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1. 发明授权

US4329148A Dye mixtures, and their use in dyeing polyesters 失效
标题翻译：染料混合物及其在染色聚酯中的应用
公开(公告)号：US4329148A
公开(公告)日：1982-05-11
申请号：US222926
申请日：1981-01-06
申请人： Guenter Hansen , Wolf-Dieter Kermer , Jochen-Wilfried Stuck
发明人： Guenter Hansen , Wolf-Dieter Kermer , Jochen-Wilfried Stuck
IPC分类号： C09B29/08 , C09B67/22 , C09B27/00 , C09B45/48 , D06P1/18
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0823 , C09B29/0828
摘要： Dye mixtures, containing dyes of the formula I ##STR1## where X is hydrogen, chlorine or bromine,R.sup.1 is hydrogen, methoxy, ethoxy or phenoxy,R.sup.2 is hydrogen, methyl, ethyl, n-propyl or iso-propyl andR is ##STR2## where R.sup.3 is allyl, methallyl, crotonyl, prenyl or benzyl,R.sup.4 is C.sub.1 -C.sub.5 -alkyl, allyl, methallyl, crotonyl, prenyl or benzyl andR.sup.4 is C.sub.1 -C.sub.5 -alkyl,the mixtures containing not less than 60% of dyes wherein R is ##STR3## or NHC.sub.2 H.sub.4 CN, from 0 to 40% of one or more dyes wherein R is ##STR4## and from 0 to 40% of one or more dyes wherein R is ##STR5## the two last-mentioned components accounting for not less than 5% of the mixture.The mixtures are exceptionally useful for dyeing polyesters.
摘要翻译：含有式I的染料的染料混合物，其中X是氢，氯或溴，R1是氢，甲氧基，乙氧基或苯氧基，R2是氢，甲基，乙基，正丙基或异丙基，R是其中R 3是烯丙基，甲代烯丙基，巴豆基，异戊烯基或苄基，R 4是C 1 -C 5 - 烷基，烯丙基，甲代烯丙基，巴豆基，异戊烯基或苄基，R 4是C 1 -C 5烷基，所述混合物含有不少于60％的染料，其中R是或NHC 2 H 4 CN，0至40％的一种或多种染料，其中R是一种或多种染料，其中R是两个最后提到的组分占不少于5％的混合物。该混合物特别适用于染色聚酯。

2. 发明授权

US4041025A P-Aminoazo disperse dyes 失效
标题翻译： P-氨基偶氮分散染料
公开(公告)号：US4041025A
公开(公告)日：1977-08-09
申请号：US612352
申请日：1975-09-11
申请人： Karl Maier , Guenter Hansen , Wolf-Dieter Kermer
发明人： Karl Maier , Guenter Hansen , Wolf-Dieter Kermer
IPC分类号： C09B29/08 , C09B31/043 , C09B43/22 , C09B29/26 , D06P3/54
CPC分类号： C09B29/08 , C09B29/0813 , C09B31/043 , C09B43/22
摘要： Disperse dyes of the formula ##STR1## in which D is the radical of a diazo component, Y is a linear or branched, unsubstituted or substituted alkylene of one to four carbon atoms;R.sup.1 is hydrogen, optionally substituted linear or branched alkyl of one to four carbon atoms, optionally substituted cycloalkyl or aralkyl, phenyl, or a radical of the formula: ##STR2## and R.sup.2 is hydrogen or C.sub.1 to C.sub.6 alkyl which may bear chloro, bromo or cyano as a substituent; andD and the rings A and B may bear one or more further substituents other than --SO.sub.3 H and --COOH;and also to their productions and their use for dyeing water-repellent fibrous materials. The dyes are eminently suitable for dyeing hydrophobic fibers, particularly polyesters, in yellow to blue-green shades of excellent fastness properties.
摘要翻译：其中D为重氮组分的基团的分子式为“IMAGE”的分散体，Y为1-4个碳原子的直链或支链，未取代或取代的亚烷基; R 1是氢，任选取代的具有1-4个碳原子的直链或支链烷基，任选取代的环烷基或芳烷基，苯基或下式的基团：其中R 2是氢或C 1 -C 6烷基，其可以带有氯，溴或氰基作为取代基; D和环A和B可以具有一个或多个除-SO 3 H和-COOH之外的其它取代基; 以及它们的生产和用于染色防水纤维材料的用途。该染料特别适用于染色疏水性纤维，特别是聚酯，黄色至蓝绿色的色牢度优良。

3. 发明授权

US4405330A Navy disperse dye mixtures 失效
标题翻译：海军分散染料混合物
公开(公告)号：US4405330A
公开(公告)日：1983-09-20
申请号：US433393
申请日：1982-10-08
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
IPC分类号： C09B29/08 , C09B67/22 , D06P3/54 , D06P1/04
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0813 , Y10S534/01 , Y10S8/922
摘要： Navy mixtures which contain dyes of the formula I ##STR1## where X is chlorine or bromine,Y is hydrogen, methoxy or ethoxy andR is N(C.sub.2 H.sub.5).sub.2, N(CH.sub.2 CH.dbd.CH.sub.2).sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2,the mixtures being composed of 10-70% of dyes with Y.dbd.H and R=N(C.sub.2 H.sub.5).sub.2, 5-40% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R.dbd.N(CH.sub.2 --CH.dbd.CH.sub.2).sub.2 and 5-80% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R=N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2.The novel mixtures have excellent tinctorial properties and give very fast dyeings on synthetic polyesters.
摘要翻译：含有式I的染料的海军混合物，其中X是氯或溴，Y是氢，甲氧基或乙氧基，R是N（C2H5）2，N（CH2CH = CH2）2或N（C2H4OCOCH3）2，该混合物由10-70％的具有Y = H和R = N（C 2 H 5）2的染料组成，5-40％的具有Y = OCH 3或OC 2 H 5和R = N（CH 2 -CH 2 CH 2）2和5 -80％的具有Y = OCH 3或OC 2 H 5和R = N（C 2 H 4 OCOCH 3）的染料。新型混合物具有优异的着色性能，并在合成聚酯上产生非常快的染色。

4. 发明授权

US4221711A Brown to violet substituted phenyl-substituted anilino azo dyes 失效
标题翻译：棕色至紫色取代的苯基取代的苯胺基偶氮染料
公开(公告)号：US4221711A
公开(公告)日：1980-09-09
申请号：US913365
申请日：1978-06-07
申请人： Norbert Grund , Guenter Hansen , Wolf-Dieter Kermer
发明人： Norbert Grund , Guenter Hansen , Wolf-Dieter Kermer
IPC分类号： C09B29/085 , C09B29/08 , D06P1/16 , C09B29/26 , D06P1/18 , D06P3/54
CPC分类号： C09B29/0813 , C09B29/08
摘要： Brown to violet azo dyes of the general formula ##STR1## where X and Y are chlorine or bromine, R.sup.1 is hydrogen, methyl, ethyl, chlorine, methoxy or ethoxy, R.sup.2 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy, C.sub.1-4 alkanoylamino, benzoylamino or alkoxycarbonylamino, where alkoxy is of 1 to 4 carbon atoms, and the radicals R.sup.3 are identical or different, unsubstituted or substituted aliphatic, cycloaliphatic or aromatic radicals. The dyes may be used for dyeing synthetic fibers, especially polyesters, and give very fast dyeings.
摘要翻译：棕色至通式为“IMAGE”的紫色偶氮染料，其中X和Y为氯或溴，R1为氢，甲基，乙基，氯，甲氧基或乙氧基，R2为氢，氯，溴，甲基，乙基，甲氧基，乙氧基，C 1-4烷酰基氨基，苯甲酰基氨基或烷氧基羰基氨基，其中烷氧基具有1至4个碳原子，并且基团R 3相同或不同，未取代或取代的脂族，脂环族或芳族基团。这些染料可用于染色合成纤维，特别是聚酯，并给予非常快的染色。

5. 发明授权

US4167394A Uniformly dyed water-swellable cellulosic fibers 失效
标题翻译：均匀染色的水溶胀纤维素纤维
公开(公告)号：US4167394A
公开(公告)日：1979-09-11
申请号：US868213
申请日：1978-01-09
申请人： Johannes Dehnert , Guenter Hansen , Hermann Kaack , Wolf-Dieter Kermer , Walter Kurtz , Ernst Schaffner
发明人： Johannes Dehnert , Guenter Hansen , Hermann Kaack , Wolf-Dieter Kermer , Walter Kurtz , Ernst Schaffner
IPC分类号： C09B29/01 , C09B29/36 , D06P3/60 , D06P3/82 , C09B29/38 , D06M1/00 , D06P1/04
CPC分类号： C09B29/0011 , C09B29/36 , D06P3/6041 , D06P3/8233
摘要： Uniformly dyed water-swellable cellulosic fibers obtained by dyeing cellulosic fibers, in the swollen state, with a dye of the formula ##STR1## where X is hydrogen, chlorine, bromine, cyano, nitro, alkylsulfonyl of 1 to 4 carbon atoms, phenylsulfonyl, methoxy or ethoxy, Y is hydrogen, chlorine, bromine, cyano or nitro, Z is a radical of the formula ##STR2## Q is oxygen or sulfur, R.sup.1 is alkyl of 1 to 4 carbon atoms, methoxymethyl, phenoxymethyl or phenyl which is unsubstituted or substituted by chlorine, bromine, nitro, methyl, methoxy or ethoxy, R.sup.2 is hydrogen, methyl, ethyl, phenyl or phenyl substituted by chlorine, bromine or methyl, R.sup.3 is hydrogen, methyl or, if R.sup.2 is methyl, is C.sub.1 to C.sub.4 alkoxycarbonyl, R.sup.2 and R.sup.3 together with the linking carbon atoms are phenylene or phenylene substituted by chlorine, methyl, methoxy or ethoxy and K is a radical of a coupling component selected from the pyrazolone, pyrazole, indole, quinolone or homophthalimide series.
摘要翻译：通过染色纤维素纤维获得的均匀染色的水溶胀性纤维素纤维，其呈溶胀状态，其中X为氢，氯，溴，氰基，硝基，1至4个碳原子的烷基磺酰基，苯基磺酰基，甲氧基或乙氧基，Y是氢，氯，溴，氰基或硝基，Z是下式的基团Q是氧或硫，R1是1至4个碳原子的烷基，甲氧基甲基，苯氧基甲基或苯基，其是未取代的或被氯，溴，硝基，甲基，甲氧基或乙氧基取代，R 2为氢，甲基，乙基，苯基或被氯，溴或甲基取代的苯基，R 3为氢，甲基或如果R 2为甲基，则为C 1至C 4 烷氧基羰基，R2和R3与连接碳原子一起被亚甲基或亚苯取代，被氯，甲基，甲氧基或乙氧基取代，K是选自吡唑啉酮，吡唑，吲哚，喹诺酮或高邻苯二甲酰亚胺系列的偶联成分的基团。

6. 发明授权

US4083684A Uniformly dyed water-swellable cellulosic fibers 失效
标题翻译：均匀染色的水溶胀纤维素纤维
公开(公告)号：US4083684A
公开(公告)日：1978-04-11
申请号：US770095
申请日：1977-02-18
申请人： Guenter Hansen , Hermann Kaack , Wolf-Dieter Kermer , Guenter Meyer
发明人： Guenter Hansen , Hermann Kaack , Wolf-Dieter Kermer , Guenter Meyer
IPC分类号： C09B29/08 , C09B31/04 , D06P3/60 , C09B27/00 , D06P1/02
CPC分类号： C09B29/08 , C09B29/0807 , C09B31/04 , D06P3/6041 , Y10S8/918
摘要： Uniformly dyed water-swellable cellulosic fibers obtained by dyeing cellulosic fibers in the swollen state with a dye of the formula ##STR1## in which D is the radical of a diazo component;R.sup.1 and R.sup.2 are optionally substituted alkyl and one of them may also be cyclohexyl, phenyl, methoxyphenyl or ethoxyphenyl and X is hydrogen, chloro, methyl or acylamino, the molecule containing in the radicals R.sup.1, R.sup.2 and X at least one group: --CO--R.sup.3 --Y--Ar where R.sup.3 is C.sub.1 to C.sub.3 alkylene; ##STR2## Y is oxygen, sulfur or R.sup.4 is hydrogen or C.sub.1 to C.sub.4 alkyl; andAr is phenyl or phenyl bearing chloro, bromo, methyl, methoxy, ethoxy, C.sub.1 to C.sub.4 alkoxycarbonyl or cyano as a substituent.
摘要翻译：通过用式“IMAGE”染料染色纤维素纤维而获得的均匀染色的水溶胀性纤维素纤维，其中D是重氮组分的基团; R1和R2是任选取代的烷基，其中一个也可以是环己基，苯基，甲氧基苯基或乙氧基苯基，X是氢，氯，甲基或酰基氨基，分子中含有R1，R2和X中至少一个基团-CO R 3 -Y-Ar，其中R 3是C 1至C 3亚烷基; Y是氧，硫或R4是氢或C1-C4烷基; 并且Ar是苯基或苯基，其带有氯，溴，甲基，甲氧基，乙氧基，C1-C4烷氧基羰基或氰基作为取代基。

7. 发明授权

US4465628A Azo dyes comprising a heterocyclic diazo component 失效
标题翻译：包含杂环重氮组分的偶氮染料
公开(公告)号：US4465628A
公开(公告)日：1984-08-14
申请号：US92182
申请日：1979-11-07
申请人： Norbert Grund , Guenter Hansen , Wolf-Dieter Kermer
发明人： Norbert Grund , Guenter Hansen , Wolf-Dieter Kermer
IPC分类号： C09B29/09 , C09B29/00 , C09B29/08 , C09B29/039 , C09B29/045 , D06P3/54
CPC分类号： C09B29/0081 , C09B29/0813
摘要： An azo dye comprising a heterocyclic diazo component, of the general formula ##STR1## where D is a radical of the formula ##STR2## Y is nitro, chlorine or bromine, Z is hydrogen, chlorine, bromine, cyano or nitro,R.sup.1 is C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, cyano, C.sub.1 -C.sub.4 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoylamino, C.sub.1 -C.sub.4 -alkylaminocarbonyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, chlorine, phenyl and/or phenoxy, or is cyclohexyl, propargyl or C.sub.3 -C.sub.5 -alkenyl, or is a radical of the formula(A-O).sub.n -R.sup.2,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl or, if n>1, may also be hydrogen,R.sup.3 is C.sub.1 -C.sub.8 -alkyl, which may be substituted by phenyl or phenoxy,R.sup.4 is hydrogen, methyl, ethyl, methoxy, ethoxy or phenoxy,X is oxygen or a direct bond,A is --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 --, ##STR3## and n is 1, 2 or 3.The dyes of the formula I are very suitable for dyeing synthetic textile materials, especially polyesters.
摘要翻译：包含通式为I的杂环重氮组分的偶氮染料，其中D是下式的基团Y是硝基，氯或溴，Z是氢，氯，溴，氰基或硝基，R 1是未取代或被羟基，C 1 -C 4 - 烷氧基，氰基，C 1 -C 4 - 烷酰氧基，C 1 -C 4 - 烷氧基羰基，C 1 -C 4 - 烷酰基氨基，C 1 -C 4烷基氨基羰基氧基，C 1 -C 4 - 烷氧基羰基氧基，或苯基和/或苯氧基，或为环己基，炔丙基或C3-C5-烯基，或为式（AO）n-R2，R2为C1-C4-烷基，苯基或（如果n≥1）可以是氢，R 3是可被苯基或苯氧基取代的C 1 -C 8 - 烷基，R 4是氢，甲基，乙基，甲氧基，乙氧基或苯氧基，X是氧或直接键，A是-CH 2 CH 2 - ，-CH 2 CH 2 CH 2 - ，和n是1,2或3.式I的染料非常适合于染色合成纺织品材料，特别是聚酯。

8. 发明授权

US4389216A Navy dye mixtures 失效
标题翻译：海军染料混合物
公开(公告)号：US4389216A
公开(公告)日：1983-06-21
申请号：US355309
申请日：1982-03-05
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
IPC分类号： C09B67/20 , C09B29/08 , C09B67/22 , D06P3/52
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0813 , C09B29/0825 , Y10S534/01 , Y10S8/922
摘要： Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## in the following amounts, based on the total weight of the mixture:______________________________________ X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 39-49%, X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 1-10%, X = Br R.sup.1 = H R.sup.2 = CH.sub.2 CHCH.sub.2 4-16%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 15-25%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 4-9%, and X = Cl ##STR2## R.sup.2 = H 4-10%. ______________________________________ The novel mixtures are very useful for dyeing synthetic polyesters.
摘要翻译：基于混合物的总重量含有以下量的通式I的化合物作为必要成分的海军染料混合物：-X = Br R1 = C2H4CN R2 = CH2CHCH2 39-49％， - X = Br R1 = C2H4CN R2 = H 1-10％，-X = Br R1 = H R2 = CH2CHCH2 4-16％，-X = C1 R1 = C2H4CN R2 = H 15-25％，-X = Cl R1 = C 2 H 4 CN R 2 = CH 2 CHCH 2 4-9％， - 和 - -X = Cl

9. 发明授权

US4386934A Navy dye mixtures 失效
标题翻译：海军染料混合物
公开(公告)号：US4386934A
公开(公告)日：1983-06-07
申请号：US370904
申请日：1982-04-22
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
IPC分类号： C09B29/08 , C09B67/22 , D06P1/18 , D06P3/54 , C09B29/00
CPC分类号： C09B67/0051 , C09B29/0813 , C09B29/0825 , D06P1/18 , Y10S534/01 , Y10S8/922
摘要： Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## where X is chlorine or bromine, Y is methoxy or ethoxy, and R is ##STR2## NHC.sub.2 H.sub.4 CN, NHCH.sub.2 CH.dbd.CH.sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2, and wherein the dye of the above formula where X is Br, Y is OCH.sub.3 or OC.sub.2 H.sub.5 and R is N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2 is present in an amount of 25-45%, based on the total weight of the mixture, are very useful for dyeing synthetic polyesters.
摘要翻译：含有作为必要组分的通式I的化合物的海军染料混合物，其中X是氯或溴，Y是甲氧基或乙氧基，R是NHC2H4CN，NHCH2CH = CH2或N（C2H4OCOCH3）2 并且其中X为Br，Y为OCH 3或OC 2 H 5且R为N（C 2 H 4 OCOCH 3）2的上式的染料的含量相对于混合物的总重量为25-45％，非常有用用于染色合成聚酯。

10. 发明授权

US4321055A Navy dye mixtures and their use in dyeing polyesters 失效
标题翻译：海军染料混合物及其在染色聚酯中的应用
公开(公告)号：US4321055A
公开(公告)日：1982-03-23
申请号：US222923
申请日：1981-01-06
申请人： Guenter Hansen , Wolf-Dieter Kermer , Hans J. Kolbinger
发明人： Guenter Hansen , Wolf-Dieter Kermer , Hans J. Kolbinger
IPC分类号： C09B29/08 , C09B67/22 , C09B29/00
CPC分类号： C09B67/0051 , C09B29/0813 , C09B29/0823 , Y10S534/01
摘要： Dye mixtures containing dyes of the formula I ##STR1## where X is hydrogen, chlorine or bromine,R.sup.1 is hydrogen, methoxy, ethoxy or phenoxy,R.sup.2 is hydrogen, methyl, ethyl, n-propyl or i-propyl andR is ##STR2## where R.sup.3 is C.sub.1 -C.sub.5 -alkyl, allyl, methallyl, crotonyl, prenyl or benzyl,R.sup.4 is unsubstituted or phenyl- or phenoxy-substituted straight-chain or branched C.sub.1 -C.sub.8 -alkyl which may be interrupted by 1, 2 or 3 0 atoms, or is C.sub.3 -C.sub.5 -alkenyl, unsubstituted or chlorine-, bromine-, C.sub.1 -C.sub.4 -alkyl- or C.sub.1 -C.sub.4 -alkoxy-substituted phenyl or benzyl,the mixtures containing not less than 40% of dyeswherein R is ##STR3## or NHC.sub.2 H.sub.4 CN, from 0 to 20% of one or more dyes wherein R is ##STR4## and from 10 to 60% of one or more dyes wherein R is ##STR5##
摘要翻译：含有式I的染料的染料混合物，其中X是氢，氯或溴，R1是氢，甲氧基，乙氧基或苯氧基，R2是氢，甲基，乙基，正丙基或异丙基，R是< 其中R 3是C 1 -C 5 - 烷基，烯丙基，甲代烯丙基，巴豆基，异戊烯基或苄基，R 4是未取代的或苯基或苯氧基取代的直链或支链C 1 -C 8 - 烷基，其可被1,2或或者是C3-C5-烯基，未取代的或氯 - ，溴 - ，C1-C4-烷基 - 或C1-C4-烷氧基取代的苯基或苄基，所述混合物含有不少于40％的染料，其中R 是一种或多种染料的0至20％，其中R是“IMAGE”，或10至60％的一种或多种染料，其中R是或NHC2H4CN，

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