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1. 发明授权

US5403964A Process for conversion of ethers to alcohols and olefins 失效
标题翻译：将醚转化为醇和烯烃的方法
公开(公告)号：US5403964A
公开(公告)日：1995-04-04
申请号：US187672
申请日：1994-01-27
申请人： Ramzi Y. Saleh , Joel R. Livingston, Jr. , Michael Siskin , Glen B. Brons
发明人： Ramzi Y. Saleh , Joel R. Livingston, Jr. , Michael Siskin , Glen B. Brons
IPC分类号： C07C1/20 , C07C11/02 , C07C29/10 , C07C31/10 , C07C31/12 , C07C27/00 , C07C29/00
CPC分类号： C07C31/12 , C07C1/20 , C07C29/10 , C07C31/10
摘要： The present invention relates to enhanced process for converting certain ethers, such as sec-butyl ether and isopropyl ether to their corresponding reaction products in the presence of water. This may be accomplished by adding a rate enhancing surfactant, such as an anionic or cationic surfactant to a mixture of the ether and water, preferably least about 10.sup.-5 molar surfactant. Under those conditions the reaction shows an increase in reaction rate over the rate of the process wherein surfactant is not used.
摘要翻译：本发明涉及在水存在下将某些醚如仲丁醚和异丙醚转化成其相应的反应产物的增强方法。这可以通过将速率增强表面活性剂例如阴离子或阳离子表面活性剂加入到醚和水的混合物中，优选至少约10-5摩尔表面活性剂来实现。在这些条件下，该反应显示反应速率相对于不使用表面活性剂的方法的速率增加。

2. 发明授权

US5300617A Potassium para-diphenyl phosphino benzene sulfonate ligand 失效
标题翻译：对二苯基膦基苯磺酸钾配体
公开(公告)号：US5300617A
公开(公告)日：1994-04-05
申请号：US6910
申请日：1993-01-21
申请人： Elena N. Suciu , Joel R. Livingston, Jr. , Edmund J. Mozeleski
发明人： Elena N. Suciu , Joel R. Livingston, Jr. , Edmund J. Mozeleski
IPC分类号： B01J31/22 , C07B61/00 , C07C29/141 , C07C31/02 , C07C45/50 , C07C47/02 , C07F9/50 , C07F15/00 , C07F9/14
CPC分类号： C07C45/50 , C07F9/5022 , C07F9/5077
摘要： A method for producing a potassium para-diphenyl phosphino sulfonate ligand which comprises reacting potassium diphenyl phosphide with a lithium salt of para-chloro benzenesulfonic acid in the presence of tetrahydrofuran at elevated temperatures.
摘要翻译：一种制备对二苯基膦基磺酸钾配位体的方法，其包括在四氢呋喃存在下在升高的温度下使二苯基磷化钾与对氯苯磺酸的锂盐反应。

3. 发明授权

US5382701A Use as catalyst in the hydroformylation of olefinic feedstock to higher aldehydes and higher alcohols 失效
标题翻译：用作烯烃原料加氢甲酰化成高级醛和高级醇的催化剂
公开(公告)号：US5382701A
公开(公告)日：1995-01-17
申请号：US154657
申请日：1993-11-18
申请人： Elena N. Suciu , Joel R. Livingston, Jr. , Edmund J. Mozeleski
发明人： Elena N. Suciu , Joel R. Livingston, Jr. , Edmund J. Mozeleski
IPC分类号： B01J31/22 , C07B61/00 , C07C29/141 , C07C31/02 , C07C45/50 , C07C47/02 , C07F9/50 , C07F15/00
CPC分类号： C07C45/50 , C07F9/5022 , C07F9/5077
摘要： A method for producing a potassium paradiphenyl phosphino sulfonate ligand which comprises reacting potassium diphenyl phosphide with a lithium salt of para-chloro benzenesulfonic acid in the presence of tetrahydrofuran at elevated temperatures.
摘要翻译：一种制备对二苯基膦基磺酸钾配位体的方法，其包括在四氢呋喃存在下在升高的温度下使二苯基磷化钾与对氯苯磺酸的锂盐反应。

4. 发明授权

US5215667A Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction 失效
标题翻译：从金属催化氢化反应中分离水溶性金属催化剂的方法
公开(公告)号：US5215667A
公开(公告)日：1993-06-01
申请号：US747597
申请日：1991-08-20
申请人： Joel R. Livingston, Jr. , Edmund J. Mozeleski , Guido Sartori
发明人： Joel R. Livingston, Jr. , Edmund J. Mozeleski , Guido Sartori
IPC分类号： B01J38/00 , B01J19/24 , B01J31/40 , B01J38/48 , C07B61/00 , C07C45/50 , C07C45/78 , C07C47/02
CPC分类号： B01J31/2404 , B01J19/2475 , B01J31/4038 , B01J31/4046 , B01J31/4053 , B01J31/4061 , B01J38/48 , C07C45/50 , C07C45/786 , B01J2231/321 , B01J2531/82 , B01J2531/822 , B01J2531/96 , B01J31/0215 , B01J31/0235 , B01J31/04 , Y02P20/584
摘要： A method for separating a water soluble Group VIII noble metal catalyst from the crude reaction product of a noble metal-catalyzed hydroformylation reaction run in aqueous solution, in an aqueous emulsion or as an aqueous suspension, the crude reaction product including an aqueous phase containing a water soluble Group VIII noble metal-ligand complex catalyst, and an organic phase containing unreacted olefin feed and an organic hydroformylation reaction product, which comprises: (a) contacting the crude reaction product with a hydrophobic membrane capable of allowing a substantial portion of the unreacted olefin feed and the organic hydroformylation reaction product to pass therethrough while retaining a substantial portion of the water soluble Group VIII noble metal-ligand complex catalyst; (b) removing unreacted olefin feed and organic hydroformylation reaction product which passes through the hydrophobic membrane as permeate; and (c) retaining the water soluble Group VIII noble metal-ligand complex catalyst as retentate.
摘要翻译：将水溶性VIII族贵金属催化剂与水溶液，水性乳液或水悬浮液中的贵金属催化加氢甲酰化反应的粗反应产物分离的方法，该粗制反应产物包括含有水溶性VIII族贵金属 - 配体配合物催化剂和含有未反应烯烃进料和有机加氢甲酰化反应产物的有机相，其包括：（a）使粗反应产物与能够允许大部分未反应的疏水膜接触烯烃进料和有机加氢甲酰化反应产物通过，同时保留大部分水溶性VIII族贵金属 - 配体配合物催化剂; （b）去除通过疏水膜作为渗透物的未反应烯烃进料和有机加氢甲酰化反应产物; 和（c）保留水溶性VIII族贵金属 - 配体配合物催化剂作为保留物。

5. 发明授权

US5395979A Method for separating catalyst from a hydroformylation reaction product using alkylated ligands 失效
标题翻译：使用烷基化配体从羰基化反应产物中分离催化剂的方法
公开(公告)号：US5395979A
公开(公告)日：1995-03-07
申请号：US23235
申请日：1993-02-25
申请人： Harry W. Deckman , Edward Kantner , Joel R. Livingston, Jr. , Michael G. Matturro , Edmund J. Mozeleski
发明人： Harry W. Deckman , Edward Kantner , Joel R. Livingston, Jr. , Michael G. Matturro , Edmund J. Mozeleski
IPC分类号： B01J31/24 , B01J31/40 , B01J38/48 , C07B61/00 , C07C45/50 , C07C47/02 , C07C45/78
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/4038 , B01J31/4046 , B01J31/4053 , B01J31/4061 , B01J38/48 , C07C45/50 , B01J2231/321 , B01J2531/80 , B01J2531/822 , Y02P20/584
摘要： A catalyst for use in hydroformylation of olefins which comprises a Group VIII noble metal complexed with a phosphine ligand having at least one alkyl or aryl group bonded thereto, such as tris-4-propylphenyl phosphines and tris-4-octylphenyl phosphines. These and other triphenylphosphine catalysts can be separated from a crude reaction product of a noble metal-catalyzed hydroformylation reaction by contacting the crude reaction product with a dense polymeric, nonpolar membrane, preferably nonpolar polyolefin membranes.
摘要翻译：用于烯烃加氢甲酰化的催化剂，其包含与其上键合有至少一个烷基或芳基的膦配体络合的VIII族贵金属，例如三-4-丙基苯基膦和三-4-辛基苯基膦。这些和其它三苯基膦催化剂可以通过使粗反应产物与致密的聚合非极性膜，优选非极性聚烯烃膜接触，从贵金属催化的加氢甲酰基化反应的粗反应产物中分离出来。

6. 发明授权

US5288818A Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction 失效
标题翻译：从贵金属催化加氢甲酰化反应中分离出水溶性贵金属催化剂的方法
公开(公告)号：US5288818A
公开(公告)日：1994-02-22
申请号：US32349
申请日：1993-03-16
申请人： Joel R. Livingston, Jr. , Edmund J. Mozeleski , Guido Sartori
发明人： Joel R. Livingston, Jr. , Edmund J. Mozeleski , Guido Sartori
IPC分类号： B01J8/00 , B01J19/24 , C07C45/50 , C07C45/78 , C07C45/80 , B01D61/14
CPC分类号： C07C45/80 , B01J19/2475 , B01J8/009 , C07C45/50 , C07C45/786
摘要： A method for separating a water soluble Group VIII noble metal catalyst from the crude reaction product of a noble metal-catalyzed hydroformylation reaction run in aqueous solution, in an aqueous emulsion or as an aqueous suspension, the crude reaction product including an aqueous phase containing a water soluble Group VIII noble metal-ligand complex catalyst, and an organic phase containing unreacted olefin feed and an organic hydroformylation reaction product, which comprises: (a) contacting the crude reaction product with a hydrophobic membrane capable of allowing a substantial portion of the unreacted olefin feed and the organic hydroformylation reaction product to pass therethrough while retaining a substantial portion of the water soluble Group VIII noble metal-ligand complex catalyst; (b) removing unreacted olefin feed and organic hydroformylation reaction product which passes through the hydrophobic membrane as permeate; and (c) retaining the water soluble Group VIII noble metal-ligand complex catalyst as retentate.
摘要翻译：将水溶性VIII族贵金属催化剂与水溶液，水性乳液或水悬浮液中的贵金属催化加氢甲酰化反应的粗反应产物分离的方法，该粗制反应产物包括含有水溶性VIII族贵金属 - 配体配合物催化剂和含有未反应烯烃进料和有机加氢甲酰化反应产物的有机相，其包括：（a）使粗反应产物与能够允许大部分未反应的疏水膜接触烯烃进料和有机加氢甲酰化反应产物通过，同时保留大部分水溶性VIII族贵金属 - 配体配合物催化剂; （b）去除通过疏水膜作为渗透物的未反应烯烃进料和有机加氢甲酰化反应产物; 和（c）保留水溶性VIII族贵金属 - 配体配合物催化剂作为保留物。

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