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1. 发明授权

US4251493A Gas purification process 失效
标题翻译：气体净化过程
公开(公告)号：US4251493A
公开(公告)日：1981-02-17
申请号：US57154
申请日：1979-07-12
申请人： Donald R. Randell , Emyr Phillips
发明人： Donald R. Randell , Emyr Phillips
IPC分类号： B01D53/52 , B01D53/14 , B01D53/77 , B01J31/02 , C01B17/05 , C01B17/46 , C07C7/11 , C07C67/00 , C07C301/00 , C07C303/22 , C07C303/32 , C07C303/38 , C07C303/40 , C07C311/14 , C07C311/15 , C07C311/16 , C07C311/19 , C09K3/00 , C10G19/02 , C10G27/06 , C10G27/12 , B01D53/34
CPC分类号： B01D53/1493 , C10G27/06
摘要： Processes for the absorption and subsequent removal as sulphur of hydrogen sulphide from gases, gas mixtures and liquid hydrocarbons in which the material containing hydrogen sulphide is washed with an aqueous alkaline solution containing one or more compounds having the general formula: ##STR1## where A is a C.sub.1 -C.sub.4 straight or branched chain alkylene radical,B is a --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 HM or --PO.sub.3 M.sub.2 grouping, whereM is hydrogen, or a cation giving a water-soluble derivative,R is hydrogen, a cation giving a water-soluble derivative, or C.sub.1 -C.sub.4 straight or branched alkyl,R.sub.1 is hydrogen, methyl or --COOH and m is 0 or 1 the hydrogen sulphide being oxidized and sulphur liberated, and the reduced anthraquinone sulphonamide being oxidized by contact with free oxygen or a gas containing it, and optionally there being present in addition a metal having at least two valency states, and if necessary a chelating or sequestering agent for retaining such metal compounds in solution.
摘要翻译：吸收和随后从气体，气体混合物和液体烃中除去硫化氢的方法，其中含有硫化氢的材料用含有一种或多种具有以下通式的化合物的碱性水溶液洗涤：其中A 是C1-C4直链或支链亚烷基，B是-SO3M，-CO2M，-PO3HM或-PO3M2基团，其中M是氢，或阳离子得到水溶性衍生物，R是氢，水溶性衍生物或C 1 -C 4直链或支链烷基，R 1为氢，甲基或-COOH，m为0或1，所述硫化氢被氧化和释放硫，还原的蒽醌磺酰胺通过与游离氧接触而被氧化或含有它的气体，并且任选地还存在另外具有至少两个价态的金属，并且如果需要，还存在用于将这些金属化合物保留在溶液中的螯合或螯合剂。

2. 发明授权

US4276224A Anthraquinone sulphonamide compounds and preparation 失效
标题翻译：蒽醌磺酰胺化合物及其制备方法
公开(公告)号：US4276224A
公开(公告)日：1981-06-30
申请号：US57157
申请日：1979-07-12
申请人： Donald R. Randell , Emyr Phillips
发明人： Donald R. Randell , Emyr Phillips
IPC分类号： B01D53/52 , B01D53/14 , B01D53/77 , B01J31/02 , C01B17/05 , C01B17/46 , C07C7/11 , C07C67/00 , C07C301/00 , C07C303/22 , C07C303/32 , C07C303/38 , C07C303/40 , C07C311/14 , C07C311/15 , C07C311/16 , C07C311/19 , C09K3/00 , C10G19/02 , C10G27/06 , C10G27/12 , C07C143/665
CPC分类号： B01D53/1493 , C10G27/06
摘要： Compounds having the general formula: ##STR1## where A is a C.sub.1 -C.sub.4 straight or branched chain alkylene radical, B is a --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 HM or --PO.sub.3 M.sub.2 grouping,M is hydrogen, or a cation giving a water-soluble derivative,R is hydrogen, a cation giving a water-soluble derivative or a C.sub.1 -C.sub.4 straight or branched alkyl, R.sub.1 is hydrogen, methyl or --COOH, and m is 0 or 1 and processes of preparing them.
摘要翻译：具有以下通式的化合物：其中A是C 1 -C 4直链或支链亚烷基，B是-SO 3 M，-CO 2 M，-PO 3 H M或-PO 3 M 2基团，M是氢或提供水的阳离子可溶性衍生物，R为氢，得到水溶性衍生物或C1-C4直链或支链烷基的阳离子，R1为氢，甲基或-COOH，m为0或1，及其制备方法。

3. 发明授权

US4810399A Aminomethyl derivatives of benzothiazolinethione as lubricant additives 失效
标题翻译：苯并噻唑硫酮的氨基甲基衍生物作为润滑剂添加剂
公开(公告)号：US4810399A
公开(公告)日：1989-03-07
申请号：US141175
申请日：1988-01-06
申请人： Hugo Camenzind , Emyr Phillips
发明人： Hugo Camenzind , Emyr Phillips
IPC分类号： C07D417/06 , C07D277/70 , C07D417/12 , C07D521/00 , C10M135/36 , C10N30/06 , C10N30/10 , C10N30/12 , C10N40/00 , C10N40/25 , C10N50/10 , C10M133/38
CPC分类号： C07D277/70 , C10M135/36 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106
摘要： The invention relates to lubricant compositions comprising(a) one or more mineral oils or synthetic oils and(b) 0.05 to 5% by weight of at least one compound of formulae I, II and III ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are as defined in claim 1; and(c) further optional lubrican additives.Some of these compounds are new and can be prepared by Mannich reaction from the appropriate 2-mercaptobenzothiazoles, an aldehyde R.sup.2 -CHO and a primary or secondary mono- or diamine. these Mannich bases are useful additives for lubricants for reducing friction, wear, corrosion and oxidation.
摘要翻译：本发明涉及润滑剂组合物，其包含（a）一种或多种矿物油或合成油和（b）0.05至5重量％的至少一种式I，II和III的化合物。 III其中R1，R2，R3，R4和R5如权利要求1中所定义; 和（c）可选的润滑添加剂。这些化合物中的一些是新的，并且可以通过适当的2-巯基苯并噻唑，醛R2-CHO和伯或仲单或二胺的曼尼希反应制备。这些曼尼希碱是用于减少摩擦，磨损，腐蚀和氧化的润滑剂的有用添加剂。

4. 发明授权

US4719036A Compositions containing heterocyclic corrosion inhibitors 失效
标题翻译：含有杂环腐蚀抑制剂的组合物
公开(公告)号：US4719036A
公开(公告)日：1988-01-12
申请号：US731816
申请日：1985-05-08
申请人： Brian G. Clubley , Emyr Phillips
发明人： Brian G. Clubley , Emyr Phillips
IPC分类号： C07D235/28 , C07D263/58 , C07D277/74 , C07D417/12 , C09D5/08 , C23F11/00 , C23F11/16 , C09K15/30
CPC分类号： C23F11/165 , C07D277/74 , C09D5/086
摘要： New anticorrosive compositions comprise:(A) an applicational medium selected from (a) surface coatings and (b) wholly or partly aqueous non-coating media,(B) as corrosion inhibitor, an amide, imide or nitrile of an aliphatic- or cycloaliphatic mono-, di-, tri- or tetra-carboxylic acid which is substituted in the aliphatic- or cycloaliphatic residue by one or more groups having the formula: ##STR1## in which X is oxygen, sulphur or NH; and each R, independently, is hydrogen, alkyl, haloalkyl, alkoxy, alkylthio, alkylsulphonyl, cycloalkyl, phenyl, alkylphenyl, phenylalkyl, halogen, cyano, nitro, hydroxy, --COOH, --COOalkyl or a primary-, secondary- or tertiary amino- or carbamoyl group; or a non-toxic base addition salts of those components (B) which contain free carboxyl groups.
摘要翻译：新的防腐组合物包括：（A）选自（a）表面涂层和（b）全部或部分水性非涂布介质的应用介质，（B）作为缓蚀剂，脂族或脂环族的酰胺，酰亚胺或腈在脂族或脂环族残基中被一个或多个具有下式的基团取代的单 - ，二 - ，三 - 或四 - 羧酸：其中X是氧，硫或NH; 并且每个R独立地是氢，烷基，卤代烷基，烷氧基，烷硫基，烷基磺酰基，环烷基，苯基，烷基苯基，苯基烷基，卤素，氰基，硝基，羟基，-COOH，-COO烷基或伯，仲或叔氨基 - 或氨基甲酰基; 或含有游离羧基的组分（B）的无毒碱加成盐。

5. 发明授权

US5102457A Anticorrosive surface coatings 失效
标题翻译：防腐表面涂料
公开(公告)号：US5102457A
公开(公告)日：1992-04-07
申请号：US683583
申请日：1991-04-10
申请人： Adalbert Braig , Emyr Phillips
发明人： Adalbert Braig , Emyr Phillips
IPC分类号： C07D277/74 , C09D5/08 , C09D5/44
CPC分类号： C09D5/086 , C07D277/74 , C09D5/4492 , Y10T428/31605 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692 , Y10T428/31696 , Y10T428/31699 , Y10T428/31703 , Y10T428/31707 , Y10T428/31714
摘要： Compounds of formula I: ##STR1## in which R, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined in claim 1, are suitable as corrosion inhibitors in surface coatings for metals.
摘要翻译：式I化合物：其中R，R 1，R 2，R 3，R 4，R 5，R 6和R 7如权利要求1中所定义的其中R 1，R 1，R 2，R 5，R 6和R 7适合作为金属表面涂层中的腐蚀抑制剂。

6. 发明授权

US4637926A Method of removing hydrogen sulphide from gases 失效
标题翻译：从气体中除去硫化氢的方法
公开(公告)号：US4637926A
公开(公告)日：1987-01-20
申请号：US758013
申请日：1985-07-24
申请人： Emyr Phillips , Brian Holt
发明人： Emyr Phillips , Brian Holt
IPC分类号： B01D53/14 , C10G19/02 , C10G27/06 , C10G27/10 , C10K1/12 , C10K1/14 , C01B17/02 , B01D53/34
CPC分类号： C10G19/02 , B01D53/1468 , B01D53/1493 , C10G27/06 , C10G27/10 , C10K1/12 , C10K1/14
摘要： Process for the absorption of hydrogen sulphide impurity from gases or liquid hydrocarbons comprising:(a) washing the gas or liquid hydrocarbon containing hydrogen sulphide with an aqueous alkaline solution of(a1) one or more compounds having the formula: ##STR1## or a water-soluble salt thereof, wherein m is 0 or 1 and R is a hydrogen atom or a methyl or carboxy group, and(a2) one or more compounds of a metal capable of existing in at least two valency states;(b) removing sulphur formed by oxidation of hydrogen sulphide; and(c) re-oxidizing the hydroquinone formed from reduction of the compound of formula I.
摘要翻译：用于从气体或液体烃吸收硫化氢杂质的方法，包括：（a）用（a1）一种或多种具有下式的化合物的碱性水溶液洗涤含有硫化氢的气体或液体烃：其中m为0或1，R为氢原子或甲基或羧基，和（a2）一种或多种能够存在至少两个价态的金属化合物; （b）除去由硫化氢氧化形成的硫; 和（c）重新氧化式I化合物还原形成的氢醌。

7. 发明授权

US5198482A Corrosion-inhibiting coating compositions 失效
标题翻译：防腐蚀涂料组合物
公开(公告)号：US5198482A
公开(公告)日：1993-03-30
申请号：US718073
申请日：1991-06-20
申请人： Emyr Phillips , Adalbert Braig
发明人： Emyr Phillips , Adalbert Braig
IPC分类号： C08K5/17 , C08K5/47 , C09D5/08
CPC分类号： C08K5/47 , C08K5/17 , C09D5/086
摘要： The present invention provides a corrosion-inhibiting coating composition comprising:a) an acid-sensitive film former; andb) as a corrosion inhibitor, an effective amount of a salt ofi) an aliphatic or cycloaliphatic mono-, di tri- or tetra-carboxylic acid which is substituted in its aliphatic or cycloaliphatic radical by at least one group of the formula ##STR1## in which each R independently of the others is hydrogen, alkyl, halogenoalkyl, alkoxy, alkylthio, alkylsulfonyl, cycloalkyl, phenyl, alkylphenyl, phenylalkyl, halogen, --CN, --NO.sub.2, --COOH, COOalkyl, --OH or a primary, secondary or tertiary amino or carbamoyl group; with ii) n molar equivalents of an amine of the formula ##STR2## in which X, Y and Z are the same or different and each it hydrogen, alkyl optionally interrupted by one or more oxygen atoms, or alkyl substituted by hydroxy, or is phenyl, phenyl alkyl or alkylphenyl; and n is 1, 2, 3 or 4 depending upon the number of carboxyl groups in the carboxylic acid b i).
摘要翻译：本发明提供了一种防腐涂料组合物，其包含：a）酸敏成膜剂; 和b）作为腐蚀抑制剂，有效量的i）脂族或脂环族单 - ，三 - 或四 - 羧酸的盐，其在其脂族或脂环族基团中被至少一个式其中每个R独立地为氢，烷基，卤代烷基，烷氧基，烷硫基，烷基磺酰基，环烷基，苯基，烷基苯基，苯基烷基，卤素，-CN，-NO 2，-COOH，COO烷基，-OH或伯，仲或叔氨基或氨基甲酰基; 其中ii）n摩尔当量的式“IMAGE”的胺，其中X，Y和Z相同或不同，并且各自为氢，任选被一个或多个氧原子中断的烷基或被羟基取代的烷基，或者是苯基，苯基烷基或烷基苯基; 并且n为1,2,3或4，这取决于羧酸b i）中羧基的数目。

8. 发明授权

US5169950A Processes for preparing phenolic benzothiazole derivatives 失效
标题翻译：酚类苯并噻唑衍生物的制备方法
公开(公告)号：US5169950A
公开(公告)日：1992-12-08
申请号：US747032
申请日：1991-08-19
申请人： Adalbert Braig , Hans-Rudolf Meier , David G. Leppard , Robert C. Wasson , Emyr Phillips
发明人： Adalbert Braig , Hans-Rudolf Meier , David G. Leppard , Robert C. Wasson , Emyr Phillips
IPC分类号： C07D277/70 , C07D277/72 , C08K5/46 , C09D5/08 , C09K15/30 , C10M135/36
CPC分类号： C07D277/70 , C07D277/72 , C08K5/46 , C09D5/086 , C09K15/30 , C10M135/36 , C10M2207/16 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/045 , C10N2210/02 , C10N2230/12
摘要： Compounds of the formula I ##STR1## wherein R, R.sup.1, R.sup.2, R.sup.3, and R.sup.5 have the meaning given in claim 1 are formed by thermal rearrangement of the isomers of formula V ##STR2## especially in the presence of basic catalysts. The compounds are corrosion inhibitors for organic materials, in particular coating materials and lubricants. In these substrates they also act as antioxidants and light-stabilizers and are very stable to heat.
摘要翻译：其中R，R 1，R 2，R 3和R 5具有权利要求1中给出的含义的式I化合物（I）通过式V（V）的异构体的热重排形成，特别是在存在下的碱性催化剂。这些化合物是有机材料的腐蚀抑制剂，特别是涂料和润滑剂。在这些基材中，它们也起到抗氧化剂和光稳定剂的作用，对热量非常稳定。

9. 发明授权

US4803001A Aminomethyl derivatives of benzothiazolinethione as lubricant additives 失效
标题翻译：苯并噻唑硫酮的氨基甲基衍生物作为润滑剂添加剂
公开(公告)号：US4803001A
公开(公告)日：1989-02-07
申请号：US141165
申请日：1988-01-06
申请人： Hugo Camenzind , Emyr Phillips
发明人： Hugo Camenzind , Emyr Phillips
IPC分类号： C07D417/06 , C07D277/70 , C07D417/12 , C07D521/00 , C10M135/36 , C10N30/06 , C10N30/10 , C10N30/12 , C10N40/00 , C10N40/25 , C10N50/10 , C10M133/38
CPC分类号： C07D277/70 , C10M135/36 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106
摘要： The invention relates to lubricant compositions comprising(a) one or more mineral oils or synthetic oils and(b) 0.05 to 5% by weight of at least one compound of formulae I, II and III ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are as defined in claim 1; and(c) further optional lubricant additives.Some of these compounds are new and can be prepared by Mannich reaction from the appropriate 2-mercaptobenzothiazoles, an aldehyde R.sup.2 --CHO and a primary or secondary mono- or diamine. These Mannich bases are useful additives for lubricants for reducing friction, wear, corrosion and oxidation.
摘要翻译：本发明涉及润滑剂组合物，其包含（a）一种或多种矿物油或合成油，和（b）0.05至5重量％的至少一种式I，II和III的化合物。 III其中R1，R2，R3，R4和R5如权利要求1中所定义; 和（c）进一步任选的润滑剂添加剂。这些化合物中的一些是新的，并且可以通过适当的2-巯基苯并噻唑，醛R2-CHO和伯或仲单或二胺的曼尼希反应制备。这些曼尼希碱是减少摩擦，磨损，腐蚀和氧化的润滑剂的有用添加剂。

10. 发明授权

US4589992A New salts useful as corrosion inhibitors 失效
标题翻译：新盐可用作腐蚀抑制剂
公开(公告)号：US4589992A
公开(公告)日：1986-05-20
申请号：US661624
申请日：1984-10-17
申请人： Emyr Phillips , David Wilson
发明人： Emyr Phillips , David Wilson
IPC分类号： C10L10/00 , C07C53/126 , C07C55/20 , C07C57/03 , C07C59/68 , C07C67/00 , C07C213/00 , C07C215/40 , C07C217/06 , C07C313/00 , C07C323/25 , C10L1/22 , C10L1/222 , C10L1/24 , C10M133/08 , C10M133/14 , C10M135/24 , C10M135/30 , C10N30/12 , C23F11/12 , C23F11/14 , C23F11/16 , C10M129/40
CPC分类号： C07C323/25 , C07C53/126 , C07C55/20 , C07C57/03 , C07C59/68 , C10L1/2225 , C10L1/2406 , C10M133/08 , C10M135/24 , C23F11/124 , C23F11/143 , C23F11/16 , C10M2215/042 , C10M2219/084 , C10M2219/086 , C10N2230/12
摘要： Salts having the formula:Y--NH.sub.3.sup.+.RCO.sub.2.sup.- Iin which Y is a group of formula R.sup.1 XCH.sub.2 CH(OH)CH.sub.2 --, R and R.sup.1 are the same or different and each is a straight- or branched chain alkyl group having from 1 to 18 carbon atoms, a straight- or branched chain alkenyl group having from 2 to 18 atoms, a cycloalkyl group having from 4 to 12 ring atoms, an aryl group having 6-10 ring atoms, or an aralkyl group having from 7 to 10 carbon atoms; and X is O, CO.sub.2, NR.sup.2 or S and R.sup.2 is hydrogen, a straight- or branched chain alkyl group having from 1 to 18 carbon atoms or an alkenyl group having from 2 to 18 C atoms.
摘要翻译：具有式Y-NH 3 +·RCO 2 -I的盐，其中Y为式R1XCH2CH（OH）CH2-基团，R和R1相同或不同，分别为直链或支链烷基，具有1〜 18个碳原子，具有2至18个原子的直链或支链烯基，具有4至12个环原子的环烷基，具有6-10个环原子的芳基或具有7至10个碳原子的芳烷基原子 X是O，CO 2，NR 2或S，R 2是氢，具有1至18个碳原子的直链或支链烷基或具有2至18个C原子的链烯基。

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