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    • 4. 发明授权
    • Thinner composition for removing spin-on-glass and photoresist
    • 用于去除旋涂玻璃和光致抗蚀剂的较薄组合物
    • US06183942B2
    • 2001-02-06
    • US09429535
    • 1999-10-28
    • Byung-Uk KimJi-Hum BaikChang-Il OhSang-Dai LeeWon-Lae KimChong-Soon Yoo
    • Byung-Uk KimJi-Hum BaikChang-Il OhSang-Dai LeeWon-Lae KimChong-Soon Yoo
    • G03F742
    • G03F7/422G03F7/168
    • The present invention relates to a thinner composition for removing a spin-on-glass coating and a photoresist which are used in the semiconductor components manufacturing process. The present invention provides a mixed thinner composition which is mixed propylene glycol monoalkyl ether with monooxycarbonic acid ester, alkyl ethanoate, and alkyl lactate in a thinner composition for cleaning and photoresist removal applications in the semiconductor components manufacturing process. A thinner composition according to the present invention has the beneficial effects that the production yield can be improved during semiconductor component manufacturing since when the thinner composition is applied after the spin coating process, the undesired coating of the edge or the backside of the substrate can be removed promptly, completely, and effectively, and residual materials adhering to the surface of a substrate which must be reuse can be completely removed so that the substrate can be economically used.
    • 本发明涉及用于去除半导体元件制造方法中的旋涂玻璃涂层和光致抗蚀剂的较薄组合物。本发明提供了混合的丙稀二醇单烷基醚与单氧碳酸酯的混合稀释剂组合物, 烷基乙酸烷基酯和乳酸烷基酯用于半导体组件制造方法中的清洁和光致抗蚀剂去除应用的较薄组合物。根据本发明的较薄组合物具有在半导体部件制造期间可以提高生产产量的有益效果,因为当薄膜 组合物在旋转涂布过程之后施加,可以迅速,完全和有效地去除衬底的边缘或背面的不期望的涂层,并且可以完全去除粘附到必须重新使用的衬底表面的残留材料,因此 基材可以是经济的 被使用。
    • 5. 发明授权
    • Photoresist remover composition
    • 光刻胶去除剂组成
    • US06908892B2
    • 2005-06-21
    • US10297646
    • 2001-06-07
    • Suk-Il YoonYoung-Woong ParkChang-Il OhSang-Dai LeeChong-Soon Yoo
    • Suk-Il YoonYoung-Woong ParkChang-Il OhSang-Dai LeeChong-Soon Yoo
    • G03F7/42H01L21/027C11D7/32C11D7/50
    • G03F7/425
    • The present invention is a photoresist remover composition used in order to remove photoresist during the manufacturing process of semiconductor devices, such as large-scale integrated circuits and very large-scale integrated circuits. The present invention comprises 2˜20 weight % of water-soluble hydroxylamine, 5˜15 weight % of oxime compound containing 2 or 3 hydroxyl groups, and 30˜55 weight % of alkyl amide. The photoresist remover composition according to the present invention can easily and quickly remove a photoresist layer that is cured by the processes of hard-bake, dry-etching, and ashing and a side-wall photoresist polymer that is produced from the lower metal film by the reaction of the photoresist with etching and ashing gases during these processes. Especially, the photoresist remover composition has a good property of removing the side-wall photoresist polymer produced from the layers of aluminum, aluminum alloy, and titanium nitride. In addition, during removing process of photoresist, the photoresist remover composition can minimize the corrosion of lower metal film, in particular, the new metallic layers which is adopted to a production line of 64 MDRAM or more-VLSL
    • 本发明是为了在诸如大规模集成电路和大规模集成电路的半导体器件的制造过程中去除光致抗蚀剂而使用的光致抗蚀剂去除剂组合物。 本发明包含2〜20重量%的水溶性羟胺,5〜15重量%的含2或3个羟基的肟化合物和30〜55重量%的烷基酰胺。 根据本发明的光致抗蚀剂去除剂组合物可以容易且快速地除去通过硬烘烤,干蚀刻和灰化过程固化的光致抗蚀剂层和由下金属膜制备的侧壁光致抗蚀剂聚合物,通过 在这些过程中光刻胶与蚀刻和灰化气体的反应。 特别地,光刻胶去除剂组合物具有除去由铝,铝合金和氮化钛层生产的侧壁光致抗蚀剂聚合物的良好性能。 此外,在光致抗蚀剂的除去过程中,光致抗蚀剂去除剂组合物可以最小化下金属膜的腐蚀,特别是在生产线上采用的64MDRAM或更高VLSL的新金属层
    • 6. 发明授权
    • Stripper composition for negative chemically amplified resist
    • 用于负化学放大抗蚀剂的剥离剂组合物
    • US06683034B1
    • 2004-01-27
    • US10019607
    • 2001-12-28
    • Chang-Il OhSang-Dai LeeChong-Soon Yoo
    • Chang-Il OhSang-Dai LeeChong-Soon Yoo
    • C11D122
    • C11D3/18C11D1/72C11D3/34G03F7/426
    • The present invention relates to a nonaqueous stripper composition for negative chemically amplified resists which shows excellent removing capabilities, has anticorrosive effects on varieties of metallic substrate plates such as Al, W, TiN, WSi, SiON, SiNx, HTO, etc., improves productivity since it can be recycled as a nonaqueous stripper even after many applications, and is suitable in electronic material fields in which high precision processing is required in the negative chemically amplified resist removing process. The present invention provides a stripper composition for negative chemically amplified resists comprising a) 20 to 35 weight % of straight chained alkylbenzenesulfonic acid; b) 10 to 34 weight % of light aromatic naphtha solvent; c) 30 to 45 weight % of organic compounds containing chlorine; d) 15 to 25 weight % of hydroxybenzenes; and e) 0.5 to 5 weight % of polyoxyethylene octylphenylether derivatives, in order to accomplish the above objects.
    • 本发明涉及一种显示出优异的除去能力的负性化学增幅抗蚀剂的非水性剥离剂组合物,对诸如Al,W,TiN,WSi,SiON,SiNx,HTO等的金属基板的各种品种具有防腐蚀效果,提高了生产率 因为即使在许多应用之后它也可以作为非水性剥离剂再循环,并且适用于负性化学放大抗蚀剂去除工艺中需要高精度加工的电子材料领域。 本发明提供了用于负化学放大抗蚀剂的剥离剂组合物,其包含a)20至35重量%的直链烷基苯磺酸; b)10〜34重量%的轻芳烃石脑油溶剂; c)30至45重量%的含氯有机化合物; d)15至25重量%的羟基苯; 和e)0.5至5重量%的聚氧乙烯辛基苯基醚衍生物,以实现上述目的。
    • 7. 发明授权
    • Photoresist remover composition
    • 光刻胶去除剂组成
    • US06579668B1
    • 2003-06-17
    • US10069243
    • 2002-02-15
    • Ji-Hum BaikChang-Il OhSang-Dai LeeChong-Soon Yoo
    • Ji-Hum BaikChang-Il OhSang-Dai LeeChong-Soon Yoo
    • G03F742
    • G03F7/425
    • A photoresist remover composition including: 10 to 30% by weight amine compound; 20 to 60% by weight glycol series solvent; 20 to 60% by weight polar solvent; and 0.01 to 3% by weight perfluoroalkylethyleneoxide. The performance of the photoresist remover composition in stripping the photoresist residue, which is generated by dry or wet etching, ashing or ion implantation, from a substrate is enhance, and the photoresist remover composition is able to be smoothly applied over a variety of metal layers including an aluminum (Al) layer. Also, the photoresist remover composition corrodes the metal layers very little.
    • 一种光致抗蚀剂去除剂组合物,其包含:10至30重量%的胺化合物; 20〜60重量%乙二醇系列溶剂; 20〜60重量%极性溶剂; 和0.01〜3重量%的全氟烷基氧化乙烯。 光致抗蚀剂去除剂组合物在从基材上进行干蚀刻或湿法蚀刻,灰化或离子注入产生的光致抗蚀剂残余物的性能得到提高,并且光刻胶去除剂组合物能够平滑地施加在各种金属层上 包括铝(Al)层。 此外,光致抗蚀剂去除剂组合物非常少地腐蚀金属层。
    • 8. 发明授权
    • Photoresist remover composition
    • 光刻胶去除剂组成
    • US6140027A
    • 2000-10-31
    • US435569
    • 1999-11-08
    • Ji-Hum BaikChang-Il OhSang-Dai LeeWon-Lae KimChong-Soon Yoo
    • Ji-Hum BaikChang-Il OhSang-Dai LeeWon-Lae KimChong-Soon Yoo
    • G03F7/32G03F7/42H01L21/311
    • H01L21/02063G03F7/425G03F7/426H01L21/31133
    • A photoresist remover composition used for removing photoresist during the manufacture of semiconductor devices such as integrated circuits (IC), large-scale integrated circuits (LSI) or very large scale integrated circuits (VLSI). The photoresist remover composition includes 10.about.40 wt % of water-soluble amine compound; 20.about.50 wt % of at least one water-soluble polar organic solvent selected from the group consisting of dimetylsulfoxide (DMSO), N-methylpyrrolidone (NMP), dimethylacetamide (DMAc), dimethylformamide (DMF) and dimethylimidezolidinone (DMI); 10.about.30 wt % of water; 0.1.about.10 wt % of organic phenol compound containing two or more hydroxy groups; 0.1.about.10 wt % of triazole compound; and 0.01.about.1 wt % of silicone surfactant. Therefore, the photoresist remover composition can easily remove, at a low temperature and in a short time, a photoresist layer which has been cured during hard baking, dry etching, ashing and/or ion-implantation processes, and the potoresist layer cross-linked by a metallic contaminants shed from a lower metal layer during these processes. Also, corrosion of the lower metal pattern during the photoresist removal process can be minimized.
    • 用于在诸如集成电路(IC),大规模集成电路(LSI)或超大规模集成电路(VLSI)的半导体器件的制造期间去除光致抗蚀剂的光刻胶去除剂组合物。 光刻胶去除剂组合物包含10重量%的水溶性胺化合物; 20重量%至少一种选自二甲基亚砜(DMSO),N-甲基吡咯烷酮(NMP),二甲基乙酰胺(DMAc),二甲基甲酰胺(DMF)和二甲基酰亚胺唑烷酮(DMI))的水溶性极性有机溶剂; 10分差30%的水; 0.1差异10重量%的含有两个或多个羟基的有机酚化合物; 0.1差异10重量%的三唑化合物; 和0.01%的有机硅表面活性剂。 因此,光刻胶去除剂组合物可以在低温和短时间内容易地在硬烘烤,干蚀刻,灰化和/或离子注入工艺中固化的光致抗蚀剂层和交联的光致抗蚀剂层 在这些过程中,金属污染物从下层金属层脱落。 而且,光致抗蚀剂去除过程中的下金属图案的腐蚀可以被最小化。