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    • 2. 发明授权
    • Ink jet inks, inks, and other compositions containing colored pigments
    • 喷墨油墨,油墨和含有着色颜料的其它组合物
    • US06494943B1
    • 2002-12-17
    • US09698468
    • 2000-10-27
    • Yuan YuFriedrich K. von GottbergRobert M. AmiciPaul S. Palumbo
    • Yuan YuFriedrich K. von GottbergRobert M. AmiciPaul S. Palumbo
    • C09D1100
    • C09D11/34C09B67/0004C09B68/24C09D11/322
    • Colored pigments having one or more desired parameters and/or properties are described. These parameters and/or properties include: a) a particles size of from about 10 nm to about 300 nm; b) an accusizer number of less than 1010 particles/ml of dispersion at 15% solids which are greater than 0.5 micron; c) a filterability such that when in a liquid medium, 100 ml having 10% solids of the colored pigment filters through a 3 micron nylon absolute filter; d) a colored pigment purity of greater than about 80%, based on extractable material; and/or e) a stability such that the above-described properties do not change by more than 50% at 25 degrees C. for at least one week. Colored pigments having at least one organic group and having one or more of the above-described characteristics is also described as well as a process for preparing surface-modified colored pigments. The process involves combining at least one treating agent and at least one type of colored pigment(s) in a container to form a mixture and subjecting the mixture to high shearing and introducing at least one diazotizing agent to the mixture at least for a portion of time while the high shearing is taking place, and preferably during the entire time that high shearing is taking place, such that a reaction product is formed and contains surface-modified colored pigment(s).
    • 描述具有一个或多个所需参数和/或性质的有色颜料。 这些参数和/或性质包括:a)约10nm至约300nm的粒度; b)大于0.5微米的15%固体的小于1010个/ ml分散体的指示剂数; c)过滤性,使得当在液体介质中,具有10%固体的着色颜料的100ml通过3微米尼龙绝对过滤器过滤; d)基于可萃取材料的有色颜料纯度大于约80%; 和/或e)稳定性,使得上述性质在25摄氏度下不会改变超过50%至少一周。 还描述了具有至少一个有机基团并且具有一种或多种上述特征的着色颜料以及制备表面改性着色颜料的方法。 该方法包括将至少一种处理剂和至少一种类型的有色颜料混合在容器中以形成混合物,并使混合物经受高剪切,并将至少一种重氮化试剂至少引入至少一部分 并且优选在高剪切发生的整个时间内形成反应产物并含有表面改性的着色颜料。
    • 5. 发明授权
    • Photographic products and processes
    • 摄影产品和工艺
    • US4468450A
    • 1984-08-28
    • US500414
    • 1983-06-02
    • Frank A. MeneghiniPaul S. Palumbo
    • Frank A. MeneghiniPaul S. Palumbo
    • C07D277/04C07D277/06G03C8/04G03C8/08G03C1/10G03C1/40G03C5/54G03C7/00
    • G03C8/08C07D277/04C07D277/06G03C8/045Y10S430/156Y10S430/159
    • This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety containing a thiazolidinyl group, said thiazolidinyl group (a) being capable of undergoing cleavage imagewise in the presence of an imagewise distribution of silver ion and/or soluble silver complex and (b) possessing a substituent on the carbon atom in the 2-position which upon cleavage of said thiazolidinyl group, undergoes a .beta.-elimination reaction followed by an intramolecularly accelerated nucleophilic displacement reaction, which moiety maintains the precursor in its colorless form at least until said thiazolidinyl group undergoes said cleavage. In a further embodiment, this sequence of reactions is used to release an imagewise distribution of a photographically useful reagent which reagent may be, for example, a photographically active reagent.
    • 本发明涉及用于从含有噻唑烷基的部分取代的预成型染料的无色前体形成染料的照相方法和产品,所述噻唑烷基(a)能够在存在 银离子和/或可溶性银络合物的成像分布和(b)在2-位上的碳原子上具有取代基,其在所述噻唑烷基裂解后进行β-消光反应,随后进行分子内加速的亲核取代反应 ,该部分将前体保持为无色形式,至少直到所述噻唑烷基基团经历所述切割。 在另一个实施方案中,该反应序列用于释放照相用试剂的成像分布,该试剂可以是例如摄影活性试剂。