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1. 发明授权

US4514326A Permanent flame retardant and anti-smoldering compositions 失效
标题翻译：永久阻燃和防闷烧组合物
公开(公告)号：US4514326A
公开(公告)日：1985-04-30
申请号：US603340
申请日：1984-04-24
申请人： Stephen I. Sallay
发明人： Stephen I. Sallay
IPC分类号： C09K21/02 , C01B35/10 , C01D5/00 , C05B7/00 , C09K21/04 , D06M11/00 , D06M11/54 , D06M11/56 , D06M11/71 , D06M11/82 , D06M23/06 , D06M101/06 , D21H19/00 , D21H21/34 , C09K3/28
CPC分类号： C01B35/1063 , C01D5/00 , C05B7/00 , Y10S428/921
摘要： When alkali metal and/or alkaline earth metal tetraborates in a water suspension are suitably treated with ammonia and sulfuric acid, sulfurdioxide or phosphoric acid, they undergo a three-step transformation resulting in a mixture of ammoniumpentaborate, the corresponding alkali metal and/or alkaline earth metal salt(s): sulfate, sulfite or hydrophosphate and ammonia (Equation 1).Alternately, tetraborates undergo the same three-step reactions upon their treatment with equimolar amounts of ammoniumsulfate, ammoniumsulfite or diammoniumhydrogenphosphate, while the liberated ammonia can be boiled off with distilling water.This application deals with the discovery of highly effective, permanent flame retardant compositions which also possess excellent antismoldering, noncorrosive and fungal resistant properties when properly applied on cellulosic fibers, cellulose-lignin fiber insulation materials.
摘要翻译：当水悬浮液中的碱金属和/或碱土金属四硼酸盐适当地用氨和硫酸，二氧化硫或磷酸处理时，它们进行三步转化，得到五硼酸铵，相应的碱金属和/或碱土壤金属盐：硫酸盐，亚硫酸盐或磷酸氢盐和氨（等式1）。或者，四硼酸盐在用等摩尔量的硫酸铵，亚硫酸铵或磷酸氢二铵处理后，经历相同的三步反应，而释放的氨可以用蒸馏水煮沸。本申请涉及高效，永久的阻燃组合物的发现，当合适地应用在纤维素纤维，纤维素 - 木质素纤维绝缘材料上时，它们也具有优异的抗焊剂，非腐蚀性和真菌性能。

2. 发明授权

US4511498A Mixed phenyl/mesityl phosphate ester composition 失效
标题翻译：混合苯基/三甲基磷酸酯组合物
公开(公告)号：US4511498A
公开(公告)日：1985-04-16
申请号：US557706
申请日：1983-12-02
申请人： Fui-Tseng H. Lee , Charles V. Juelke , Joseph H. Finley
发明人： Fui-Tseng H. Lee , Charles V. Juelke , Joseph H. Finley
IPC分类号： C07F9/12 , C08K5/523 , C09K3/28
CPC分类号： C08K5/523 , C07F9/12
摘要： A mixed phenyl/mesityl phosphate ester composition that is useful as a fire retardant additive, having a phosphorus content of from about 8.2% to about 8.4% is prepared by reacting with agitation at about 120.degree. C. to 130.degree. C. distilled still bottom phenols with phosphorus oxychloride in the presence of a Friedel-Crafts catalyst to form a reaction product containing a substantial quantity of monoaryl phosphodichloridate and diaryl phosphochloridate. This reaction product is then further reacted at an elevated temperature with sufficient phenol to form a triaryl phosphate ester mixture. The mixed phenyl/mesityl phosphate ester so obtained remains a liquid at room temperature over a substantial period of time.
摘要翻译：通过在约120℃至130℃下搅拌反应制备磷含量为约8.2％至约8.4％的可用作阻燃添加剂的混合苯基/均三磷酸酯组合物，蒸馏的底部苯酚与磷酰氯在Friedel-Crafts催化剂存在下反应形成含有大量单芳基磷酸二氯化物和二芳基磷酸氯化物的反应产物。然后将该反应产物在升高的温度下与足够的苯酚反应以形成磷酸三芳基酯混合物。如此获得的混合苯基/均三甲基磷酸酯在相当长的时间内在室温下保持液体。

3. 发明授权

US4505850A Stabilizers for vinyl resins 失效
标题翻译：乙烯基树脂稳定剂
公开(公告)号：US4505850A
公开(公告)日：1985-03-19
申请号：US594953
申请日：1984-04-02
申请人： Derek G. Pearson
发明人： Derek G. Pearson
IPC分类号： A42B3/06 , C08K3/22 , C08K3/32 , C08K5/09 , C08K5/098 , C09K3/28
CPC分类号： A42B3/06 , C08K3/22 , C08K3/32 , C08K5/09 , C08K5/098
摘要： The fire hazard associated with the use of dibasic lead phosphite as a stabilizer for vinyl resins is reduced by mixing with the dibasic lead phosphite an additive selected from hydroxides or hydrated oxides of aluminium, magnesium or antimony, stearates of barium or calcium, dibasic lead stearate and carbonates of calcium or magnesium.
摘要翻译：与使用二价亚磷酸铅作为乙烯基树脂稳定剂相关的火灾危险可以通过与二价亚磷酸铅混合，从而选择铝，镁或锑的氢氧化物或水合氧化物，钡或钙的硬脂酸盐，二硬脂酸铅和钙或镁的碳酸盐。

4. 发明授权

US4442157A Fireproofing composition and door rabbet coated therewith 失效
标题翻译：防火组合物和涂覆的门拉布
公开(公告)号：US4442157A
公开(公告)日：1984-04-10
申请号：US220964
申请日：1980-12-29
申请人： Hans-Norbert Marx , Reimer Gottsche
发明人： Hans-Norbert Marx , Reimer Gottsche
IPC分类号： C08L61/06 , C09D5/18 , C09K21/00 , B32B3/00 , C09K3/28
CPC分类号： C09D5/185 , C08L61/06 , C09K21/00 , Y10S428/921 , Y10S521/907 , Y10T428/2462 , Y10T428/31855
摘要： Heat-foamable fireproofing compositions contain thermosetting phenolic resins, thermally decomposable organic nitrogen compounds, eg. dicyandiamide, an ammonium salt and a carbohydrate or polyhydric alcohol, and on decomposition form a stiff carbonaceous foam.
摘要翻译：热发泡防火组合物含有热固性酚醛树脂，可热分解的有机氮化合物，例如。双氰胺，铵盐和碳水化合物或多元醇，并且在分解时形成硬质含碳泡沫。

5. 发明授权

US4394306A Bromine containing fire retardant compositions of matter 失效
标题翻译：含溴阻燃物质的组成物
公开(公告)号：US4394306A
公开(公告)日：1983-07-19
申请号：US256476
申请日：1981-04-22
申请人： Manny Ravey
发明人： Manny Ravey
IPC分类号： C07C41/01 , C07C43/30 , C08K5/06 , C09K3/28
CPC分类号： C07C41/50 , C08K5/06 , Y10S428/921
摘要： The present invention relates to novel fire retardant compositions, based on the compounds 2-bromomethyl-2-hydroxy-methylpropane-1,3-diol, 2,2-bis(bromomethyl)propane-1,3-diol, 2-bromomethyl-2-hydroxymethyl-1,3-dibromopropane, and mixtures thereof, the compositions having a general formula (BrCH.sub.2).sub.m C[CH.sub.2 O(CH.sub.2 O).sub.x H].sub.4-m wherein m is between 1.6 to 2.3 and x is between 0.75 to 1.10. These compositions are characterized by their particular infra-red spectra.The novel fire retardant compositions are produced by the reaction of formaldehyde or its polymeric forms with the above compounds, followed by the removal of water from the reaction system.The fire retardant compositions according to the present invention are suitable as active or additive fire retardant ingredients for various polymeric materials, such as polyurethane, polyester or epoxide resins.
摘要翻译：本发明涉及基于化合物2-溴甲基-2-羟基 - 甲基丙烷-1,3-二醇，2,2-双（溴甲基）丙烷-1,3-二醇，2-溴甲基 - 2-羟甲基-1,3-二溴丙烷及其混合物，所述组合物具有通式（BrCH 2）m C [CH 2 O（CH 2 O）x H] 4-m，其中m为1.6至2.3，x为0.75至1.10。这些组合物的特征在于其特别的红外光谱。通过甲醛或其聚合物形式与上述化合物的反应，然后从反应体系中除去水来制备新的阻燃组合物。根据本发明的阻燃剂组合物适用于各种聚合物材料如聚氨酯，聚酯或环氧树脂的活性或添加剂阻燃剂成分。

6. 发明授权

US4362658A Process for preparing a flame retardant composition from sodium antimonate and composition thereby produced 失效
标题翻译：由锑酸锑制备阻燃剂组合物及由此制得的组合物的方法
公开(公告)号：US4362658A
公开(公告)日：1982-12-07
申请号：US184009
申请日：1980-09-04
申请人： Fulvio Contin
发明人： Fulvio Contin
IPC分类号： C08K3/00 , C01G30/00 , C01G30/02 , C08K3/22 , C08K3/24 , C08L1/00 , C08L27/00 , C08L67/00 , C09K21/02 , C09K3/28 , C08F6/00
CPC分类号： C01G30/004 , C01G30/023 , C08K3/24 , C09K21/02 , C01P2006/80 , C01P2006/82
摘要： Sodium antimonate is made to react with an acid solution so as to transform a fraction of the sodium antimonate into pentavalent antimony oxide, thus producing a mixture of pentavalent antimony oxide and sodium antimonate, the so produced mixture is separated from the solution and that mixture is dried and pulverized. The so produced powder presents good flame retardant properties.
摘要翻译：使锑酸钠与酸溶液反应，将锑酸钠的一部分转化为五价氧化锑，从而制备五价氧化锑和锑酸钠的混合物，将所得混合物与溶液分离，该混合物为干燥并粉碎。所生产的粉末具有良好的阻燃性能。

7. 发明授权

US4360450A Colloidal aqueous dispersion of an alkali metal polyantimonate and a process of making said 失效
标题翻译：碱金属聚锑酸盐的胶体水分散体及其制备方法
公开(公告)号：US4360450A
公开(公告)日：1982-11-23
申请号：US325079
申请日：1981-11-25
申请人： Destin A. LeBlanc
发明人： Destin A. LeBlanc
IPC分类号： C09K21/02 , D06M11/47 , B01J13/00 , C09K3/28
CPC分类号： D06M11/47 , C09K21/02
摘要： A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.
摘要翻译：一种在不存在卤素化合物的情况下改善含纤维材料的阻燃性能的方法，其包括用有效量的含有碱金属与锑的摩尔比的碱金属聚锑酸盐的胶体水分散体处理所述纤维材料描述了至少约0.3:1的分散体和干燥所述材料。

8. 发明授权

US4307148A Flame retardant with improved durability comprising an alkali metal polyantimonate and cellulosic materials treated therewith in the absence of chlorine 失效
标题翻译：具有改进的耐久性的阻燃剂，其包含碱金属聚锑酸盐和在不存在氯的情况下用其处理的纤维素材料
公开(公告)号：US4307148A
公开(公告)日：1981-12-22
申请号：US68260
申请日：1979-08-20
申请人： Destin A. LeBlanc
发明人： Destin A. LeBlanc
IPC分类号： D06M11/47 , B27K3/28 , C09K3/28 , D06M11/04
CPC分类号： D06M11/47 , Y10S428/92 , Y10T428/3188 , Y10T428/31891 , Y10T428/31895 , Y10T428/31906 , Y10T428/31949 , Y10T428/31953 , Y10T428/31964 , Y10T442/2656
摘要： A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.
摘要翻译：一种在不存在卤素化合物的情况下改善含纤维材料的阻燃性能的方法，其包括用有效量的含有碱金属与锑的摩尔比的碱金属聚锑酸盐的胶体水分散体处理所述纤维材料描述了至少约0.3:1的分散体和干燥所述材料。

9. 发明授权

US4299708A Fire-extinguishing or fire-preventive composition 失效
标题翻译：灭火或防火组合物
公开(公告)号：US4299708A
公开(公告)日：1981-11-10
申请号：US41749
申请日：1979-05-23
申请人： Trevor M. James
发明人： Trevor M. James
IPC分类号： A62D1/00 , C09K3/28
CPC分类号： A62D1/0014
摘要： A fire extinguishing or fire preventing composition comprising sawdust combined with a dry coloring material which reacts with the sawdust at elevated temperature to improve the fire extinguishing properties. In one form the coloring material comprises a transition metal compound such as ferric oxide Fe.sub.2 O.sub.3 which forms complexes with glucose units derived from the cellulose in sawdust. In another form the coloring material is organic, for example, an azo-compound which forms a complex with the cellulose in the sawdust, and this also improves the fire extinguishing properties.
摘要翻译：一种灭火或防火组合物，其包括与高温下与锯屑一起反应的干燥着色材料的锯屑，以提高灭火性能。在一种形式中，着色材料包括过渡金属化合物如氧化铁Fe 2 O 3，其与来自锯屑中的纤维素的葡萄糖单元形成复合物。在另一种形式中，着色材料是有机的，例如与木屑中的纤维素形成络合物的偶氮化合物，这也提高了灭火性能。

10. 发明授权

US4272414A Chemical retardants for forest fires 失效
标题翻译：森林火灾的化学阻燃剂
公开(公告)号：US4272414A
公开(公告)日：1981-06-09
申请号：US48566
申请日：1979-06-14
申请人： H. Lawrence Vandersall
发明人： H. Lawrence Vandersall
IPC分类号： A62D1/00 , C09K21/04 , C09D5/18 , C09K3/28
CPC分类号： C09K21/04 , A62D1/0035
摘要： Fire retardant compositions comprising (a) ammonium sulfate; (b) a carboxyalkyl or hydroxyalkyl ether of a polygalactomannan; and optionally (c) other fire retardant chemicals from the groups consisting of monoammonium orthophosphate, diammonium orthophosphate; monoammonium pyrophosphate; diammonium pyrophosphate; triammonium pyrophosphate; tetraammonium pyrophosphate; ammonium, substituted ammonium, amide and melamine polyphosphates; ammonium-alkali metal mixed salts of ortho-, pyro- and polyphosphates; ammonium-alkaline earth metal mixed salts of ortho-, pyro- and polyphosphates; and mixtures thereof. There are disclosed both aqueous forms and concentrated non-aqueous forms of the compositions which are particularly useful for preventing, extinguishing and suppressing forest fires.
摘要翻译：阻燃组合物，其包含（a）硫酸铵; （b）聚半乳甘露聚糖的羧基烷基或羟烷基醚; 和（c）由正磷酸正铵，正磷酸二铵组成的组中的其它阻燃化学品; 焦磷酸单铵; 焦磷酸二铵; 焦磷酸三铵; 焦磷酸四铵; 铵，取代的铵，酰胺和三聚氰胺多磷酸盐; 邻位，焦磷酸和多磷酸的铵 - 碱金属混合盐; 邻位，焦磷酸和多磷酸的铵 - 碱土金属混合盐; 及其混合物。公开了特别可用于防止，扑灭和抑制森林火灾的组合物的水性形式和浓缩的非水性形式。

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