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1. 发明授权

US4433179A Process for the preparation of di- and poly-allyl ethers 失效
标题翻译：制备二 - 和聚 - 烯丙基醚的方法
公开(公告)号：US4433179A
公开(公告)日：1984-02-21
申请号：US293810
申请日：1981-08-17
申请人： Friedrich Lohse , Charles E. Monnier
发明人： Friedrich Lohse , Charles E. Monnier
IPC分类号： C07B41/04 , B01J31/00 , C07B31/00 , C07B61/00 , C07C41/00 , C07C41/16 , C07C43/14 , C07C43/15 , C07C43/166 , C07C43/188 , C07C43/196 , C07C67/00
CPC分类号： C07C41/16 , C07C43/188 , C07C43/196 , C07C2101/14
摘要： A process for the preparation of allyl ethers of the formulaR--O--CH.sub.2 --CH.dbd.CH.sub.2).sub.nin which R and n are as defined in claim 1, by reacting hydroxy compounds of the formulaR--OH).sub.nwith allyl chloride or allyl bromide by phase transfer catalysis, 0.8 to 5 mols of allyl chloride or allyl bromide, 1 to 6 mols of aqueous or solid sodium hydroxide and, as the phase transfer catalyst, 2 to 20 mol % of a quaternary ammonium salt, a quaternary ammonium base or a crown ether being employed per hydroxyl equivalent of the compound of the formula II, and the reaction being carried out in the temperature range from 20.degree. to 100.degree. C.
摘要翻译：通过使式R-OH）n的羟基化合物与烯丙基氯或烯丙基溴反应制备式RO-CH2-CH = CH2）n的方法，其中R和n如权利要求1所定义相转移催化剂为0.8〜5摩尔烯丙基氯或烯丙基溴，1〜6摩尔的水性或固体氢氧化钠，相转移催化剂为2〜20摩尔％的季铵盐，季铵碱或每个羟基当量使用式II的化合物的冠醚，该反应在20℃至100℃的温度范围内进行。

2. 发明授权

US4412047A Cycloaliphatic diepoxide, its preparation and its use 失效
标题翻译：环脂族二环氧化物，其制备及其用途
公开(公告)号：US4412047A
公开(公告)日：1983-10-25
申请号：US419690
申请日：1982-09-20
申请人： Charles E. Monnier , Friedrich Lohse
发明人： Charles E. Monnier , Friedrich Lohse
IPC分类号： C07D493/04 , C08G59/00 , C08G59/20 , C08G59/24
CPC分类号： C07D493/04 , C08G59/24
摘要： 1,5-Dimethyl-1,2;5,6-diepoxycyclooctane is prepared by epoxidizing 1,5-dimethylcycloocta-1,5-diene with aqueous peracetic or perpropionic acid at a temperature not exceeding 50.degree. C. and within a pH range from 1.5 to 5.5.The diepoxide according to the invention can be cured by means of curing agents for epoxide resins to give moulded materials having valuable mechanical properties. It is also suitable for use as a reactive, latent diluent.
摘要翻译： 1,5-二甲基-1,2; 5,6-二环氧环辛烷是通过在不超过50℃的温度和pH范围内环氧化1,5-二甲基环辛-1,5-二烯与过乙酸或过丙酸水溶液制备的从1.5到5.5。根据本发明的二环氧化物可以通过环氧树脂的固化剂固化，得到具有有价值的机械性能的模塑材料。它也适合用作反应性潜在稀释剂。

3. 发明授权

US4649181A Glycidyloxy diketones 失效
标题翻译：糖基氧基二酮
公开(公告)号：US4649181A
公开(公告)日：1987-03-10
申请号：US718575
申请日：1985-04-01
申请人： Roland Darms , Charles E. Monnier
发明人： Roland Darms , Charles E. Monnier
IPC分类号： C07D303/32 , C07B61/00 , C07D301/28 , C07D303/24 , C07D303/27 , C08G59/00 , C08G59/20 , C08G59/24 , C08G59/30 , C08G59/32 , C08F283/00
CPC分类号： C08G59/3218 , C07D303/24 , C08G59/245
摘要： Novel glycidyloxy diketones of the formula I ##STR1## (in which, for example, X is glycidyloxy, Y is H and R is 1,3-phenylene) are described.The compounds of the formula can be used together with customary curing agents and/or curing catalysts for the preparation of crosslinked (cured) products which have good thermal and mechanical properties.
摘要翻译：描述了式I的新型缩水甘油氧基二酮（I）（其中，例如，X是缩水甘油氧基，Y是H，R是1,3-亚苯基）。式的化合物可以与常规固化剂和/或固化催化剂一起使用，用于制备具有良好热和机械性能的交联（固化）产物。

4. 发明授权

US4609741A Phthalic acid derivatives which are substituted by 2-propynyloxy groups, processes for their preparation and their use 失效
标题翻译：被2-丙炔氧基取代的邻苯二甲酸衍生物，其制备方法及其应用
公开(公告)号：US4609741A
公开(公告)日：1986-09-02
申请号：US639048
申请日：1984-08-09
申请人： Roland Darms , Vratislav Kvita , Charles E. Monnier
发明人： Roland Darms , Vratislav Kvita , Charles E. Monnier
IPC分类号： C07C51/00 , C07C51/06 , C07C65/21 , C07C65/28 , C07C65/40 , C07C67/00 , C07D209/48 , C08G59/00 , C08G59/42 , C07D307/89
CPC分类号： C07D209/48 , C07C65/28 , C07C65/40
摘要： Novel phthalic acid derivatives are described which are substituted by 2-propynyloxy groups, of the formula I ##STR1## in which Q.sub.1, and Q.sub.2 independently of one another are --OH or --O.sup.- M.sup.+, or Q.sub.1 and Q.sub.2 together form the grouping --O--, [O.sup.- ].sub.2 M.sub.1.sup.++ or --N(R.sub.2)--, M.sup.+ is an alkali metal ion, a trialkyl ammonium ion having 3-24 carbon atoms or a quaternary ammonium ion and M.sub.1.sup.++ is an alkaline earth metal ion, R.sub.2 is an alkyl group or an unsubstituted or substituted aryl group, n is 1 or 2 and R.sub.1 is hydrogen, if n is 1, or a direct bond, if n is 2, are described. The phthalic anhydrides which are substituted by 2-propynyloxy, of the formula I, can be used for curing epoxy resins, cured products with outstanding physical properties being obtained.
摘要翻译：描述了新的邻苯二甲酸衍生物，它们被2-丙炔氧基取代，其中Q 1和Q 2彼此独立地是-OH或-O-M +，或者Q 1和Q 2一起形成分组-O-，[O-] 2M1 ++或-N（R2） - ，M +是碱金属离子，具有3-24个碳原子的三烷基铵离子或季铵离子，M1 ++是碱土金属离子， R2为烷基或未取代或取代的芳基，n为1或2，R1为氢，n为1时，n为2时为直接键。由式I的2-丙炔氧基取代的邻苯二甲酸酐可用于固化环氧树脂，获得具有优异物理性能的固化产物。

5. 发明授权

US4908423A Advanced epoxide resins based on cyclohex-1-ylmethylenediphenol derivatives or bicyclo[2.2.1]hept-1-ylmethylenediphenol derivatives 失效
标题翻译：基于环己-1-基亚甲基二酚衍生物或双环[2.2.1]庚-1-基亚甲基二苯酚衍生物的高级环氧树脂
公开(公告)号：US4908423A
公开(公告)日：1990-03-13
申请号：US270995
申请日：1988-11-14
申请人： Martin Roth , Charles E. Monnier
发明人： Martin Roth , Charles E. Monnier
IPC分类号： C07D303/24 , C07D303/28 , C08G59/06 , C08G59/20 , C08G59/24 , C08G59/32
CPC分类号： C07D303/28 , C07D303/24 , C08G59/066 , C08G59/24 , C08G59/3218
摘要： The invention relates to compounds of the formula I or II ##STR1## in which A is a radical ##STR2## R.sup.1 is hydrogen or methyl, R.sup.2 is the radical of an aliphatic, cycloaliphatic, aromatic or araliphatic diol after both of the hydroxyl groups have been removed, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another are hydrogen, C.sub.1 -C.sub.6 alkyl, chlorine or bromine, R.sup.7 is a radical of the formula III, IV, V or VI ##STR3## R.sup.8, R.sup.10, R.sup.12 and R.sup.14 are hydrogen, C.sub.1 -C.sub.6 alkyl or phenyl, R.sup.9, R.sup.11, R.sup.13 and R.sup.15 are hydrogen or C.sub.1 -C.sub.6 alkyl and the average value of n (number average) is a number from 1 to 20, it being possible for the radicals R.sup.1 to R.sup.15, within a given molecule, to assume different meanings within the scope of the definitions given.These compounds or also the epoxidized intermediates of the formula X ##STR4## in which R.sup.1 to R.sup.3 are as defined above and R.sup.7 is a radical of the formula IV or VI can be processed to give cured products having a high glass transition temperature and a low tendency to discoloration.

6. 发明授权

US4808740A So-called advanced epoxide resins based on cyclohex-1-ylmethylenediphenol derivatives or bicyclo(2.2.1)hept-1-ylmethylenediphenol derivatives 失效
标题翻译：基于环己-1-基亚甲基二酚衍生物或双环（2.2.1）庚-1-基亚甲基二苯酚衍生物的所谓先进环氧树脂
公开(公告)号：US4808740A
公开(公告)日：1989-02-28
申请号：US147389
申请日：1988-01-25
申请人： Martin Roth , Charles E. Monnier
发明人： Martin Roth , Charles E. Monnier
IPC分类号： C07D303/24 , C07D303/28 , C08G59/06 , C08G59/20 , C08G59/24 , C08G59/32 , C08G59/02
CPC分类号： C07D303/28 , C07D303/24 , C08G59/066 , C08G59/24 , C08G59/3218
摘要： The invention relates to compounds of the formula I or II ##STR1## in which A is a radical ##STR2## R.sup.1 is hydrogen or methyl, R.sup.2 is the radical of an aliphatic, cycloaliphatic, aromatic or araliphatic diol after both of the hydroxyl groups have been removed, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another are hydrogen, C.sub.1 -C.sub.6 alkyl, chlorine or bromine, R.sup.7 is a radical of the formula III, IV, V or VI ##STR3## R.sup.8, R.sup.10, R.sup.12 and R.sup.14 are hydrogen, C.sub.1 -C.sub.6 alkyl or phenyl, R.sup.9, R.sup.11, R.sup.13 and R.sup.15 are hydrogen or C.sub.1 -C.sub.6 alkyl and the average value of n (number average) is a number from 1 to 20, it being possible for the radicals R.sup.1 to R.sup.15, within a given molecule, to assume different meanings within the scope of the definitions given.These compounds or also the epoxidized intermediates of the formula X ##STR4## in which R.sup.1 to R.sup.3 are defined above and R.sup.7 is a radical of the formula IV or VI can be processed to give cured products having a high glass transition temperature and a low tendency to discoloration.
摘要翻译：本发明涉及式Ⅰ或Ⅱ的化合物，其中A是一个基团，其中R 1是（R 1，R 2，R 3，氢或甲基，R2是除去羟基之后脂族，脂环族，芳族或芳脂族二醇的基团，R3，R4，R5和R6彼此独立地是氢，C1-C6烷基，氯或溴，（VI）R8是R 1，R 2，R 2和R 14是氢，C 1 -C 6烷基， C 6烷基或苯基，R 9，R 11，R 13和R 15是氢或C 1 -C 6烷基，n（数均）的平均值为1至20的数，在给定的分子内可以为基团R 1至R 15，在给定的定义范围内承担不同的含义。这些化合物或者其中R 1至R 3如上所定义并且R 7为式Ⅳ或Ⅵ基团的式ⅩⅩⅩⅥ的环氧化中间体可加工得到具有高玻璃化度的固化产物转变温度和变色偏低。

7. 发明授权

US4677170A Polyepoxides and the use thereof 失效
标题翻译：聚环氧化物及其用途
公开(公告)号：US4677170A
公开(公告)日：1987-06-30
申请号：US870608
申请日：1986-06-04
申请人： Charles E. Monnier , Sheik Abdul-Cader Zahir
发明人： Charles E. Monnier , Sheik Abdul-Cader Zahir
IPC分类号： C07D303/18 , C07D303/22 , C07D303/24 , C08G59/00 , C08G59/02 , C08G59/06 , C08G59/20 , C08G59/32
CPC分类号： C07D303/22 , C07D303/24 , C08G59/02 , C08G59/066 , C08G59/3218
摘要： The invention relates to polyepoxides which are obtainable by reacting compounds of formula I ##STR1## wherein n is 1 or 2, and X, if n is 1, is a group R.sub.3, or, if n is 2, X is a group of the formula ##STR2## each of R.sub.1 and R.sub.3 independently of the other is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, allyl, a halogen atom or C.sub.6 -C.sub.10 aryl and R.sub.2 is allyl, 1-propenyl or 2-propenyl, with compounds containing phenolic OH groups, and subsequently epoxidizing the resultant adducts in the presence of a peracid. Said polyepoxides can be used, together with customary epoxy resin hardeners, for the preparation of cured products, in particular for coating electronic components, or as adhesives.
摘要翻译：本发明涉及可通过使其中n为1或2的式I的化合物（I）和如果n为1的基团R3与X反应得到的聚环氧化物，或者如果n为2，则X为 R1和R3各自独立地是C1-C4烷基，C1-C4烷氧基，烯丙基，卤素原子或C6-C10芳基，R2是烯丙基，1-丙烯基或2-丙烯基，其中含有酚OH基团，随后在过酸存在下将所得加合物环氧化。所述聚环氧化物可与常规环氧树脂固化剂一起用于制备固化产物，特别是用于涂覆电子部件或作为粘合剂。

8. 发明授权

US4789711A Multifunctional epoxide resins 失效
标题翻译：多功能环氧树脂
公开(公告)号：US4789711A
公开(公告)日：1988-12-06
申请号：US124200
申请日：1987-11-23
申请人： Charles E. Monnier , Sameer H. Eldin , Peter Flury
发明人： Charles E. Monnier , Sameer H. Eldin , Peter Flury
IPC分类号： C08G59/08 , C07D303/24 , C07D303/27 , C07D303/28 , C08G59/02 , C08G59/32
CPC分类号： C08G59/3218 , C07D303/24 , C07D303/28 , C08G59/02
摘要： The invention relates to compounds of the formula I ##STR1## in which A is a group ##STR2## R.sup.1 is hydrogen or methyl R.sup.2 is C.sub.1 -C.sub.6 -alkyl, halogen or phenyl,X is a direct C--C bond, --CH.sub.2 -- or --SO.sub.2 --,m is 0, 1, 2 or 3, n is 0, 1 or 2 andp is 0 or, in the case of X=--CH.sub.2 --, can also be an integer from 1 to 6, with the proviso that the groups --A and --O--A are in the ortho-position relative to one another.The compounds can preferably be used as matrix resins for composite materials.The invention also relates to the allyl glycidyl ether intermediates, from which the compounds of the formula I are as a rule prepared by epoxidation with peracids.
摘要翻译：本发明涉及式Ⅰ化合物，其中A是一个基团，R 1是氢或甲基，R 2是C 1 -C 6 - 烷基，卤素或苯基，X是直接的CC键，-CH 2 - 或-SO 2 - ，m为0,1,2或3，n为0,1或2，p为0或在X = -CH 2 - 的情况下，也可为1至6的整数，与条件是基团-A和-OA相对于彼此位于邻位。该化合物可优选用作复合材料的基质树脂。本发明还涉及烯丙基缩水甘油醚中间体，其中通式I的化合物通过用过酸环氧化制备。

9. 发明授权

US4754003A Phenol ethers containing epoxide groups 失效
标题翻译：含有环氧基团的酚醚
公开(公告)号：US4754003A
公开(公告)日：1988-06-28
申请号：US38575
申请日：1987-04-15
申请人： Charles E. Monnier , Martin Roth
发明人： Charles E. Monnier , Martin Roth
IPC分类号： H01L23/29 , C08G59/02 , C08G59/08 , C08G59/20 , C08G59/32 , C08G59/38 , H01B3/40 , H01L23/31 , C08G8/28 , C08G8/36 , C08G59/24
CPC分类号： H01B3/40 , C08G59/02 , C08G59/3218 , C08G59/38
摘要： Novel epoxidised phenol ethers of formula I ##STR1## are described wherein R.sup.1 denotes C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.9 cycloalkyl or C.sub.7 -C.sub.14 aralkyl, R.sup.2 has one of the meanings of R.sup.1 or is, in addition hydrogen or a radical or formula II ##STR2## R.sup.3 denotes C.sub.1 -C.sub.6 alkyl or halogen, R.sup.4 and R.sup.5 denotes hydrogen or C.sub.1 -C.sub.6 alkyl, R.sup.6 denotes hydrogen or methyl, m is 0, 1 or 2 and n is an integer from 0 to 30, with the proviso that at least two radicals, R.sup.2, must be epoxide groups of formula II. The compounds are especially suitable for encasing electronic components.
摘要翻译：描述了式I的新型环氧化酚醚（I），其中R1表示C1-C20烷基，C5-C9环烷基或C7-C14芳烷基，R2具有R1的含义之一，或另外是氢或基团或式II （II）R3表示C1-C6烷基或卤素，R4和R5表示氢或C1-C6烷基，R6表示氢或甲基，m表示0,1或2，n表示0至30的整数，条件是至少两个基团R2必须是式II的环氧基团。这些化合物特别适用于包装电子元件。

10. 发明授权

US4724031A 2,6-disubstituted 4-epoxypropylphenyl glycidyl ethers and the use thereof 失效
标题翻译： 2,6-二取代的4-环氧丙基苯基缩水甘油醚及其用途
公开(公告)号：US4724031A
公开(公告)日：1988-02-09
申请号：US870607
申请日：1986-06-04
申请人： Charles E. Monnier , Sheik Abdul-Cader Zahir , Sameer H. Eldin
发明人： Charles E. Monnier , Sheik Abdul-Cader Zahir , Sameer H. Eldin
IPC分类号： C07B61/00 , C07D301/14 , C07D303/28 , C08G59/00 , C08G59/02 , C08G59/32 , C08G59/24
CPC分类号： C08G59/3218 , C07D303/28
摘要： 2,6-Disubstituted 4-epoxypropyl glycidyl ethers of the formula ##STR1## wherein X is a group R' or X is a group of the formula ##STR2## and each of R and R' independently of the other is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, a halogen atom or C.sub.6 -C.sub.10 aryl, can be used, together with customary epoxy resin hardeners, for the preparation of cured products, in particular for application in the electronics industry, or as adhesives. Compounds of the formula are also valuable reactive diluents for curable epoxy resin mixtures.
摘要翻译：式（I）的2,6-二取代的4-环氧丙基缩水甘油醚，其中X是基团R'或X是式“IMAGE”的基团，R和R'各自独立地为C1 -C4烷基，C1-C4烷氧基，卤素原子或C6-C10芳基，可与常规环氧树脂硬化剂一起用于制备固化产物，特别是用于电子工业或作为粘合剂。式的化合物也是可固化环氧树脂混合物的有价值的反应性稀释剂。

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