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1. 发明授权

US5372731A Composition and process for the finishing of textiles 失效
标题翻译：纺织品整理的组成和工艺
公开(公告)号：US5372731A
公开(公告)日：1994-12-13
申请号：US25488
申请日：1993-03-03
申请人： Gisbert Michels , Hans-Albert Ehlert , Hans-Josef Laas , Joachim Probst , Helmut Reiff , Rolf-Volker Meyer
发明人： Gisbert Michels , Hans-Albert Ehlert , Hans-Josef Laas , Joachim Probst , Helmut Reiff , Rolf-Volker Meyer
IPC分类号： C08G18/54 , C08G18/62 , C08G18/70 , C08G18/79 , D06M13/02 , D06M13/322 , D06M13/395 , D06M15/277 , D06M15/53 , D06M15/568 , D06M15/576 , D06M11/58 , D06M11/67 , D06M11/73
CPC分类号： D06M15/576 , C08G18/544 , C08G18/6279 , C08G18/706 , C08G18/792 , D06M15/277 , D06M15/53 , D06M15/568
摘要： Textiles can be finished in a wash- and cleaning-resistant manner by impregnation if aqueous dispersions are employed for this purpose which contain reactive copolymers and/or cocondensates having perfluoroalkyl groups and water-dispersible polyisocyanate mixtures whose NCO groups are not blocked.
摘要翻译：如果使用水性分散体用于含有具有全氟烷基的反应性共聚物和/或共缩合物和其NCO基团不被阻断的水分散性多异氰酸酯混合物，纺织品可以通过浸渍以完全洗涤和清洁方式完成。

2. 发明授权

US5739249A Chlorine-free multifunctional resins for paper finishing 失效
标题翻译：无氯多功能树脂，用于纸张整理
公开(公告)号：US5739249A
公开(公告)日：1998-04-14
申请号：US512612
申请日：1995-08-08
申请人： Jurgen Reiners , Hans-Josef Laas , Joachim Konig , Helmut Reiff , Joachim Probst , Bruno Bomer , Reinhard Halpaap , Fritz Puchner , Harro Traubel
发明人： Jurgen Reiners , Hans-Josef Laas , Joachim Konig , Helmut Reiff , Joachim Probst , Bruno Bomer , Reinhard Halpaap , Fritz Puchner , Harro Traubel
IPC分类号： C09D175/08 , C08G18/00 , C08G18/70 , C08G18/80 , D21H17/07 , D21H17/08 , D21H17/53 , D21H19/00 , D21H19/24 , D21H21/18 , D21H21/20
CPC分类号： D21H17/07 , C08G18/706 , C08G18/807 , D21H17/08 , D21H17/53 , D21H21/18 , D21H21/20
摘要： The invention relates to a new process for the preparation of cellulose-containing material provided with a dry-strength and wet-strength finish and/or sized, characterised in that the cellulose-containing material is treated with a water-dispersible polyisocyanate mixture (I), which contains tertiary amino and/or ammonium groups, optionally polyether units and optionally hydrophobic groups.
摘要翻译：本发明涉及一种制备含有干强度和湿强度和/或尺寸的含纤维素材料的新方法，其特征在于含纤维素材料用水分散性多异氰酸酯混合物（I ），其含有叔氨基和/或铵基团，任选的聚醚单元和任选的疏水基团。

3. 发明授权

US5503714A Chlorine-free multifunctional resins for paper finishing 失效
标题翻译：无氯多功能树脂，用于纸张整理
公开(公告)号：US5503714A
公开(公告)日：1996-04-02
申请号：US100024
申请日：1993-07-30
申请人： Jurgen Reiners , Hans-Josef Laas , Joachim Konig , Helmut Reiff , Joachim Probst , Bruno Bomer , Reinhard Halpaap , Fritz Puchner , Harro Traubel
发明人： Jurgen Reiners , Hans-Josef Laas , Joachim Konig , Helmut Reiff , Joachim Probst , Bruno Bomer , Reinhard Halpaap , Fritz Puchner , Harro Traubel
IPC分类号： C09D175/08 , C08G18/00 , C08G18/70 , C08G18/80 , D21H17/07 , D21H17/08 , D21H17/53 , D21H19/00 , D21H19/24 , D21H21/18 , D21H21/20
CPC分类号： D21H17/07 , C08G18/706 , C08G18/807 , D21H17/08 , D21H17/53 , D21H21/18 , D21H21/20
摘要： The invention relates to a new process for the preparation of cellulose-containing material provided with a dry-strength and wet-strength finish and/or sized, characterized in that the cellulose-containing material is treated with a water-dispersible polyisocyanate mixture (I), which contains tertiary amino and/or ammonium groups, optionally polyether units and optionally hydrophobic groups.
摘要翻译：本发明涉及一种制备含有干强度和湿强度和/或尺寸的含纤维素材料的新方法，其特征在于含纤维素材料用水分散性多异氰酸酯混合物（I ），其含有叔氨基和/或铵基团，任选的聚醚单元和任选的疏水基团。

4. 发明授权

US06583215B2 Aqueous 2-component PU systems 失效
公开(公告)号：US06583215B2
公开(公告)日：2003-06-24
申请号：US09944447
申请日：2001-08-30
申请人： Joachim Probst , Erhard Lühmann , Horst Clemens , Wolfgang Kremer , Jürgen Meixner , Hans-Josef Laas
发明人： Joachim Probst , Erhard Lühmann , Horst Clemens , Wolfgang Kremer , Jürgen Meixner , Hans-Josef Laas
IPC分类号： C08J300
CPC分类号： B01D47/00 , B08B3/024 , B08B3/026 , B08B2203/0229 , B44D3/16 , C08G18/4063 , C08G18/6254 , C08G18/706 , C09D175/04 , E04G23/00 , Y10T428/31551
摘要： The invention relates to an aqueous 2-component polyurethane (PU) coating composition comprising a vinyl polymer polyol dispersion, having a hydroxyl number between 10 and 264 mg KOH/g solid resin, an acid value (calculated from the sum of neutralized and non-neutralized acid groups) between 0 and 55 mg KOH/g solid resin, a number-average molecular weight Mn of at least 5000 g/mol and a weight average molecular weight Mw of at least 30,000 g/mol, a glass transition temperature of at least 20° C. and an average particle diameter of no greater than 300 nm, which is prepared in the presence of 0.1 to 10.0 wt. %, relative to the sum of the solids contents of polymer polyol and polyisocyanate, of a non-ionic polyether surfactant and a polyisocyanate having a viscosity at 23° C. of no more than 12,000 mPa*s and either a non-hydrophilic or a non-ionically or anionically hydrophilic character, whereby the equivalent ratio of isocyanate groups of component b) to hydroxyl groups of component a) is 0.2:1 to 5:1; a process for the preparation of such aqueous 2-component coating compositions, and their use as 2-component PU paints for painting any type of substrate.

5. 发明授权

US06376602B1 Coating compositions, a process for their production and their use for coating water-resistant substrates 失效
标题翻译：涂料组合物，其制备方法及其用于涂覆耐水基材的用途
公开(公告)号：US06376602B1
公开(公告)日：2002-04-23
申请号：US08432560
申请日：1995-05-01
申请人： Joachim Probst , Werner Kubitza , Rolf Roschu , Hans Josef Laas
发明人： Joachim Probst , Werner Kubitza , Rolf Roschu , Hans Josef Laas
IPC分类号： C08J300
CPC分类号： C08G18/6245 , C08G18/0819 , C08G18/283 , C08G18/6229 , C08G18/706 , C08G18/8064
摘要： The present invention relates to water-borne coating compositions wherein the binder contains a mixture of a) a polyol component dispersed in water or a water/solvent mixture which contains at least one polymer prepared from olefinically unsaturated monomers and having a molecular weight (Mn) of at least 500, at least two alcoholic hydroxyl groups per molecule, a hydroxyl value of 15 to 250 mg KOH/g, an acid value of 0 to 7 mg KOH/g and a total content of sulfonate and carboxylate groups of 0 to 4.5 milliquivalents per 100 g of solid resin and b) a polyisocyanate component which is emulsified in the dispersion of polyol component a), has a viscosity at 23° C. of 50 to 10,000 mPa.s and an average NCO functionality of 1.8 to 4.2, and contains 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups and, optionally, 2 to 20% by weight of ethylene oxide units present within polyether chains, the polyether chains containing a statistical average of 5 to 70 ethylene oxide units, wherein the components are present in quantities corresponding to an equivalent ratio of isocyanate groups of component b) to alcoholic hydroxyl groups of component a) of 0.2:1 to 5:1. The present invention also relates to a process for the production of these coating compositions and to coated water-resistant substrates prepared from these coating compositions.
摘要翻译：本发明涉及水性涂料组合物，其中粘合剂含有分散在水中的多元醇组分或含有至少一种由烯属不饱和单体制备的聚合物的水/溶剂混合物的混合物，其分子量（Mn）为每分子至少500个，至少两个醇羟基，羟基值为15-250mg KOH / g，酸值为0-7mg KOH / g，磺酸盐和羧酸酯基团的总含量为0-4.5毫克每100g固体树脂和b）在多元醇组分a）的分散体中乳化的多异氰酸酯组分，其在23℃下的粘度为50至10,000mPa.s，平均NCO官能度为1.8至4.2，并且包含 12.0至21.5重量％的（环）脂族结合的异氰酸酯基团和任选地2至20重量％存在于聚醚链内的环氧乙烷单元，所述聚醚链含有5-70个环氧乙烷单元的统计平均值其中组分以对应于组分b）的异氰酸酯基团与组分a）的醇羟基的当量比为0.2:1至5:1存在。本发明还涉及制备这些涂料组合物的方法和由这些涂料组合物制备的涂覆的耐水基材。

6. 发明授权

US6130285A Binder composition and its use for coating metallic and mineral substrates 失效
标题翻译：粘合剂组合物及其用于涂覆金属和矿物基材的用途
公开(公告)号：US6130285A
公开(公告)日：2000-10-10
申请号：US911510
申请日：1997-08-14
申请人： Martin Melchiors , Jurgen Schwindt , Gerhard Ruttmann , Wieland Hovestadt , Joachim Probst , Josef Pedain
发明人： Martin Melchiors , Jurgen Schwindt , Gerhard Ruttmann , Wieland Hovestadt , Joachim Probst , Josef Pedain
IPC分类号： C08G18/62 , C08G18/40 , C08G18/63 , C09D175/04 , C08L75/00
CPC分类号： C08G18/632 , C08G18/4063 , C08G18/638 , C08G2150/90
摘要： The present invention relates to a solvent-free, low viscosity binder composition which contains, in amounts sufficient to provide an NCO:OH equivalent ratio of 0.5:1 to 2.0:1,A) a polyisocyanate component containing one or more organic polyisocyanates andB) a solvent-free polyhydroxy component having a hydroxyl group content of 3.0 to 18 wt. % and a viscosity at 23.degree. C. of 200 to 10,000 mPa.s, which containsB.sub.1) a hydroxy-functional polyacrylate component which is prepared by polymerizing a mixture of olefinically unsaturated monomers in which at least one monomer is hydroxy-functional in the presence ofB.sub.2) a compound containing ether groups and having one or more hydroxy groups.The invention also relates to the use of this binder composition in solvent-free two-component polyurethane coating compositions for coating metallic or mineral substrates.
摘要翻译：本发明涉及无溶剂的低粘度粘合剂组合物，其含量足以提供0.5：1至2.0：1的NCO:OH当量比，A）含有一种或多种有机多异氰酸酯和B ）无羟基含量为3.0-18重量％的无溶剂多羟基组分％，在23℃下的粘度为200至10,000mPa.s，其含有B1）羟基官能的聚丙烯酸酯组分，其通过聚合烯属不饱和单体的混合物而制备，其中至少一种单体在存在B2）含有醚基并具有一个或多个羟基的化合物。本发明还涉及这种粘合剂组合物在无溶剂双组分聚氨酯涂料组合物中用于涂覆金属或矿物基材的用途。

7. 发明授权

US5468804A Water-soluble or water-dispersible polyisocyanate composition, a process for its preparation and its use in coating compositions 失效
标题翻译：水溶性或水分散性多异氰酸酯组合物，其制备方法及其在涂料组合物中的应用
公开(公告)号：US5468804A
公开(公告)日：1995-11-21
申请号：US306335
申请日：1994-09-15
申请人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
发明人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/10 , C08G18/28 , C08G18/32 , C08G18/48 , C08G18/62 , C08G18/70 , C08G18/76 , C08G18/80 , C09D175/00 , C09D175/04 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/283 , C08G18/706 , C08G18/8035 , C08G18/8064 , Y10T428/31551
摘要： A water-dispersible polyisocyanate composition obtained by the partial urethanization of the isocyanate groups of 2,4- and/or 2,6-diisocyanatotoluene with monohydric and polyhydric alcohols, a process for its production, its use as the binder for an aqueous two-component coating composition in combination with a water-soluble or water-dispersible polyhydroxyl component and coatings for water-resistant sheet-form substrates prepared from this coating composition.
摘要翻译：通过2,4-和/或2,6-二异氰酸基甲苯与一元醇和多元醇的异氰酸酯基团的部分氨基甲酸酯化获得的水分散性多异氰酸酯组合物，其生产方法，其用作二级和多元醇的粘合剂，组合涂料组合物与水溶性或水分散性多羟基组分的组合以及由该涂料组合物制备的用于防水片状基材的涂料。

8. 发明授权

US4997873A Copolymers containing perfluoroalkyl groups 失效
标题翻译：含全氟烷基的共聚物
公开(公告)号：US4997873A
公开(公告)日：1991-03-05
申请号：US355727
申请日：1989-05-22
申请人： Carlhans Suling , Jutta Rottger , Henning Bachem , Joachim Probst , Wilfried Kortmann
发明人： Carlhans Suling , Jutta Rottger , Henning Bachem , Joachim Probst , Wilfried Kortmann
IPC分类号： B01F17/52 , C08F2/16 , C08F2/22 , C08F2/28 , C08F20/34 , C08F20/52 , C08F212/00 , C08F212/08 , C08F220/24 , C08F220/34 , C08F220/60 , C08F265/00 , C08F267/06 , D06M13/02 , D06M13/07 , D06M13/224 , D06M13/236 , D06M13/322 , D06M13/402 , D06M13/41 , D06M15/277 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34
CPC分类号： C08F220/24 , C08F265/00 , D06M15/277
摘要： Aqueous dispersions of copolymers and graft copolymers which are formed from ethylenically unsaturated perfluoroalkyl monomers and ethylenically unsaturated monomers from from perfluoroalkyl groups and which are prepared in the presence of emulsifiers containing cationic groups are used for imparting a water-repellent and oleo-repellent finish to textiles, leather and paper.
摘要翻译：由烯属不饱和全氟烷基单体和烯属不饱和单体由全氟烷基形成并且在含有阳离子基团的乳化剂存在下制备的共聚物和接枝共聚物的水分散体用于赋予纺织品拒水拒油，皮革和纸张。

9. 发明授权

US4806591A Cationic sizing agents for paper 失效
标题翻译：阳离子上胶剂纸
公开(公告)号：US4806591A
公开(公告)日：1989-02-21
申请号：US921173
申请日：1986-10-20
申请人： Joachim Probst , Heinz Baumgen , Bruno Bomer , Joachim Konig , Renke Mottweiler
发明人： Joachim Probst , Heinz Baumgen , Bruno Bomer , Joachim Konig , Renke Mottweiler
IPC分类号： C08F2/28 , C08F2/24 , C08F257/02 , D21H17/35 , D21H17/37 , D21H17/45 , C08L33/20
CPC分类号： D21H17/455 , C08F2/24 , C08F257/02 , D21H17/35 , D21H17/37
摘要： Cationic sizing agents for paper, obtainable by a process in which a water-soluble cationic terpolymer compound, built up in a chemically uniform manner, of (a) 7 to 40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate, (b) 40 to 80% by weight of styrene and (c) 4 to 50% by weight of acrylonitrile, the sum of components (a) to (c) always being 100% by weight and at least 10% of the dimethylamino groups of the terpolymer being quaternized with monoepoxides, with the exception of epihalogenohydrins, and the remainder being protonated, is dissolved in an aqueous medium and, in the presence of 10 to 70% by weight--based on the following monomer mixture--of this emulsifier, (d) 5 to 95% by weight of acrylonitrile, meth-acrylonitrile or styrene or mixtures thereof and (e) 5 to 95% by weight of acrylic acid ester and/or methacrylic acid ester with 1 to 12 C atoms in the alcohol radical--the sum of components (d) and (e) always being 100% by weight--are emulsified and the emulsion thus obtained is subjected to emulsion polymerization, initiated by free radicals, at temperatures of 20.degree. to 150.degree. C.
摘要翻译：可通过以下方法获得的阳离子上胶剂：其中以（a）7〜40重量％的N，N-二甲基氨基乙基丙烯酸酯和/或甲基丙烯酸酯组成的以化学均匀的方式构成的水溶性阳离子三元共聚物，（b）40至80重量％的苯乙烯和（c）4至50重量％的丙烯腈，组分（a）至（c）的总和总是100重量％，并且至少10重量％的二甲基氨基的三元共聚物被单过氧化物季铵化，除了表卤代醇，其余的被质子化，溶解在水性介质中，并且在该乳化剂的基于下列单体混合物的10至70重量％的存在下，（d）5至95重量％的丙烯腈，甲基丙烯腈或苯乙烯或其混合物，和（e）5至95重量％的醇基中具有1至12个C原子的丙烯酸酯和/或甲基丙烯酸酯组分（d）和（e）总是为100重量％的总和被乳化和乳液由此获得的乳液聚合在20℃至150℃的温度下由自由基引发。

10. 发明授权

US4165431A Chlorination of polyolefins in the presence of complex formers 失效
标题翻译：在复合成型剂存在下氯化聚烯烃
公开(公告)号：US4165431A
公开(公告)日：1979-08-21
申请号：US881675
申请日：1978-02-27
申请人： Franz Alfes , Diez Heine , Reinhard Kaiser , Gunter Kolb , Joachim Probst , Franz Weider
发明人： Franz Alfes , Diez Heine , Reinhard Kaiser , Gunter Kolb , Joachim Probst , Franz Weider
IPC分类号： C08F8/00 , C08F8/20 , C08F8/22
CPC分类号： C08F8/22
摘要： A chlorinated colorless polyolefin, preferably a chlorinated colorless isotactic polypropylene, soluble in carbon tetrachloride and having a chlorine content of from 60% to 70% by weight and an average degree of polymerization of from 2000 to 6000, produced by chlorinating polyolefins having a degree of polymerization of from 2000 to 20,000 in suspension or solution or in suspension and solution at 40 to 60.degree. C. in the presence of a halogen transfer agent, a chlorination catalyst and from 0.2 to 0.5% by weight, based on polyolefin, of at least one compound corresponding to the general Formula (I):h.sub.2 n--r--nh>.sub.n H (I)in which R represents the ethylene, propylene or butylene group and n=1-6.
摘要翻译：氯化无色聚烯烃，优选氯化无色全同立构聚丙烯，其可溶于四氯化碳，氯含量为60〜70重量％，平均聚合度为2000〜6000，通过氯化具有一定程度的聚烯烃在卤素转移剂，氯化催化剂和基于聚烯烃的0.2至0.5重量％的存在下，在悬浮液或溶液中或悬浮液和溶液中在40至60℃下聚合2000至20,000，至少对应于通式（I）的一种化合物：

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