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1. 发明授权

US4981885A Polymer dispersions, process for their preparation, and their use as binders 失效
标题翻译：聚合物分散体，其制备方法及其作为粘合剂的用途
公开(公告)号：US4981885A
公开(公告)日：1991-01-01
申请号：US397770
申请日：1989-08-23
申请人： Dieter Engel , Kurt Kraft
发明人： Dieter Engel , Kurt Kraft
IPC分类号： C08F291/06 , C08F2/24 , C08F283/10 , C08F291/00 , C08F291/10 , C09D5/25 , C09D151/00 , C09D151/06
CPC分类号： C09D151/003 , C08F283/10
摘要： Aqueous polymer dispersions based on (A) 1 to 99% by weight of a carboxy-functional polymer which additionally contains epoxy groups, (B) 1 to 99% by weight of a polymer obtained from at least one .alpha.,.beta.-olefinically unsaturated monomer, the polymer (B) having been prepared in the presence of polymer (A), (C) 0 to 20% by weight of anionic or non-ionic emulsifiers or a mixture of the two or protective colloids, the quantity data relating to the solids content of components (A) to (C), and if appropriate further conventional additives, the sum of all the components always being 100%.The invention also relates to a process for the preparation of such polymer dispersions, which are particularly suitable as a binder component in metallic basecoats or metal-free, (uni) basecoats and electrocoatings.
摘要翻译：基于（A）1至99重量％的另外含有环氧基的羧基官能聚合物的水性聚合物分散体，（B）1至99重量％的由至少一种α，β-烯属不饱和单体获得的聚合物，聚合物（B）已经在聚合物（A），（C）0-20重量％的阴离子或非离子乳化剂或两者或保护胶体的混合物存在下制备，数量数据与组分（A）至（C）的固体含量，如果合适的话另外的常规添加剂，所有组分的总和总是100％。本发明还涉及一种制备这种聚合物分散体的方法，其特别适合作为金属底漆或无金属（uni）底涂层和电涂层中的粘合剂组分。

2. 发明授权

US4758615A Polymers containing urethane groups prepared by the reaction of polyamino compounds and cyclic carbonates 失效
标题翻译：通过聚氨基化合物和环状碳酸酯反应制备的含有氨基甲酸酯基团的聚合物
公开(公告)号：US4758615A
公开(公告)日：1988-07-19
申请号：US53088
申请日：1987-05-22
申请人： Dieter Engel , Christoph Just , Gerhard Brindopke , Gerd Walz
发明人： Dieter Engel , Christoph Just , Gerhard Brindopke , Gerd Walz
IPC分类号： C08G18/30 , C08G18/28 , C08G18/64 , C08G71/04 , C09D175/00 , C09D175/04 , C08G67/00
CPC分类号： C09D175/04 , C08G18/6415 , C08G71/04
摘要： Polymers which contain urethane groups and are capable of being crosslinked by extraneous crosslinking agents, solutions thereof and aqueous dispersions thereof, prepared without the use of isocyanates by reacting polyamino compounds with polycarbonates and, if appropriate, reacting the reaction product further with polycarboxylic acids to give products having an acid number between 0 and 100, and, if appropriate, neutralizing the resulting products partly or completely by adding basic compounds, preferably organic bases, and, if appropriate, mixing the partly or completely neutralized products vigorously with an amount of water such that aqueous polymer dispersions having a solids content of up to 75% by weight, relative to the dispersion, are obtained.The use of the polymers containing urethane groups on their own or as a mixture with further reactive components, as extraneous crosslinking agents, from the group comprising isocyanate, melamine, alkyd and epoxy resins, in non-aqueous or aqueous formulations of adhesives and paints, especially in aqueous baking paint formulations and in aqueous, curable paint formulations which can be deposited by anaphoresis.
摘要翻译：通过使聚氨基化合物与聚碳酸酯反应制备而不使用异氰酸酯的外来交联剂，其溶液和水分散体的聚合物可以通过外来交联剂，其溶液和水分散体进行交联，并且如果合适，使反应产物进一步与多元羧酸反应，得到酸值在0和100之间的产物，如果合适，通过添加碱性化合物，优选有机碱部分或完全中和所得产物，并且如果合适，将部分或完全中和的产物与一定量的水获得相对于分散体具有高达75重量％的固体含量的聚合物水分散体。含有氨基甲酸酯基团的聚合物在其非水或水性粘合剂和涂料制剂中独立地或作为与来自包含异氰酸酯，三聚氰胺，醇酸树脂和环氧树脂的组中的另外的反应性组分作为外来交联剂的混合物的使用，特别是在水性烘烤漆配方中以及可以通过吸水沉积的水性，可固化涂料配方中。

3. 发明授权

US4758475A Isocyanate-free polyurethane dispersions 失效
标题翻译：不含异氰酸酯的聚氨酯分散体
公开(公告)号：US4758475A
公开(公告)日：1988-07-19
申请号：US943625
申请日：1986-12-18
申请人： Helmut Eckes , Dieter Engel
发明人： Helmut Eckes , Dieter Engel
IPC分类号： C08G12/00 , C08G12/20 , C08G71/00 , C08G71/04 , C08J3/03 , C08L61/20 , C09D175/04
CPC分类号： C08J3/03 , C08G71/04 , C09D175/04 , C08J2375/04 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , Y10T428/31551 , Y10T428/31558 , Y10T428/31591 , Y10T428/31601 , Y10T428/31605 , Y10T428/31942
摘要： Polyurethane dispersions based on reaction products from (A) bismethylolated urethanes having at least 2 urethane groups and (B) polyhydroxyl compounds which contain groups which are capable of ion formation, these groups being present in neutralized form, and a process for the preparation thereof. The use of the dispersions for the surface-coating of metal, plastics, glass, leather and paper.
摘要翻译：基于具有至少2个氨基甲酸酯基团的（A）双羟甲基化氨基甲酸酯的反应产物和（B）含有能够离子形成的基团的多羟基化合物的反应产物的聚氨酯分散体，这些基团以中和形式存在，以及其制备方法。使用分散体对金属，塑料，玻璃，皮革和纸张进行表面涂层。

4. 发明授权

US06742399B2 Respiratory flow sensor with flow channel having a measuring transducer and air resistance body 失效
标题翻译：具有流量通道的呼吸流量传感器具有测量传感器和空气阻力体
公开(公告)号：US06742399B2
公开(公告)日：2004-06-01
申请号：US09846623
申请日：2001-05-01
申请人： Rainer Kunz , Götz Kullik , Dieter Engel , Thomas Leyer
发明人： Rainer Kunz , Götz Kullik , Dieter Engel , Thomas Leyer
IPC分类号： G01F137
CPC分类号： A61B5/0876
摘要： A respiratory flow sensor, which is suitable for use near a patient, covers a broad gas volume flow measuring range with a low breathing flow resistance and good, reproducible measured signal quality at the same time. The respiratory flow sensor has a first air resistance body (3) with a blunt end and with an opposite pointed end. The air resistance body (3) is arranged between the measuring transducer (5), of which there is at least one, and the patient-side end (P) of the respiratory flow sensor. The pointed end of the first air resistance body (3) points toward the measuring transducer (5). A second air resistance body (4) with a pointed end is arranged between the measuring transducer (5), of which there is at least one, and the end of the respiratory flow sensor that is away from the patient. The pointed end of the second air resistance body (4) also points toward the measuring transducer (5).
摘要翻译：适用于患者附近的呼吸流量传感器可同时覆盖宽气体体积流量测量范围，呼吸流阻低，测量信号质量好，重现性好。呼吸流量传感器具有具有钝端并且具有相对尖端的第一空气阻力体（3）。空气阻力体（3）配置在至少有一个的测量传感器（5）和呼吸流量传感器的患者侧端（P）之间。第一空气阻挡体（3）的尖端朝向测量传感器（5）。具有尖端的第二空气阻力体（4）布置在其中至少有一个的测量传感器（5）和远离患者的呼吸流量传感器的末端之间。第二空气阻挡体（4）的尖端也指向测量传感器（5）。

5. 发明授权

US5908667A Multilayer lacquering process 失效
标题翻译：多层涂漆工艺
公开(公告)号：US5908667A
公开(公告)日：1999-06-01
申请号：US952684
申请日：1997-11-25
申请人： Joachim Blum , Dieter Stranghoner , Dieter Engel , Klausjorg Klein , Walter Kuhhirt , Matthias Kimpel , Friedrich-Ludwig Siever
发明人： Joachim Blum , Dieter Stranghoner , Dieter Engel , Klausjorg Klein , Walter Kuhhirt , Matthias Kimpel , Friedrich-Ludwig Siever
IPC分类号： B05D1/36 , B05D7/00 , B05D7/14 , B05D7/16 , C25D13/00 , C25D13/22 , B05D1/38 , B05D3/02 , B05D7/26
CPC分类号： B05D7/576 , B05D7/577 , C25D13/22
摘要： Process for producing a multilayer lacquer coating, in which a primer of an electrophoretically depositable aqueous coating agent (1) is electrophoretically applied on to an electrically conductive substrate and is then stoved, whereupon a color-giving and/or effect-producing base lacquer coat of an aqueous coating agent (II) is applied and stoved and this coat is then provided with one or more clear lacquer coatings, in which processa) as the coating agent (I), a coating agent which, in the stoved state, will produce an electrically conductive primary coat is used,b) the base lacquer coat is formed by an electrophoretically depositable aqueous coating agent (II) by a process of electrophoretical deposition,c) the overall dry layer thickness of the dry lacquer coat or dry lacquer coats is about 40 and 80 .mu.m, andd) the overall dry layer thickness of the multilayer lacquer coating is about 80 to 110 .mu.m.
摘要翻译： PCT No.PCT / EP96 / 02233 Sec。 371日期：1997年11月25日 102（e）日期1997年11月25日PCT提交1996年5月24日PCT公布。 WO96 / 38234 PCT公开号日期1996年12月5日制造多层漆层的方法，其中将电泳可沉积的水性涂料（1）的底漆电泳施加到导电基材上，然后将其加热，由此产生颜色和/或效果涂覆水性涂料（II）的生产基漆漆，并烘烤，然后向该涂层提供一种或多种透明漆层，其中a）作为涂层剂（I），涂覆剂烘烤状态，将使用导电的初级涂层，b）通过电泳沉积方法由电泳可沉积的水性涂层剂（II）形成基底漆层，c）干漆的总干层厚度涂层或干漆涂层的厚度约为40-80微米，d）多层漆层的总干层厚度约为80至110微米。

6. 发明授权

US5882734A Multilayer lacquering process 失效
标题翻译：多层涂漆工艺
公开(公告)号：US5882734A
公开(公告)日：1999-03-16
申请号：US952728
申请日：1997-11-25
申请人： Joachim Blum , Dieter Stranghoner , Dieter Engel , Klausjorg Klein , Walter Kuhhirt , Matthias Kimpel , Friedrich-Ludwig Siever
发明人： Joachim Blum , Dieter Stranghoner , Dieter Engel , Klausjorg Klein , Walter Kuhhirt , Matthias Kimpel , Friedrich-Ludwig Siever
IPC分类号： B05D1/36 , B05D7/00 , B05D7/14 , B05D7/16 , C25D13/00 , B05D1/38 , B05D3/02 , B05D7/26
CPC分类号： B05D7/576 , B05D7/577
摘要： In a process for producing a multilayer lacquer coating, eg for motor vehicles, a first coating layer of an aqueous coating agent (1) is electrophoretically applied on to an electrically conductive substrate and is then stoved. As the coating agent (I), a coating agent which, in the stoved state, will produce an electrically conductive coating layer is used. An electrically insulating second coating layer of an aqueous coating agent (II), which differs from (I), is electrophoretically deposited and stoved. A third basic lacquer coating layer of a colour-giving and/or effect-producing coating agent is applied, and a fourth transparent coating layer of a clear lacquer coating agent is applied, the last-mentioned two coats being stoved together. One or more further transparent coating layers may be applied.
摘要翻译： PCT No.PCT / EP96 / 02234 Sec。 371日期：1997年11月25日 102（e）日期1997年11月25日PCT提交1996年5月24日PCT公布。公开号WO96 / 38235 日期1996年12月5日在用于制造多层漆涂层的方法中，例如机动车辆，将水性涂料（1）的第一涂层电泳施加到导电基材上，然后将其加热。作为涂布剂（I），使用在烘烤状态下将产生导电性涂层的涂布剂。与（I）不同的水性涂布剂（II）的电绝缘的第二涂层被电泳沉积并烘烤。施加着色赋予和/或效果产生涂层剂的第三基本漆层，并施加透明漆涂层剂的第四透明涂层，将最后提到的两层涂在一起。可以施加一个或多个另外的透明涂层。

7. 发明授权

US4610898A Process for bake coating the surfaces of solid substances 失效
标题翻译：烘烤涂布固体物质表面的工艺
公开(公告)号：US4610898A
公开(公告)日：1986-09-09
申请号：US714043
申请日：1985-03-19
申请人： Dieter Engel , Josef Mondt , Helmut Rinno
发明人： Dieter Engel , Josef Mondt , Helmut Rinno
IPC分类号： B05D7/14 , B05D3/02 , B05D7/24 , B05D7/26 , C09D5/00 , C09D5/02 , C09D201/00
CPC分类号： C09D5/02
摘要： Process for bake coating the surfaces of solid materials by applying the required amount of an aqueous dispersion to the surface to be coated, the dispersion containing, as the binder, a coarse-grained, crosslinkable dispersion copolymer formed from olefinically unsaturated monomers and, if appropriate, further customary lacquer formulation constituents, and the crosslinkable dispersion copolymer being composed of a mixture of at least 2 components which can contain identical or different monomer units, of which at least one component A, which is coarse-grained, has a relatively low average molecular weight, and at least one component B, which can be coarse-grained or fine-grained, has a relatively high average high molecular weight, and the ratio by weight of the components A:B being preferably within the range from 99:1 to 1:1, drying the applied amount of dispersion at a temperature below its minimum film-formation temperature and cross-linking the dried coating by baking at a temperature above the glass transition temperature of the copolymer.
摘要翻译：通过将所需量的水分散体施加到待涂覆的表面上来烘烤涂覆固体材料的表面的方法，该分散体含有作为粘合剂的由烯属不饱和单体形成的粗粒度可交联的分散体共聚物，如果合适，进一步的常规漆配方组分，以及可交联分散共聚物由至少两种可以含有相同或不同单体单元的组分的混合物组成，其中至少一种粗粒度的组分A具有相对较低的平均值分子量和至少一种可以是粗粒度或细粒度的组分B具有相对高的平均高分子量，并且组分A:B的重量比优选在99:1的范围内至1：1，在低于其最低成膜温度的温度下干燥所施加的分散体量，并通过在温度下烘烤使干燥的涂层交联高于共聚物的玻璃化转变温度。

8. 发明授权

US4360639A Poly-2-isopropenylnaphthalene poly-butadiene-1,3-block copolymers and method for their production 失效
标题翻译：聚-2-异丙烯基萘聚丁二烯-1,3-嵌段共聚物及其制备方法
公开(公告)号：US4360639A
公开(公告)日：1982-11-23
申请号：US328093
申请日：1981-12-07
申请人： Rolf C. Schulz , Dieter Engel
发明人： Rolf C. Schulz , Dieter Engel
IPC分类号： C08F297/00 , C08F297/04
CPC分类号： C08F297/04
摘要： Poly-2-isopropenylnaphthalene-poly-butadiene-1,3-block copolymers and method for their production. Di- or tri-block polymers with molecular weights of at least 10,000 are formed from, respectively, a poly-2-isopropenylnaphthalene block and a poly-butadiene-1,3 block, and a poly-2-isopropenylnaphthalene block and a poly-butadiene-1,3 block as well as a further poly-2-isopropenylnaphthalene block. The products display rubber-elastic characteristics of the known block polymerizates, with improved high-temperature stability. The polymers are formed by reacting 2-isopropenylnaphthalene in an inert, aliphatic or cycloaliphatic hydrocarbon solvent, at low temperature, with alkalimetal, alkalimetalalkylene, -arylene or -hydride catalyst, into a poly-2-isopropenylnaphthalene block. This formed polymeric anion then has poly-butadiene-1,3-block added to it at its active chain end. If necessary, a second poly-2-isopropenylnaphthalene block is added. The reaction becomes terminated in known manner through the addition of water, alcohol or acid. Lithium-alkyl is the preferred catalyst; tetrahydrofuran is the preferred solvent; the reaction is performed at temperatures between 0.degree. and -80.degree. C., preferably between about -50.degree. C. and -80.degree. C. It is also preferred to initially provide the 2-isopropenylnaphthalene in the solvent at about 0.degree. to 5.degree. C.
摘要翻译：聚-2-异丙烯基萘 - 聚丁二烯-1,3-嵌段共聚物及其制备方法。分子量至少为10,000的二嵌段或三嵌段聚合物分别由聚-2-异丙烯基萘嵌段和聚丁二烯-1,3-嵌段和聚-2-异丙烯基萘嵌段和聚 - 丁二烯-1,3-嵌段以及另外的聚-2-异丙烯基萘嵌段。该产品展示了已知的嵌段聚合物的橡胶弹性特性，具有改善的高温稳定性。聚合物是通过使2-异丙烯基萘在惰性，脂族或脂环族烃溶剂中在低温下与碱金属，碱金属亚烷基， - 亚芳基 - 酐催化剂反应，形成聚-2-异丙烯基萘嵌段。然后，形成的聚合物阴离子在其活性链端加入聚丁二烯-1,3-嵌段。如果需要，加入第二聚-2-异丙烯基萘嵌段。反应以已知方式通过加入水，醇或酸终止。锂 - 烷基是优选的催化剂; 四氢呋喃是优选的溶剂; 该反应在0℃至-80℃之间的温度下进行，优选在约-50℃至-80℃之间进行。最好在约0℃至5℃下最初在溶剂中提供2-异丙烯基萘 DEG C.

9. 发明授权

US6071401A Electrolytic method for purifying gases 失效
标题翻译：净化气体的电解方法
公开(公告)号：US6071401A
公开(公告)日：2000-06-06
申请号：US838688
申请日：1997-04-09
申请人： Dieter Engel , Thomas Lehmann , Harald Troll
发明人： Dieter Engel , Thomas Lehmann , Harald Troll
IPC分类号： B01D53/32 , C02F1/461 , C02F1/467 , B01D17/06 , B01D59/40 , B01D59/50
CPC分类号： B01D53/326 , C02F1/46109 , C02F1/46114 , C02F1/467
摘要： An electrolysis cell with a fixed-bed electrode and its use for the purification of waste gases. The electrolysis cell includes a fixed-bed electrode, a counterelectrode which is separated from it and designed as a gas diffusion electrode, devices for the supply and flow-off of an electrolyte as well as for the inlet and outlet of the gas to be purified and a space associated with the counterelectrode with devices for the supply and the removal of a gas. In order to purify gas the fixed-bed electrode is operated as a trickle bed and the gas to be purified flows in cocurrent or countercurrent flow to the electrolyte. In reductive purification hydrogen is supplied to the gas diffusion electrode and in oxidative purification oxygen is used.
摘要翻译：一种具有固定床电极的电解槽及其废气净化用途。电解槽包括固定床电极，与其分离并设计为气体扩散电极的反电极，用于供应和流出电解质的装置以及用于待净化的气体的入口和出口的装置以及与反电极相关联的空间，其具有用于供应和移除气体的装置。为了净化气体，固定床电极作为滴流床操作，待净化的气体以并流或逆流流向电解液。在还原净化中，氢气被供应到气体扩散电极，并且在氧化净化中使用氧气。

10. 发明授权

US5045347A Reclaimable polyester film having adhesion-promoting coating 失效
标题翻译：具有粘附促进涂层的可回收聚酯膜
公开(公告)号：US5045347A
公开(公告)日：1991-09-03
申请号：US514994
申请日：1990-04-26
申请人： John D. Gribbin , Hermann Dallmann , Dieter Engel , Hartmut Hensel
发明人： John D. Gribbin , Hermann Dallmann , Dieter Engel , Hartmut Hensel
IPC分类号： C08J7/04 , C09J7/02 , C09J133/06 , C09J151/08
CPC分类号： C08J7/047 , C09J133/068 , C09J151/08 , C09J7/0207 , C09J7/0285 , C08J2367/02
摘要： A reclaimable polyester film is disclosed which comprises an oriented polyester film which has been coated with an adhesion-promoting coating. The coating is applied to the film as an aqueous dispersion and is dried and crosslinked by the application of heat. The coating is prepared by the free-radical emulsion polymerizable of the following components:A) 1 to 99% by weight of a polymer having carboxy and epoxy groups in the form of an aqueous system with,B) 1 to 99% by weight of at least one copolymerizable .alpha.-.beta.-olefinic unsaturated monomer, each with reference to the total solids content of the components, andC) 0.01 to 10% by weight of at least one polymerization initiator, based upon the monomer proportion of the components B), andD) 0 to 20% by weight of anionic or nonionic emulsifiers or a mixture of both, or also of protective colloids, with reference to the proportion of component B).
摘要翻译：公开了一种可回收的聚酯膜，其包含已经涂覆有粘合促进涂层的取向聚酯膜。将涂层作为水分散体施加到膜上，并通过加热进行干燥和交联。该涂层由以下组分可聚合的自由基乳液制备：A）1至99重量％的具有水性体系形式的羧基和环氧基团的聚合物，B）1至99重量％至少一种可共聚的α-β-烯属不饱和单体，各自相对于组分的总固体含量，以及C）基于组分B）的单体比例的0.01至10重量％的至少一种聚合引发剂，和D）0至20重量％的阴离子或非离子乳化剂或两者的混合物，或者还有保护胶体，参考组分B）的比例。

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