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1. 发明授权

US07723409B2 Coupling agents between filler and elastomer 有权
标题翻译：填料与弹性体之间的偶联剂
公开(公告)号：US07723409B2
公开(公告)日：2010-05-25
申请号：US10581214
申请日：2004-12-06
申请人： Francesco Fuso , Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Francesco Fuso , Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/548 , C08K9/06
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成的弹性体，b）白色增强填料，和c）作为偶联剂，至少一种式（I）化合物，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

2. 发明授权

US08119710B2 Filled rubber compounds with improved processability 失效
标题翻译：填充橡胶化合物具有改进的加工性能
公开(公告)号：US08119710B2
公开(公告)日：2012-02-21
申请号：US11991813
申请日：2006-09-12
申请人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
发明人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
IPC分类号： C08K5/5393 , C08L23/26
CPC分类号： C08K3/36 , C07F7/1804 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
摘要翻译：本发明描述了一种制备具有改进的加工性能的填充橡胶化合物的方法，其包括在一步a）橡胶，b）白色增强填料和c）式（I）的偶联剂中混合，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

3. 发明申请

US20100317778A1 Filled Rubber Compounds with Improved Processability 失效
标题翻译：填充橡胶化合物具有改进的加工性能
公开(公告)号：US20100317778A1
公开(公告)日：2010-12-16
申请号：US11991813
申请日：2006-09-12
申请人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
发明人： Michèle Gerster , Gerrit Knobloch , Pierre Rota-Graziosi , Francesco Fuso
IPC分类号： C08K5/5393 , C08L23/26 , C08K3/22 , C08K5/05 , C08K5/17 , C08K5/52 , C07F7/08 , C07D307/20
CPC分类号： C08K3/36 , C07F7/1804 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
摘要翻译：本发明描述了一种制备具有改进的加工性能的填充橡胶化合物的方法，其包括在一步a）橡胶，b）白色增强填料和c）式（I）的偶联剂中混合，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

4. 发明申请

US20090227730A1 Non-Staining Antidegradants for Vulcanized Elastomers 有权
标题翻译：用于硫化弹性体的非染色抗蚀剂
公开(公告)号：US20090227730A1
公开(公告)日：2009-09-10
申请号：US11992925
申请日：2006-10-02
申请人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K11/00 , C08F8/34 , C07C211/53 , C09K15/28
CPC分类号： C07C323/29 , C07C317/28 , C07C317/44 , C07C323/52 , C07C2601/14 , C08K5/005 , C08K5/36 , C08K5/372 , C08K5/3725 , C08K5/42 , C08L21/00
摘要： The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2. The instant invention discloses also novel compounds of the formula (I), new mixtures of compounds of the formula (I) and compositions thereof in elastomers.
摘要翻译：本发明公开了一种防止与弹性体接触的基材的接触变色和稳定弹性体以防止氧化，热，动态，光诱导和/或臭氧引起的降解的方法，其包括加入到弹性体中或应用于这些至少一种其中R 1为C 1 -C 12烷基，R 2为C 1 -C 12烷基或R 1和R 2与它们所连接的碳原子一起形成未取代的或具有C 1 -C 4烷基取代的C 5 -C 12环烷基的式（I）化合物环; R 3是氢或-CH 2 -S（O）m -R 5，R 4和R 5彼此独立地是未取代的或具有氰基取代的C 5 -C 18 - 烷基; C 7 -C 9苯基烷基，未取代或与卤素，羟基，氰基或C 1 -C 4烷基取代的苯基或萘基; 苯并噻唑基或-R6-CO2-R7，R6是C1-C18亚烷基，R7是C1-C18烷基，m是0,1或2.本发明还公开了新的式（I）化合物，式（I）及其组合物。

5. 发明授权

US07799951B2 Non-staining antidegradants for vulcanized elastomers 有权
标题翻译：用于硫化弹性体的非染色抗降解剂
公开(公告)号：US07799951B2
公开(公告)日：2010-09-21
申请号：US11992925
申请日：2006-10-02
申请人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
发明人： Michèle Gerster , Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi
IPC分类号： C08K5/00 , C08K5/42 , C08K5/372 , C07C317/48 , C07C323/52
CPC分类号： C07C323/29 , C07C317/28 , C07C317/44 , C07C323/52 , C07C2601/14 , C08K5/005 , C08K5/36 , C08K5/372 , C08K5/3725 , C08K5/42 , C08L21/00
摘要： The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2. The instant invention discloses also novel compounds of the formula (I), new mixtures of compounds of the formula (I) and compositions thereof in elastomers.
摘要翻译：本发明公开了一种防止与弹性体接触的基材的接触变色和稳定弹性体以防止氧化，热，动态，光诱导和/或臭氧引起的降解的方法，其包括加入到弹性体中或应用于这些至少一种其中R 1为C 1 -C 12烷基，R 2为C 1 -C 12烷基或R 1和R 2与它们所连接的碳原子一起形成未取代的或具有C 1 -C 4烷基取代的C 5 -C 12环烷基的式（I）化合物环; R 3是氢或-CH 2 -S（O）m -R 5，R 4和R 5彼此独立地是未取代的或具有氰基取代的C 5 -C 18 - 烷基; C 7 -C 9苯基烷基，未取代或与卤素，羟基，氰基或C 1 -C 4烷基取代的苯基或萘基; 苯并噻唑基或-R6-CO2-R7，R6是C1-C18亚烷基，R7是C1-C18烷基，m是0,1或2.本发明还公开了新的式（I）化合物，式（I）及其组合物。

6. 发明授权

US07947831B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07947831B2
公开(公告)日：2011-05-24
申请号：US11523441
申请日：2006-09-19
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C07C317/00 , C07C317/04 , C07C317/06 , C07C317/10 , C07C317/18 , C07C317/44
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, wherein the general symbols are as defined within, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I化合物接枝的聚合物，其中通式如上所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性。

7. 发明授权

US07160955B2 Sulfoxides or sulfones grafted onto polymers 失效
标题翻译：接枝到聚合物上的亚砜或砜
公开(公告)号：US07160955B2
公开(公告)日：2007-01-09
申请号：US10473848
申请日：2002-03-26
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Pierre Rota-Graziosi , Samuel Evans , Paul Dubs , Michèle Gerster
IPC分类号： C08F8/34
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1804 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compound of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation [R1—SOmnR—SOp—R2. (I)
摘要翻译：用式I化合物（I）接枝的聚合物，其中通式如权利要求1所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性，公式描述=“在线公式”end =“lead”？> [R＆lt; 1＆lt;＆lt;＆lt;＆lt;＆gt;＆lt; img id =“PRIVATE-USE-CHARACTER-00001” =“6.77mm”wi =“8.47mm”file =“US07160955-20070109-Brketclosest.TIF”alt =“私人使用字符Brketclosest”img-content =“character”img-format =“tif”/> R 2 SO 2 -R 2。（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>

8. 发明授权

US08246859B2 S-perfluoroalkyl substituted hydroxybenzylthioethers and derivatives as surface modifiers 失效
标题翻译： S-全氟烷基取代的羟基苄基硫醚及其衍生物作为表面改性剂
公开(公告)号：US08246859B2
公开(公告)日：2012-08-21
申请号：US12308036
申请日：2007-06-04
申请人： Michèle Gerster , Manuel Mihalic
发明人： Michèle Gerster , Manuel Mihalic
IPC分类号： C09K15/10 , C09K15/12 , C07C317/00 , C07C319/00
CPC分类号： C08K5/42
摘要： The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.
摘要翻译：本发明描述了一种减少有机材料的表面能的方法，例如增加有机材料的防水和防水性和污迹释放，其包括用至少一种式I化合物处理有机材料，其中通式为如权利要求1所定义; 特别是其中基团R 2，R 3或R 4中的至少一个为-CH（R 11）-S（O）p -R 12; R11是氢，未被取代的C 1 -C 8烷基或与C 1 -C 4烷基取代的苯基; R12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或烯基，直链或支链有机基团，p是0,1或2。

9. 发明申请

US20110160357A1 STABILIZATION AND SURFACE MODIFICATION OF ORGANIC MATERIALS 有权
标题翻译：有机材料的稳定和表面改性
公开(公告)号：US20110160357A1
公开(公告)日：2011-06-30
申请号：US12937731
申请日：2009-03-31
申请人： Michèle Gerster , Manuel Mihalic
发明人： Michèle Gerster , Manuel Mihalic
IPC分类号： C08K5/46 , C07D327/06 , C07C321/20 , C08L23/12
CPC分类号： C07D327/06 , C07B63/04 , C07C323/16 , C07C323/52
摘要： Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation and/or are able to reduce the surface energy of organic materials comprise at least one compound of the formula (I) wherein the general symbols are as defined in claim 1.
摘要翻译：具有优异的氧化，热或光诱导降解稳定性和/或能够降低有机材料表面能的有机材料包含至少一种式（I）化合物，其中通式如权利要求1所定义。

10. 发明申请

US20100010135A1 Oligo-and poly-carbonates terminated with silicon containing groups as surface modifiers 有权
标题翻译：用含硅基团作为表面改性剂封端的聚碳酸酯和聚碳酸酯
公开(公告)号：US20100010135A1
公开(公告)日：2010-01-14
申请号：US11921808
申请日：2006-06-07
申请人： Fabien Jean Brand , Archana Kishore Desai , Michèle Gerster , Shrirang Bhikaji Hindalekar , Suhas Dattatraya Sahasrabudhe , Paragkumar Nathalal Thanki , Michael Tinkl , Andrea Preuss , Jürgen Wiethan , Kishor Prabhakar Kumbhar
发明人： Fabien Jean Brand , Archana Kishore Desai , Michèle Gerster , Shrirang Bhikaji Hindalekar , Suhas Dattatraya Sahasrabudhe , Paragkumar Nathalal Thanki , Michael Tinkl , Andrea Preuss , Jürgen Wiethan , Kishor Prabhakar Kumbhar
IPC分类号： C08L83/00 , C08G77/00 , C08K5/05
CPC分类号： C08G64/14 , C08G64/085 , C08G77/448 , C08L67/00 , C08L69/00 , C08L2666/18
摘要： The instant invention relates to new compounds of the formula I wherein the general symbols are as defined in claim 1 and R1 and R2 are each independently of the other a silicon containing group. These new compounds of the formula I are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an “easy to clean”, “self-cleaning” “antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption”, “dirt pickup resistance”, “slip properties” and “hydrophobic surface”; and antiadhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.
摘要翻译：本发明涉及新的式I化合物，其中通式为如权利要求1中所定义，R1和R2各自独立地为含硅基团。这些式I化合物可用作有机材料如聚碳酸酯，聚酯或聚酮或其混合物，共混物或合金的表面能的还原剂。具有这种表面能降低的聚合物具有“易清洁”，“自清洁”，“防污”，“释放”“防泼溅”，“耐油性”，“耐溶剂性”，“耐化学性” 润滑性“，”耐刮擦性“，”低吸湿性“，”吸尘性“，”滑爽性“，”疏水性表面“等。和抗蛋白质和抗微生物（例如细菌，真菌和藻类）的抗粘附性质。

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