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1. 发明申请

US20100317778A1 Filled Rubber Compounds with Improved Processability 失效
标题翻译：填充橡胶化合物具有改进的加工性能
公开(公告)号：US20100317778A1
公开(公告)日：2010-12-16
申请号：US11991813
申请日：2006-09-12
申请人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
发明人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
IPC分类号： C08K5/5393 , C08L23/26 , C08K3/22 , C08K5/05 , C08K5/17 , C08K5/52 , C07F7/08 , C07D307/20
CPC分类号： C08K3/36 , C07F7/1804 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
摘要翻译：本发明描述了一种制备具有改进的加工性能的填充橡胶化合物的方法，其包括在一步a）橡胶，b）白色增强填料和c）式（I）的偶联剂中混合，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

2. 发明授权

US08119710B2 Filled rubber compounds with improved processability 失效
标题翻译：填充橡胶化合物具有改进的加工性能
公开(公告)号：US08119710B2
公开(公告)日：2012-02-21
申请号：US11991813
申请日：2006-09-12
申请人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
发明人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
IPC分类号： C08K5/5393 , C08L23/26
CPC分类号： C08K3/36 , C07F7/1804 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
摘要翻译：本发明描述了一种制备具有改进的加工性能的填充橡胶化合物的方法，其包括在一步a）橡胶，b）白色增强填料和c）式（I）的偶联剂中混合，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

3. 发明授权

US07723409B2 Coupling agents between filler and elastomer 有权
标题翻译：填料与弹性体之间的偶联剂
公开(公告)号：US07723409B2
公开(公告)日：2010-05-25
申请号：US10581214
申请日：2004-12-06
申请人： Francesco Fuso , Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Francesco Fuso , Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/548 , C08K9/06
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成的弹性体，b）白色增强填料，和c）作为偶联剂，至少一种式（I）化合物，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

4. 发明申请

US20090227730A1 Non-Staining Antidegradants for Vulcanized Elastomers 有权
标题翻译：用于硫化弹性体的非染色抗蚀剂
公开(公告)号：US20090227730A1
公开(公告)日：2009-09-10
申请号：US11992925
申请日：2006-10-02
申请人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K11/00 , C08F8/34 , C07C211/53 , C09K15/28
CPC分类号： C07C323/29 , C07C317/28 , C07C317/44 , C07C323/52 , C07C2601/14 , C08K5/005 , C08K5/36 , C08K5/372 , C08K5/3725 , C08K5/42 , C08L21/00
摘要： The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2. The instant invention discloses also novel compounds of the formula (I), new mixtures of compounds of the formula (I) and compositions thereof in elastomers.
摘要翻译：本发明公开了一种防止与弹性体接触的基材的接触变色和稳定弹性体以防止氧化，热，动态，光诱导和/或臭氧引起的降解的方法，其包括加入到弹性体中或应用于这些至少一种其中R 1为C 1 -C 12烷基，R 2为C 1 -C 12烷基或R 1和R 2与它们所连接的碳原子一起形成未取代的或具有C 1 -C 4烷基取代的C 5 -C 12环烷基的式（I）化合物环; R 3是氢或-CH 2 -S（O）m -R 5，R 4和R 5彼此独立地是未取代的或具有氰基取代的C 5 -C 18 - 烷基; C 7 -C 9苯基烷基，未取代或与卤素，羟基，氰基或C 1 -C 4烷基取代的苯基或萘基; 苯并噻唑基或-R6-CO2-R7，R6是C1-C18亚烷基，R7是C1-C18烷基，m是0,1或2.本发明还公开了新的式（I）化合物，式（I）及其组合物。

5. 发明授权

US07799951B2 Non-staining antidegradants for vulcanized elastomers 有权
标题翻译：用于硫化弹性体的非染色抗降解剂
公开(公告)号：US07799951B2
公开(公告)日：2010-09-21
申请号：US11992925
申请日：2006-10-02
申请人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/00 , C08K5/42 , C08K5/372 , C07C317/48 , C07C323/52
CPC分类号： C07C323/29 , C07C317/28 , C07C317/44 , C07C323/52 , C07C2601/14 , C08K5/005 , C08K5/36 , C08K5/372 , C08K5/3725 , C08K5/42 , C08L21/00
摘要： The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2. The instant invention discloses also novel compounds of the formula (I), new mixtures of compounds of the formula (I) and compositions thereof in elastomers.
摘要翻译：本发明公开了一种防止与弹性体接触的基材的接触变色和稳定弹性体以防止氧化，热，动态，光诱导和/或臭氧引起的降解的方法，其包括加入到弹性体中或应用于这些至少一种其中R 1为C 1 -C 12烷基，R 2为C 1 -C 12烷基或R 1和R 2与它们所连接的碳原子一起形成未取代的或具有C 1 -C 4烷基取代的C 5 -C 12环烷基的式（I）化合物环; R 3是氢或-CH 2 -S（O）m -R 5，R 4和R 5彼此独立地是未取代的或具有氰基取代的C 5 -C 18 - 烷基; C 7 -C 9苯基烷基，未取代或与卤素，羟基，氰基或C 1 -C 4烷基取代的苯基或萘基; 苯并噻唑基或-R6-CO2-R7，R6是C1-C18亚烷基，R7是C1-C18烷基，m是0,1或2.本发明还公开了新的式（I）化合物，式（I）及其组合物。

6. 发明授权

US07947831B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07947831B2
公开(公告)日：2011-05-24
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C07C317/00 , C07C317/04 , C07C317/06 , C07C317/10 , C07C317/18 , C07C317/44
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined within, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式如上所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性。

7. 发明授权

US07160955B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07160955B2
公开(公告)日：2007-01-09
申请号：US10473848
申请日：2002-03-26
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C08F8/34
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation [R1—SOmnR—SOp—R2. (I)
摘要翻译：用式I化合物（I）接枝的聚合物，其中通式如权利要求1所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性，公式描述=“在线公式”end =“lead”？> [R＆lt; 1＆lt;＆lt;＆lt;＆lt;＆gt;＆lt; img id =“PRIVATE-USE-CHARACTER-00001” =“6.77mm”wi =“8.47mm”file =“US07160955-20070109-Brketclosest.TIF”alt =“私人使用字符Brketclosest”img-content =“character”img-format =“tif”/> R 2 SO 2 -R 2。（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>

8. 发明申请

US20080287578A1 Coupling Agents Between Filler and Elastomer 有权
标题翻译：填料与弹性体之间的偶联剂
公开(公告)号：US20080287578A1
公开(公告)日：2008-11-20
申请号：US10581214
申请日：2004-12-06
申请人： Francesco Fuso , Michele Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Francesco Fuso , Michele Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/548 , C08K9/06 , C08K5/3462 , C08K5/357
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成的弹性体，b）白色增强填料，和c）作为偶联剂，至少一种式（I）化合物，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

9. 发明授权

US08101679B2 Processing stabilizers for rubber compounding 失效
标题翻译：橡胶复合加工稳定剂
公开(公告)号：US08101679B2
公开(公告)日：2012-01-24
申请号：US12531514
申请日：2008-03-10
申请人： Gerrit Knobloch , Eva Peregi , Pierre Rota-Graziosi
发明人： Gerrit Knobloch , Eva Peregi , Pierre Rota-Graziosi
IPC分类号： C08K5/375 , C08K5/103 , C08L21/00
CPC分类号： C08K5/103 , C08K5/0016 , C08K5/005 , C08K5/375 , C08L21/00
摘要： The invention describes an improved method for the preparation of rubber compounds which comprises compounding the rubber and the components at 125-200° C. in the presence of an amount of 0.1-2% based on the weight of the rubber of a processing stabilizer of the formula (I) wherein R1 is hydrogen, C1-C20alkyl, styryl, α-methyl-styryl or —CH2—S—R3; or C1-C20alkyl substituted with C2-C20alkenyl, C3-C20alkinyl, C5-C9cycloalkyl, phenyl or tolyl; R2 is C1-C20alkyl or —CH2—S—R3, R3 is C1-C20alkyl; with phenyl, hydroxyl, cyano, formyl, acetyl or —O—CO—R5 substituted C1-C20alkyl; C2-C20alkenyl, C3-C20alkinyl, C5-C9cycloalkyl; or with hydroxyl, phenyl, 4-chloro-phenyl, 2-methoxycarbonylphenyl, p-tolyl, 1,3-benzthiazol-2-yl, —(CHR5)COOR6 or —(CHR5)nCONR7R8 substituted C5-C9cycloalkyl; R4 is hydrogen or methyl, R5 is hydrogen or C1-C6alkyl, R6 is C1-C20alkyl; with oxygen or sulfur interrupted C3-C20alkyl; C5-C9cycloalkyl, phenyl, benzyl or tolyl, R7 and R8 are independently of each other hydrogen or C1-C6alkyl, and n is 1 or 2.
摘要翻译：本发明描述了一种用于制备橡胶化合物的改进方法，其包括在125-200℃下，以0.1-2％的量加入橡胶和组分，所述量基于加工稳定剂的橡胶的重量，式（I）其中R1是氢，C1-C20烷基，苯乙烯基，α-甲基苯乙烯基或-CH2-S-R3; 或被C 2 -C 20烯基，C 3 -C 20炔基，C 5 -C 9环烷基，苯基或甲苯基取代的C 1 -C 20烷基; R2是C1-C20烷基或-CH2-S-R3，R3是C1-C20烷基; 苯基，羟基，氰基，甲酰基，乙酰基或-O-CO-R 5取代的C 1 -C 20烷基; C 2 -C 20烯基，C 3 -C 20炔基，C 5 -C 9环烷基; 或具有羟基，苯基，4-氯 - 苯基，2-甲氧基羰基苯基，对甲苯基，1,3-苯并噻唑-2-基， - （CHR 5）COOR 6或 - （CHR 5）nCONR 7 R 8取代的C 5 -C 9环烷基; R4是氢或甲基，R5是氢或C1-C6烷基，R6是C1-C20烷基; 与氧或硫中断C3-C20烷基; C 5 -C 9环烷基，苯基，苄基或甲苯基，R 7和R 8彼此独立地为氢或C 1 -C 6烷基，n为1或2。

10. 发明申请

US20070015870A1 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US20070015870A1
公开(公告)日：2007-01-18
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michele Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michele Gerster
IPC分类号： C08L63/00
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式符号如权利要求1所定义，对氧化，热，动态，光诱导和/或臭氧诱导的降解具有突出的稳定性。

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