter Heitz
发明人： Rudolf Binsack , Karl-Heinz Kohler , Leo Morbitzer , Ludwig Bottenbruch , Walter Heitz
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181 , C08F283/00 , C08F283/02
CPC分类号： C08G63/18 , C08G63/00
摘要： Block copolyesters based on polyalkylene terephthalates which contain polyene blocks show an extremely low deformation even when they are processed into thin articles. They still have a crystallinity which is decreased by less than the ratio corresponding to the polyene portion.
摘要翻译：基于含有多烯嵌段的聚对苯二甲酸亚烷基酯的嵌段共聚酯即使在加工成薄的制品时也显示极低的变形。它们仍然具有比对应于多烯部分的比例降低的结晶度。

5. 发明授权

US4381366A Fibre reinforced polyamide moulding compounds 失效
标题翻译：纤维增强聚酰胺模塑料
公开(公告)号：US4381366A
公开(公告)日：1983-04-26
申请号：US266957
申请日：1981-05-26
申请人： John R. Sanderson , Rudolf Binsack , Dietrich Michael , Heinrich Bonten
发明人： John R. Sanderson , Rudolf Binsack , Dietrich Michael , Heinrich Bonten
IPC分类号： C08L51/00 , C08K7/02 , C08L51/06 , C08L77/00
CPC分类号： C08L77/00
摘要： Reinforced polyamide moulding blends with improved impact strength containing as modifying agent a graft product consisting of a polyolefine as graft-substrate and grafted units of unsaturated carboxylic acids and/or derivatives therefrom and which graft product is prepared by a special oxidation process.
摘要翻译：具有改进的冲击强度的增强聚酰胺模塑混合物，其包含作为改性剂的由聚烯烃作为接枝基材和由不饱和羧酸和/或其衍生物接枝的接枝单元组成的接枝产物，并且该接枝产物通过特殊的氧化方法制备。

6. 发明授权

US4370450A Process for the production of polar-modified polypropylene and its use 失效
标题翻译：生产极性改性聚丙烯的方法及其用途
公开(公告)号：US4370450A
公开(公告)日：1983-01-25
申请号：US266949
申请日：1981-05-26
申请人： Ulrich Grigo , Josef Merten , Rudolf Binsack
发明人： Ulrich Grigo , Josef Merten , Rudolf Binsack
IPC分类号： C08F220/00 , C08F2/18 , C08F30/00 , C08F30/08 , C08F220/04 , C08F255/00 , C08F255/02 , C08L23/12
CPC分类号： C08F255/02 , C08L23/12 , C08K7/14 , C08L51/06
摘要： A process for the production of modified polypropylene particles by polymerizing vinyl monomers in aqueous suspension wherein (a) an aqueous suspension is prepared which, based on 100 to 2000 parts by weight of water, contains 100 parts by weight of polypropylene particles, 4 to 30 parts by weight of a polar vinyl monomer and based on 100 parts by weight of the monomer, 0.1 to 10 parts by weight of a radical chain polymerization initiator which has a half life of at least 2 h at a temperature of 80.degree. to 135.degree. C. and 10 to 1200 parts by weight of an organic solvent which is capable of swelling polypropylene, of which the boiling point at 760 Torr is at least 100.degree. C. and which is miscible with the monomers in any proportion; (b) the aqueous suspension is heated without decomposition of the initiator, the polypropylene being swollen and the monomer penetrating into the polypropylene, after which (c) the aqueous suspension is kept at temperatures of .gtoreq.85.degree. C. until polymerization of the monomer has ceased. The modified polypropylene is used to improve the mechanical properties of unmodified, optionally glass-fibre-reinforced polypropylene.
摘要翻译：一种通过在水性悬浮液中聚合乙烯基单体生产改性聚丙烯颗粒的方法，其中（a）制备水性悬浮液，其基于100至2000重量份的水，包含100重量份的聚丙烯颗粒，4至30 重量份的极性乙烯基单体，基于100份单体，0.1至10份重量的自由基链聚合引发剂，其在80至135℃的温度下具有至少2小时的半衰期和10〜1200重量份能够溶胀聚丙烯的有机溶剂，其沸点在760乇至少为100℃，并且可与任何比例的单体混溶; （b）水性悬浮液加热而不分解引发剂，聚丙烯溶胀，单体渗透到聚丙烯中，然后（c）将水悬浮液保持在≥85℃的温度，直到单体已停止。改性聚丙烯用于改善未改性的任选的玻璃纤维增强聚丙烯的机械性能。

7. 发明授权

US4338406A High-impact polyamide moulding compositions 失效
标题翻译：高抗冲聚酰胺成型组合物
公开(公告)号：US4338406A
公开(公告)日：1982-07-06
申请号：US283824
申请日：1981-07-16
申请人： John R. Sanderson , Rudolf Binsack , Friedrich Fahnler , Christian Lindner
发明人： John R. Sanderson , Rudolf Binsack , Friedrich Fahnler , Christian Lindner
IPC分类号： C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L77/00
CPC分类号： C08L77/00
摘要： High impact resistant optionally reinforced moulding compositions consisting of polyamide and a graft product of polybutadiene and grafted units of t-butyl acrylate and an acrylic acid ester with 1-4 C-atoms in the alcoholic moiety.
摘要翻译：由聚酰胺和聚丁二烯的接枝产物和丙烯酸叔丁酯的接枝单元和在醇部分中具有1-4个C原子的丙烯酸酯组成的高抗冲击性可选增强的模制组合物。

8. 发明授权

US4292222A Homogeneous thermoplastic mixtures of propylene-ethylene copolymers and liquid, saturated diorganopolysiloxanes within a certain viscosity range 失效
标题翻译：丙烯 - 乙烯共聚物和液体，饱和二有机聚硅氧烷的均匀热塑性混合物在一定粘度范围内
公开(公告)号：US4292222A
公开(公告)日：1981-09-29
申请号：US119939
申请日：1980-02-08
申请人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
发明人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
IPC分类号： C08L23/00 , C08L7/00 , C08L21/00 , C08L23/14 , C08L23/16 , C08L51/00 , C08L51/02 , C08L77/00 , C08L83/04 , C08L101/00 , C08L23/10 , C08L23/04
CPC分类号： C08L23/142 , C08L83/04
摘要： A homogeneous thermoplastic mixture comprising (A) from 85 to 99.5% by weight of a propylene-ethylene copolymer containing from 0.5 to 15% by weight of copolymerized ethylene units and having a melt index of from 1.0 to 30 g/min at 230.degree. C. and under a load of 5 kg; and (B) from 0.5 to 15% by weight of a saturated diorganopolysiloxane having a viscosity of from 30,000 to 80,000 Cst at 20.degree. C.The mixtures of the present invention are particularly suitable for the manufacture of elastic polypropylene based moulded articles which are dimensionally stable in heat.
摘要翻译：一种均匀的热塑性混合物，其包含（A）85至99.5重量％的含有0.5至15重量％共聚乙烯单元并且在230℃下熔体指数为1.0至30g / min的丙烯 - 乙烯共聚物并在5公斤的负荷下; 和（B）0.5至15重量％的在20℃下具有30,000至80,000Cst粘度的饱和二有机基聚硅氧烷。本发明的混合物特别适用于制造尺寸为弹性聚丙烯的模塑制品热稳定

9. 发明授权

US4176224A Poly (ethylene/alkylene) terephthalates which crystallize rapidly 失效
标题翻译：聚（乙烯/亚烷基）对苯二甲酸酯快速结晶
公开(公告)号：US4176224A
公开(公告)日：1979-11-27
申请号：US889584
申请日：1978-03-23
申请人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
发明人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181
CPC分类号： C08G63/18
摘要： The present invention is concerned with thermoplastic terephthalic acid copolyesters which crystallize more rapidly than homopolyethylene terephthalate and are based on a diol component which is about 98 to 99.9 mol % of ethylene glycol and the balance 2-ethylhexane-1,3-diol. The acid component may be up to about 10.0 mol % of other than terephthalic acid or its dimethyl ester.This invention is also concerned with a process of synthesizing such copolyesters by esterifying or transesterifying the acid and diol components between about 150.degree. and 250.degree. C. in the presence of appropriate catalysts. The condensation product may be subject to polycondensation at about 200.degree. to 300.degree. C. under reduced pressure in the presence of esterification catalysts. In a preferred embodiment the 2-ethylhexane-1,3-diol is added after the initial reaction between the acid component and the ethylene glycol and preferably after the degree of polycondensation is greater than 4.
摘要翻译：本发明涉及热塑性对苯二甲酸共聚酯，其比对苯二甲酸聚对苯二甲酸丙二醇酯更快地结晶，并且基于约98-99.9摩尔％的乙二醇和余量的2-乙基己烷-1,3-二醇的二醇组分。除了对苯二甲酸或其二甲酯之外，酸组分可以高达约10.0mol％。本发明还涉及通过在合适的催化剂存在下在约150℃和250℃之间酯化酯化或酯交换合成这种共聚酯的方法。在酯化催化剂存在下，缩合产物可在减压下在约200℃至300℃下进行缩聚反应。在优选的实施方案中，在酸组分和乙二醇的最初反应之后，优选在缩聚度大于4之后加入2-乙基己烷-1,3-二醇。

10. 发明授权

US3996197A Method of preparing polybenoxazindione polymers from aminophenoxy salicyclic acid compounds 失效
标题翻译：从氨基苯氧基水杨酸化合物制备聚苯氧基二酮聚合物的方法
公开(公告)号：US3996197A
公开(公告)日：1976-12-07
申请号：US537664
申请日：1974-12-31
申请人： Rudolf Binsack
发明人： Rudolf Binsack
IPC分类号： C08G73/06
CPC分类号： C08G73/06
摘要： New aminophenoxy salicyclic acid compounds which can be used to prepare polybenz-oxazin dione.
摘要翻译：可用于制备聚苯并恶嗪二酮的新氨基苯氧基水杨酸化合物。

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