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1. 发明授权

US5585518A Hydroxyphenylureas 失效
标题翻译：羟基苯基脲
公开(公告)号：US5585518A
公开(公告)日：1996-12-17
申请号：US419282
申请日：1995-04-10
申请人： Claus Marschner , Knut Kessel , Manfred Patsch
发明人： Claus Marschner , Knut Kessel , Manfred Patsch
IPC分类号： C07C275/32 , C07C275/40 , C07C309/45 , C07C309/51 , C07C317/32 , C09B67/20 , C07C275/06
CPC分类号： C07C309/51
摘要： Useful ureas have the formula ##STR1##
摘要翻译：有用的尿素具有公式

2. 发明授权

US5962730A Aromatic sulphonyl compounds having an additional thioether, sulphoxide or sulphonyl group 失效
标题翻译：具有另外的硫醚，亚砜或磺酰基的芳族磺酰基化合物
公开(公告)号：US5962730A
公开(公告)日：1999-10-05
申请号：US981497
申请日：1998-01-09
申请人： Claus Marschner , Manfred Patsch
发明人： Claus Marschner , Manfred Patsch
IPC分类号： C07C317/14 , C07C317/18 , C07C317/32 , C07C317/36 , C07C317/40 , C07C323/65 , C07C305/04
CPC分类号： C07C317/18 , C07C317/36 , C07C317/40 , C07C323/65
摘要： Sulfonyl compounds have the formula ##STR1## where n is 0, 1 or 2,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 Q, where Q is hydroxyl or an alkali-detachable group,E is C.sub.3 -C.sub.6 -alkylene with or without interruption by 1 or 2 oxygen atoms in ether function,Ar is the radical of benzene or naphthalene, andR.sup.1, R.sup.2 and R.sup.3 are each hydrogen, unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, hydroxyl, halogen, nitro, amino, hydroxysulfonyl, carboxyl, carbamoyl, sulfamoyl, cyano or a radical of the formula (NH--).sub.m (CH.sub.2 --).sub.q SO.sub.2 --Y, where m is 0 or 1, q is 0, 2 or 3, and Y is as defined above.
摘要翻译： PCT No.PCT / EP96 / 02929 Sec。 371日期1998年1月9日 102（e）1998年1月9日PCT PCT 1996年7月4日PCT公布。公开号WO97 / 03955 日期1997年2月6日磺酰化合物具有下式其中n为0,1或2，Y为乙烯基或式C2H4Q基团，其中Q为羟基或碱可分离基团，E为C 3 -C 6 - 没有中断1或2个氧原子的醚官能团，Ar是苯或萘的基团，R1，R2和R3各自是氢，未取代或取代的C1-C6-烷基，C1-C6-烷氧基，羟基，卤素，硝基，氨基，羟基磺酰基，羧基，氨基甲酰基，氨磺酰基，氰基或式（NH-）m（CH2-）qSO2-Y的基团，其中m为0或1，q为0或2，如上所述。

3. 发明授权

US5387674A Reactive formazan dyes and hydrazones 失效
标题翻译：活性甲an染料和腙
公开(公告)号：US5387674A
公开(公告)日：1995-02-07
申请号：US117686
申请日：1993-09-08
申请人： Claus Marschner , Manfred Patsch
发明人： Claus Marschner , Manfred Patsch
IPC分类号： C07C317/32 , C07C317/44 , C07C381/02 , C09B62/503 , D06P1/384
CPC分类号： C09B62/5036 , C07C317/44 , C07C381/02
摘要： There are described formazan dyes of the formula ##STR1## where n is 1 or 2,Kat.sup..sym. is the equivalent of a cation,Me is copper or nickel,X is a radical of the formula CO--O or SO.sub.2 --O,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, where Q is a group which is detachable under alkaline reaction conditions,the ring A may be substituted and benzofused, the ring B is substituted and may be benzofused, and the ring C may be substituted, the use thereof for dyeing or printing hydroxyl- or nitrogen-containing organic substrates, and novel hydrazones.
摘要翻译：描述了通式“IMAGE”的甲an染料，其中n是1或2，Kat（+）是阳离子的当量，Me是铜或镍，X是式CO-O或SO2-O的基团， Y是乙烯基或式C2H4-Q的基团，其中Q是在碱性反应条件下可分离的基团，环A可以被取代和苯并稠合，环B被取代并且可以是苯并稠合的，并且环C可以被用于染色或印刷含羟基或含氮有机底物和新型腙的用途。

4. 发明授权

US5241055A Reactive dyes with a reactive system based on alkenylsulfonyl and benzyl compounds as intermediates therefor 失效
标题翻译：具有基于烯基磺酰基和苄基化合物的反应体系的活性染料作为其中间体
公开(公告)号：US5241055A
公开(公告)日：1993-08-31
申请号：US899943
申请日：1992-06-17
申请人： Claus Marschner , Joerg L. Jessen , Klaus Pandl , Manfred Patsch
发明人： Claus Marschner , Joerg L. Jessen , Klaus Pandl , Manfred Patsch
IPC分类号： C07C317/14 , C07C317/36 , C09B62/44
CPC分类号： C09B62/4403 , C07C317/14 , C07C317/36
摘要： Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where U is vinyl, propenyl or the radical of the formula ##STR2## in which Z.sup.1 is hydrogen or methyl and Z.sup.2 is a group which is detachable under alkaline reaction conditions,X isa) the radical of a chromophore orb) the radical of a coupling component to which may be additionally attached the radical of a diazo component via an azo linkage and which may contain an additional reactive group, andL isa) a bridge member of the formula ##STR3## where Q.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, Q.sup.2 and Q.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl, and Q.sup.4 is a leaving group, orb) an azo linkage,the radical X-L being bonded to the benzene ring meta or para to the CH.sub.2 -SO.sub.3 H group,and their preparation may involve novel benzyl compounds as intermediates.
摘要翻译：可用于染色或印刷含羟基或含氮底物的活性染料具有式“IMAGE”，其中U是乙烯基，丙烯基或式（IMAGE）基团，其中Z1是氢或甲基，Z2是可分离的基团在碱性反应条件下，X是a）发色团的基团或b）偶联组分的基团，其可以另外通过偶氮键连接重氮组分的基团，并且可以含有另外的反应性基团，并且L 是a）式为“IMAGE”的桥式成员，其中Q1为氢或C1-C4-烷基，Q2和Q3各自独立于另一个氢或C 1 -C 4 - 烷基，Q 4为离去基团，或b）偶氮键，基团XL键合到CH2-SO3H基团的间位或对位的苯环上，它们的制备可以包括新的苄基化合物作为中间体。

5. 发明授权

US5231171A Reactive dyes having an allylsulfonyl or propargylesulfonyl group 失效
标题翻译：具有聚乙二醇醚或丙烷磺酸基团的反应性染料
公开(公告)号：US5231171A
公开(公告)日：1993-07-27
申请号：US806262
申请日：1991-12-13
申请人： Claus Marschner , Matthias Niedenbrueck , Bernd Siegel , Manfred Patsch , Klaus Pandl
发明人： Claus Marschner , Matthias Niedenbrueck , Bernd Siegel , Manfred Patsch , Klaus Pandl
IPC分类号： C09B62/44 , C09B62/443 , C09B62/78
CPC分类号： C09B62/4401 , C09B62/443 , C09B62/78
摘要： Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where Rg is a radical of the formula ##STR2## Ar is the radical of a benzene or naphthalene ring, Z.sup.1 and Z.sup.2 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano, halogen or hydroxysulfonyl,Z.sup.3, Z.sup.4 and Z.sup.5 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl,U is a group which is detachable under alkaline reaction conditions,X is in case a) the radical of a chromophore or in case b) the radical of a coupling component to which may additionally be attached, via an azo bridge, the radical of a diazo component and which may have additional reactive groups, andL is in case a) a bridge member or in case b) an azo bridge.
摘要翻译：可用于染色或印刷含羟基或含氮底物的活性染料具有式（I）其中R g是下式的基团：其中R a是苯或萘环的基团，Z 1和Z 2分别为氢，取代或未取代的C 1 -C 4 - 烷基，取代或未取代的苯基，C 1 -C 4 - 烷氧基，羧基，C 1 -C 4 - 烷氧基羰基，氰基，卤素或羟基磺酰基，Z 3，Z 4和Z 5各自为氢， C 4 - 烷基或取代或未取代的苯基，U是在碱性反应条件下可分离的基团，X是在a）发色团的基团的情况下，或在b）可以另外附着的偶合组分的基团的情况下，通过偶氮桥，重氮组分的基团并且可以具有额外的反应性基团，并且L是在a）桥构件的情况下或在b）偶氮桥中的情况下。

6. 发明授权

US5910623A Mixtures of sulfo-containing 1:2 metal complexes with vinyl polymers 失效
标题翻译：含有1：2的金属络合物与乙烯基聚合物的混合物
公开(公告)号：US5910623A
公开(公告)日：1999-06-08
申请号：US910669
申请日：1997-08-13
申请人： Knut Kessel , Manfred Patsch , Manfred Herrmann , Kurt Reiner , Jorg Jessen , Matthias Wiesenfeldt
发明人： Knut Kessel , Manfred Patsch , Manfred Herrmann , Kurt Reiner , Jorg Jessen , Matthias Wiesenfeldt
IPC分类号： C09B67/24 , C14C11/00 , D06P1/52 , D06P3/30 , D06P3/32 , D21H21/28 , D06P1/39 , D06P1/90
CPC分类号： D21H21/28 , C09B67/0072 , C14C11/003 , D06P1/5228 , D06P1/5242 , D06P3/3008 , D06P3/3206
摘要： Liquid or solid mixtures of low-salt sulfo-containing 1:2 metal complex dyes and poly-N-vinylpyrrolidone or copolymers of N-vinylpyrrolidone and vinyl acetate are especially useful for dyeing paper and wood and also for dyeing and finishing leather and fur.
摘要翻译：低盐含磺基的1：2金属配合物染料和聚-N-乙烯基吡咯烷酮或N-乙烯基吡咯烷酮和乙酸乙烯酯的共聚物的液体或固体混合物特别适用于染色纸和木材，也可用于染色和整理皮革和毛皮。

7. 发明授权

US5488127A Aminophenols useful as intermediates for formazan reactive dyes 失效
标题翻译：氨基酚可用作甲an活性染料的中间体
公开(公告)号：US5488127A
公开(公告)日：1996-01-30
申请号：US407956
申请日：1995-03-22
申请人： Claus Marschner , Manfred Patsch
发明人： Claus Marschner , Manfred Patsch
IPC分类号： C07C323/44 , C07C317/28 , C07D295/20 , C09B62/018 , C09B62/44 , C09B62/503
CPC分类号： C09B62/4401 , C07C317/28 , C09B62/018 , C09B62/5036
摘要： There are described formazan dyes of the formula ##STR1## where m and n are each 1 or 2,Kat.sup..sym. is the equivalent of a cation,Me is copper or nickel,X is oxygen or a radical of the formula CO--O or SO.sub.2 --0,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, wherein Q is a group that is detachable under alkaline reaction conditions,E is a fiber-reactive radical,the rings A and B may be substituted and benzofused, andthe ring C may be substituted,the use thereof for dyeing or printing hydroxyl- or nitrogen-containing organic substrates, novel aminophenols and a process for preparing same.
摘要翻译：描述了式IMAMA的甲an染料，其中m和n各自为1或2，Kat（+）为阳离子的当量，Me为铜或镍，X为氧或式CO-O基团或SO 2 -O，Y为乙烯基或式C 2 H 4 -Q基团，其中Q为在碱性反应条件下可分离的基团，E为纤维反应性基团，环A和B可以被取代和苯并，并且环C可以被取代，其用于染色或印刷羟基或含氮有机底物，新型氨基苯酚及其制备方法的用途。

8. 发明授权

US5410027A Method of preparing fiber-reactive formazan dyes involving hydrolysis of a formyl amino moiety 失效
标题翻译：制备涉及甲酰氨基部分水解的纤维反应性甲an染料的方法
公开(公告)号：US5410027A
公开(公告)日：1995-04-25
申请号：US74608
申请日：1993-06-11
申请人： Claus Marschner , Manfred Patsch
发明人： Claus Marschner , Manfred Patsch
IPC分类号： C07C233/43 , C09B62/04 , C09B62/44 , D06P1/382 , C09B62/018 , C09B43/16 , C09B50/00 , C09B62/038
CPC分类号： C09B62/4407 , C07C233/43 , C09B62/046 , Y02P20/55
摘要： Fiber-reactive formazan dyes are prepared by diazotizing a protectively formylated hydroxyphenylenediamine, coupling with a hydrazone compound, metallizing, eliminating the protective group, and reacting with a halotriazine and optionally thereafter with an amine or a hydroxy compound via novel aminophenol intermediates.
摘要翻译：通过将保护性甲酰化羟基苯二胺重氮化，与腙化合物偶合，金属化，除去保护基，并与卤代三嗪反应，然后任选地通过新的氨基苯酚中间体与胺或羟基化合物反应制备纤维反应性甲an染料。

9. 发明授权

US5225595A Arylsulfonyl compounds with unsaturated radicals 失效
标题翻译：具有不饱和基团的芳基磺酰基化合物
公开(公告)号：US5225595A
公开(公告)日：1993-07-06
申请号：US971270
申请日：1992-11-04
申请人： Bernd Siegel , Claus Marschner , Manfred Patsch
发明人： Bernd Siegel , Claus Marschner , Manfred Patsch
IPC分类号： C07C317/14 , C07C317/32 , C07C317/36 , C07C317/40 , C09B62/447 , C09B62/82
CPC分类号： C07C317/14 , C07C317/32 , C07C317/36 , C07C317/40 , C09B62/447 , C09B62/82
摘要： Sulfonyl compounds of the formula ##STR1## where Ar is the radical of a benzene or naphthalene ring,R.sup.1 and R.sup.2 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano, halogen or hydroxysulfonyl,R.sup.3 is nitro, amino, C.sub.1 -C.sub.4 -alkanoylamino or benzoylamino, andR.sup.4 is a radical of the formula ##STR2## where X.sup.1, X.sup.2 and X.sup.3 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, andX.sup.4 is a group which is detachable under alkaline conditions,either in the free form or in the form of their salts, are useful for synthesizing reactive dyes.
摘要翻译：式（I）的磺酰化合物其中Ar是苯或萘环的基团，R 1和R 2各自为氢，取代或未取代的C 1 -C 4 - 烷基，取代或未取代的苯基，C 1 -C 4 - 烷氧基，羧基，C 1 -C 4 - 烷氧基羰基，氰基，卤素或羟基磺酰基，R 3是硝基，氨基，C 1 -C 4 - 烷酰基氨基或苯甲酰基氨基，R 4是下式的基团：其中X 1，X 2和X 3各自为氢，取代或未取代的C1-C4烷基或取代或未取代的苯基，X4是在碱性条件下以游离形式或其盐形式可分离的基团，可用于合成活性染料。

10. 发明授权

US5929217A Reactive dyes with a benzo-fused heterocycle as anchor 失效
标题翻译：具有苯并稠合杂环作为锚的活性染料
公开(公告)号：US5929217A
公开(公告)日：1999-07-27
申请号：US620306
申请日：1996-03-22
申请人： Manfred Patsch , Hermann Loffler , Claus Marschner
发明人： Manfred Patsch , Hermann Loffler , Claus Marschner
IPC分类号： C07D401/12 , C07D209/34 , C07D209/46 , C07D401/14 , C07D403/12 , C07D403/14 , C07D413/14 , C07D498/04 , C09B62/44 , C09B62/503 , C09B62/006 , C09B62/08 , C09B62/22 , C09B62/507
CPC分类号： C07D403/12 , C07D209/46 , C07D403/14 , C09B62/4403 , C09B62/503
摘要： Reactive dyes of the formula I ##STR1## where a is 1 or 2,b is 0 or 1,Z.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen, nitro, amino, hydroxysulfonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, carbamoyl or C.sub.1 -C.sub.6 -mono- or dialkylcarbamoyl,A is methylene, carbonyl, sulfonyl or a radical of the formula CH.sub.2 --CO or CH.sub.2 --SO.sub.2,X is a direct linkage or a linker,Y.sup.1 is vinyl or a radical of the formula C.sub.2 H.sub.4 Q where Q is a group which can be eliminated under alkaline conditions,W is in case 1) the radical of a chromophore which may have further reactive groups, or in case 2) the radical of a coupling component to which additionally the radical of a diazo component may be linked via an azo bridge and which may have additional reactive groups, andL.sup.1 and L.sup.2 are each linkers,their intermediates and a process for dyeing or printing substrates having hydroxyl groups or nitrogen atoms using the novel dyes are described.
摘要翻译：式Ⅰ的反应性染料，其中a为1或2，b为0或1，Z1为氢，C1-C6-烷基，C1-C6-烷氧基，卤素，硝基，氨基，羟基磺酰基，C1-C6烷氧基羰基，氨基甲酰基或C 1 -C 6单 - 或二烷基氨甲酰基，A为亚甲基，羰基，磺酰基或式CH 2 -CO或CH 2 -SO 2的基团，X为直接键或连接基，Y 1为乙烯基或式C 2 H 4 Q基其中Q是可以在碱性条件下被除去的基团，W是在情况1的情况下）可以具有进一步反应性基团的发色团的基团，或者在情况2中，另外是重氮基团的偶合组分的基团组分可以通过偶氮桥连接并且可以具有另外的反应性基团，并且L1和L2各自是连接体，它们的中间体以及使用新型染料染色或印刷具有羟基或氮原子的底物的方法。

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