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1. 发明申请

US20080274033A1 Methods of generating hydrogen with nitrogen-containing hydrogen storage materials 审中-公开
标题翻译：用含氮储氢材料生成氢的方法
公开(公告)号：US20080274033A1
公开(公告)日：2008-11-06
申请号：US11743826
申请日：2007-05-03
申请人： Gregory P. Meisner , Aimee G. Bailey , Michael P. Balogh , Frederick E. Pinkerton , Martin S. Meyer
发明人： Gregory P. Meisner , Aimee G. Bailey , Michael P. Balogh , Frederick E. Pinkerton , Martin S. Meyer
IPC分类号： C01B21/00 , C01B3/02
CPC分类号： C01B3/065 , C01B6/04 , C01B6/21 , C01C1/026 , Y02E60/327 , Y02E60/362 , Y02E60/364
摘要： Methods of generating hydrogen-containing streams having a minimal concentration of gaseous reactive nitrogen-containing compounds, e.g., ammonia, are provided. Hydrogen storage material systems are also provided that generate such hydrogen-containing streams. A first composition comprising a nitride, a second composition comprising a hydride, and a third composition having a cation selected from the group consisting of: alkali metals, alkaline earth metals, and mixtures thereof are combined together. The hydrogen-containing stream thus generated has a minimal concentration of gaseous reactive nitrogen-containing compounds.
摘要翻译：提供了产生具有最小浓度的气态反应性含氮化合物例如氨的含氢气流的方法。还提供了产生这种含氢流的储氢材料体系。包含氮化物的第一组合物，包含氢化物的第二组合物和具有选自碱金属，碱土金属及其混合物的阳离子的第三组合物组合在一起。由此产生的含氢气流具有最小浓度的气态反应性含氮化合物。

2. 发明授权

US07314579B2 Hydrogen generation material 失效
标题翻译：氢发生材料
公开(公告)号：US07314579B2
公开(公告)日：2008-01-01
申请号：US11231543
申请日：2005-09-21
申请人： Frederick E. Pinkerton , Michael P. Balogh , Martin S. Meyer , Gregory P. Meisner
发明人： Frederick E. Pinkerton , Michael P. Balogh , Martin S. Meyer , Gregory P. Meisner
IPC分类号： C09K3/00
CPC分类号： C01B21/092 , C01B3/001 , C01B3/0031 , C01B21/08 , C01B21/0923 , C01P2002/72 , C01P2002/88 , Y02E60/327 , Y02E60/364
摘要： The dispersion of metal-element containing additives with hydrogen storage particles of the family of hydrogen-rich materials, M′xM″yNzHd as specified herein, markedly lowers the temperature at which hydrogen is removed from the particles. For example, the dispersion of additives containing one or more of iron, nickel, palladium, or platinum with particles of Li50B17N33H133 provides a composition from which hydrogen is readily removed by heating. Use of these metals as their chloride salts makes particularly effective hydrogen release additives.
摘要翻译：含有金属元素的添加剂与富氢材料族的储氢颗粒的分散体，M'，X“M” 如本文所述，显着降低从颗粒中除去氢的温度。例如，将含有一种或多种铁，镍，钯或铂的添加剂的分散体与Li 50 B 13 N 33 提供了通过加热容易地除去氢的组合物。使用这些金属作为它们的氯化物盐使得特别有效的氢释放添加剂。

3. 发明授权

US06967012B2 Imide/amide hydrogen storage materials and methods 失效
标题翻译：酰亚胺/酰胺储氢材料及方法
公开(公告)号：US06967012B2
公开(公告)日：2005-11-22
申请号：US10603474
申请日：2003-06-25
申请人： Gregory P. Meisner , Frederick E. Pinkerton , Martin S. Meyer , Michael P. Balogh , Matthew D. Kundrat
发明人： Gregory P. Meisner , Frederick E. Pinkerton , Martin S. Meyer , Michael P. Balogh , Matthew D. Kundrat
IPC分类号： C01B3/00 , C01B21/092 , C01B6/02 , C01B6/04 , C01B6/06 , C01B6/24
CPC分类号： C01B3/001 , C01B21/0926 , Y02E60/324 , Y02E60/364
摘要： In one aspect, the invention provides a hydrogen storage composition having a hydrogenated state and a dehydrogenated state. In the hydrogenated state, such composition comprises an amide and a hydride. In a dehydrogenated state, the composition comprises an imide.
摘要翻译：一方面，本发明提供具有氢化状态和脱氢状态的储氢组合物。在氢化状态下，这种组合物包含酰胺和氢化物。在脱氢状态下，组合物包含酰亚胺。

4. 发明授权

US07462344B2 Methods for reversibly storing hydrogen 失效
标题翻译：氢可逆储存方法
公开(公告)号：US07462344B2
公开(公告)日：2008-12-09
申请号：US11758114
申请日：2007-06-05
申请人： John J. Vajo , Florian O. Mertens , Sky Skeith , Michael P. Balogh , Frederick E. Pinkerton , Martin S. Meyer
发明人： John J. Vajo , Florian O. Mertens , Sky Skeith , Michael P. Balogh , Frederick E. Pinkerton , Martin S. Meyer
IPC分类号： C01B3/02 , C01B6/00 , C01B6/04
CPC分类号： C01B3/0078 , C01B3/0026 , C01B3/0031 , C01B3/065 , Y02E60/327 , Y02E60/362
摘要： The invention provides a method of reversibly storing hydrogen at industrially practicable temperature and pressure conditions. A stable hydrogen storage hydride is mixed with a destabilizing hydride. The stable hydride is capable of releasing hydrogen at a first energy level. When the stable hydride is in the presence of the destabilizing hydride, the stable hydride releases hydrogen at a second energy level. The second energy level is significantly reduced from the first energy level.
摘要翻译：本发明提供了一种在工业上可行的温度和压力条件下可逆地储存氢的方法。将稳定的储氢氢化物与不稳定的氢化物混合。稳定的氢化物能够在第一能级释放氢。当稳定的氢化物存在不稳定的氢化物时，稳定的氢化物在第二能级释放氢。第二个能源水平从第一个能源水平显着降低。

5. 发明申请

US20120285583A1 CERIUM BASED PERMANENT MAGNET MATERIAL 审中-公开
标题翻译：基于CERIUM的永久磁铁材料
公开(公告)号：US20120285583A1
公开(公告)日：2012-11-15
申请号：US13367427
申请日：2012-02-07
申请人： Martin S. Meyer , Jan F. Herbst , Frederick E. Pinkerton
发明人： Martin S. Meyer , Jan F. Herbst , Frederick E. Pinkerton
IPC分类号： C21D6/00 , H01F1/053 , C22C38/00
CPC分类号： C22F1/002 , B22F1/0018 , B22F9/04 , B22F2009/048 , B22F2998/10 , C22C33/003 , C22C38/002 , C22C38/005 , C22C45/02 , C22C2202/02 , H01F1/0571 , H01F1/0576 , H01F1/0578 , B22F9/002 , B22F1/0085
摘要： Useful permanent magnet materials are formed by processing molten alloys of cerium, iron, and boron to form permanent magnet compositions with appreciable coercivity and remanence. For example, Ce16.7Fe77.8B5.6 has been produced with coercivity, Hci of 6.18 kOe and remanence, Br of 4.92 kG. In one practice, streams of the molten alloy are rapidly quenched (e.g., by melt spinning) to form magnetically-soft melt-spun material which is suitably annealed to obtain permanent magnet properties. In another practice, the streams of molten alloy are quenched at a predetermined quench rate to directly obtain permanent magnet properties in the cerium-iron-boron material.
摘要翻译：通过加工铈，铁和硼的熔融合金形成有用的永磁材料，以形成具有可观的矫顽力和剩磁性的永磁体组合物。例如，Ce16.7Fe77.8B5.6已经生产出矫顽力，Hci为6.18 kOe和剩磁，Br为4.92 kG。在一个实践中，熔融合金的流被快速淬火（例如通过熔融纺丝）以形成适当退火的磁软熔融材料，以获得永磁体性能。在另一个实践中，熔融合金流以预定的淬火速率淬火以直接获得铈 - 铁 - 硼材料中的永磁体性质。

6. 发明申请

US20120225008A1 MITIGATING DIBORANE RELEASE FROM BOROHYDRIDE-BASED HYDROGEN STORAGE MATERIALS 有权
标题翻译：从基于硼氢化物的储氢材料中缓解二氧化硅释放
公开(公告)号：US20120225008A1
公开(公告)日：2012-09-06
申请号：US13038520
申请日：2011-03-02
申请人： Frederick E. Pinkerton
发明人： Frederick E. Pinkerton
IPC分类号： C01B3/04
CPC分类号： C01B3/001 , C01B3/0078 , C01B3/04 , Y02E60/324 , Y02E60/364
摘要： A method is disclosed for storing and releasing hydrogen from a mass of transition metal borohydride particles, or a mass of mixed, transition metal and alkali metal-containing, borohydride particles where hydrogen is to be released by heating the mass of particles upon a demand for hydrogen in a hydrogen-using application. Particles of a metal hydride are mixed with the metal borohydride particles to form a mass of hydrogen storage particles. The composition and amount of the metal hydride mixed into the hydrogen storage particles serves to react with boron from the borohydride particles to form a metal boride and to suppress release of diborane as hydrogen is released from the heated metal borohydride particles.
摘要翻译：公开了一种用于从大量过渡金属硼氢化物颗粒或大量混合的过渡金属和含碱金属的硼氢化物颗粒中储存和释放氢的方法，其中通过根据需要加热颗粒物质来释放氢气氢在使用氢的应用中。将金属氢化物的颗粒与金属硼氢化物颗粒混合以形成大量的储氢颗粒。混入储氢颗粒中的金属氢化物的组成和用量与硼氢化物颗粒中的硼反应，形成金属硼化物，并抑制从加热的金属硼氢化物颗粒中释放氢而释放乙硼烷。

7. 发明申请

US20130118913A1 ELECTROCHEMICAL PROCESS AND DEVICE FOR HYDROGEN GENERATION AND STORAGE 失效
标题翻译：电化学过程和氢生成和储存装置
公开(公告)号：US20130118913A1
公开(公告)日：2013-05-16
申请号：US13293432
申请日：2011-11-10
申请人： John J. Vajo , Wen Li , Ping Liu , Frederick E. Pinkerton
发明人： John J. Vajo , Wen Li , Ping Liu , Frederick E. Pinkerton
IPC分类号： C25B1/02 , C25B11/04
CPC分类号： C25B1/02 , C25D11/04 , H01M8/04216 , H01M8/0656
摘要： Both the reaction of hydride-forming compositions with hydrogen to form hydrides, and the decomposition of such hydrides to release hydrogen may be promoted electrochemically. These reactions may be conducted reversibly, and if performed in a suitable cell, the cell will serve as a hydrogen storage and release device.
摘要翻译：氢化物形成组合物与氢形成氢化物的反应以及这种氢化物分解以释放氢，可以电化学地促进。这些反应可以可逆地进行，并且如果在合适的电池中进行，则电池将用作储氢和释放装置。

8. 发明授权

US5395459A Method for forming samarium-iron-nitride magnet alloys 失效
标题翻译：形成钐 - 铁 - 氮化物磁体合金的方法
公开(公告)号：US5395459A
公开(公告)日：1995-03-07
申请号：US154678
申请日：1993-11-18
申请人： Frederick E. Pinkerton , Carlton D. Fuerst
发明人： Frederick E. Pinkerton , Carlton D. Fuerst
IPC分类号： H01F1/059 , H01F1/02
CPC分类号： H01F1/059
摘要： In a preferred method, a molten alloy of samarium and iron is formed with a proportion of about 1:4 to about 1:9 of samarium to iron. The molten alloy is then quenched in a non-oxidizing environment at a rate sufficient to form a solid crystalline alloy in the form of a thin ribbon. The ribbon is comminuted to form a powder and the powder is nitrided in a gaseous nitrogen atmosphere. Nitriding causes nitrogen to penetrate and occupy interstitial sites in the Sm-Fe alloy, producing a magnetically hard powder with a high coercivity typically 10 kOe, usually greater than 15 kOe and as high as about 20 to about 23 kOe.
摘要翻译：在优选的方法中，钐和铁的熔融合金以约1:4至约1:9的钐与铁的比例形成。熔融合金然后在非氧化环境中以足以形成薄带形式的固体结晶合金的速率淬火。将带粉碎以形成粉末，并将粉末在氮气气氛中氮化。氮化导致氮气穿透并占据Sm-Fe合金中的间隙位置，产生具有高矫顽力的磁性硬质粉末，通常为10kOe，通常大于15kOe，高达约20至约23kOe。

9. 发明授权

US4741464A Multiple orifice nozzle for jet casting rapidly solidified molten metal 失效
标题翻译：用于喷射铸造的多孔喷嘴快速固化熔融金属
公开(公告)号：US4741464A
公开(公告)日：1988-05-03
申请号：US866257
申请日：1986-05-23
申请人： Frederick E. Pinkerton
发明人： Frederick E. Pinkerton
IPC分类号： B22D11/06 , B22D11/10
CPC分类号： B22D11/0642
摘要： A stopper rod which has a plug at one end fits snugly into the inside of the nozzle having multiple ejection orifices. The plug is provided with at least one slot or opening which can be located directly over a selected orifice to allow passage of molten metal therethrough. When erosion occurs, the plug is indexed to locate the opening over a different, uneroded orifice.
摘要翻译：在一端具有塞子的塞杆紧密地配合到具有多个喷射口的喷嘴的内部。插头设置有至少一个狭槽或开口，其可以直接位于选定的孔上方，以允许熔融金属通过其中。当发生侵蚀时，塞子被索引以将开口定位在不同的未编码的孔口上。

10. 发明授权

US09145296B2 Mitigating diborane release from borohydride-based hydrogen storage materials 有权
标题翻译：缓解硼氢化物储氢材料中乙硼烷的释放
公开(公告)号：US09145296B2
公开(公告)日：2015-09-29
申请号：US13038520
申请日：2011-03-02
申请人： Frederick E. Pinkerton
发明人： Frederick E. Pinkerton
IPC分类号： C01B3/00 , C01B3/04
CPC分类号： C01B3/001 , C01B3/0078 , C01B3/04 , Y02E60/324 , Y02E60/364
摘要： A method is disclosed for storing and releasing hydrogen from a mass of transition metal borohydride particles, or a mass of mixed, transition metal and alkali metal-containing, borohydride particles where hydrogen is to be released by heating the mass of particles upon a demand for hydrogen in a hydrogen-using application. Particles of a metal hydride are mixed with the metal borohydride particles to form a mass of hydrogen storage particles. The composition and amount of the metal hydride mixed into the hydrogen storage particles serves to react with boron from the borohydride particles to form a metal boride and to suppress release of diborane as hydrogen is released from the heated metal borohydride particles.
摘要翻译：公开了一种用于从大量过渡金属硼氢化物颗粒或大量混合的过渡金属和含碱金属的硼氢化物颗粒中储存和释放氢的方法，其中通过根据需要加热颗粒物质来释放氢气氢在使用氢的应用中。将金属氢化物的颗粒与金属硼氢化物颗粒混合以形成大量的储氢颗粒。混入储氢颗粒中的金属氢化物的组成和用量与硼氢化物颗粒中的硼反应，形成金属硼化物，并抑制从加热的金属硼氢化物颗粒中释放氢而释放乙硼烷。

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