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    • 3. 发明授权
    • Method of recovering metals and producing a secondary slag from base
metal smelter slag
    • 从金属冶炼炉渣中回收金属和生产二次炉渣的方法
    • US5865872A
    • 1999-02-02
    • US815508
    • 1997-03-12
    • David KrofchakWerner Dresler
    • David KrofchakWerner Dresler
    • C04B5/06C04B7/147C04B7/19C04B18/14C04B28/02C21B3/04C21B3/06C22B7/04C22B5/04C21B15/02
    • C04B7/147C04B18/144C04B5/06C04B7/19C21B3/04C21B3/06C22B7/04Y02P10/212Y02P40/143Y02W30/542Y02W30/543Y02W30/94Y10S75/959
    • A method of recovering metals and producing a secondary slag from base metal smelter slag produced by a copper or nickel smelter includes mixing the smelter slag with at least one reducing agent selected from the group consisting of carbon, calcium carbide, ferrosilicon and aluminum, said carbon and calcium carbide (if present) being from about 1% to about 40% by weight of the slag and said aluminum (if present) being from about 2% to about 35% by weight of the slag and with from zero to about 70% calcium oxide by weight of the slag, heating the mixture aluminothermically if Al is present as reducing agent above the melting point to reduce the smelter slag to a metal alloy containing iron and possibly silicon and aluminum, depending on the quantity of aluminum added to the smelter slag, and heavy metals such as copper, nickel and cobalt which were in the smelter slag and thereby also producing a secondary slag containing at least one compound selected from the group consisting of calcium silicate, calcium aluminate, fused alumina and calcium iron aluminum silicate, and separating the metal alloy from the secondary slag.
    • 由铜或镍冶炼炉生产的从金属冶炼炉渣回收金属和生产二次炉渣的方法包括将冶炼炉渣与选自碳,碳化钙,硅铁和铝的至少一种还原剂混合,所述碳 并且碳化钙(如果存在)为渣的约1重量%至约40重量%,并且所述铝(如果存在)为炉渣的约2重量%至约35重量%,并且为零至约70重量% 氧化钙以炉渣的重量加热,如果铝作为还原剂存在于熔点以上,则将铝混合物加热,以将冶炼炉渣还原成含铁和可能的硅和铝的金属合金,这取决于添加到冶炼厂中的铝量 渣和重金属如铜,镍和钴,在熔渣中,从而也产生含有至少一种选自以下的化合物的二次渣: 硅酸铝,铝酸钙,熔融氧化铝和铁酸钙铝硅酸盐,并将金属合金与二次渣分离。
    • 4. 发明授权
    • Recovery of sodium thiocyanate
    • 回收硫氰酸钠
    • US3965243A
    • 1976-06-22
    • US504776
    • 1974-09-10
    • David Krofchak
    • David Krofchak
    • B01D53/14B01D53/52B01D53/77C01C3/20C10K1/12B01D53/34
    • C01C3/20C10K1/12
    • A process is described whereby accumulated impurities, consisting mainly of sodium tiocyanate are continuously removed from scrubbing liquors used for removal of hydrogen sulphide from fuel gases and the liquors thereby regenerated and re-used in the hydrogen sulphide scrubbing operation. The thiocyanate is removed by contacting the used scrubbing liquor with an organic solvent, e.g. n-butanol, separating the thiocyanate-bearing solvent from the scrubbing liquor, re-using the treated scrubbing liquor, recovering the thiocyanate from the solvent and re-using the solvent. The extracted sodium thiocyanate can be converted to pure, saleable chemicals or converted to an alkali which can be re-used in the absorbing liquors, thereby producing a completely closed system with no effluent.
    • 描述了一种方法,其中主要由硫氰酸钠组成的积累的杂质从用于从燃料气体中除去硫化氢的洗涤液连续地除去,并且由此在硫化氢洗涤操作中再次使用和再次使用。 通过使用的洗涤液与有机溶剂接触除去硫氰酸盐,例如, 正丁醇,将含硫氰酸酯的溶剂与洗涤液分离,重新使用经处理的洗涤液,从溶剂中回收硫氰酸盐并重新使用溶剂。 提取的硫氰酸钠可以转化成纯的,可销售的化学物质,或者转化成可以在吸收液中再次使用的碱,从而产生没有流出物的完全封闭的体系。
    • 6. 发明授权
    • Treatment of phosphatic wastes
    • 处理磷酸盐废物
    • US06231767B1
    • 2001-05-15
    • US09250151
    • 1999-02-16
    • David KrofchakRoberto Berardi
    • David KrofchakRoberto Berardi
    • C02F100
    • C04B7/24B03B9/061C04B18/0481C05B11/08C05B17/00Y02P40/145Y02W30/91Y10S210/906Y10S210/907C04B20/02
    • A process for treating thickened phosphatic clay suspensions, waste clay and phosphogypsum produced in the processing of phosphate ore by water beneficiation and chemical processing, the thickened phosphatic clay suspension having a solid content of from about 4 to about 40 percent by weight, includes mixing a sufficient amount of deflocculating agent with a thickened phosphatic clay suspension to cause deflocculation of the suspension to an extent sufficient to reduce the viscosity thereof to a value enabling the deflocculated suspension to be readily pumped from one location to another, the deflocculating agent comprising an alkali compound of a phosphorus oxide. The deflocculated suspension of reduced viscosity is pumped from one location to another and separated into a clay suspension and a phosphatic mineral and sand suspension. The non-clay minerals are dissolved in the phosphatic mineral and sand suspension in dilute sulfuric acid to separate a phosphatic fraction as phosphoric acid from a sand fraction. A cementitious material is produced by heating clay, phosphogypsum and sand in a kiln, and the cementitious material is mixed with the clay suspension and the sand fraction in an amount sufficient to cause the formation of large silicate molecules with resultant gelling and setting of the suspensions into an inert solid material.
    • 一种处理通过水精选和化学处理在磷酸盐矿石加工中产生的增稠的磷酸钙粘土悬浮液,废粘土和磷石膏的方法,固体含量为约4至约40重量%的增稠的磷酸粘土悬浮液包括混合 足够量的具有增稠的磷酸钙粘土悬浮液的抗絮凝剂以使悬浮液的抗絮凝程度足以将其粘度降低到能够使絮凝的悬浮液容易地从一个位置泵送到另一个位置的值,所述抗絮凝剂包含碱性化合物 的磷氧化物。 降低粘度的絮凝悬浮液从一个位置泵送到另一个位置,并分离成粘土悬浮液和磷矿物和砂悬浮液。 将非粘土矿物质溶解在稀硫酸中的磷酸矿物和砂悬浮液中,以从磷砂中分离磷酸盐级分。 通过在窑中加热粘土,磷石膏和砂子来生产水泥材料,并且将水泥质材料与粘土悬浮液和沙子组分混合,其量足以引起大的硅酸盐分子的形成,从而形成胶凝和凝固悬浮液 成为惰性固体材料。