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1. 发明授权

US06129862A Composite oxides of A-site defect type perovskite structure 失效
标题翻译： A型缺陷型钙钛矿结构复合氧化物
公开(公告)号：US06129862A
公开(公告)日：2000-10-10
申请号：US971957
申请日：1997-11-17
申请人： Fumio Munakata , Hiroaki Kaneko , Takeshi Miyamoto
发明人： Fumio Munakata , Hiroaki Kaneko , Takeshi Miyamoto
IPC分类号： B01D53/94 , B01J23/00 , B01J23/83 , H01B1/02
CPC分类号： B01J23/83 , B01D53/945 , B01J23/002 , B01J2523/00 , Y02T10/22 , Y10S502/525
摘要： An electrode material is disclosed which includes: a composite oxide of an A-site defect perovskite structure represented by the following general formula(A'.sub.1-x A".sub.x).sub.1-y (B'.sub.1-y B".sub.y)O.sub.3-.delta.wherein A' is at least one element selected from the group consisting of La, Nd and Y, and A" is at least one element selected from the group consisting of Ba, Sr and Ca, and B' is Co and B" is at least one element selected from the group consisting of Mn, Fe, Ni and Cu, and 0.1.ltoreq..alpha.
摘要翻译：公开了一种电极材料，其包括：由以下通式（A'1-xA'x）1-y（B'1-yB''y）O3-表示的A位缺陷钙钛矿结构的复合氧化物，其中A'是选自La，Nd和Y中的至少一种元素，A“是选自Ba，Sr和Ca中的至少一种元素，B'是Co和B' '是选自由Mn，Fe，Ni和Cu组成的组中的至少一种元素，和0.1≤0.2,0<δ≤1,0

2. 发明授权

US6060420A Composite oxides of A-site defect type perovskite structure as catalysts 失效
标题翻译： A位缺陷型钙钛矿结构复合氧化物作为催化剂
公开(公告)号：US6060420A
公开(公告)日：2000-05-09
申请号：US536185
申请日：1995-09-29
申请人： Fumio Munakata , Hiroaki Kaneko , Takeshi Miyamoto
发明人： Fumio Munakata , Hiroaki Kaneko , Takeshi Miyamoto
IPC分类号： B01D53/94 , B01J23/00 , B01J23/83 , B01J23/32 , B01J23/40 , B01J23/42
CPC分类号： B01J23/83 , B01D53/945 , B01J23/002 , B01J2523/00 , Y02T10/22 , Y10S502/525
摘要： A novel composite oxide has an A-site defect type perovskite structure represented by a general formula:A.sub.1--.alpha. BO.sub.3--.delta.wherein A is at least one element selected from the group consisting of alkali metals, alkaline earth metals, rare earth elements, Y and Pb, and B is at least one element selected from the group consisting of Ti, Mn, Fe, Co, Ni, Cu and Al, and .alpha. is 0
摘要翻译：一种新型复合氧化物具有由以下通式表示的A位缺陷型钙钛矿结构：A1-αBB3-δ，其中A为选自碱金属，碱土金属，稀土元素，Y Pb，B为选自Ti，Mn，Fe，Co，Ni，Cu和Al中的至少一种元素，α为0 <α<0.2，δ为0 条件是只有已知的钙钛矿型氧化物（La1-xSrx）1-αMnO3-δ（当α为0.06时，x为0.08≤x≤0.30，而当x的值为0.11时，α为0.06 <α<0.11）被排除。

3. 发明授权

US5665176A n-Type thermoelectric materials 失效
标题翻译： n型热电材料
公开(公告)号：US5665176A
公开(公告)日：1997-09-09
申请号：US277820
申请日：1994-07-20
申请人： Kazuhiko Shinohara , Masakazu Kobayashi , Keiko Ikoma , Fumio Munakata
发明人： Kazuhiko Shinohara , Masakazu Kobayashi , Keiko Ikoma , Fumio Munakata
IPC分类号： H01L35/14 , H01L35/22 , H01L29/00
CPC分类号： H01L35/22 , Y10S257/93
摘要： An n-type thermoelectric material composed mainly of an iron-silicite compound represented by a chemical formula of FeSi.sub.2+z in which -0.1
摘要翻译：主要由化学式FeSi2 + z表示的铁 - 硅酸盐化合物组成的n型热电材料，其中-0.1

4. 发明授权

US07368095B2 Composite oxide for solid oxide fuel cell and method for preparation thereof 有权
标题翻译：固体氧化物燃料电池用复合氧化物及其制备方法
公开(公告)号：US07368095B2
公开(公告)日：2008-05-06
申请号：US10494372
申请日：2002-11-15
申请人： Fumio Munakata , Kenji Furuya , Masaharu Hatano , Yoshinori Fujie , Manabu Suhara
发明人： Fumio Munakata , Kenji Furuya , Masaharu Hatano , Yoshinori Fujie , Manabu Suhara
IPC分类号： C01B13/00 , C01B11/00 , H01M6/18 , H01M4/48
CPC分类号： C04B35/01 , C04B35/6262 , C04B35/6267 , C04B2235/3205 , C04B2235/3206 , C04B2235/3213 , C04B2235/3217 , C04B2235/3224 , C04B2235/3227 , C04B2235/3229 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3286 , C04B2235/449 , C04B2235/5436 , C04B2235/5445 , C04B2235/768 , C04B2235/81 , C04B2235/9607 , H01M4/8885 , H01M4/9033 , H01M8/1246 , H01M2008/1293 , Y02E60/525 , Y02P70/56
摘要： The present invention provides a composite oxide for a high performance solid oxide fuel cell which can be fired at a relatively low temperature, and which has little heterogeneous phases of impurities other than the desired composition. The composite oxide is the one having a perovskite type crystal structure containing rare earth elements, and having constituent elements homogeneously dispersed therein. A homogeneous composite oxide having an abundance ratio of heterogeneous phases of at most 0.3% by average area ratio, and a melting point of at least 1470° C., is obtained by using metal carbonates, oxides or hydroxides, and reacting them with citric acid in an aqueous system.
摘要翻译：本发明提供一种用于高性能固体氧化物燃料电池的复合氧化物，其可以在相对较低的温度下烧制，并且除了所需组合物之外几乎没有杂质的杂质相。复合氧化物是具有包含稀土元素的钙钛矿型晶体结构，并且具有均匀分散在其中的构成元素。通过使用金属碳酸盐，氧化物或氢氧化物，并使其与柠檬酸反应，获得具有至多0.3％平均面积比和熔点至少为1470℃的非均相的丰度比的均匀复合氧化物在水系统中。

5. 发明授权

US06447944B1 Solid electrolyte, method of producing same and fuel cell using same 有权
标题翻译：固体电解质，其制造方法和使用其的燃料电池
公开(公告)号：US06447944B1
公开(公告)日：2002-09-10
申请号：US09642652
申请日：2000-08-22
申请人： Yoshio Akimune , Mikiya Shinohara , Fumio Munakata
发明人： Yoshio Akimune , Mikiya Shinohara , Fumio Munakata
IPC分类号： H01M810
CPC分类号： H01M8/124 , C04B35/01 , C04B35/6262 , C04B35/62655 , C04B35/62675 , C04B2235/3206 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3284 , C04B2235/3286 , C04B2235/5436 , C04B2235/5445 , C04B2235/656 , C04B2235/6567 , C04B2235/786 , H01M8/1246 , H01M2300/0074 , Y02E60/525 , Y02P70/56
摘要： A solid electrolyte used in a cell and represented by the following formula: La(1−x−y)LnxAyGa(1−z)BzO3−0.5(x+y+z) where Ln is at least one element selected from the group consisting of Gd, Sm and Nd; A is Ba; B is Mg; x is 0.1; y is 0.1; and z is 0.2, wherein the solid electrolyte is formed of particles whose means diameter is within a range of from 4 to 10 &mgr;m, the solid electrolyte being produced by a method comprising: (a) mixing lanthanum oxide, gallium oxide, oxide of at least one rate earth element selected from the group consisting of Gd, Sm and Nd, barium oxide and magnesium oxide to form a mixture; (b) firing the mixture in air at a temperature ranging from 1100 to 1200° C. for a time ranging from 2 to 8 hours to accomplish synthesizing a compound material; (c) pulverizing the compound material; (d) compacting the pulverized compound material; (e) adjusting mean diameter of the pulverized compound material within a range of from 0.5 to 0.8 &mgr;m; and (f) sintering the compacting compound material in air at a temperature ranging from 1400 to 1500° C. for a time ranging from 2 to 8 hours to form the solid electrolyte.
摘要翻译：在电池中使用的由下式表示的固体电解质：其中Ln是选自Gd，Sm和Nd中的至少一种元素; A是Ba B是Mg; x为0.1; y为0.1; z为0.2，其中，所述固体电解质由其直径在4〜10μm的范围内的颗粒形成，所述固体电解质通过以下方法制造：（a）将氧化镧，氧化镓，选自Gd，Sm和Nd，氧化钡和氧化镁的至少一种速率的土元素以形成混合物; （b）将空气中的混合物在1100〜1200℃的温度下焙烧2〜8小时，以合成复合材料; （c）粉碎复合材料; （d）压碎粉碎的复合材料; （e）将粉碎的化合物材料的平均直径调节在0.5至0.8μm的范围内; 和（f）在空气中在1400〜1500℃的温度下烧结压实复合材料2至8小时以形成固体电解质。

6. 发明授权

US4786476A Gas sensor element using porously fired mass of titania 失效
标题翻译：气体传感器元件采用大量烧结的二氧化钛
公开(公告)号：US4786476A
公开(公告)日：1988-11-22
申请号：US886080
申请日：1986-07-16
申请人： Fumio Munakata , Masayuki Touda , Masaaki Uchida , Fumio Yukawa
发明人： Fumio Munakata , Masayuki Touda , Masaaki Uchida , Fumio Yukawa
IPC分类号： G01N27/12 , G01N27/46
CPC分类号： G01N27/12
摘要： The invention relates to a gas sensor element which utilizes a change in the electric resistance of a porously fired TiO.sub.2 layer. To improve the speed of response of the gas sensor element, and also to strengthen the adhesion of the fired TiO.sub.2 layer to a ceramic substrate, at least one kind of metal oxide which hardly undergoes solid phase reaction with TiO.sub.2 and serves as a sintering suppressing agent, such as Er.sub.2 O.sub.3, Sm.sub.2 O.sub.3 and/or In.sub.2 O.sub.3, is added to TiO.sub.2 in advance of firing. The speed of response is further enhanced by the addition of at least one kind of noble metal such as Pt and/or Rh to TiO.sub.2 together with the sintering suppressing oxide(s).
摘要翻译：本发明涉及一种气体传感器元件，其利用烧结TiO 2层的电阻的变化。为了提高气体传感器元件的响应速度，并且还增强了烧结的TiO 2层与陶瓷基板的粘附性，至少一种与TiO 2几乎不发生固相反应并用作烧结抑制剂的金属氧化物，例如Er 2 O 3，Sm 2 O 3和/或In 2 O 3。与烧结抑制氧化物一起添加至少一种贵金属如Pt和/或Rh至TiO 2，进一步提高了响应速度。

7. 发明授权

US06903495B2 Piezoelectric material and method for manufacture thereof 有权
标题翻译：压电材料及其制造方法
公开(公告)号：US06903495B2
公开(公告)日：2005-06-07
申请号：US10173975
申请日：2002-06-19
申请人： Yoshio Akimune , Fumio Munakata , Mikiya Shinohara
发明人： Yoshio Akimune , Fumio Munakata , Mikiya Shinohara
IPC分类号： C01G33/00 , C04B35/495 , H01L41/187 , H01L41/09
CPC分类号： C01G33/006 , C01P2004/62 , C01P2006/10 , C04B35/495 , C04B35/6262 , C04B35/62645 , C04B35/62675 , C04B35/6268 , C04B35/64 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3251 , C04B2235/3298 , C04B2235/442 , C04B2235/5445 , C04B2235/604 , C04B2235/656 , C04B2235/6567 , C04B2235/661 , C04B2235/77 , C04B2235/786 , H01L41/187
摘要： A piezoelectric material includes a polycrystalline piezoelectric compound having a component composition defined as Sr2-xCaxNaNb5O15, where x=0.05 to 0.35, and at least one rare earth oxide compound selected from the group consisting of Y2O3, La2O3, Dy2O3, Nd2O3, Yb2O3, Sm2O3, Er2O3, Gd2O3 and Pr6O11 to be added to the piezoelectric compound by 0.5 to 3.0 wt %. Moreover, a method of manufacturing the piezoelectric material includes blending ceramic materials, synthesizing, milling, pressing and sintering processes. In the synthesizing process, calcining is conducted at a temperature in a range from 1,050° C. to 1,150° C. for 2 to 12 hours in the atmosphere. And the sintering process includes first firing at temperature in a range from 1,180° C. to 1,270° C. for 4 to 8 hours in the atmosphere, and second firing at a temperature in a range from 1,370° C. to 1,400° C. for 10 to 75 hours in the atmosphere.
摘要翻译：压电材料包括具有定义为Sr 2-x Ca x Na 2 Nb 5 O 15的组分组成的多晶压电化合物， SUB>，其中x = 0.05至0.35，以及至少一种选自Y 2 O 3 O 3，La 2 O 3的稀土氧化物， N 2 O 3，N 2 O 3，N 2 O 3， Yb 2 O 3，Sm 2 O 3，O 2 O 3， > 3 ，Gd 2 O 3 3和Pr 6 O 11，加到压电化合物为0.5〜3.0重量％。此外，制造压电材料的方法包括混合陶瓷材料，合成，研磨，压制和烧结工艺。在合成过程中，在大气中，在1050℃〜1150℃的温度范围内进行煅烧2〜12小时。并且烧结过程包括在大气中首先在1180℃至1270℃的温度范围内烧制4至8小时，然后在1370℃至1,400℃的温度下进行第二次烧制。在大气中10至75小时。

8. 发明授权

US06849354B2 Solid oxide fuel cell having perovskite solid electrolytes 失效
标题翻译：具有钙钛矿固体电解质的固体氧化物燃料电池
公开(公告)号：US06849354B2
公开(公告)日：2005-02-01
申请号：US09897116
申请日：2001-07-03
申请人： Naoki Hara , Fumio Munakata , Yasukazu Iwasaki
发明人： Naoki Hara , Fumio Munakata , Yasukazu Iwasaki
IPC分类号： H01M8/02 , H01M8/12
CPC分类号： H01M8/1246 , H01M8/1253 , H01M8/126 , H01M2008/1293 , H01M2300/0094 , Y02E60/525 , Y02P70/56
摘要： A solid oxide fuel cell (SOFC) contains a first solid electrolyte layer of LaGa-based perovskite, an air electrode, a fuel electrode and a second solid electrolyte layer (having a hole transport number smaller than that of the first solid electrolyte layer), which is provided between the first solid electrolyte layer and an air electrode. Also, another SOFC contains a first solid electrolyte layer of LaGa-based perovskite, an air electrode, a fuel electrode and a third solid electrolyte layer (having electron and proton conductivity lower than that of the first solid electrolyte layer), which is provided between the first solid electrolyte layer and the fuel electrode. Still another SOFC contains the second solid electrolyte layer provided between a first solid electrolyte layer and an air electrode and the third solid electrolyte layer provided between the first solid electrolyte layer and a fuel electrode.
摘要翻译：固体氧化物型燃料电池（SOFC）含有LaGa系钙钛矿的第一固体电解质层，空气电极，燃料极和第二固体电解质层（空穴传输数小于第一固体电解质层的空穴传输数）其设置在第一固体电解质层和空气电极之间。此外，另一种SOFC包含LaGa系钙钛矿的第一固体电解质层，空气电极，燃料电极和第三固体电解质层（电子和质子传导性低于第一固体电解质层的电导率）第一固体电解质层和燃料电极。另一SOFC包含设置在第一固体电解质层和空气电极之间的第二固体电解质层和设置在第一固体电解质层和燃料电极之间的第三固体电解质层。

9. 发明授权

US06384607B2 Battery state sensing apparatus 失效
标题翻译：电池状态检测装置
公开(公告)号：US06384607B2
公开(公告)日：2002-05-07
申请号：US09796555
申请日：2001-03-02
申请人： Hideaki Horie , Osamu Shimamura , Takaaki Abe , Fumio Munakata
发明人： Hideaki Horie , Osamu Shimamura , Takaaki Abe , Fumio Munakata
IPC分类号： G01N27416
CPC分类号： H01M10/488 , H01M10/0525
摘要： A voltage-responsive optical sensing device such as a semiconductor device of a light emitting device and/or liquid crystal device of a sensing apparatus for sensing an excessive charge and/or excessive discharge state of a battery, such as a lithium ion secondary battery is incorporated into an inside of a cell of a cell group to form the battery. For example, with electrodes of the liquid crystal device connected in parallel to the cell and a light beam of an external light source introduced into the liquid crystal device, a photo sensor senses a change in a light-transmissive characteristic of the liquid crystal device so that the state of the cell constituting the battery can be sensed.
摘要翻译：诸如锂离子二次电池的电池的过度充电和/或过度放电状态的感测装置的发光装置和/或液晶装置的半导体装置等电压响应光感测装置，并入电池组的电池内部以形成电池。例如，通过与液晶装置并联连接的液晶装置的电极和引入液晶装置的外部光源的光束，光传感器检测到液晶装置的透光特性的变化，可以感测构成电池的电池的状态。

10. 发明申请

US20140147341A1 LAYERED COMPLEX OXIDE, OXIDATION CATALYST, AND DIESEL PARTICULATE FILTER 有权
标题翻译：层状复合氧化物，氧化催化剂和柴油颗粒过滤器
公开(公告)号：US20140147341A1
公开(公告)日：2014-05-29
申请号：US13881242
申请日：2011-10-03
申请人： Kohji Masuda , Fumio Munakata
发明人： Kohji Masuda , Fumio Munakata
IPC分类号： B01J23/889 , F01N3/28
CPC分类号： F01N3/2803 , B01D53/944 , B01D2255/204 , B01D2255/2063 , B01D2255/2073 , B01D2255/20738 , B01D2255/20761 , B01D2255/402 , B01D2255/65 , B01J23/007 , B01J23/8892 , B01J23/8946 , B01J35/004 , B01J37/0036 , B01J37/04 , B01J37/08 , B01J2523/00 , C01G45/1278 , C01G49/0072 , C01G51/60 , C01G53/60 , C01P2002/34 , C01P2002/54 , F01N3/035 , F01N2510/065 , F01N2510/0684 , H01M4/9025 , Y02E60/50 , Y02T10/22 , B01J2523/17 , B01J2523/24 , B01J2523/3706 , B01J2523/72 , B01J2523/842
摘要： A layered composite oxide is provided which is excellent in oxygen ion conductivity and, is capable of effectively decreasing a PM oxidation temperature without using a noble metal such as platinum or the like. The layered composite oxide is used in an oxidation catalyst, DPF, a ternary catalyst, and a NOx purification catalyst. The layered composite oxide has a composition represented by the following formula (1), La1.5Sr1.5Mn2-yByO7 . . . (1) (wherein B represents Cu and/or Fe, and y satisfies 0
摘要翻译：提供氧离子传导性优异的层状复合氧化物，能够在不使用铂等贵金属的情况下有效地降低PM氧化温度。层状复合氧化物用于氧化催化剂，DPF，三元催化剂和NOx净化催化剂。层状复合氧化物具有由下式（1）表示的组成，La 1.5 Sr 1.5 Mn 2-y B y O 7。。。（1）（其中B表示Cu和/或Fe，y满足0

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