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    • 4. 发明授权
    • Catalytic hydrodechlorination of a chloromethane
    • 甲烷的催化加氢脱氯
    • US5426252A
    • 1995-06-20
    • US138291
    • 1993-10-15
    • Fawzy G. Sherif
    • Fawzy G. Sherif
    • B01J27/22B01J37/02C07C17/23C07C17/354
    • B01J27/22B01J37/0244C07C17/23
    • Chloromethane compounds including carbon tetrachloride and the chlorofluoromethane compounds, such as dichlorodifluoromethane, can be catalytically hydrodechlorinated, e.g., in the case of dichlorodifluoromethane to monochlorodifluoromethane and/or difluoromethane, by treatment with hydrogen in the presence of a transition metal carbide catalyst, for example, a Group IVB metal carbide, such as tungsten carbide, supported on an oxidic support, such as alumina, optionally with a passivating layer of ceramic, such as silicon carbide, between the oxidic support and catalyst. The catalyst preferably has a surface area of no less than about 1 m.sup.2 /gm.
    • 包括四氯化碳和氯氟甲烷化合物如二氯二氟甲烷的氯甲烷化合物可以催化加氢脱氯,例如在二氯二氟甲烷到一氯二氟甲烷和/或二氟甲烷的情况下,通过在过渡金属碳化物催化剂存在下用氢处理, 在氧化载体和催化剂之间负载在氧化物载体如氧化铝上的IVB族金属碳化物,例如碳化钨,任选地具有诸如碳化硅的陶瓷钝化层。 催化剂优选具有不小于约1m 2 / gm的表面积。
    • 10. 发明授权
    • Reforming hydrocarbons using transition metal carbide catalyst and
gaseous oxygen
    • 使用过渡金属碳化物催化剂和气态氧改性碳氢化合物
    • US5384027A
    • 1995-01-24
    • US149426
    • 1993-11-09
    • Fawzy G. Sherif
    • Fawzy G. Sherif
    • B01J27/22C10G35/06
    • B01J27/22C10G35/06
    • A process for reforming a hydrocarbon which comprises treating the hydrocarbon, while at elevated temperature, with a transition metal catalyst while in the presence of an effective amount of gaseous oxygen to improve the selectivity of the catalyst to aromatic formation and reduce the hydrogenolysis activity of the catalyst. The transition metal may be tungsten, and the transition metal catalyst may be supported on an oxidic support, optionally with a ceramic passivation layer lying between the support and the transition metal catalyst. The amount of gaseous oxygen used may be from about 50 ppm to about 5000 ppm, based upon the weight of the hydrocarbon.
    • 一种重整烃的方法,其包括在升高的温度下用过渡金属催化剂处理烃,同时在有效量的气态氧的存在下,以改善催化剂对芳族形成的选择性并降低催化剂的氢解活性 催化剂。 过渡金属可以是钨,并且过渡金属催化剂可以负载在氧化载体上,任选地具有位于载体和过渡金属催化剂之间的陶瓷钝化层。 基于烃的重量,使用的气态氧的量可以为约50ppm至约5000ppm。