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1. 发明授权

US5600017A Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide hydrogen ethylene and acetylene-(LAW072) 失效
标题翻译：含有一氧化碳氢乙烯和乙炔的多组分合成气的直接加氢甲酰化（LAW072）
公开(公告)号：US5600017A
公开(公告)日：1997-02-04
申请号：US563838
申请日：1995-11-28
申请人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
发明人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译：本发明是一种通过使多组分合成气进料流与油溶性铑配合物催化剂溶液接触而将含有CO，H 2，C 2至C 5烯烃及其混合物和C 2 -C 5炔烃及其混合物的多组分合成气原料流加氢甲酰化的方法，在低价Rh和油溶性三有机磷化合物溶液中络合，其中催化剂的P / Rh比为至少30，溶液中Rh的浓度为约1至约1000重量ppm，配位活性P 至少约0.01mol / l，[P] / pco为至少0.1mmol / l / kPa的比例，其中[P]是溶液中配位活性磷的总浓度，pco是分压的CO，以产生相应的C3至C6醛。该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

2. 发明授权

US5162599A Rapid thermal pyrolysis of gaseous feeds containing hydrocarbon molecules mixed with an inert working gas 失效
标题翻译：含有与惰性工作气体混合的烃分子的气态进料的快速热解
公开(公告)号：US5162599A
公开(公告)日：1992-11-10
申请号：US762189
申请日：1991-09-19
申请人： Michael G. Matturro , Harry W. Deckman , Frank Hershkowitz , Anthony M. Dean
发明人： Michael G. Matturro , Harry W. Deckman , Frank Hershkowitz , Anthony M. Dean
IPC分类号： C07C2/76
CPC分类号： C07C2/76 , Y10S585/91 , Y10S585/943
摘要： In its simplest sense, the present invention is directed toward a process for the thermal conversion of methane into unsaturated gaseous hydrocarbons, especially olefins, comprising first compressing methane in the presence of an inert gas having a higher ratio of heat capacities, Cp/Cv, than methane. The inert gas used is present in an amount sufficient to provide a compressed gas mixture having a peak temperature of adiabatic compression in the range of about 900.degree. C. to about 2200.degree. C. Under these conditions, at least some of the methane is converted to unsaturated gaseous hydrocarbons. Immediately thereafter, the compressed gas mixture is expanded, thereby substantially preventing thermal conversion of the gaseous hydrocarbons. Importantly, the compression and expansion are achieved in a single cycle of less than about one second.
摘要翻译：在最简单的意义上，本发明涉及一种将甲烷热转化为不饱和气态烃，特别是烯烃的方法，包括在惰性气体存在下首先压缩甲烷，所述惰性气体具有较高的热容比Cp / Cv，比甲烷。使用的惰性气体的存在量足以提供具有在约900℃至约2200℃范围内的绝热压缩峰值温度的压缩气体混合物。在这些条件下，至少一些甲烷被转化到不饱和气态烃。之后立即压缩气体混合物膨胀，从而基本上防止了气态烃的热转化。重要的是，压缩和膨胀在小于约1秒的单个循环中实现。

3. 发明授权

US6090986A Organic compounds and processes for their manufacture 失效
标题翻译：有机化合物及其制造方法
公开(公告)号：US6090986A
公开(公告)日：2000-07-18
申请号：US860638
申请日：1997-10-27
申请人： Allen David Godwin , Richard Henry Schlosberg , Frank Hershkowitz , Michael G. Matturro , Gabor Kiss , Kirk Christian Nadler , Philippe Louis Buess , Richard C. Miller , Paul William Allen , Harry William Deckman , Raf Caers , Edmund John Mozeleski , Robert P Reynolds , Francis Joseph Healy
发明人： Allen David Godwin , Richard Henry Schlosberg , Frank Hershkowitz , Michael G. Matturro , Gabor Kiss , Kirk Christian Nadler , Philippe Louis Buess , Richard C. Miller , Paul William Allen , Harry William Deckman , Raf Caers , Edmund John Mozeleski , Robert P Reynolds , Francis Joseph Healy
IPC分类号： B01J21/06 , B01J23/04 , B01J23/44 , B01J23/74 , B01J27/232 , B01J31/24 , C07B61/00 , C07C29/141 , C07C29/17 , C07C31/125 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C51/235 , C07C53/126 , C07C53/128 , C07C67/08 , C07C69/14 , C07C69/24 , C07C69/44 , C07C69/76 , C07C69/80 , C08K5/10 , C10M105/38 , C11B9/00 , C07C45/00
CPC分类号： C07C45/74 , C07C29/141 , C07C45/50 , C07C45/62
摘要： Esters of branched C.sub.9 alcohols suitable as plasticizers are formed by esterification of a C.sub.9 alcohol produced by the aldol condensation from propanal and a C.sub.6 aldehyde and hydrogenation, the propanal optionally having been made from natural gas streams.
摘要翻译： PCT No.PCT / EP96 / 00267 Sec。 371日期1997年10月27日第 102（e）1997年10月27日PCT PCT 1996年1月17日PCT公布。公开号WO96 / 22268 日期1996年7月25日适合作为增塑剂的分支C 9醇的酯通过由丙醛和C 6醛醛醛缩合产生的C 9醇酯化并氢化而形成，丙醛任选地由天然气流制成。

4. 发明授权

US5186833A Composite metal-ceramic membranes and their fabrication 失效
标题翻译：复合金属陶瓷膜及其制造
公开(公告)号：US5186833A
公开(公告)日：1993-02-16
申请号：US775656
申请日：1991-10-10
申请人： James A. Mchenry , Harry W. Deckman , Wen-Yih F. Lai , Michael G. Matturro , Allan J. Jacobson , Jack W. Johnson
发明人： James A. Mchenry , Harry W. Deckman , Wen-Yih F. Lai , Michael G. Matturro , Allan J. Jacobson , Jack W. Johnson
IPC分类号： B01D71/02 , C23C26/00
CPC分类号： B01D67/0048 , B01D67/0083 , B01D71/02 , C23C26/00 , B01D2323/08 , B01D2325/04
摘要： The present invention provides a novel, porous, composite membrane comprising a metallic support having large pores and a microporous ceramic membrane deposited on the support and integral therewith. Preferably, the support is steel having pores in the range of from about 0.25 .mu.m to about 50 .mu.m and the ceramic membrane is alumina having pores ranging from about 5 .ANG.to about 2500 .ANG..

5. 发明授权

US5395979A Method for separating catalyst from a hydroformylation reaction product using alkylated ligands 失效
标题翻译：使用烷基化配体从羰基化反应产物中分离催化剂的方法
公开(公告)号：US5395979A
公开(公告)日：1995-03-07
申请号：US23235
申请日：1993-02-25
申请人： Harry W. Deckman , Edward Kantner , Joel R. Livingston, Jr. , Michael G. Matturro , Edmund J. Mozeleski
发明人： Harry W. Deckman , Edward Kantner , Joel R. Livingston, Jr. , Michael G. Matturro , Edmund J. Mozeleski
IPC分类号： B01J31/24 , B01J31/40 , B01J38/48 , C07B61/00 , C07C45/50 , C07C47/02 , C07C45/78
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/4038 , B01J31/4046 , B01J31/4053 , B01J31/4061 , B01J38/48 , C07C45/50 , B01J2231/321 , B01J2531/80 , B01J2531/822 , Y02P20/584
摘要： A catalyst for use in hydroformylation of olefins which comprises a Group VIII noble metal complexed with a phosphine ligand having at least one alkyl or aryl group bonded thereto, such as tris-4-propylphenyl phosphines and tris-4-octylphenyl phosphines. These and other triphenylphosphine catalysts can be separated from a crude reaction product of a noble metal-catalyzed hydroformylation reaction by contacting the crude reaction product with a dense polymeric, nonpolar membrane, preferably nonpolar polyolefin membranes.
摘要翻译：用于烯烃加氢甲酰化的催化剂，其包含与其上键合有至少一个烷基或芳基的膦配体络合的VIII族贵金属，例如三-4-丙基苯基膦和三-4-辛基苯基膦。这些和其它三苯基膦催化剂可以通过使粗反应产物与致密的聚合非极性膜，优选非极性聚烯烃膜接触，从贵金属催化的加氢甲酰基化反应的粗反应产物中分离出来。

6. 发明授权

US5183788A Modular surface catalyzed membrane containing a microporous membrane catalyst layer and transport layer 失效
标题翻译：模块化表面催化膜含有微孔膜催化剂层和输送层
公开(公告)号：US5183788A
公开(公告)日：1993-02-02
申请号：US775646
申请日：1991-10-10
申请人： Allan J. Jacobson , Wen-Yih F. Lai , Michael G. Matturro , Harry W. Deckman , James A. McHenry , Robert P. Reynolds , Qiyao Zhang
发明人： Allan J. Jacobson , Wen-Yih F. Lai , Michael G. Matturro , Harry W. Deckman , James A. McHenry , Robert P. Reynolds , Qiyao Zhang
IPC分类号： B01J23/652 , B01J35/06 , B01J35/10 , B01J37/02 , C04B41/85 , C04B41/89 , C07C5/03 , C07C43/18
CPC分类号： B01J37/0244 , B01J35/065
摘要： Accordingly, there is provided a catalytic membrane comprising a porous substrate having a first surface and a second surface. The substrate has micropores, for example, pores ranging from about 10 .ANG. to about 2000 .ANG. in diameter, at least in a region extending from the first surface toward the second surface for a preselected distance. Preferably, the preselected distance will be sufficient to provide a measurable resistance to the flow of a fluid, such as a gas, through the micropores. A catalyst is deposited at least on the first surface of the substrate, although optionally, the catalyst is deposited on the substrate in the micorpore region. A transport layer is provided on the first surface of the substrate, including any catalyst on the first surface.

7. 发明授权

US06740718B2 Non-linear polymer product derived from dilute multi-component feeds 失效
标题翻译：衍生自稀释多组分进料的非线性聚合物产物
公开(公告)号：US06740718B2
公开(公告)日：2004-05-25
申请号：US10320931
申请日：2002-12-17
申请人： Abhimanyu O. Patil , Donald N. Schulz , Raymond A. Cook , Michael G. Matturro
发明人： Abhimanyu O. Patil , Donald N. Schulz , Raymond A. Cook , Michael G. Matturro
IPC分类号： C08F432
CPC分类号： C08G67/02
摘要： The invention relates to a method of forming carbon monoxide-containing polymers from multi-component syngas feeds and at least one vinyl comonomer. Feeds useful in the practice of the invention comprise ethylene in an amount ranging from about 5 to about 40 mole %, carbon monoxide is an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about 10 mole %. The feed may contain at least one free radical-polymerizable vinyl comonomer, or a cofeed containing such a comonomer can be used.
摘要翻译：本发明涉及从多组分合成气进料和至少一种乙烯基共聚单体形成含一氧化碳的聚合物的方法。在本发明的实践中有用的进料包含量为约5至约40摩尔％的乙烯，一氧化碳的量为约1至约40摩尔％，氢量为约4至约55摩尔％，约3至约10摩尔％的量的二氧化碳和约4至约85摩尔％的量的甲烷。进料还可以包括高达约10摩尔％的量的乙炔。饲料可以含有至少一种可自由基聚合的乙烯基共聚单体，或者可以使用含有这种共聚单体的共进料。

8. 发明授权

US06541586B2 Polymerization processes for using dilute multicomponent feeds (LAW624) 失效
标题翻译：使用稀释多组分进料的聚合方法（LAW624）
公开(公告)号：US06541586B2
公开(公告)日：2003-04-01
申请号：US09233353
申请日：1999-01-19
申请人： Abhimanyu O. Patil , Donald N. Schulz , Raymond A. Cook , Michael G. Matturro
发明人： Abhimanyu O. Patil , Donald N. Schulz , Raymond A. Cook , Michael G. Matturro
IPC分类号： C08F434
CPC分类号： C08G67/02
摘要： The invention relates to a method of forming carbon monoxide-containing polymers from multi-component syngas feeds and at least one vinyl comonomer. Feeds useful in the practice of the invention comprise ethylene in an amount ranging from about 5 to about 40 mole %, carbon monoxide is an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about 10 mole %. The feed may contain at least one free radical-polymerizable vinyl comonomer, or a cofeed containing such a comonomer can be used.
摘要翻译：本发明涉及从多组分合成气进料和至少一种乙烯基共聚单体形成含一氧化碳的聚合物的方法。在本发明的实践中有用的进料包含量为约5至约40摩尔％的乙烯，一氧化碳的量为约1至约40摩尔％，氢量为约4至约55摩尔％，约3至约10摩尔％的量的二氧化碳和约4至约85摩尔％的量的甲烷。进料还可以包括高达约10摩尔％的量的乙炔。饲料可以含有至少一种可自由基聚合的乙烯基共聚单体，或者可以使用含有这种共聚单体的共进料。

9. 发明授权

US6156872A Paraffin-soluble polymers and copolymers 失效
标题翻译：石蜡溶解聚合物和共聚物
公开(公告)号：US6156872A
公开(公告)日：2000-12-05
申请号：US233362
申请日：1999-01-19
申请人： Abhimanyu O. Patil , Donald N. Schulz , Raymond A. Cook , Michael G. Matturro
发明人： Abhimanyu O. Patil , Donald N. Schulz , Raymond A. Cook , Michael G. Matturro
IPC分类号： C08G67/02 , C08F238/02 , C08G61/00
CPC分类号： C08G67/02
摘要： The invention is related to non-linear, paraffin-soluble olefin/carbon monoxide and olefin/acetylene/carbon monoxide copolymers. The invention is also related to a method for preparing olefin/carbon monoxide copolymers by heating a feed of at least one olefin, carbon monoxide, carbon dioxide, hydrogen, and methane in the presence of a free radical polymerization initiator. More particularly, the feed comprises at least one olefin, the total olefin amount ranging from about 5 to about 40 mole %, carbon monoxide in an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about mole %.
摘要翻译：本发明涉及非线性，石蜡溶解的烯烃/一氧化碳和烯烃/乙炔/一氧化碳共聚物。本发明还涉及通过在自由基聚合引发剂的存在下加热至少一种烯烃，一氧化碳，二氧化碳，氢气和甲烷的进料来制备烯烃/一氧化碳共聚物的方法。更具体地，进料包含至少一种烯烃，总烯烃量为约5至约40摩尔％，量为约1至约40摩尔％的一氧化碳，其量为约4至约40摩尔％ 55摩尔％，量为约3至约10摩尔％的二氧化碳，以及范围为约4至约85摩尔％的甲烷。进料还可以包括高达约摩尔％的量的乙炔。

10. 发明授权

US06977277B2 Polyvinyl chloride resins 失效
标题翻译：聚氯乙烯树脂
公开(公告)号：US06977277B2
公开(公告)日：2005-12-20
申请号：US10420420
申请日：2003-04-22
申请人： Abhimanyu O. Patil , Donald N. Schulz , Manika Varma-Nair , David J. Lohse , Christine A. Costello , Richard H. Schlosberg , Michael G. Matturro
发明人： Abhimanyu O. Patil , Donald N. Schulz , Manika Varma-Nair , David J. Lohse , Christine A. Costello , Richard H. Schlosberg , Michael G. Matturro
IPC分类号： C08G67/02 , C08L27/06 , C08L73/00 , C08F67/02
CPC分类号： C08L27/06 , C08G67/02 , C08L73/00 , C08L2666/14 , C08L2666/04
摘要： The invention is directed towards a PVC resin composition comprising polyvinyl chloride and a liquid plasticizer selected from the group consisting of: (i) a non-linear, paraffin-soluble olefin-CO copolymer; ii) a non-linear olefin-CO copolymer derived from non-pure feeds; iii) an olefin-CO—X terpolymer derived from non-pure feeds; and iv) a non-linear olefin-CO—X terpolymer. A method of preparing the resins is also described.
摘要翻译：本发明涉及一种PVC树脂组合物，其包含聚氯乙烯和选自以下的液体增塑剂：（i）非线性，链烷烃可溶的烯烃-CO共聚物; ii）衍生自非纯饲料的非线性烯烃-CO共聚物; iii）衍生自非纯饲料的烯烃-CO-X三元共聚物; 和iv）非线性烯烃-CO-X三元共聚物。还描述了制备树脂的方法。

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