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1. 发明授权

US4287108A Mixtures of polypropylene and liquid saturated diorganopolysiloxanes 失效
标题翻译：聚丙烯和液体饱和二有机聚硅氧烷的混合物
公开(公告)号：US4287108A
公开(公告)日：1981-09-01
申请号：US119940
申请日：1980-02-08
申请人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
发明人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
IPC分类号： C08L23/00 , C08L23/12 , C08L87/00 , C08L101/00 , C08L83/04
CPC分类号： C08L23/12 , C08L83/04
摘要： A homogeneous, thermoplastic mixture comprising (A) from 85 to 99.5% by weight of isotactic polypropylene; and (B) from 15 to 0.5% by weight of a liquid, saturated diorganopolysiloxane having a viscosity of from 30,000 to 80,000 cSt at 20.degree. C.The elastic properties of moulded articles produced from the polypropylene/diorganopolysiloxane mixtures of the present invention are substantially improved by the addition of small quantities of diorganopolysiloxane while their dimensional stability under heat and their rigidity are largely preserved.
摘要翻译：一种均匀的热塑性混合物，其包含（A）85-99.5重量％的全同立构聚丙烯; 和（B）15至0.5重量％的在20℃下粘度为30,000至80,000cSt的液体饱和二有机聚硅氧烷。由本发明的聚丙烯/二有机聚硅氧烷混合物制备的模制品的弹性性质基本上通过添加少量的二有机聚硅氧烷来改善，同时它们在加热下的尺寸稳定性和它们的刚性被大大保持。

2. 发明授权

US4292222A Homogeneous thermoplastic mixtures of propylene-ethylene copolymers and liquid, saturated diorganopolysiloxanes within a certain viscosity range 失效
标题翻译：丙烯 - 乙烯共聚物和液体，饱和二有机聚硅氧烷的均匀热塑性混合物在一定粘度范围内
公开(公告)号：US4292222A
公开(公告)日：1981-09-29
申请号：US119939
申请日：1980-02-08
申请人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
发明人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
IPC分类号： C08L23/00 , C08L7/00 , C08L21/00 , C08L23/14 , C08L23/16 , C08L51/00 , C08L51/02 , C08L77/00 , C08L83/04 , C08L101/00 , C08L23/10 , C08L23/04
CPC分类号： C08L23/142 , C08L83/04
摘要： A homogeneous thermoplastic mixture comprising (A) from 85 to 99.5% by weight of a propylene-ethylene copolymer containing from 0.5 to 15% by weight of copolymerized ethylene units and having a melt index of from 1.0 to 30 g/min at 230.degree. C. and under a load of 5 kg; and (B) from 0.5 to 15% by weight of a saturated diorganopolysiloxane having a viscosity of from 30,000 to 80,000 Cst at 20.degree. C.The mixtures of the present invention are particularly suitable for the manufacture of elastic polypropylene based moulded articles which are dimensionally stable in heat.
摘要翻译：一种均匀的热塑性混合物，其包含（A）85至99.5重量％的含有0.5至15重量％共聚乙烯单元并且在230℃下熔体指数为1.0至30g / min的丙烯 - 乙烯共聚物并在5公斤的负荷下; 和（B）0.5至15重量％的在20℃下具有30,000至80,000Cst粘度的饱和二有机基聚硅氧烷。本发明的混合物特别适用于制造尺寸为弹性聚丙烯的模塑制品热稳定

3. 发明授权

US4567226A Elastomeric block copolyamides 失效
标题翻译：弹性嵌段共聚酰胺
公开(公告)号：US4567226A
公开(公告)日：1986-01-28
申请号：US453539
申请日：1982-12-27
申请人： Ulrich Grigo , Karl-Heinz Kohler , Rudolf Binsack , Leo Morbitzer , Josef Merten , Ludwig Trabert , Walter Heitz
发明人： Ulrich Grigo , Karl-Heinz Kohler , Rudolf Binsack , Leo Morbitzer , Josef Merten , Ludwig Trabert , Walter Heitz
IPC分类号： C08G69/00 , C08G69/36 , C08G81/02 , C08F8/30 , C08L23/00 , C08L51/00
CPC分类号： C08G69/00 , C08G81/028 , Y10S525/94
摘要： Block copolyamides consisting of from 1 to 80% by weight of hydrogenated telechelic diene polymers having M.sub.n molecular weight of from 400 to 6000 and from 99 to 20% by weight of polyamides or polyamide-forming components.
摘要翻译：由1至80重量％的Mn分子量为400至6000和99至20重量％的聚酰胺或聚酰胺形成组分的氢化遥爪二烯聚合物组成的嵌段共聚酰胺。

4. 发明授权

US4473686A Block copolymers 失效
标题翻译：嵌段共聚物
公开(公告)号：US4473686A
公开(公告)日：1984-09-25
申请号：US500007
申请日：1983-06-01
申请人： Ulrich Grigo , Karl-Heinz Kohler , Rudolf Binsack , Leo Morbitzer , Josef Merten , Ludwig Bottenbruch , Walter Heitz
发明人： Ulrich Grigo , Karl-Heinz Kohler , Rudolf Binsack , Leo Morbitzer , Josef Merten , Ludwig Bottenbruch , Walter Heitz
IPC分类号： C08G81/00 , C08G69/00 , C08G81/02 , C08F8/30 , C08L77/00
CPC分类号： C08G81/028 , C08G69/00 , Y10S525/911
摘要： A block copolymer is produced fromI. 1 to 60% by weight of at least one telechelic diene polymer containing terminal carbonate ester, --OH--, --NH.sub.2 --, carboxylic acid or carboxylic acid ester groups and having a molecular weight M.sub.n of from about 400 to 1300, andII. 99 to 40% by weight of at least one polyamide or polyamide-forming component.
摘要翻译：至少一种含有末端碳酸酯，-OH-，-NH2-，羧酸或羧酸酯基的分子量Mn为约1-60％（重量）的嵌段共聚物 400至1300，和II。 99至40重量％的至少一种聚酰胺或聚酰胺形成组分。

5. 发明授权

US4276193A Catalyst on a solid carrier for the polymerization of .alpha.-olefins 失效
标题翻译：用于α-烯烃聚合的固体载体上的催化剂
公开(公告)号：US4276193A
公开(公告)日：1981-06-30
申请号：US72085
申请日：1979-09-04
申请人： Klaus-Peter Arlt , Ulrich Grigo , Rudolf Binsack
发明人： Klaus-Peter Arlt , Ulrich Grigo , Rudolf Binsack
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： A process for the preparation of a stereospecific .alpha.-olefin polymerization catalyst which comprises (i) forming a solid carrier from an anhydrous magnesium compound and an electron donor compound; (ii) contacting the solid carrier obtained in step (i) with a solution of TiCl.sub.4 in an inert solvent; and (iii) reducing the TiCl.sub.4 with a reducing agent of the formulaAlR.sub.n X.sub.3-nwherein R is an alkyl group having from 1 to 18 carbon atoms, X is a halogen atom, and n is an integer such that 0
摘要翻译：一种制备立体有择性α-烯烃聚合催化剂的方法，其包括（i）由无水镁化合物和电子给体化合物形成固体载体; （ii）将步骤（i）中获得的固体载体与TiCl 4在惰性溶剂中的溶液接触; 和（iii）用式AlRnX 3-n的还原剂还原TiCl 4，其中R是具有1至18个碳原子的烷基，X是卤素原子，n是整数，使得0

6. 发明授权

US4423196A Copolymers of propylene and allyl alcohol 失效
标题翻译：丙烯和烯丙醇的共聚物
公开(公告)号：US4423196A
公开(公告)日：1983-12-27
申请号：US321277
申请日：1981-11-13
申请人： Klaus-Peter Arlt , Rudolf Binsack , Ulrich Grigo , Dieter Neuray
发明人： Klaus-Peter Arlt , Rudolf Binsack , Ulrich Grigo , Dieter Neuray
IPC分类号： C08F4/00 , C08F4/60 , C08F12/00 , C08F16/00 , C08F16/02 , C08F210/00 , C08F210/06 , C08F212/00 , C08F220/00 , C08F220/04 , C08F216/08 , C08F220/62
CPC分类号： C08F210/00 , C08F210/06
摘要： Copolymers of (a) one or more .alpha.-olefins having the formula (A) ##STR1## wherein R is a C.sub.1 -C.sub.16 alkyl group or a phenyl group; and (b) one or more substituted .alpha.-olefins having the formula (B) ##STR2## wherein R.sup.1 is a hydrogen atom or a methyl group, R.sup.2 is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, and Z is an --OH, --COOH, ##STR3## in which R.sup.3 is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, and each of R.sup.4 and R.sup.5 is a C.sub.1 -C.sub.4 alkyl group, said copolymers having from 1 to 50% by weight of the monomers of formula (B) incorporated therein in polymerized form and a melt flow index (MSI 230/5) of from 2 to 20 g/10 min. and a process for their manufacture.
摘要翻译：（a）一种或多种具有式（A）的α-烯烃的共聚物（A）其中R是C 1 -C 16烷基或苯基; 和（b）一种或多种具有式（B）的取代的α-烯烃（B）其中R1是氢原子或甲基，R2是氢原子或C1-C4烷基，Z是其中R 3是氢原子或C 1 -C 4烷基，R 4和R 5各自是C 1 -C 4烷基的-OH，-COOH，＆lt; IMAGE＆gt;所述共聚物具有1至50重量％其中以聚合形式掺入的式（B）单体和2至20g / 10min的熔体流动指数（MSI 230/5）。及其制造工艺。

7. 发明授权

US4369291A Polyene/.alpha.-olefin copolymers 失效
标题翻译：聚烯烃/α-烯烃共聚物
公开(公告)号：US4369291A
公开(公告)日：1983-01-18
申请号：US289389
申请日：1981-08-03
申请人： Klaus-Peter Arlt , Ulrich Grigo , Rudolf Binsack
发明人： Klaus-Peter Arlt , Ulrich Grigo , Rudolf Binsack
IPC分类号： C08F4/00 , C08F4/60 , C08F279/00 , C08F279/02 , C08F297/00 , C08F297/06
CPC分类号： C08F297/06 , C08F279/02
摘要： Copolymers or graft copolymers of from 5 to 95% by weight of .alpha.-olefins corresponding to the following general formula (A): ##STR1## wherein R.sup.1 represents alkyl having from 1 to 16 carbon atoms or phenyl; and from 5 to 95% by weight of straight-chain, branch-chain or crosslinked 1,4-polyenes, and a process for the preparation of such polymers, wherein one or more .alpha.-olefins (A) are reacted with a solid catalytic complex based on TiCl.sub.3 and aluminum compounds corresponding to the following general formula (C):Al R.sup.2.sub.n X.sub.3-n (C)wherein R.sup.2 represents C.sub.1 -C.sub.18 alkyl; X represents halogen, preferably chlorine; and 0
摘要翻译：对应于下列通式（A）的5至95重量％的α-烯烃的共聚物或接枝共聚物：其中R 1表示具有1至16个碳原子的烷基或苯基; 和5至95重量％的直链，支链或交联的1,4-多烯，以及制备这种聚合物的方法，其中一种或多种α-烯烃（A）与固体催化剂基于TiCl 3和对应于以下通式（C）的铝化合物：Al R2nX3-n（C）其中R2表示C1-C18烷基; X表示卤素，优选氯; 和0

8. 发明授权

US4686262A Thermoplastic block copolyesters, a process for the preparation thereof and their use for the production of mouldings 失效
标题翻译：热塑性嵌段共聚酯，其制备方法及其用于生产模制品的用途
公开(公告)号：US4686262A
公开(公告)日：1987-08-11
申请号：US330766
申请日：1981-12-14
申请人： Rudolf Binsack , Karl-Heinz Kohler , Ulrich Grigo , Leo Morbitzer , Ludwig Bottenbruch , Walter Heitz
发明人： Rudolf Binsack , Karl-Heinz Kohler , Ulrich Grigo , Leo Morbitzer , Ludwig Bottenbruch , Walter Heitz
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181 , C08G81/02
CPC分类号： C08G63/00 , C08G63/18
摘要： Block copolyesters based on polyalkylene terephthalates which contain polydiene blocks show an extremely low deformation even when they are processed into thin articles. They still have a crystallinity which is decreased by less than the ratio corresponding to the polydiene portion.
摘要翻译：基于含有聚二烯嵌段的聚对苯二甲酸亚烷基酯的嵌段共聚酯即使在加工成薄制品时也显示极低的变形。它们的结晶度仍然低于对应于聚二烯部分的比例。

9. 发明授权

US4370450A Process for the production of polar-modified polypropylene and its use 失效
标题翻译：生产极性改性聚丙烯的方法及其用途
公开(公告)号：US4370450A
公开(公告)日：1983-01-25
申请号：US266949
申请日：1981-05-26
申请人： Ulrich Grigo , Josef Merten , Rudolf Binsack
发明人： Ulrich Grigo , Josef Merten , Rudolf Binsack
IPC分类号： C08F220/00 , C08F2/18 , C08F30/00 , C08F30/08 , C08F220/04 , C08F255/00 , C08F255/02 , C08L23/12
CPC分类号： C08F255/02 , C08L23/12 , C08K7/14 , C08L51/06
摘要： A process for the production of modified polypropylene particles by polymerizing vinyl monomers in aqueous suspension wherein (a) an aqueous suspension is prepared which, based on 100 to 2000 parts by weight of water, contains 100 parts by weight of polypropylene particles, 4 to 30 parts by weight of a polar vinyl monomer and based on 100 parts by weight of the monomer, 0.1 to 10 parts by weight of a radical chain polymerization initiator which has a half life of at least 2 h at a temperature of 80.degree. to 135.degree. C. and 10 to 1200 parts by weight of an organic solvent which is capable of swelling polypropylene, of which the boiling point at 760 Torr is at least 100.degree. C. and which is miscible with the monomers in any proportion; (b) the aqueous suspension is heated without decomposition of the initiator, the polypropylene being swollen and the monomer penetrating into the polypropylene, after which (c) the aqueous suspension is kept at temperatures of .gtoreq.85.degree. C. until polymerization of the monomer has ceased. The modified polypropylene is used to improve the mechanical properties of unmodified, optionally glass-fibre-reinforced polypropylene.
摘要翻译：一种通过在水性悬浮液中聚合乙烯基单体生产改性聚丙烯颗粒的方法，其中（a）制备水性悬浮液，其基于100至2000重量份的水，包含100重量份的聚丙烯颗粒，4至30 重量份的极性乙烯基单体，基于100份单体，0.1至10份重量的自由基链聚合引发剂，其在80至135℃的温度下具有至少2小时的半衰期和10〜1200重量份能够溶胀聚丙烯的有机溶剂，其沸点在760乇至少为100℃，并且可与任何比例的单体混溶; （b）水性悬浮液加热而不分解引发剂，聚丙烯溶胀，单体渗透到聚丙烯中，然后（c）将水悬浮液保持在≥85℃的温度，直到单体已停止。改性聚丙烯用于改善未改性的任选的玻璃纤维增强聚丙烯的机械性能。

10. 发明授权

US4210579A Thermoplastic mixtures of polypropylene with ethylene/vinyl acetate and ethylene/propylene copolymers 失效
标题翻译：聚丙烯与乙烯/乙酸乙烯酯和乙烯/丙烯共聚物的热塑性混合物
公开(公告)号：US4210579A
公开(公告)日：1980-07-01
申请号：US19448
申请日：1979-03-12
申请人： Ulrich Grigo , Josef Merten , Rudolf Binsack , Erhard Tresper
发明人： Ulrich Grigo , Josef Merten , Rudolf Binsack , Erhard Tresper
IPC分类号： C08L23/00 , C08L7/00 , C08L21/00 , C08L23/08 , C08L23/12 , C08L23/16 , C08L23/22 , C08L31/04 , C08L101/00 , C08L45/00 , C08L53/00
CPC分类号： C08L23/12 , C08L2205/03 , C08L23/0815 , C08L23/0853 , C08L23/16 , C08L31/04
摘要： A thermoplastic mixture comprising (A) from 2 to 40% by weight of a partially crystalline ethylene/propylene copolymer or terpolymer having an ethylene content of from 70 to 90% by weight and an endothermic heat of fusion of from 6 to 18 cal/g, (B) from 30 to 93% by weight of a crystalline polypropylene, and (C) from 5 to 30% by weight of a copolymer of ethylene and vinyl acetate containing from 20 to 70% by weight of vinyl acetate, the percentages being based on the sum of (A)+(B)+(C).
摘要翻译：一种热塑性混合物，其包含（A）2至40重量％的部分结晶的乙烯/丙烯共聚物或三元共聚物，其乙烯含量为70至90重量％，熔融吸热热为6至18卡/克，（B）30〜93重量％的结晶聚丙烯，（C）5〜30重量％的含有20〜70重量％乙酸乙烯酯的乙烯和乙酸乙烯酯的共聚物，其百分比为基于（A）+（B）+（C）的总和。

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