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1. 发明授权

US4351960A Production of an isomeric mixture of secondary phosphines 失效
标题翻译：生产次膦的异构体混合物
公开(公告)号：US4351960A
公开(公告)日：1982-09-28
申请号：US190448
申请日：1980-09-24
申请人： Georg Elsner , Hartfrid Vollmer , Gero Heymer
发明人： Georg Elsner , Hartfrid Vollmer , Gero Heymer
IPC分类号： C07F9/50
CPC分类号： C07F9/5018
摘要： The invention relates to a process for making an isomeric mixture of secondary phosphines with the summation formula C.sub.20 H.sub.27 P. To this end, hydrogen phosphide is reacted with dicyclopentadiene in the presence of an agent yielding free radicals. More specifically, hydrogen phosphide and dicyclopentadiene are used in a molar ratio of 1 to at least 2 and the reaction is effected under a pressure of 5 to 90 bars. The mixture is used in the production of flotation aids and as an ingredient of catalytically active transition metal complexes.
摘要翻译：本发明涉及一种制备仲膦与异构体混合物的方法，其中R为总和式C20H27P。为此，在产生自由基的试剂存在下，磷化氢与二环戊二烯反应。更具体地，使用磷化氢和二环戊二烯的摩尔比为1至至少2，反应在5至90巴的压力下进行。该混合物用于生产浮选助剂和作为催化活性过渡金属络合物的成分。

2. 发明授权

US4156697A Production of alkylphosphines 失效
标题翻译：生产烷基膦
公开(公告)号：US4156697A
公开(公告)日：1979-05-29
申请号：US823140
申请日：1977-08-09
申请人： Klaus Hestermann , Hartfrid Vollmer , Gero Heymer , Ernst-Gunther Schlosser
发明人： Klaus Hestermann , Hartfrid Vollmer , Gero Heymer , Ernst-Gunther Schlosser
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines of the general formula:R.sub.n PH.sub.3-n (I)are made. To this end hydrogen phosphide, a primary or a secondary phosphine is reacted with an alkylamine of the general formula:R.sub.n NH.sub.3-n (II)in a molar ratio of 0.1 to 10 mols of the alkylamine of formula II per mol of hydrogen phosphide or primary or secondary phosphine. The reaction is effected at a 150.degree. to 400.degree. C., at atmospheric pressure or a superatmospheric pressure up to 1 atmosphere gauge, and in contact with a catalyst comprising active carbon, copper (II) chromite, or one or more metals of Group Ib or VIII of the Periodic System of the elements. The starting materials are passed through a reaction zone at a rate which permits a contact time between them and the catalyst of 0.1 to 400 seconds.
摘要翻译：具有以下通式的烷基膦：

3. 发明授权

US4163760A Continuous production of organic phosphines 失效
标题翻译：连续生产有机膦
公开(公告)号：US4163760A
公开(公告)日：1979-08-07
申请号：US872250
申请日：1978-01-25
申请人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
发明人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
IPC分类号： C07F9/50 , C07F9/6568 , C07F9/54
CPC分类号： C07F9/5059 , C07F9/65683
摘要： Organic phosphines are produced by reacting an alkylene, cycloalkylene or aralkylene in the presence of a free radical-yielding catalyst. More specifically, a pressure reactor, which is provided in its interior with mixing elements, kept free from oxygen, and subdivided so as to comprise an upper cooling zone and a lower reaction zone, is continuously supplied from above with (a) a solution of the alkylene, cycloalkylene or aralkylene and the catalyst in an inert solvent, and (b) a stoichiometric excess of hydrogen phosphide, the said (a) and (b) reactants being supplied jointly with but separately from one another; the (a) and (b) reactants are mixed in the upper cooling zone of the reactor at about 0.degree. to 35.degree. C. and under a PH.sub.3 -pressure of about 80 to 300 bars; the resulting mixture, which travels downwardly in the reactor, is reacted in the lower reaction zone at about 90.degree. to 190.degree. C., the reactants being allowed to remain in the reactor for a period of time about 13 to 15 times longer than the half life period of the catalyst; the reaction mixture is removed through the bottom portion of the reactor and subjected to distillation so as to separate the organic phosphines.
摘要翻译：有机膦通过在产生自由基的催化剂存在下使亚烷基，亚环烷基或亚芳烷基反应来制备。更具体地，在其内部设置有保持无氧的并且被分为包括上部冷却区和下部反应区的混合元件的压力反应器从上方连续地供给（a）所述（a）和（b）反应物是由彼此共同供应的;（b）化学计量过量的磷酸氢盐，所述（a）和（b）（a）和（b）反应物在反应器的上部冷却区中在约0℃至35℃下混合，并在约80至300巴的PH3压力下混合; 在反应器中向下移动的所得混合物在下部反应区中在约90℃至190℃下反应，使反应物在反应器中保留约13至15倍的时间催化剂的半衰期; 将反应混合物通过反应器的底部除去并进行蒸馏以分离有机膦。

4. 发明授权

US4639331A Process for making pulverulent ammonium polyphosphates stable to hydrolysis 失效
标题翻译：制备粉末状聚磷酸铵稳定水解的方法
公开(公告)号：US4639331A
公开(公告)日：1987-01-27
申请号：US603120
申请日：1984-04-23
申请人： Georg Elsner , Horst Staendeke , Gero Heymer
发明人： Georg Elsner , Horst Staendeke , Gero Heymer
IPC分类号： C08L1/00 , A62D1/00 , C01B25/40 , C08G18/00 , C08K3/32 , C08K9/04 , C08K9/08 , C08K9/10 , C08L75/00 , C08L75/04 , C09K21/02 , C09K21/04 , C09K21/12 , D06M11/00 , D06M11/72 , D06M15/423 , D06M23/12 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D21H17/10 , D21H17/47 , D21H17/51 , D21H17/63 , D21H21/34 , D21H27/00 , C08K3/28 , C09K21/10
CPC分类号： C01B25/405 , C08K3/32 , C08K9/08 , C08K9/10 , C09K21/02 , C09K21/12 , D21H5/0002 , D21H21/34 , Y10S521/907
摘要： The disclosure relates to a process for making a particulate agent stable to hydrolysis based on free-flowing, pulverulent ammonium polyphosphate by treating the ammonium polyphosphate with a thermosetting, artificial resin being water-insoluble when cured. More specifically, the disclosure provides for the ammonium polyphosphate, an aliphatic alcohol as a diluent, and a melamine/formaldehyde-resin or phenol/formaldehyde-resin to be placed in an autoclave and intimately mixed at room temperature; for the mixture to be heated to a temperature of about 80.degree. to about 180.degree. C. and allowed to remain over a period of 15 to 240 minutes at that temperature and under the pressure corresponding to the vapor pressure of the diluent; for the diluent to be separated and for the product so obtained to be dried.
摘要翻译：本公开涉及一种通过在固化时用热固性人造树脂处理水不溶性的方法，通过用聚酰亚胺铵处理聚磷酸铵来制备基于自由流动的多磷酸铵的水解稳定的颗粒剂的方法。更具体地，本公开内容提供了多磷酸铵，脂肪醇作为稀释剂，将三聚氰胺/甲醛树脂或酚/甲醛树脂置于高压釜中并在室温下充分混合; 将混合物加热到约80℃至约180℃的温度，并在该温度和在与稀释剂的蒸汽压力相对应的压力下保持15至240分钟的时间; 用于分离稀释剂和所得产品进行干燥。

5. 发明授权

US4258022A Continuous production of phosphine 失效
标题翻译：连续生产磷化氢
公开(公告)号：US4258022A
公开(公告)日：1981-03-24
申请号：US75001
申请日：1979-09-12
申请人： Georg Elsner , Werner Klose , Christian May , Gero Heymer
发明人： Georg Elsner , Werner Klose , Christian May , Gero Heymer
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： The invention relates to the continuous production of phosphine. To this end, elemental phosphorus is reacted with an aqueous alkali metal hydroxide solution and at least one alcohol, the reactants being used in admixture with 0.01 to 2 weight % of a surfactant, the percentage being based on the alcohol.
摘要翻译：本发明涉及磷化氢的连续生产。为此，元素磷与碱金属氢氧化物水溶液和至少一种醇反应，反应物与0.01至2重量％的表面活性剂混合使用，其百分比基于醇。

6. 发明授权

US4705529A Process for reducing the reactivity and improving the flow behavior of phosphorus pentoxide 失效
标题翻译：减少五氧化二磷的反应活性和改善流动行为的方法
公开(公告)号：US4705529A
公开(公告)日：1987-11-10
申请号：US818719
申请日：1986-01-14
申请人： Gunther Schimmel , Werner Kowalski , Gero Heymer , Reinhard Gradl
发明人： Gunther Schimmel , Werner Kowalski , Gero Heymer , Reinhard Gradl
IPC分类号： C01B25/12
CPC分类号： C01B25/12
摘要： The reactivity of phosphorus pentoxide is reduced and its flow behavior improved. To this end, phosphorus pentoxide in the form of its hexagonal modification is annealed over a period of 0.5 to 8 hours at temperatures of 200.degree. to 390.degree. C.
摘要翻译：五氧化二磷的反应性降低，流动性提高。为此，以六角形改性形式的五氧化二磷在200〜390℃的温度下退火0.5〜8小时。

7. 发明授权

US4678650A Process for making an alkali phosphate solution 失效
标题翻译：碱式磷酸盐溶液的制备方法
公开(公告)号：US4678650A
公开(公告)日：1987-07-07
申请号：US715167
申请日：1985-03-22
申请人： Reinhard Gradl , Gero Heymer
发明人： Reinhard Gradl , Gero Heymer
IPC分类号： C01B25/46 , C01B15/16
CPC分类号： C01B25/46
摘要： An aqueous alkali phosphate solution is made. An organic phase is countercurrently mixed with an aqueous phase, the two phases being used in a volume ratio larger than 1:1 and formed aqueous alkali phosphate solution is separated from the remaining organic phase. The two phases are mixed and reacted in a reaction zone comprised of a mixing and separating zone. The organic phase is continuously dispersed in the aqueous phase. A volume excess of aqueous phase is maintained in the mixing zone and the two phases are used in an overall quantity sufficient to provide a volume ratio of organic to aqueous phase of 4:6 to 2:8.
摘要翻译：制备磷酸碱水溶液。有机相与水相逆流混合，两相以体积比大于1:1使用，形成的碱式磷酸碱水溶液与剩余的有机相分离。将两相混合并在由混合和分离区组成的反应区中反应。有机相连续分散在水相中。在混合区中维持体积过量的水相，并且两相的使用量足以提供4:6至2:8的有机相与水相的体积比。

8. 发明授权

US4668492A Process for dearsenifying phosphoric acid solutions 失效
标题翻译：脱磷酸溶液的工艺
公开(公告)号：US4668492A
公开(公告)日：1987-05-26
申请号：US801737
申请日：1985-11-26
申请人： G/u/ nther Schimmel , Reinhard Gradl , Gero Heymer
发明人： G/u/ nther Schimmel , Reinhard Gradl , Gero Heymer
IPC分类号： C01B25/237 , C01B25/238 , C01B25/30 , C01B25/46 , C01B25/16 , C01B25/26
CPC分类号： C01B25/237 , C01B25/238 , C01B25/308 , C01B25/461
摘要： Phosphoric acid solutions are dearsenified by treating them with a sulfide and separating the resulting precipitate from the purified solution. The sulfide is at least one compound of the general formula P.sub.4 S.sub.x in which x stands for a number of 3 to 10.
摘要翻译：通过用硫化物处理磷酸溶液进行脱砷，并将所得沉淀物与纯化溶液分离。硫化物是至少一种通式为P4Sx的化合物，其中x代表3至10个数。

9. 发明授权

US4482527A Process for removing nitrogen dioxide from off-gas 失效
标题翻译：从废气中除去二氧化氮的方法
公开(公告)号：US4482527A
公开(公告)日：1984-11-13
申请号：US538130
申请日：1983-10-03
申请人： Klaus Lehr , Gero Heymer
发明人： Klaus Lehr , Gero Heymer
IPC分类号： B01D53/56 , C01B21/00 , B01J8/00
CPC分类号： B01D53/56 , Y02C20/10
摘要： The disclosure relates to a process for removing nitrogen dioxide from off-gas. To this end, the disclosure provides for the off-gas to be intimately contacted with a suspension consisting of red phosphorus and a liquid being inert with respect to red phosphorus, e.g. water.
摘要翻译：本公开涉及从废气中除去二氧化氮的方法。为此，本公开内容提供废气与由红磷和相对于红磷惰性的液体组成的悬浮液紧密接触。水。

10. 发明授权

US4273752A Process for making red phosphorus 失效
标题翻译：制造红磷的工艺
公开(公告)号：US4273752A
公开(公告)日：1981-06-16
申请号：US123106
申请日：1980-02-20
申请人： Klaus Lehr , Gero Heymer , Hans-Werner Stephan , Ursus Thummler
发明人： Klaus Lehr , Gero Heymer , Hans-Werner Stephan , Ursus Thummler
IPC分类号： B01J8/10 , B01J19/28 , B02C17/00 , C01B25/02 , C01B25/023 , C01B25/01 , C01B25/04
CPC分类号： C01B25/023
摘要： The invention relates to a process for making red phosphorus by subjecting molten yellow phosphorus to a thermal conversion reaction in a closed reaction zone. To this end, a hollow shaft-provided and closed ball mill is preheated to a reaction temperature within the range 280.degree. to 590.degree. C. Yellow phosphorus is continuously introduced into the ball mill through the hollow shaft in quantities per unit time which permit the reaction temperature prevailing inside the ball mill to be maintained without supply of heat from the outside. More particularly, decreasing quantities of yellow phosphorus are introduced per unit time at increasing temperature and increasing quantities of yellow phosphorus are introduced per unit time at decreasing temperature within the limits specified. Red phosphorus is allowed to cool inside the ball mill, water is poured over it and the whole is subjected to wet-grinding. An aqueous suspension of red phosphorus is finally removed from the ball mill.
摘要翻译：本发明涉及通过使熔融黄磷在封闭反应区中进行热转化反应来制备红磷的方法。为此，空心轴提供和封闭的球磨机被预热到280℃至590℃的反应温度。黄磷通过空心轴以每单位时间的量连续地引入球磨机，这允许球磨机内部的反应温度保持不受外界的热量的限制。更特别地，在增加的温度下每单位时间引入黄磷的减少量，并且在规定的限度内在降低的温度下每单位时间引入增加量的黄磷。使红磷在球磨机内冷却，将水倒在其上，整体进行湿磨。最终从球磨机中除去红磷水悬浮液。

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