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    • 1. 发明授权
    • Method for producing an aqueous polymer dispersion
    • 聚合物水分散体的制造方法
    • US07632902B2
    • 2009-12-15
    • US10513335
    • 2003-05-21
    • Dirk WulffJesper FeldthusenGerhard AuchterGerald WildburgRalf Fink
    • Dirk WulffJesper FeldthusenGerhard AuchterGerald WildburgRalf Fink
    • C08F291/00C08F2/24C08F257/02C08F265/04C08F285/00
    • C08F257/02C08F265/04C08F285/00C08F291/00C08L51/003C09J151/003
    • The invention relates to a method for producing an aqueous polymer dispersion having a polymer solids content of ≧50% by weight by carrying out the radically initiated aqueous emulsion polymerization of ethylenically unsaturated compounds (monomers). The inventive method is characterized in that: a) a mixture is provided in a polymerization vessel and contains a partial quantity 1 consisting of: deionized water, 0.001 to 0.5 parts by weight of a polymer with a weighted average particle diameter of ≦100 nm; 0.0001 to 0.1 parts by weight of dispersants, and 0.5 to 10 parts by weight of monomers, and the monomers are polymerized with a conversion of ≧80% [polymerization step A], and; b) afterwards, a monomer emulsion containing partial quantity 2, which consists of deionized water, 0.1 to 5 parts by weight of dispersants and 90 to 99.5 parts by weight of monomers, is fed under polymerization conditions to the obtained reaction mixture [polymerization step B], whereby; c) the total amount of the monomers used for the polymerization is equal to 100 parts by weight, and the total amount of deionized water is ≦100 parts by weight.
    • 本发明涉及通过进行烯键式不饱和化合物(单体)的自由引发的水乳液聚合来制备聚合物固体含量≥50重量%的聚合物水分散体的制备方法。 本发明的方法的特征在于:a)在聚合容器中提供混合物,并含有部分量1,其组成为:去离子水,0.001至0.5重量份的加权平均粒径<= 100nm的聚合物 ; 0.0001〜0.1重量份分散剂和0.5〜10重量份单体,单体以≥80%的转化率[聚合步骤A]进行聚合, b)之后,在聚合条件下将得自部分量2的由去离子水,0.1至5重量份分散剂和90至99.5重量份单体组成的单体乳液加入到所得反应混合物中[聚合步骤B ], c)用于聚合的单体的总量等于100重量份,去离子水的总量<100重量份。