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1. 发明授权

US4396552A Novel metal mercaptides of esters of .beta.-mercaptoalkanols 失效
标题翻译： β-巯基烷醇的酯的新型金属硫醇盐
公开(公告)号：US4396552A
公开(公告)日：1983-08-02
申请号：US229201
申请日：1981-01-28
申请人： Gerrit Knobloch , Wolfgang Wehner , Hermann O. Wirth
发明人： Gerrit Knobloch , Wolfgang Wehner , Hermann O. Wirth
IPC分类号： C10M139/06 , C07C67/00 , C07C313/00 , C07C323/12 , C07F3/00 , C07F7/00 , C07F7/22 , C08K5/37 , C09K15/32 , C10M135/24 , C10N10/04 , C10N10/08 , C10N10/10 , C10N30/08 , C10N30/10 , C08H3/00
CPC分类号： C10M135/24 , C07F3/003 , C07F7/006 , C07F7/2268 , C09K15/326 , C10M2219/084 , C10M2227/06 , C10M2227/065 , C10M2227/083
摘要： Metal mercaptides of the formula ##STR1## wherein Me is a metal, oxometal, alkoxymetal or organo-metal cation from the 1st-5th group of the periodic system, n is 0, 1 or 2, m is an integer from 1 to 4, R.sup.1 is hydrogen, alkyl, acyloxymethyl or alkoxymethyl, R.sup.2 is a sterically hindered phenol group, and R.sup.3 is a monovalent organic radical, are stabilizers for organic materials which are sensitive to heat and oxygen. They can be used in particular as stabilizers for chlorine-containing thermoplasts, for elastomers and for lubricants. Preferred cations are organotin cations.
摘要翻译：其中Me是周期系的第1〜5组的金属，氧化金属，烷氧基金属或有机金属阳离子，n为0,1或2，m为整数 1至4，R1为氢，烷基，酰氧基甲基或烷氧基甲基，R2为空间位阻酚基，R3为单价有机基团，是对热和氧敏感的有机材料的稳定剂。它们可以特别用作含氯热塑性塑料的稳定剂，用于弹性体和润滑剂。优选的阳离子是有机锡阳离子。

2. 发明授权

US07947831B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07947831B2
公开(公告)日：2011-05-24
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C07C317/00 , C07C317/04 , C07C317/06 , C07C317/10 , C07C317/18 , C07C317/44
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined within, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式如上所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性。

3. 发明申请

US20100317778A1 Filled Rubber Compounds with Improved Processability 失效
标题翻译：填充橡胶化合物具有改进的加工性能
公开(公告)号：US20100317778A1
公开(公告)日：2010-12-16
申请号：US11991813
申请日：2006-09-12
申请人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
发明人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
IPC分类号： C08K5/5393 , C08L23/26 , C08K3/22 , C08K5/05 , C08K5/17 , C08K5/52 , C07F7/08 , C07D307/20
CPC分类号： C08K3/36 , C07F7/1804 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
摘要翻译：本发明描述了一种制备具有改进的加工性能的填充橡胶化合物的方法，其包括在一步a）橡胶，b）白色增强填料和c）式（I）的偶联剂中混合，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

4. 发明授权

US06797755B1 Stabilizers and antiozonants for elastomers 失效
标题翻译：用于弹性体的稳定剂和抗臭氧剂
公开(公告)号：US06797755B1
公开(公告)日：2004-09-28
申请号：US10110620
申请日：2002-04-15
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Samuel Evans
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Samuel Evans
IPC分类号： C08L541
CPC分类号： C07C323/25 , C07C317/28 , C07C317/44 , C07C323/52 , C07C2601/14 , C08K5/3725 , C08K5/41 , C08L21/00
摘要： Elastomers which have excellent stability to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation comprise, as stabilizers, at least one compound of the formula (I): [R—S(═O)m—CH2—CH(OH)—CH2]n—N(R1)2−n—R2, in which R is C4-C20alkyl, hydroxyl-substituted C4-C20alkyl; phenyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl, cyclohexyl or —(CH2)qCOOR3, and, if m is 0, R may additionally be (a); and, if n is 1 and R4 is hydrogen, R may additionally be R2—R1N—CH2—CH(OH)—CH2—S(═O)m—(CH2)x— or R2—R1N—CH2—CH(OH)—CH2—S(═O)m—CH2—CH2—(OCH2—CH2)y—, R1 is hydrogen, cyclohexyl or C3-C12alkyl, R2 is (b), R3 is C1-C18alkyl, R4 is hydrogen or —CH2—CH(OH)—CH2—S(═O)m—R, X is C1-C8alkyl, Y is C1-C8alkyl, m is 0 or 1, n is 1 or 2, q is 1 or 2, x is from 2 to 6, and y is 1 or 2. The compounds of the formula (I) are also suitable as stabilizes for elastomers to prevent contact discoloration of substrates coming into contact with elastomers.
摘要翻译：具有优异稳定性以防止氧化，热，动态，光诱导和/或臭氧诱导的降解的弹性体包含作为稳定剂的至少一种式（I）化合物：[RS（= O）m -CH 2 -CH （OH）-CH 2] n N（R 1）2-n R 2，其中R是C 4 -C 20烷基，羟基取代的C 4 -C 20烷基; 苯基，苄基，α-甲基苄基，α，α-二甲基苄基，环己基或 - （CH 2）q COOR 3，如果m为0，则R可另外为（a）。并且如果n为1且R 4为氢，则R可以另外为R 2 -R 1 N-CH 2 -CH（OH）-CH 2 -S（= O）m - （CH 2）x - 或R 2 -R 1 N-CH 2 -CH（OH）-CH 2 -S（= O）m -CH 2 -CH 2 - （OCH 2 -CH 2）y - ，R 1是氢，环己基或C 3 C 12烷基，R 2是（b），R 3是C 1 -C 18烷基，R 4是氢或-CH 2 -CH（OH）-CH 2 -S（= O）m R，X是C 1 -C 8烷基，Y为C1-C8烷基，m为0或1，n为1或2，q为1或2，x为2至6，y为1或2.式（I）化合物也适用稳定弹性体以防止与弹性体接触的基底的接触变色。

5. 发明授权

US06365781B2 Process for the preparation of mercaptomethylphenois 失效
标题翻译：巯基甲基苯酚的制备方法
公开(公告)号：US06365781B2
公开(公告)日：2002-04-02
申请号：US09755369
申请日：2001-01-05
申请人： Fabio Pizzoli , Reto Luisoli , Gerrit Knobloch , Hans-Rudolf Meier
发明人： Fabio Pizzoli , Reto Luisoli , Gerrit Knobloch , Hans-Rudolf Meier
IPC分类号： C07C31900
CPC分类号： C07C319/14 , C08K5/375 , C08L21/00 , C07C323/16
摘要： There is disclosed an improved process for the preparation of a compound of the formula I wherein n is 0 or 1, R1 is C1-C12alkyl or —CH2SR3, R2 is C1-C12alkyl, C7-C9phenylalkyl, C7-C9-phenylalkyl substituted on the phenyl radical by from 1 to 3 C1-C4alkyl groups; or —CH2SR3, R3 is C6-C18alkyl, phenyl or benzyl, R4 is hydrogen or methyl, R5 is hydrogen or methyl, with the proviso that R4 and R5 are not simultaneously methyl, by reacting a compound of the formula II wherein n, R4 and R5 are as previously defined, R11 is hydrogen or C1-C12alkyl; and R12 is hydrogen, C1-C12alkyl, C7-C9phenylalkyl, C7-C9phenylalkyl substituted on the phenyl radical by from 1 to 3 C1-C4alkyl groups; with formaldehyde or a compound that liberates formaldehyde under the reaction conditions and with at least one compound of the formula III R3SH (III) wherein R3 is as previously defined, in the presence of a base, said base being mono- or dimethylamine or mono- or diethylamine, which process comprises treating afterwards the reaction product with a reducing agent.
摘要翻译：公开了一种制备式I化合物的改进方法，其中n为0或1，R1为C1-C12烷基或-CH2SR3，R2为C1-C12烷基，C7-C9苯基烷基，C7-C9-苯基烷基取代苯基由1至3个C 1 -C 4烷基基团; 或-CH 2 S R 3，R 3是C 6 -C 18烷基，苯基或苄基，R 4是氢或甲基，R 5是氢或甲基，条件是R 4和R 5不同时为甲基，通过使式II的化合物在n， R 5如前所定义，R 11为氢或C 1 -C 12烷基; 并且R 12是氢，C 1 -C 12烷基，C 7 -C 9苯基烷基，在苯基上被1至3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基; 与甲醛或在反应条件下释放甲醛的化合物，以及至少一种式III的化合物，其中R 3如前所定义，在碱的存在下，所述碱是单或二甲胺或一或二乙胺，该方法包括用还原剂处理反应产物。

6. 发明授权

US5059661A Phenolic compounds as chain-terminators for the anionic solution polymerization of dienes 失效
标题翻译：酚类化合物作为二烯阴离子溶液聚合的链终止剂
公开(公告)号：US5059661A
公开(公告)日：1991-10-22
申请号：US570498
申请日：1990-08-21
申请人： Gerrit Knobloch
发明人： Gerrit Knobloch
IPC分类号： C09K15/14 , C08C19/44 , C08F2/38 , C08F2/42 , C08F4/48 , C08F36/00 , C08F36/04
CPC分类号： C08C19/44 , C08F36/04
摘要： Compounds of formula I ##STR1## wherein n is 0 to 3, R.sub.1 and R.sub.2 are C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.8 cycloalkyl or --CH.sub.2 SR.sub.3, R.sub.3 is C.sub.1 -C.sub.18 alkyl, phenyl or benzyl, and R.sub.4 is hydrogen or CH.sub.3, are admirably suitable as chain-terminators in the anionic solution polymerisation of 1,3-dienes.
摘要翻译：式I的化合物其中n为0至3，R 1和R 2为C 1 -C 12烷基，C 5 -C 8环烷基或-CH 2 S R 3，R 3为C 1 -C 18烷基，苯基或苄基，且R 4为氢或CH 3， 1,3-二烯阴离子溶液聚合中的链终止剂。

7. 发明授权

US4857572A Substituted phenols as stabilizers 失效
标题翻译：取代酚作为稳定剂
公开(公告)号：US4857572A
公开(公告)日：1989-08-15
申请号：US157116
申请日：1988-02-10
申请人： Hans-Rudolf Meier , Gerrit Knobloch
发明人： Hans-Rudolf Meier , Gerrit Knobloch
IPC分类号： C07C321/18 , C07B31/00 , C07B63/04 , C07C67/00 , C07C313/00 , C07C323/16 , C08K5/13 , C08K5/36 , C08K5/37 , C08K5/375 , C08L21/00 , C08L53/02 , C08L75/00 , C08L75/04 , C09K15/14 , C09K15/28 , C10M135/24 , C10N30/00 , C10N30/10 , C10N40/00 , C10N40/25
CPC分类号： C07C323/00 , C08K5/375 , C10M135/24 , C10M2219/084
摘要： Novel compositions are described which contain an elastomer or a tackifying resin and at least one compound of formula I ##STR1## The symbols R.sub.1 is alkyl or cycloalkyl, R.sub.2 is alkyl, hydroxyalkyl, phenyl or benzyl, and R.sub.3 is hydrogen or methyl with the proviso that, when R.sub.1 is other than methyl, R.sub.3 is methyl.
摘要翻译：描述了包含弹性体或增粘树脂和至少一种式I化合物的新型组合物（I）符号R1是烷基或环烷基，R2是烷基，羟基烷基，苯基或苄基，R3是氢或甲基条件是当R1不是甲基时，R3是甲基。

8. 发明授权

US09309379B2 Basic stabilisation systems for emulsion polymerised rubber 有权
标题翻译：乳液聚合橡胶的基本稳定体系
公开(公告)号：US09309379B2
公开(公告)日：2016-04-12
申请号：US12992099
申请日：2009-05-06
申请人： Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/18 , C08K5/375 , C08L21/00
CPC分类号： C08K5/18 , C08K3/01 , C08K5/0008 , C08K5/375 , C08L21/00
摘要： There are described compositions comprising a) an emulsion crude rubber, synthetic latex or natural rubber latex subject to oxidative, thermal, dynamic and/or light-induced degradation, b) a compound of the formula (I) wherein R1 is C8-C12alkyl, R2 is hydrogen, C1-C12alkyl, cyclohexyl, 1-methylcyclohexyl, benzyl, α-methylbenzyl, α,α-dimethylbenzyl or —CH2—S—R1, R3 is C1-C12alkyl, benzyl, α-methylbenzyl, α,α-dimethylbenzyl or —CH2—S—R1, R4 is hydrogen or methyl, and c) a styrenated diphenylamine of the formula (II).
摘要翻译：描述的组合物包含a）经受氧化，热，动态和/或光诱导降解的乳液粗橡胶，合成胶乳或天然橡胶胶乳，b）式（I）化合物，其中R 1是C 8 -C 12烷基， R2是氢，C1-C12烷基，环己基，1-甲基环己基，苄基，α-甲基苄基，α，α-二甲基苄基或-CH2-S-R1，R3是C1-C12烷基，苄基，α-甲基苄基，α，或-CH 2 -S-R 1，R 4是氢或甲基，和c）式（II）的苯乙烯化二苯胺。

9. 发明申请

US20100130660A1 PROCESSING STABILIZERS FOR RUBBER COMPOUNDING 失效
标题翻译：用于橡胶混合物的加工稳定剂
公开(公告)号：US20100130660A1
公开(公告)日：2010-05-27
申请号：US12531514
申请日：2008-03-10
申请人： Gerrit Knobloch , Eva Peregi , Pierre Rota-Graziosi
发明人： Gerrit Knobloch , Eva Peregi , Pierre Rota-Graziosi
IPC分类号： C08K5/375
CPC分类号： C08K5/103 , C08K5/0016 , C08K5/005 , C08K5/375 , C08L21/00
摘要： The invention describes an improved method for the preparation of rubber compounds which comprises compounding the rubber and the components at 125-200° C. in the presence of an amount of 0.1-2% based on the weight of the rubber of a processing stabilizer of the formula (I) wherein R1 is hydrogen, C1-C20alkyl, styryl, α-methyl-styryl or —CH2—S—R3; or C1-C20alkyl substituted with C2-C20alkenyl, C3-C20alkinyl, C5-C9cycloalkyl, phenyl or tolyl; R2 is C1-C20alkyl or —CH2—S—R3, R3 is C1-C20alkyl; with phenyl, hydroxyl, cyano, formyl, acetyl or —O—CO—R5 substituted C1-C20alkyl; C2-C20alkenyl, C3-C20alkinyl, C5-C9cycloalkyl; or with hydroxyl, phenyl, 4-chloro-phenyl, 2-methoxycarbonylphenyl, p-tolyl, 1,3-benzthiazol-2-yl, —(CHR5)COOR6 or —(CHR5)CONR7R8 substituted C5-C9cycloalkyl; R4 is hydrogen or methyl, R5 is hydrogen or C1-C6alkyl, R6 is C1-C20alkyl; with oxygen or sulfur interrupted C3-C20alkyl; C5-C9cycloalkyl, phenyl, benzyl or tolyl, R7 and R8 are independently of each other hydrogen or C1-C6alkyl, and n is 1 or 2.
摘要翻译：本发明描述了一种用于制备橡胶化合物的改进方法，其包括在125-200℃下，以0.1-2％的量加入橡胶和组分，所述量基于加工稳定剂的橡胶的重量，式（I）其中R1是氢，C1-C20烷基，苯乙烯基，α-甲基苯乙烯基或-CH2-S-R3; 或被C 2 -C 20烯基，C 3 -C 20炔基，C 5 -C 9环烷基，苯基或甲苯基取代的C 1 -C 20烷基; R2是C1-C20烷基或-CH2-S-R3，R3是C1-C20烷基; 苯基，羟基，氰基，甲酰基，乙酰基或-O-CO-R 5取代的C 1 -C 20烷基; C 2 -C 20烯基，C 3 -C 20炔基，C 5 -C 9环烷基; 或羟基，苯基，4-氯 - 苯基，2-甲氧基羰基苯基，对甲苯基，1,3-苯并噻唑-2-基， - （CHR 5）COOR 6或 - （CHR 5）CONR 7 R 8取代的C 5 -C 9环烷基; R4是氢或甲基，R5是氢或C1-C6烷基，R6是C1-C20烷基; 与氧或硫中断C3-C20烷基; C 5 -C 9环烷基，苯基，苄基或甲苯基，R 7和R 8彼此独立地为氢或C 1 -C 6烷基，n为1或2。

10. 发明授权

US07723409B2 Coupling agents between filler and elastomer 有权
标题翻译：填料与弹性体之间的偶联剂
公开(公告)号：US07723409B2
公开(公告)日：2010-05-25
申请号：US10581214
申请日：2004-12-06
申请人： Francesco Fuso , Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Francesco Fuso , Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/548 , C08K9/06
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成的弹性体，b）白色增强填料，和c）作为偶联剂，至少一种式（I）化合物，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

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