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    • 2. 发明授权
    • Fluorescent whitening agents
    • 荧光增白剂
    • US5656760A
    • 1997-08-12
    • US530975
    • 1995-09-20
    • Jean-Pierre BacherClaude EckhardtDieter Reinehr
    • Jean-Pierre BacherClaude EckhardtDieter Reinehr
    • C07D251/52C07D251/68C07D251/70C11D3/395D06L3/12D06M13/07C07D251/48C07D251/54C07D403/02
    • D06L3/1214C07D251/68D06L3/1257D06M13/07D06M2101/06
    • The present invention provides a compound having the formula: ##STR1## in which M is hydrogen, sodium, potassium, calcium, magnesium, ammonium, mono-, di-, tri- or tetra-C.sub.1 -C.sub.4 alkylammonium, mono-, di- or tri-C.sub.1 -C.sub.4 hydroxyalkylammonium or ammonium that is di- or tri-substituted by a mixture of C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 hydroxyalkyl groups; R.sub.1 is a group having the formula: ##STR2## in which M has its previous significance and n is 1 or 2; and R.sub.2 is O--C.sub.1 -C.sub.12 alkyl or N(R.sub.3)(R.sub.4) in which R.sub.3 and R.sub.4, independently, are hydrogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl, or R.sub.3 and R.sub.4, together with the nitrogen atom, are the atoms required to form a pyrrolidine, piperidine or morpholine group.The compounds of formula (1) are particularly useful as fluorescent whitening agents for cotton in discontinuous processes, in the course of which an acidic treatment, especially a finishing treatment using a polymer resin, occurs.
    • 本发明提供具有下式的化合物:其中M是氢,钠,钾,钙,镁,铵,一,二,三或四-C 1 -C 4烷基铵, 被C1-C4烷基和C1-C4羟烷基的混合物二或三取代的单,二或三-C 1 -C 4羟烷基铵或铵; R1是具有下式的组:其中M具有其先前的含义,n是1或2; 并且R 2为O-C 1 -C 12烷基或N(R 3)(R 4),其中R 3和R 4独立地为氢,C 1 -C 12烷基或C 1 -C 4羟烷基,或者R 3和R 4与氮原子一起为所需原子 以形成吡咯烷,哌啶或吗啉基团。 式(1)的化合物特别可用作不连续工艺中用于棉花的荧光增白剂,其中酸性处理,特别是使用聚合物树脂的整理处理发生。
    • 7. 发明授权
    • Process for the preparation of 2-hydroxy-4,6-diaryl-1,3,5-triazines
    • 制备2-羟基-4,6-二芳基-1,3,5-三嗪的方法
    • US5288867A
    • 1994-02-22
    • US11931
    • 1993-02-01
    • Dieter ReinehrJean-Pierre Bacher
    • Dieter ReinehrJean-Pierre Bacher
    • C07D251/22C07D251/52
    • C07D251/22
    • There is disclosed a process for the preparation of 2-hydroxy-4,6-diaryl-1,3,5-triazines, which comprises reacting the compound of formula ##STR1## wherein R is hydrogen, C.sub.1 -C.sub.4 alkyl or halogen, with urea, using a base selected from the class of the alkali metal hydrides, alkaline earth metal hydrides, or alkali metal amides, alkaline earth metal amides, or of the alkali metal C.sub.1 -C.sub.4 alcoholates in the presence of a polar solvent, to give the final products in a one step process in which the molar ratio of urea to base is 1:2 to 1:3 and the molar ratio of compound of formula (1) to urea is 2:1 to 5:1.2-Hydroxy-4,6-diaryl-1,3,5-triazines are prepared in very good yield by the inventive process. The compounds are used as intermediates for the synthesis of UV absorbers.
    • 公开了2-羟基-4,6-二芳基-1,3,5-三嗪的制备方法,该方法包括使式(*化学结构*)(1)的化合物(其中R是氢,C1- C4烷基或卤素与尿素反应,使用选自碱金属氢化物,碱土金属氢化物或碱金属氨化物,碱土金属氨化物或碱金属C1-C4醇化物的碱在极性溶剂存在下 在一步法中给出最终产物,其中脲与碱的摩尔比为1:2至1:3,式(1)化合物与脲的摩尔比为2:1至5:1。 通过本发明方法以非常好的收率制备2-羟基-4,6-二芳基-1,3,5-三嗪。 该化合物用作合成UV吸收剂的中间体。