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    • 6. 发明申请
    • SELF-CLEANING COATINGS
    • 自清洁涂料
    • US20120010314A1
    • 2012-01-12
    • US13143781
    • 2010-01-08
    • Paul A. CharpentierKevin D. Burgess
    • Paul A. CharpentierKevin D. Burgess
    • C09D175/04C08L75/04C08G18/76B82Y30/00
    • C08G18/4854C08G18/0823C08G18/10C08G18/348C08G18/3897C08G18/7671C08G18/82C08G18/838C08K3/22C08K9/02C08K2003/2241C08L75/04C08L75/08C09D7/62C09D7/67C09D7/68C09D175/04C09D175/08
    • The present invention provides two methods for synthesizing novel titania-polyurethane (nTiO2-PU) nanocomposites for self-cleaning coatings, one a polymer functionalization method (“grafting to”) and the other, a monomer functionalization method (“grafting from”). Here, 2,2 bis(hydroxymethyl) propionic acid (HMPA) was used as the coordination agent, which was reacted with n-TiO2 (50:50 anatase/rutile) to form nTiO2-HMPA, then polymerized in the monomer functionalization method. In the polymer functionalization method, HMPA was reacted with a pre-polymer to form the PU, and then subsequently reacted with n-TiO2 to form the polymer nanocomposite. The photocatalytic cleanability of the nanocomposites was investigated when exposed to ultraviolet radiation using additional unreacted HMPA or stearic acid as the model “dirt” compounds. Nanocomposites prepared using both strategies showed similar self-cleaning behavior, although the monomer technique gave less substrate degradation.
    • 本发明提供两种用于自清洁涂层的新型二氧化钛 - 聚氨酯(nTiO 2 -PU)纳米复合材料的方法,一种是聚合物官能化方法(“接枝”),另一种是单体官能化方法(“从...接枝”)。 这里,使用2,2双(羟甲基)丙酸(HMPA)作为配位剂,与n-TiO2(50:50锐钛型/金红石)反应形成nTiO 2 -HMPA,然后以单体官能化方法进行聚合。 在聚合物官能化方法中,HMPA与预聚物反应形成PU,然后与n-TiO 2反应形成聚合物纳米复合材料。 当使用附加的未反应的HMPA或硬脂酸作为模型“污垢”化合物暴露于紫外线照射时,研究了纳米复合材料的光催化清洁性。 使用这两种策略制备的纳米复合材料显示出类似的自清洁行为,尽管单体技术给出较少的底物降解。