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1. 发明授权

US06485527B1 Use of reactive dyes for dyeing hair 失效
标题翻译：使用活性染料染发
公开(公告)号：US06485527B1
公开(公告)日：2002-11-26
申请号：US09462679
申请日：2000-01-11
申请人： Frank Prechtl , Manfred Patsch , Peter Hössel
发明人： Frank Prechtl , Manfred Patsch , Peter Hössel
IPC分类号： A61K713
CPC分类号： A61Q5/065 , A61K8/466 , A61K8/4946 , A61K2800/57
摘要： Reactive dyes of the formula I where a is 1 or 2, b is 0 or 1, Y is vinyl or a radical of the formula C2H4Q, where Q is an alkali-detachable group, L3 is a direct bond or a bridge member of the formula CO—NH—M1, where M1 is C2-C6-alkylene with or without interruption by 1 or 2 unadjacent oxygen atoms, imino or C1-C4-alkylimino groups, A1 is hydroxysulfonyl or a radical of the formula SO2Y, A2 is hydrogen, hydroxysulfonyl, methoxy, chlorine, bromine or carboxyl, W is either in case 1) the radical of a coupling component, of a monoazo dye or additionally, when b=0, of a disazo dye, which may each bear further fiber-reactive groups, or in case 2) the radical of a chromophore which optionally has further reactive groups, L1 and L2 are each a bridge member, are useful for hair dyeing and for use in cosmetic preparations for dyeing hair.
摘要翻译：式I的活性染料为1或2，b为0或1，Y为乙烯基或式C2H4Q基，其中Q为碱可分离基团，L3为直接键或式CO的桥连构件 -NH-M1，其中M1是具有或不具有1个或2个不相邻的氧原子的中间的C2-C6-亚烷基，亚氨基或C1-C4-烷基亚氨基，A1是羟基磺酰基或式SO2Y的基团，A2是氢，羟基磺酰基，甲氧基，氯，溴或羧基的情况下，W是在偶联组分的单偶氮染料的基团或另外当b = 0时的双偶氮染料，其可以各自承载进一步的纤维反应性基团，或者在情况2中）任选地具有其它反应性基团的发色团的基团，L1和L2各自为桥连构件，可用于染发和用于染发头发的化妆品制剂中。

2. 发明授权

US06410698B1 Reactive dyes with a combination anchor 失效
标题翻译：具有组合锚的活性染料
公开(公告)号：US06410698B1
公开(公告)日：2002-06-25
申请号：US09622919
申请日：2000-09-07
申请人： Frank Prechtl , Manfred Patsch
发明人： Frank Prechtl , Manfred Patsch
IPC分类号： C09B6251
CPC分类号： C09B62/4413
摘要： The reactive dyes have the general formula I where n is 0 or 1, m is 0 or 1, Y is vinyl or a radical of the formula C2H4Q, where Q is an alkali-detachable group, L is C2-C6-alkylene with or without interruption by 1 or 2 nonadjacent oxygen atoms or 1 or 2 imino groups or is cyclohexylene, Hal is fluorine or chlorine, R1 is hydrogen or hydroxysulfonylmethyl, R2 is hydrogen or hydroxysulfonylmethyl, and R3 is carboxyl or hydroxysulfonyl and may also be hydrogen when R1 and/or R2 are each hydroxysulfonylmethyl.
摘要翻译：活性染料具有通式为1或1，m为0或1，Y为乙烯基或式C2H4Q基团，其中Q为碱可分离基团，L为具有或不具有中断的C 2 -C 6亚烷基 1或2个不相邻的氧原子或1或2个亚氨基，或者是亚环己基，Hal是氟或氯，R 1是氢或羟基磺酰基甲基，R 2是氢或羟基磺酰基甲基，R 3是羧基或羟基磺酰基，当R1和/或 R2各自为羟基磺酰基甲基。

3. 发明授权

US6011140A Reactive azo dyes with an aminonaphthalenesulfonic acid coupling component and intermediates therefor 失效
标题翻译：反应性偶氮染料与氨基萘磺酸偶合成分及其中间体
公开(公告)号：US6011140A
公开(公告)日：2000-01-04
申请号：US101183
申请日：1998-07-06
申请人： Andrea Zamponi , Manfred Patsch , Hermann Loffler
发明人： Andrea Zamponi , Manfred Patsch , Hermann Loffler
IPC分类号： C07C309/47 , C07C309/50 , C09B62/44 , C09B62/51 , C09B62/513 , C09B62/08 , C09B62/507 , D06P1/38
CPC分类号： C09B62/4415 , C07C309/47 , C07C309/50 , C09B62/513
摘要： Reactive dyes of the formula ##STR1## where n is 1 or 2,G.sup.1 is hydrogen or hydroxyl,G.sup.2 is hydrogen or hydroxysulfonyl,G.sup.3 is hydrogen or arylazo,R.sup.1 is hydrogen or hydroxysulfonylmethyl,R.sup.2 is hydrogen or hydroxysulfonylmethyl, andD is the radical of a diazo or tetraazo component having in each case at least one anchor radical of the formula SO.sub.2 --Y, where Y is vinyl or substituted ethyl,their use for dyeing or printing hydroxyl-containing or nitrogenous organic substrates, and naphthylamines as intermediates therefor.
摘要翻译： PCT No.PCT / EP97 / 00013 Sec。 371日期：1998年7月6日 102（e）日期1998年7月6日PCT 1997年1月3日PCT PCT。公开号WO97 / 25377 PCT 日期：1997年7月17日，其中n为1或2，G1为氢或羟基，G2为氢或羟基磺酰基，G3为氢或芳基偶氮，R1为氢或羟基磺酰基甲基，R2为氢或羟基磺酰基甲基，在每种情况下，重氮或四氮组分的基团具有至少一个式SO 2 -Y的锚定基团，其中Y是乙烯基或取代的乙基，它们用于染色或印刷含羟基或含氮有机底物和萘胺作为中间体的用途因此。

4. 发明授权

US5962730A Aromatic sulphonyl compounds having an additional thioether, sulphoxide or sulphonyl group 失效
标题翻译：具有另外的硫醚，亚砜或磺酰基的芳族磺酰基化合物
公开(公告)号：US5962730A
公开(公告)日：1999-10-05
申请号：US981497
申请日：1998-01-09
申请人： Claus Marschner , Manfred Patsch
发明人： Claus Marschner , Manfred Patsch
IPC分类号： C07C317/14 , C07C317/18 , C07C317/32 , C07C317/36 , C07C317/40 , C07C323/65 , C07C305/04
CPC分类号： C07C317/18 , C07C317/36 , C07C317/40 , C07C323/65
摘要： Sulfonyl compounds have the formula ##STR1## where n is 0, 1 or 2,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 Q, where Q is hydroxyl or an alkali-detachable group,E is C.sub.3 -C.sub.6 -alkylene with or without interruption by 1 or 2 oxygen atoms in ether function,Ar is the radical of benzene or naphthalene, andR.sup.1, R.sup.2 and R.sup.3 are each hydrogen, unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, hydroxyl, halogen, nitro, amino, hydroxysulfonyl, carboxyl, carbamoyl, sulfamoyl, cyano or a radical of the formula (NH--).sub.m (CH.sub.2 --).sub.q SO.sub.2 --Y, where m is 0 or 1, q is 0, 2 or 3, and Y is as defined above.
摘要翻译： PCT No.PCT / EP96 / 02929 Sec。 371日期1998年1月9日 102（e）1998年1月9日PCT PCT 1996年7月4日PCT公布。公开号WO97 / 03955 日期1997年2月6日磺酰化合物具有下式其中n为0,1或2，Y为乙烯基或式C2H4Q基团，其中Q为羟基或碱可分离基团，E为C 3 -C 6 - 没有中断1或2个氧原子的醚官能团，Ar是苯或萘的基团，R1，R2和R3各自是氢，未取代或取代的C1-C6-烷基，C1-C6-烷氧基，羟基，卤素，硝基，氨基，羟基磺酰基，羧基，氨基甲酰基，氨磺酰基，氰基或式（NH-）m（CH2-）qSO2-Y的基团，其中m为0或1，q为0或2，如上所述。

5. 发明授权

US5910623A Mixtures of sulfo-containing 1:2 metal complexes with vinyl polymers 失效
标题翻译：含有1：2的金属络合物与乙烯基聚合物的混合物
公开(公告)号：US5910623A
公开(公告)日：1999-06-08
申请号：US910669
申请日：1997-08-13
申请人： Knut Kessel , Manfred Patsch , Manfred Herrmann , Kurt Reiner , Jorg Jessen , Matthias Wiesenfeldt
发明人： Knut Kessel , Manfred Patsch , Manfred Herrmann , Kurt Reiner , Jorg Jessen , Matthias Wiesenfeldt
IPC分类号： C09B67/24 , C14C11/00 , D06P1/52 , D06P3/30 , D06P3/32 , D21H21/28 , D06P1/39 , D06P1/90
CPC分类号： D21H21/28 , C09B67/0072 , C14C11/003 , D06P1/5228 , D06P1/5242 , D06P3/3008 , D06P3/3206
摘要： Liquid or solid mixtures of low-salt sulfo-containing 1:2 metal complex dyes and poly-N-vinylpyrrolidone or copolymers of N-vinylpyrrolidone and vinyl acetate are especially useful for dyeing paper and wood and also for dyeing and finishing leather and fur.
摘要翻译：低盐含磺基的1：2金属配合物染料和聚-N-乙烯基吡咯烷酮或N-乙烯基吡咯烷酮和乙酸乙烯酯的共聚物的液体或固体混合物特别适用于染色纸和木材，也可用于染色和整理皮革和毛皮。

6. 发明授权

US5585518A Hydroxyphenylureas 失效
标题翻译：羟基苯基脲
公开(公告)号：US5585518A
公开(公告)日：1996-12-17
申请号：US419282
申请日：1995-04-10
申请人： Claus Marschner , Knut Kessel , Manfred Patsch
发明人： Claus Marschner , Knut Kessel , Manfred Patsch
IPC分类号： C07C275/32 , C07C275/40 , C07C309/45 , C07C309/51 , C07C317/32 , C09B67/20 , C07C275/06
CPC分类号： C07C309/51
摘要： Useful ureas have the formula ##STR1##
摘要翻译：有用的尿素具有公式

7. 发明授权

US5387674A Reactive formazan dyes and hydrazones 失效
标题翻译：活性甲an染料和腙
公开(公告)号：US5387674A
公开(公告)日：1995-02-07
申请号：US117686
申请日：1993-09-08
申请人： Claus Marschner , Manfred Patsch
发明人： Claus Marschner , Manfred Patsch
IPC分类号： C07C317/32 , C07C317/44 , C07C381/02 , C09B62/503 , D06P1/384
CPC分类号： C09B62/5036 , C07C317/44 , C07C381/02
摘要： There are described formazan dyes of the formula ##STR1## where n is 1 or 2,Kat.sup..sym. is the equivalent of a cation,Me is copper or nickel,X is a radical of the formula CO--O or SO.sub.2 --O,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, where Q is a group which is detachable under alkaline reaction conditions,the ring A may be substituted and benzofused, the ring B is substituted and may be benzofused, and the ring C may be substituted, the use thereof for dyeing or printing hydroxyl- or nitrogen-containing organic substrates, and novel hydrazones.
摘要翻译：描述了通式“IMAGE”的甲an染料，其中n是1或2，Kat（+）是阳离子的当量，Me是铜或镍，X是式CO-O或SO2-O的基团， Y是乙烯基或式C2H4-Q的基团，其中Q是在碱性反应条件下可分离的基团，环A可以被取代和苯并稠合，环B被取代并且可以是苯并稠合的，并且环C可以被用于染色或印刷含羟基或含氮有机底物和新型腙的用途。

8. 发明授权

US5241055A Reactive dyes with a reactive system based on alkenylsulfonyl and benzyl compounds as intermediates therefor 失效
标题翻译：具有基于烯基磺酰基和苄基化合物的反应体系的活性染料作为其中间体
公开(公告)号：US5241055A
公开(公告)日：1993-08-31
申请号：US899943
申请日：1992-06-17
申请人： Claus Marschner , Joerg L. Jessen , Klaus Pandl , Manfred Patsch
发明人： Claus Marschner , Joerg L. Jessen , Klaus Pandl , Manfred Patsch
IPC分类号： C07C317/14 , C07C317/36 , C09B62/44
CPC分类号： C09B62/4403 , C07C317/14 , C07C317/36
摘要： Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where U is vinyl, propenyl or the radical of the formula ##STR2## in which Z.sup.1 is hydrogen or methyl and Z.sup.2 is a group which is detachable under alkaline reaction conditions,X isa) the radical of a chromophore orb) the radical of a coupling component to which may be additionally attached the radical of a diazo component via an azo linkage and which may contain an additional reactive group, andL isa) a bridge member of the formula ##STR3## where Q.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, Q.sup.2 and Q.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl, and Q.sup.4 is a leaving group, orb) an azo linkage,the radical X-L being bonded to the benzene ring meta or para to the CH.sub.2 -SO.sub.3 H group,and their preparation may involve novel benzyl compounds as intermediates.
摘要翻译：可用于染色或印刷含羟基或含氮底物的活性染料具有式“IMAGE”，其中U是乙烯基，丙烯基或式（IMAGE）基团，其中Z1是氢或甲基，Z2是可分离的基团在碱性反应条件下，X是a）发色团的基团或b）偶联组分的基团，其可以另外通过偶氮键连接重氮组分的基团，并且可以含有另外的反应性基团，并且L 是a）式为“IMAGE”的桥式成员，其中Q1为氢或C1-C4-烷基，Q2和Q3各自独立于另一个氢或C 1 -C 4 - 烷基，Q 4为离去基团，或b）偶氮键，基团XL键合到CH2-SO3H基团的间位或对位的苯环上，它们的制备可以包括新的苄基化合物作为中间体。

9. 发明授权

US5231171A Reactive dyes having an allylsulfonyl or propargylesulfonyl group 失效
标题翻译：具有聚乙二醇醚或丙烷磺酸基团的反应性染料
公开(公告)号：US5231171A
公开(公告)日：1993-07-27
申请号：US806262
申请日：1991-12-13
申请人： Claus Marschner , Matthias Niedenbrueck , Bernd Siegel , Manfred Patsch , Klaus Pandl
发明人： Claus Marschner , Matthias Niedenbrueck , Bernd Siegel , Manfred Patsch , Klaus Pandl
IPC分类号： C09B62/44 , C09B62/443 , C09B62/78
CPC分类号： C09B62/4401 , C09B62/443 , C09B62/78
摘要： Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where Rg is a radical of the formula ##STR2## Ar is the radical of a benzene or naphthalene ring, Z.sup.1 and Z.sup.2 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano, halogen or hydroxysulfonyl,Z.sup.3, Z.sup.4 and Z.sup.5 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl,U is a group which is detachable under alkaline reaction conditions,X is in case a) the radical of a chromophore or in case b) the radical of a coupling component to which may additionally be attached, via an azo bridge, the radical of a diazo component and which may have additional reactive groups, andL is in case a) a bridge member or in case b) an azo bridge.
摘要翻译：可用于染色或印刷含羟基或含氮底物的活性染料具有式（I）其中R g是下式的基团：其中R a是苯或萘环的基团，Z 1和Z 2分别为氢，取代或未取代的C 1 -C 4 - 烷基，取代或未取代的苯基，C 1 -C 4 - 烷氧基，羧基，C 1 -C 4 - 烷氧基羰基，氰基，卤素或羟基磺酰基，Z 3，Z 4和Z 5各自为氢， C 4 - 烷基或取代或未取代的苯基，U是在碱性反应条件下可分离的基团，X是在a）发色团的基团的情况下，或在b）可以另外附着的偶合组分的基团的情况下，通过偶氮桥，重氮组分的基团并且可以具有额外的反应性基团，并且L是在a）桥构件的情况下或在b）偶氮桥中的情况下。

10. 发明授权

US5196573A Process for the preparation of sulfonated anthranilic acids 失效
标题翻译：磺化邻氨基苯甲酸的制备方法
公开(公告)号：US5196573A
公开(公告)日：1993-03-23
申请号：US888444
申请日：1992-05-28
申请人： Manfred Patsch , Klaus Pandl , Jacques Dupuis , Helmut Hagen
发明人： Manfred Patsch , Klaus Pandl , Jacques Dupuis , Helmut Hagen
IPC分类号： C07C309/46 , C07C309/48
CPC分类号： C07C309/48 , C07C309/46
摘要： A process for the preparation of 4-sulfonated anthranilic acids by sulfonation of ortho-nitrotoluenes with chlorosulfonic acid or oleum followed by oxidation of the methyl group and, finally, reduction of the nitro group.
摘要翻译：通过用氯磺酸或发烟硫酸磺化邻 - 硝基甲苯，然后氧化甲基，最后还原硝基来制备4-磺化邻氨基苯甲酸的方法。

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