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1. 发明授权

US4681811A Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat 失效
标题翻译：颜色加透明涂层，在透明涂层中使用聚环氧化物和多元酸固化剂
公开(公告)号：US4681811A
公开(公告)日：1987-07-21
申请号：US837118
申请日：1986-03-07
申请人： Dennis A. Simpson , Debra L. Singer , Rostyslaw Dowbenko , William P. Blackburn , Charles M. Kania
发明人： Dennis A. Simpson , Debra L. Singer , Rostyslaw Dowbenko , William P. Blackburn , Charles M. Kania
IPC分类号： B05D7/00 , C09D163/00 , B05D1/36 , B32B15/08 , B32B27/38
CPC分类号： B05D7/536 , C09D163/00 , Y10T428/31511
摘要： A color-plus-clear coating system is disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent top coat to the base coat. The transparent top coat composition is a liquid crosslinkable composition comprising a polyepoxide and a polyacid curing agent. The polyepoxide-polyacid curing agent in the transparent top coat provides a composite coating with outstanding gloss and distinctness of image making the composite coating particularly useful as an automotive top coat.
摘要翻译：公开了一种彩色透明涂层系统。首先将着色或着色的底涂层施加到基材上，然后向基底涂层施加透明的顶涂层。透明面漆组合物是包含聚环氧化物和多元酸固化剂的液体可交联组合物。透明面漆中的聚环氧化物 - 多元酸固化剂提供了复合涂层，其具有优异的光泽度和独特的图像，使复合涂层特别适用于汽车顶涂层。

2. 发明授权

US4650718A Color plus clear coatings employing polyepoxides and polyacid curing agents 失效
标题翻译：彩色加透明涂料采用聚环氧化物和多元酸固化剂
公开(公告)号：US4650718A
公开(公告)日：1987-03-17
申请号：US767020
申请日：1985-08-19
申请人： Dennis A. Simpson , Debra L. Singer , Rostyslaw Dowbenko , William P. Blackburn , Charles M. Kania
发明人： Dennis A. Simpson , Debra L. Singer , Rostyslaw Dowbenko , William P. Blackburn , Charles M. Kania
IPC分类号： B05D7/00 , C09D163/00 , B05D1/36 , B32B15/08 , B32B27/38
CPC分类号： B05D7/536 , C09D163/00 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529
摘要： A color-plus-clear coating system is disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent top coat to the base coat. Either the transparent top coat, the base coat or both the top coat and base coat compositions are crosslinkable compositions comprising a polyepoxide and a polyacid curing agent which comprises a half-ester formed from reacting an acid anhydride with a polyol. The polyepoxide-polyacid curing agent in the transparent top coat provides a composite coating with outstanding gloss and distinctness of image making the composite coating particularly useful as an automotive top coat.
摘要翻译：公开了一种彩色透明涂层系统。首先将着色或着色的底涂层施加到基材上，然后向基底涂层施加透明的顶涂层。透明顶涂层，底涂层或顶涂层和底涂层组合物都是包含聚环氧化物和多酸固化剂的可交联组合物，其包含由酸酐与多元醇反应形成的半酯。透明面漆中的聚环氧化物 - 多元酸固化剂提供了复合涂层，其具有优异的光泽度和独特的图像，使复合涂层特别适用于汽车顶涂层。

3. 发明授权

US4703101A Liquid crosslinkable compositions using polyepoxides and polyacids 失效
标题翻译：使用聚环氧化物和多元酸的液体可交联组合物
公开(公告)号：US4703101A
公开(公告)日：1987-10-27
申请号：US767019
申请日：1985-08-19
申请人： Debra L. Singer , Rostyslaw Dowbenko , Dennis A. Simpson
发明人： Debra L. Singer , Rostyslaw Dowbenko , Dennis A. Simpson
IPC分类号： B05D7/00 , C09D163/00 , C08G63/42
CPC分类号： B05D7/536 , C09D163/00
摘要： A crosslinkable composition comprising a polyepoxide and a polyacid which is the half-ester formed from reacting an acid anhydride with a polyol is disclosed. The compositions are useful as coatings, particularly as clear coats in color-plus-clear coatings.
摘要翻译：公开了一种包含聚环氧化物和多酸的可交联组合物，其是由酸酐与多元醇反应形成的半酯。该组合物可用作涂料，特别是作为透明涂料在彩色 - 透明涂料中。

4. 发明授权

US09708504B2 Branched polyester polymers and coatings comprising the same 有权
公开(公告)号：US09708504B2
公开(公告)日：2017-07-18
申请号：US12752570
申请日：2010-04-01
申请人： Debra L. Singer , Dennis A. Simpson , John M. Dudik , Anthony M. Chasser , Kam Lun Lock , Richard Woods , Nigel Francis Masters
发明人： Debra L. Singer , Dennis A. Simpson , John M. Dudik , Anthony M. Chasser , Kam Lun Lock , Richard Woods , Nigel Francis Masters
IPC分类号： C09D167/06 , C08F299/04
CPC分类号： C09D167/06 , C08F299/04 , Y10T428/1355 , Y10T428/31786
摘要： A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.

5. 发明申请

US20110244157A1 BRANCHED POLYESTER POLYMERS AND COATINGS COMPRISING THE SAME 有权
标题翻译：分支聚酯聚合物和包含它的涂料
公开(公告)号：US20110244157A1
公开(公告)日：2011-10-06
申请号：US12752570
申请日：2010-04-01
申请人： Debra L. Singer , Dennis A. Simpson , John M. Dudik , Anthony M. Chasser , Kam Lun Lock , Richard Woods , Nigel Francis Masters
发明人： Debra L. Singer , Dennis A. Simpson , John M. Dudik , Anthony M. Chasser , Kam Lun Lock , Richard Woods , Nigel Francis Masters
IPC分类号： B32B27/36 , C08F220/26 , C08L33/14 , B32B15/09
CPC分类号： C09D167/06 , C08F299/04 , Y10T428/1355 , Y10T428/31786
摘要： A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.
摘要翻译：公开了通过不饱和聚酯预聚物的自由基聚合制备的聚酯，其中聚合主要通过不饱和键的反应而发生。还公开了包含该涂层的涂层，以及至少部分地涂覆有这样的涂层的基材。

6. 发明授权

US5256452A One package stable etch resistant coating process 失效
标题翻译：一包耐腐蚀涂层工艺
公开(公告)号：US5256452A
公开(公告)日：1993-10-26
申请号：US976062
申请日：1992-11-13
申请人： Susan U. McMonigal , Debra L. Singer , Dennis A. Simpson , Joseph A. Klanica , Michael A. Mayo
发明人： Susan U. McMonigal , Debra L. Singer , Dennis A. Simpson , Joseph A. Klanica , Michael A. Mayo
IPC分类号： C08F8/00 , C09D133/14 , C09D163/00 , B05D1/36 , B05D7/04 , B05D7/14
CPC分类号： C09D133/14 , C08F8/00 , C09D163/00
摘要： A stable one package etch-resistant film-forming composition is disclosed. The composition includes a polyepoxide component having an epoxy equivalent weight on resin solids of less than about 600. The composition further includes a polyacid curing agent having an average acid functionality of greater than 2. The composition is substantially free of basic esterification catalyst, has a cured softening point of greater than about 20.degree. C., and is stable for use as a single-component composition. Also disclosed is a process for applying a color-plus-clear composite coating to a substrate which includes applying a acid-catalyzed thermosetting film-forming composition to a substrate to form a basecoat. The process also comprises applying a stable etch-resistant film-forming composition to the basecoat which includes a polyepoxide and a polyacid curing agent as described above, wherein the topcoat is substantially free of basic esterification catalyst, has a cured softening point of greater than about 20.degree. C. The composition and process are useful in original equipment finishing of automobile and trucks.
摘要翻译：公开了一种稳定的一种包装耐蚀刻成膜组合物。该组合物包含具有小于约600的树脂固体的环氧当量的聚环氧化物组分。该组合物还包含平均酸官能度大于2的多元酸固化剂。该组合物基本上不含碱性酯化催化剂，具有固化软化点大于约20℃，并且稳定用作单组分组合物。还公开了一种将彩色透明复合涂层施加到基底上的方法，其包括将酸催化的热固性成膜组合物施加到基底上以形成底涂层。该方法还包括将如上所述的包含聚环氧化物和多元酸固化剂的底涂层施加稳定的耐蚀刻成膜组合物，其中面漆基本上不含碱性酯化催化剂，其固化软化点大于约 20℃。组合物和工艺可用于汽车和卡车的原始设备整理。

7. 发明授权

US5196485A One package stable etch resistant coating 失效
标题翻译：一包耐腐蚀涂层
公开(公告)号：US5196485A
公开(公告)日：1993-03-23
申请号：US692885
申请日：1991-04-29
申请人： Susan U. McMonigal , Debra L. Singer , Dennis A. Simpson , Joseph A. Klanica , Michael A. Mayo
发明人： Susan U. McMonigal , Debra L. Singer , Dennis A. Simpson , Joseph A. Klanica , Michael A. Mayo
IPC分类号： C09D161/20 , B05D7/24 , C08F8/00 , C08G59/42 , C09D133/14 , C09D163/00 , C09D167/00 , C09D167/02
CPC分类号： C09D133/14 , C08F8/00 , C09D163/00 , Y10T428/31511 , Y10T428/31522
摘要： A stable one package etch-resistant film-forming composition is disclosed. The composition includes a polyepoxide component having an epoxy equivalent weight on resin solids of less than about 600. The composition further includes a polyacid curing agent having an average acid functionality of greater than 2. The composition is substantially free of basic esterification catalyst, has a cured softening point of greater than about 20.degree. C., and is stable for use as a single-component composition. Also disclosed is a process for applying a color-plus-clear composite coating to a substrate which includes applying a acid-catalyzed thermosetting film-forming composition to a substrate to form a basecoat. The process also comprises applying a stable etch-resistant film-forming composition to the basecoat which includes a polyepoxide and a polyacid curing agent as described above, wherein the topcoat is substantially free of basic esterification catalyst, has a cured softening point of greater than about 20.degree. C. The composition and process are useful in original equipment finishing of automobile and trucks.
摘要翻译：公开了一种稳定的一种包装耐蚀刻成膜组合物。该组合物包含具有小于约600的树脂固体的环氧当量的聚环氧化物组分。该组合物还包含平均酸官能度大于2的多元酸固化剂。该组合物基本上不含碱性酯化催化剂，具有固化软化点大于约20℃，并且稳定用作单组分组合物。还公开了一种将彩色透明复合涂层施加到基底上的方法，其包括将酸催化的热固性成膜组合物施加到基底上以形成底涂层。该方法还包括将如上所述的包含聚环氧化物和多元酸固化剂的底涂层施加稳定的耐蚀刻成膜组合物，其中面漆基本上不含碱性酯化催化剂，其固化软化点大于约 20℃。组合物和工艺可用于汽车和卡车的原始设备整理。

8. 发明授权

US4917955A Color plus clear composite coating having a catalyst-free base coat comprising polyepoxides and polyacid curing agents 失效
标题翻译：颜色加透明复合涂层，其具有不含催化剂的底涂层，其包含聚环氧化物和多元酸固化剂
公开(公告)号：US4917955A
公开(公告)日：1990-04-17
申请号：US72302
申请日：1987-07-13
申请人： Samuel Porter, Jr. , Dennis A. Simpson , William P. Blackburn , Mark E. Endlish
发明人： Samuel Porter, Jr. , Dennis A. Simpson , William P. Blackburn , Mark E. Endlish
IPC分类号： B05D1/38 , B05D7/16 , C08J3/24 , C09D163/00
CPC分类号： B05D1/36 , B05D7/53 , C08J3/24 , C09D163/00 , B05D2202/00 , B05D2504/00 , C08J2363/00 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31699
摘要： There is disclosed herein a composite coating comprising a colored base coat over which is applied a clear top coat, the improvement comprising the base coat which comprises a liquid crosslinkable composition comprising a polyepoxide and a polyacid curing agent; said composition is characterized in that it is substantially free of a cure catalyst, and the top coat comprises a cure catalyst system in an amount sufficient to cure both the base coat and the top coat.
摘要翻译：本文公开了一种复合涂层，其包含着色底涂层，在其上施加透明的顶涂层，改进包括底涂层，其包含含有聚环氧化物和多元酸固化剂的液体可交联组合物; 所述组合物的特征在于其基本上不含固化催化剂，并且顶涂层包含足以固化底涂层和顶涂层的量的固化催化剂体系。

9. 发明授权

US4849283A Composite coatings employing polyepoxides and polyacid curing agents in base coats 失效
标题翻译：复合涂层在底漆中采用聚环氧化物和多元酸固化剂
公开(公告)号：US4849283A
公开(公告)日：1989-07-18
申请号：US74130
申请日：1987-07-16
申请人： Samuel Porter, Jr. , Dennis A. Simpson , William P. Blackburn
发明人： Samuel Porter, Jr. , Dennis A. Simpson , William P. Blackburn
IPC分类号： B05D5/06 , B05D7/00 , C09D163/00
CPC分类号： B05D7/534 , B05D5/068 , C09D163/00 , B05D2451/00 , B05D2504/00 , B05D2601/08 , Y10T428/25 , Y10T428/31515 , Y10T428/31529 , Y10T428/31699 , Y10T428/31855
摘要： A color plus clear composite coating and process are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent top coat to the base coat. The base coat composition is a liquid crosslinkable composition comprising a polyepoxide and a polyacid curing agent which comprises a half ester formed from reacting an acid anhydride with a polyol. The top coat composition is a powder coating. The resultant composite coating exhibits improved distinctness of image, making the composite coating particularly useful as an automotive top coat.
摘要翻译：公开了一种颜色加透明复合涂层和方法。首先将着色或着色的底涂层施加到基材上，然后向基底涂层施加透明的顶涂层。底涂层组合物是包含聚环氧化物和多酸固化剂的液体可交联组合物，其包含由酸酐与多元醇反应形成的半酯。面漆组合物是粉末涂料。所得复合涂层表现出改善的图像清晰度，使得复合涂层特别适用于汽车顶涂层。

10. 发明申请

US20110045725A1 FILM-FORMING COMPOSITIONS, RELATED PROCESSES AND COATED SUBSTRATES 审中-公开
标题翻译：成膜组合物，相关工艺和涂层基材
公开(公告)号：US20110045725A1
公开(公告)日：2011-02-24
申请号：US12545889
申请日：2009-08-24
申请人： Shan Cheng , Thomas R. Hockswender , Anthony M. Chasser , James P. Rowley , Dennis A. Simpson
发明人： Shan Cheng , Thomas R. Hockswender , Anthony M. Chasser , James P. Rowley , Dennis A. Simpson
IPC分类号： B32B5/02 , C08L83/00 , C08L63/00 , C08L67/00 , B32B21/08 , B32B15/092 , B32B17/10 , B32B27/06 , B05D1/36
CPC分类号： C08G59/306 , C08G59/3254 , C08L63/00 , C09D163/00 , Y10T428/249991 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , Y10T442/20 , C08L2666/22
摘要： Film-forming coating compositions are disclosed. The composition comprises a) an epoxy-containing polymer system; and b) a polyacid curing agent comprising two acid functional groups per molecule; wherein the epoxy-containing polymer system comprises: (i) an epoxy resin comprising at least two epoxy functional groups per molecule and which is different from (ii); and (ii) an epoxy functional silsesquioxane. Also disclosed are processes for applying the film-forming composition to a basecoat, and substrates coated in part by a coating deposited from the film-forming compositions.
摘要翻译：公开了成膜涂料组合物。该组合物包含a）含环氧基的聚合物体系; 和b）每分子含有两个酸官能团的多元酸固化剂; 其中所述含环氧基的聚合物体系包括：（i）每分子包含至少两个环氧官能团并且不同于（ⅱ）的环氧树脂; 和（ii）环氧官能硅倍半氧烷。还公开了将成膜组合物施用于底涂层的方法，以及通过由成膜组合物沉积的涂层部分涂覆的基材。

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