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    • 7. 发明授权
    • Mitigating diborane release from borohydride-based hydrogen storage materials
    • 缓解硼氢化物储氢材料中乙硼烷的释放
    • US09145296B2
    • 2015-09-29
    • US13038520
    • 2011-03-02
    • Frederick E. Pinkerton
    • Frederick E. Pinkerton
    • C01B3/00C01B3/04
    • C01B3/001C01B3/0078C01B3/04Y02E60/324Y02E60/364
    • A method is disclosed for storing and releasing hydrogen from a mass of transition metal borohydride particles, or a mass of mixed, transition metal and alkali metal-containing, borohydride particles where hydrogen is to be released by heating the mass of particles upon a demand for hydrogen in a hydrogen-using application. Particles of a metal hydride are mixed with the metal borohydride particles to form a mass of hydrogen storage particles. The composition and amount of the metal hydride mixed into the hydrogen storage particles serves to react with boron from the borohydride particles to form a metal boride and to suppress release of diborane as hydrogen is released from the heated metal borohydride particles.
    • 公开了一种用于从大量过渡金属硼氢化物颗粒或大量混合的过渡金属和含碱金属的硼氢化物颗粒中储存和释放氢的方法,其中通过根据需要加热颗粒物质来释放氢气 氢在使用氢的应用中。 将金属氢化物的颗粒与金属硼氢化物颗粒混合以形成大量的储氢颗粒。 混入储氢颗粒中的金属氢化物的组成和用量与硼氢化物颗粒中的硼反应,形成金属硼化物,并抑制从加热的金属硼氢化物颗粒中释放氢而释放乙硼烷。
    • 10. 发明授权
    • Method of enhancing thermal conductivity in hydrogen storage systems
    • 提高储氢系统热导率的方法
    • US08883117B2
    • 2014-11-11
    • US13850412
    • 2013-03-26
    • Ford Global Technologies, LLC
    • Jun YangDonald J. SiegelAndrea SudikAndrew Robert DrewsShinichi HiranoChristopher Mark Wolverton
    • B01J7/00C01B3/04C01B6/24C01B3/00
    • C01B3/0078C01B3/001C01B3/0026Y02E60/327
    • A method of forming a material for reversible hydrogen storage within a storage tank includes charging a mixture of a metal amide and a metal hydride to the storage tank, and chemically reacting the mixture at a reaction condition within the storage tank to form a thermally conducting composite material situated in the storage tank and for reversibly storing hydrogen. The composite material includes a three-dimensional and interconnected framework including a conductive metal. A method for reversibly storing hydrogen includes providing a storage tank and in situ chemically forming a composite material by charging a mixture of a metal amide and a metal hydride to the storage tank and chemically reacting the mixture at a reaction condition to form a thermally conducting composite material including a metal hydride and a substantially unreactive elemental metal framework. Hydrogen is absorbed into the composite material and is desorbed from the composite material.
    • 在储罐内形成用于可逆储氢的材料的方法包括将金属酰胺和金属氢化物的混合物加入到储罐中,并在储罐内的反应条件下使混合物化学反应,形成导热复合材料 材料位于储罐中,并可逆地储存氢气。 复合材料包括三维和互连的框架,其包括导电金属。 一种用于可逆地储存氢的方法包括提供储罐并通过将金属酰胺和金属氢化物的混合物加入到储罐中并在化学上形成复合材料,并在反应条件下使混合物化学反应以形成导热复合材料 材料包括金属氢化物和基本上不反应的元素金属骨架。 氢被吸收到复合材料中并从复合材料中解吸。