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1. 发明授权

US4083793A Washing compositions containing aluminosilicates and nonionics and method of washing textiles 失效
标题翻译：含有硅铝酸盐和非离子表面活性剂的洗涤组合物和洗涤纺织品的方法
公开(公告)号：US4083793A
公开(公告)日：1978-04-11
申请号：US723728
申请日：1976-09-16
申请人： Gunter Jakobi , Peter Krings , Milan Johann Schwuger , Heinz Smolka
发明人： Gunter Jakobi , Peter Krings , Milan Johann Schwuger , Heinz Smolka
IPC分类号： C11D1/83 , C11D3/08 , C11D3/12 , B01J1/04 , C11D1/825 , C11D1/831
CPC分类号： C11D3/08 , C11D1/8305 , C11D3/1286
摘要： A method of washing soiled textiles, wherein the soiled textiles are immersed in an aqueous liquor which contains at least one compound inhibiting alkaline earth metal ion precipitation on said soiled textiles and surface-active compounds comprising using finely-dispersed, water-insoluble silicate compounds having a calcium-binding power of at least 50 mg CaO/gm of anhydrous active substance and having the formula, combined water not shown(M.sub.2/n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is a member selected from aluminum and boron and y is a number of from 0.8 to 6, as said compound inhibiting alkaline earth metal ion precipitation, together with surface-active compounds including non-ionic surface-active compounds being constituted by a mixture of compounds of different degrees of ethoxylation where one of the ethoxylated compounds has 8 to 20 ethylene oxide units and the other has from 2 to 6 ethylene oxide units; as well as washing compositions containing said silicate compounds and said surface-active compounds.
摘要翻译：一种洗涤污染织物的方法，其中将污染的纺织品浸入含有至少一种抑制碱土金属离子沉淀的化合物的水性液体中，所述化合物在所述污染的纺织品和表面活性化合物上包括使用细分散的水不溶性硅酸盐化合物，具有至少50mg CaO / gm无水活性物质并具有下式的组合水（M2 / nO）x的钙结合力。 Me2O3。（SiO 2）y其中M是价数为n的阳离子，可与钙交换，x为0.7至1.5的数，Me为选自铝和硼的成员，y为0.8至6的数，如所述化合物抑制碱土金属离子沉淀，以及包括非离子表面活性化合物在内的表面活性化合物由不同程度乙氧基化的化合物的混合物构成，其中一种乙氧基化合物具有8至20个环氧乙烷单元，另一种具有2至6个环氧乙烷单元; 以及含有所述硅酸盐化合物和所述表面活性化合物的洗涤组合物。

2. 发明授权

US4071377A Method of mechanical dishwashing and compositions 失效
标题翻译：机械洗碗和组合物的方法
公开(公告)号：US4071377A
公开(公告)日：1978-01-31
申请号：US458333
申请日：1974-04-05
申请人： Milan Johann Schwuger , Heinz Smolka , Theodor Altenschopfer , Manfred Rostek
发明人： Milan Johann Schwuger , Heinz Smolka , Theodor Altenschopfer , Manfred Rostek
IPC分类号： C11D7/60 , A47L15/44 , C11D3/00 , C11D3/02 , C11D3/08 , C11D3/10 , C11D3/12 , A47L15/00 , C02B1/44 , C11D3/60
CPC分类号： C11D3/128 , C11D1/72 , C11D11/0023 , C11D3/044 , C11D3/08 , C11D3/10 , C11D3/3955 , Y10S423/24
摘要： A method for the mechanical washing of dishes, wherein the soiled dishes are treated with an aqueous alkaline liquor having a pH of from 8 to 13 which contains at least one compound inhibiting alkaline earth metal ion precipitation, rinsing and recovering cleaned dishes comprising using finely-dispersed, water-insoluble silicate compounds having a calcium-binding power of at least 50 mg CaO/gm of anhydrous substance and having the formula, combined water not shown, of(M.sub.2/n O).sub.x .multidot. Me.sub.2 O.sub.3 .multidot. (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is a member selected from aluminum and boron and y is a number of from 0.8 to 6, as said compound inhibiting alkaline earth metal ion precipitation as well as alkaline-reacting mechanical dish washing compositions containing said silicate compounds.
摘要翻译：一种用于机械洗涤餐具的方法，其中用含有至少一种抑制碱土金属离子沉淀的化合物的pH为8至13的碱性水溶液处理污染的菜肴，冲洗并回收清洁的菜肴，（M2 / nO）xxMe2O3 x（SiO2）y WHERE M为（M2 / nO）xxMe2O3 x（SiO2）y的组合水，分散的水不溶性硅酸盐化合物，其钙结合能力为至少50mg CaO / gm无水物质，化合价n的阳离子可与钙交换，x为0.7〜1.5，Me为选自铝和硼的成员，y为0.8〜6的数，作为所述抑制碱土金属离子析出的化合物以及含有所述硅酸盐化合物的碱性反应机械洗碗组合物。

3. 发明授权

US4092261A Process for the production of powdery washing and cleansing agent compositions 失效
标题翻译：生产粉状洗涤剂和清洁剂组合物的方法
公开(公告)号：US4092261A
公开(公告)日：1978-05-30
申请号：US620386
申请日：1975-10-07
申请人： Gerhard Sperling , Dieter Jung , Klaus Hachmann , Milan Johann Schwuger , Heinz Smolka
发明人： Gerhard Sperling , Dieter Jung , Klaus Hachmann , Milan Johann Schwuger , Heinz Smolka
IPC分类号： C11D1/02 , C11D1/66 , C11D1/72 , C11D1/88 , C11D3/00 , C11D3/12 , C11D10/04 , C11D11/00 , C02B1/44 , C11D9/18 , C11D11/02
CPC分类号： C11D11/0082 , C11D10/04 , C11D3/128 , C11D1/02 , C11D1/66 , C11D1/72 , C11D1/88
摘要： An improvement in the process for the production of powdery washing and cleansing agent compositions containing finely-divided water-insoluble silicate compounds, capable of binding calcium, soap, and, optionally, other surface-active compounds, builders and other customary detergent additives by spray-drying a slurry and recovering said powdery washing and cleansing agent composition which comprises separately spray-drying a slurry rich in said silicate compounds and combining the spray-dried powders with the remaining ingredients in powdery form; as well as the powdery washing and cleansing agents so produced.
摘要翻译：生产含有精细分散的水不溶性硅酸盐化合物的粉末洗涤和清洁剂组合物的方法的改进，其能够通过喷雾结合钙，皂和任选的其它表面活性化合物，助洗剂和其它常规洗涤剂添加剂干燥浆料并回收所述粉末洗涤和清洁剂组合物，其包括分别喷雾富含所述硅酸盐化合物的浆料并将喷雾干燥的粉末与粉末形式的其余成分组合; 以及如此生产的粉末洗涤和清洁剂。

4. 发明授权

US3962116A Compositions of optical brightness and aluminosilicates and methods of their production 失效
标题翻译：光学亮度和铝酸盐的组成及其生产方法
公开(公告)号：US3962116A
公开(公告)日：1976-06-08
申请号：US541208
申请日：1975-01-15
申请人： Helmut Bloching , Heinz Smolka , Milan Johann Schwuger
发明人： Helmut Bloching , Heinz Smolka , Milan Johann Schwuger
IPC分类号： D06L3/12 , C09K11/30
CPC分类号： D06L3/1264
摘要： Heat dried, finely-divided compositions of optical brighteners and fillers comprising as said fillers at least partly of a finely-divided water-insoluble silicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis(M.sub.2 /.sub.n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a member of from 0.7 to 1.5, Me is a member selected from the group consisting of aluminum and boron, and y is a number from 0.8 to 6, preferably from 1.3 to 4, in an amount of at least 5% by weight of the mixture, as well as a process for producing the same comprising the steps of mixing said silicate compound, while at least still moist from its production, with said optical brighteners and converting the entire mixture of components into a pourable product.
摘要翻译： 1499902荧光增白剂和填充剂DEUTSCHE GOLD - UND SILBER-SCHEIDEAN雪松和HENKEL＆CIE GmbH 1975年1月16日[1974年1月17日] 1869/75标题D1P干粉状组合物含有荧光增白剂和细分（最大粒径0.1mm）具有至少50mg CaO / g无水硅酸盐（= AS）的钙结合能力和通式的水不溶性铝 - 或硼硅酸盐; 其中Cat表示可与钙交换的阳离子和n价的x，x表示0.7至1.5的数，M表示硼或铝，y表示0.8至6的数。可交换阳离子可以是氢，锂，钾，铵或镁或水溶性有机碱的阳离子，但优选为钠。增白剂对棉，聚酰胺或聚酯可能是实质的，并且可以是二氨基芪二磺酸，二芳基吡唑啉喹诺酮，1,2-二（2-苯并恶唑基） - 或1,2-二 - （2-苯甲酰亚氨基唑基） - 乙烯，苯并恶唑基噻吩，香豆素或曲辛二烯二苯基衍生物。组合物可以通过热干燥形成。通过单一喷雾或辊子，组分的浆料。在改性中，形成硅酸盐，例如，通过将铝酸钠和硅酸钠混合在水性悬浮液中，在光亮剂存在下，其在干燥时由硅酸盐涂覆。因此可以形成空心珠。硅酸盐可以是无定形或微晶的。其他水溶性或细分散的水不溶性惰性物质也可能存在。

5. 发明授权

US3954642A Impregnated textile fibrous structures for cleaning purposes 失效
标题翻译：浸渍纺织纤维结构用于清洁目的
公开(公告)号：US3954642A
公开(公告)日：1976-05-04
申请号：US418725
申请日：1973-11-23
申请人： Milan Johann Schwuger
发明人： Milan Johann Schwuger
IPC分类号： A47L13/17 , C11D17/04 , C11D17/00
CPC分类号： C11D17/049 , A47L13/17
摘要： The invention relates to textile fibrous structures suitable for cleaning purposes and impregnated with surface-active agents, in which the textile fibrous structures are built up from water-insoluble high polymers with a content of carboxyl groups able to form salts, which are present substantially as free carboxyl groups, and the impregnation consists of at least one non-ionic surface-active agent from the group of water-soluble alkylene oxide derivatives, the turbidity or cloud point of which lies above 20.degree.C, as well as the method of production.
摘要翻译：本发明涉及适用于清洁目的并用表面活性剂浸渍的纺织纤维结构，其中织物纤维结构由具有能形成盐的羧基含量的水不溶性高聚物构成，其基本上以游离羧基，并且浸渍由至少一种来自水溶性烯化氧衍生物的非离子表面活性剂组成，其浊度或浊点在20℃以上，以及生产方法。

6. 发明授权

US4118189A Method of washing textiles 失效
标题翻译：纺织品洗涤方法
公开(公告)号：US4118189A
公开(公告)日：1978-10-03
申请号：US700864
申请日：1976-06-29
申请人： Elmar Reinwald , Milan Johann Schwuger
发明人： Elmar Reinwald , Milan Johann Schwuger
IPC分类号： C11D11/00 , D06F35/00 , D06L1/12 , B08B3/00
CPC分类号： C11D3/0094 , C11D11/0017 , C11D11/0058 , D06F35/006 , D06L1/12
摘要： An improved method for washing textiles comprising contacting soiled textiles with a foamed detergent solution, said solution containing from 10 to 5o gm per liter of a cleaning composition containing at least some non-ionic surface-active compounds, and being employed in a liquor ratio of 1:1 to 1:5, said detergent solution being foamed by air to a liter weight of 5 to 30 gm before contacting said soiled textiles, agitating said soiled textiles in the presence of said foamed detergent solution for at least 30 seconds, spinning off said foamed detergent solution under sufficient force to break said foam, and to extract said detergent solution, repeating the above steps at least five times, then rinsing said textiles and recovering cleaned textiles.
摘要翻译：一种用于洗涤纺织品的改进方法，包括使污染的纺织品与泡沫洗涤剂溶液接触，所述溶液含有10至5gm /升含有至少一些非离子表面活性化合物的清洁组合物，并且以比例 1：1至1：5，所述洗涤剂溶液在接触所述污染的纺织品之前通过空气发泡至5至30gm的升重量，在所述泡沫洗涤剂溶液存在下搅拌所述污染的纺织品至少30秒，所述泡沫洗涤剂溶液在足够的力下破坏所述泡沫，并提取所述洗涤剂溶液，重复上述步骤至少五次，然后冲洗所述纺织品并回收清洁的纺织品。

7. 发明授权

US3956155A Textile fibrous cleaning structures 失效
标题翻译：纺织纤维清洁结构
公开(公告)号：US3956155A
公开(公告)日：1976-05-11
申请号：US418689
申请日：1973-11-23
申请人： Milan Johann Schwuger
发明人： Milan Johann Schwuger
IPC分类号： A47L13/17 , C11D17/04 , C11D17/00
CPC分类号： A47L13/17 , C11D17/049
摘要： The invention relates to textile fibrous structures impregnated with nonionic surface active agents and suitable for cleaning purposes, in which the textile fibrous structures are built up from water-insoluble high polymers with a content of carboxyl groups, which are mostly present in the form of the alkali metal salts or ammonium salts or as salts of organic ammonium bases, and the impregnation comprises at least one nonionic surface-active agent from the group of the alkylene oxide derivatives, the turbidity or cloud point of which lies below 80.degree.C, as well as the method of preparation.
摘要翻译：本发明涉及浸渍有非离子表面活性剂并适用于清洁目的的纺织纤维结构，其中织物纤维结构由具有羧基含量的水不溶性高聚物构成，其主要以碱金属盐或铵盐或有机铵碱的盐，并且浸渍包括至少一种来自环境氧化物衍生物的组合物的非离子表面活性剂，其浊度或浊点低于80℃，以及作为制备方法。

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