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1. 发明授权

US5919869A Polymers having terminal hydroxyl, aldehyde, or alkylamino substituents and derivatives thereof 失效
标题翻译：具有末端羟基，醛或烷基氨基取代基及其衍生物的聚合物
公开(公告)号：US5919869A
公开(公告)日：1999-07-06
申请号：US36031
申请日：1998-03-06
申请人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
发明人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
IPC分类号： C10M145/20 , C08F8/00 , C08F8/28 , C08F8/30 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58 , C10N30/04
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端羟基，醛或烷基氨基取代基的聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自多烯（二烯，例如），式H2C = CHR4的单体，其中R 4是氢或直链或支链烷基。优选地，聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

2. 发明授权

US5880219A Polymers having terminal hydroxyl, aldehyde, or alkylamino substituents and derivatives thereof 失效
公开(公告)号：US5880219A
公开(公告)日：1999-03-09
申请号：US826938
申请日：1997-04-08
申请人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
发明人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
IPC分类号： C10M145/20 , C08F8/00 , C08F8/28 , C08F8/30 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58 , C10N30/04
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.

3. 发明授权

US5780554A Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof 失效
标题翻译：具有末端醛或羟基取代基的饱和聚烯烃及其衍生物
公开(公告)号：US5780554A
公开(公告)日：1998-07-14
申请号：US742957
申请日：1996-11-01
申请人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
发明人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
IPC分类号： C08F8/00 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端醛或羟基取代基的饱和聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中饱和聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自式H2C = CHR4的单体，其中R4是氢或直链或支链烷基，并且其中聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

4. 发明授权

US5777041A Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof 失效
公开(公告)号：US5777041A
公开(公告)日：1998-07-07
申请号：US787360
申请日：1997-01-22
申请人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
发明人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
IPC分类号： C08F8/00 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C=CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.

5. 发明授权

US5674950A Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof 失效
标题翻译：具有末端羟基醛的聚合物或烷基氨基取代基及其衍生物
公开(公告)号：US5674950A
公开(公告)日：1997-10-07
申请号：US391845
申请日：1995-02-27
申请人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
发明人： Warren A. Thaler , Jacob I. Emert , Istvan T. Horvath , Richard H. Schlosberg , David A. Young , Stephen Zushma
IPC分类号： C10M145/20 , C08F8/00 , C08F8/28 , C08F8/30 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58 , C10N30/04
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A polymer having a terminal hydroxyl, aldehyde or alkylamino substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a polyene (diene, e.g.), monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical. Preferably, the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端羟基，醛或烷基氨基取代基的聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自多烯（二烯，例如），式H2C = CHR4的单体，其中R 4是氢或直链或支链烷基。优选地，聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

6. 发明授权

US5691422A Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof 失效
标题翻译：具有末端醛或羟基取代基的饱和聚烯烃及其衍生物
公开(公告)号：US5691422A
公开(公告)日：1997-11-25
申请号：US662835
申请日：1996-06-12
申请人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
发明人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
IPC分类号： C08F8/00 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端醛或羟基取代基的饱和聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中饱和聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自式H2C = CHR4的单体，其中R4是氢或直链或支链烷基，并且其中聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

7. 发明授权

US5600017A Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide hydrogen ethylene and acetylene-(LAW072) 失效
标题翻译：含有一氧化碳氢乙烯和乙炔的多组分合成气的直接加氢甲酰化（LAW072）
公开(公告)号：US5600017A
公开(公告)日：1997-02-04
申请号：US563838
申请日：1995-11-28
申请人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
发明人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译：本发明是一种通过使多组分合成气进料流与油溶性铑配合物催化剂溶液接触而将含有CO，H 2，C 2至C 5烯烃及其混合物和C 2 -C 5炔烃及其混合物的多组分合成气原料流加氢甲酰化的方法，在低价Rh和油溶性三有机磷化合物溶液中络合，其中催化剂的P / Rh比为至少30，溶液中Rh的浓度为约1至约1000重量ppm，配位活性P 至少约0.01mol / l，[P] / pco为至少0.1mmol / l / kPa的比例，其中[P]是溶液中配位活性磷的总浓度，pco是分压的CO，以产生相应的C3至C6醛。该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

8. 发明授权

US5463082A Fluorous multiphase systems 失效
标题翻译：氟多相体系
公开(公告)号：US5463082A
公开(公告)日：1995-10-31
申请号：US88706
申请日：1993-07-08
申请人： Istvan T. Horvath , Jozsef Rabai
发明人： Istvan T. Horvath , Jozsef Rabai
IPC分类号： B01J31/02 , B01J31/20 , B01J31/22 , B01J31/24 , B01J31/40 , C07C17/38 , C07C45/50 , C07C315/02 , C07C317/14 , C07D303/32 , C07D333/76 , C07F9/09 , C07F9/141 , C07F9/50 , C07C37/58 , C07C45/62
CPC分类号： C07F9/1411 , B01J31/183 , B01J31/185 , B01J31/20 , B01J31/24 , B01J31/4046 , C07C17/38 , C07C315/02 , C07C45/50 , C07D303/32 , C07D333/76 , C07F9/091 , C07F9/5004 , B01J2231/321 , B01J2231/70 , B01J2531/025 , B01J2531/822 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2531/94 , B01J2531/98 , B01J2540/225 , B01J2540/64 , B01J31/2234 , Y02P20/582 , Y02P20/584
摘要： Stoichiometric and catalytic chemical transformations may be carried out in solution using novel fluorous multiphase systems (FMS). The term "fluorous" is defined as a carbon-fluorine bond rich organic molecule. The FMS consists of a fluorous phase containing a fluorous solvent, typically a fluorocarbon or a fluorohydrocarbon and a reagent or a catalyst containing a sufficient number of fluorous moieties to render it preferentially soluble in the fluorous solvent without impairing the ability of the catalyst or reagent to be effective in the reaction and while maintaining the reaction in a liquid or fluid phase. The nonfluorous solvent may be any suitable organic or nonorganic solvent(s) with limited or no solubility in the fluorous solvent that is effective for dissolving the reactant(s) and most desirably, for separating the resulting product(s). Typically, such solvents have a Hildebrand solubility parameter of at least about 18.0 MPa1/2. Appropriate fluorous moieties are linear, branched and carbocyclic fluorocarbon alkyl chains with high carbon numbers. FMS reagents and catalysts can be prepared by (1) fluorination (i.e., replacement of C--H bonds with fluorine); (2) fluorofunctionalization, e.g., the attachment of fluorous moieties to the reagents or catalysts; or (3) by total synthesis. The invention is useful in separations technology and in catalyst design and synthesis.
摘要翻译：化学计量和催化化学转化可以在溶液中使用新的氟多相体系（FMS）进行。术语“氟”被定义为富含氟 - 氟的有机分子。 FMS由含氟溶剂（通常为碳氟化合物或氟代烃）的氟相和含有足够数量的氟部分的试剂或催化剂组成，使其优先溶于氟溶剂中而不损害催化剂或试剂的能力在反应中有效并且在液体或流体相中保持反应。非氟溶剂可以是在氟溶剂中溶解有限或不溶性的任何合适的有机溶剂或非有机溶剂，其有效溶解反应物，最理想的是用于分离所得产物。通常，这样的溶剂具有至少约18.0MPa1 / 2的希尔德布兰德溶解度参数。合适的氟部分是具有高碳数的直链，支链和碳环碳氟烷基链。 FMS试剂和催化剂可以通过（1）氟化（即用氟取代C-H键）来制备; （2）氟官能化，例如将氟部分连接到试剂或催化剂上; 或（3）通过总合成。本发明在分离技术和催化剂设计和合成中是有用的。

9. 发明授权

US5675041A Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene 失效
标题翻译：含有一氧化碳，氢气，乙烯和乙炔的多组分合成气的直接加氢甲酰化
公开(公告)号：US5675041A
公开(公告)日：1997-10-07
申请号：US573052
申请日：1995-12-15
申请人： Gabor Kiss , Frank Hershkowitz , Harry W. Deckman , Michael Gerard Matturro , Istvan T. Horvath , Anthony M. Dean , Raymond A. Cook
发明人： Gabor Kiss , Frank Hershkowitz , Harry W. Deckman , Michael Gerard Matturro , Istvan T. Horvath , Anthony M. Dean , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.B is 35(N-1) cal/mole/.degree.K., N is the number of P-Rh attachments per ligand molecule. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译：本发明是通过加氢甲酰化含有：（a）C 2〜C 5烯烃及其混合物的混合物，和（b）（ⅰ）C2〜C5炔烃及其混合物或（ⅱ）C3〜C5 累积的二烯及其混合物，或（iii）（ⅰ）和（ⅱ）的混合物与CO，H 2和铑络合物催化剂的溶液形成，所述铑配合物催化剂是通过使Rh和溶液中Rh浓度为1〜1000的有机磷化合物重量ppm。或者，铑络合物催化剂的溶液的P / Rh原子比可以至少为30.另外，铑络合物催化剂的溶液可以具有大于由下式定义的值RL的P / Rh原子比：其中RB是催化活性Rh配合物的P / Rh比，pKaTPP是三苯基膦的pKa值，pKaL是三有机磷化合物的pKa值，R是气体常数，DELTA SB是35（N-1 ）cal / mole / DEGK，N是每个配体分子的P-Rh附着物的数目。该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

10. 发明授权

US5276226A Low temperature halogenation of alkanes 失效
标题翻译：低温卤化烷烃
公开(公告)号：US5276226A
公开(公告)日：1994-01-04
申请号：US956706
申请日：1992-10-05
申请人： Istvan T. Horvath , Raymond A. Cook , Gabor Kiss
发明人： Istvan T. Horvath , Raymond A. Cook , Gabor Kiss
IPC分类号： C07C17/10 , C07C17/00 , C07C19/00
CPC分类号： C07C17/10
摘要： The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at relatively mild temperatures and pressures in an organic liquid phase in the presence of halogen and transition metal complex. The alkane may be neat if in a liquid form, or may be solubilized with a suitable organic solvent, if the alkane not a liquid at reaction conditions. The reaction is for a time, under conditions of temperature and pressure and in effective amounts that will permit the formation of alkyl halides. Optional hydrolysis to the corresponding alcohols may follow. The alkyl halides have utility as precursors for alternative fuels, such as methanol.
摘要翻译：本发明涉及在卤素和过渡金属络合物存在下，在有机液相中相对温和的温度和压力下从烷烃如甲烷和乙烷中选择性地制备烷基卤的方法。如果在反应条件下烷烃不是液体，则烷烃可以是纯的，如果是液体形式，或者可以用合适的有机溶剂溶解。在温度和压力的条件下反应一段时间，并且有效量可以形成烷基卤。可以按照相应的醇进行任选的水解。烷基卤化物可用作替代燃料（例如甲醇）的前体。

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