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    • 3. 发明授权
    • Purified catalyst support
    • 纯化催化剂载体
    • US4680350A
    • 1987-07-14
    • US462252
    • 1983-01-31
    • Carl C. Greco
    • Carl C. Greco
    • C08F4/02C08F10/00
    • C08F10/00Y10S526/906
    • This invention relates to pretreating the support material for a polymerization catalyst comprising magnesium chloride with an active hydrogen compound such as an organic acid phosphate or a phenol in order to transform substantially elemental magnesium and other impurities. The impure magnesium chloride originates as a by-product from the manufacture of magnesium alkyls by the reaction of alkyl chlorides with elemental magnesium. Succeeding steps are activating the support material with an electron donor and treating the activated product with a titanium halide. The invention also includes the novel catalytic component containing titanium halide, itself, the process for making that component, use of this catalytic system for polymerizing olefins such as propylene, and the purification step for magnesium chloride, itself.
    • 本发明涉及预处理包含氯化镁的聚合催化剂的载体材料与活性氢化合物如有机酸式磷酸酯或苯酚,以转化基本上元素的镁和其它杂质。 不纯的氯化镁通过烷基氯与元素镁的反应来源于烷基镁制备的副产物。 成功的步骤是用电子给体激活载体材料并用卤化钛处理活化产物。 本发明还包括含有卤化钛的新型催化组分本身,制备该组分的方法,该催化体系用于聚合烯烃如丙烯的用途,以及氯化镁本身的纯化步骤。