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    • 3. 发明授权
    • Treatment of phosphatic wastes
    • 处理磷酸盐废物
    • US06231767B1
    • 2001-05-15
    • US09250151
    • 1999-02-16
    • David KrofchakRoberto Berardi
    • David KrofchakRoberto Berardi
    • C02F100
    • C04B7/24B03B9/061C04B18/0481C05B11/08C05B17/00Y02P40/145Y02W30/91Y10S210/906Y10S210/907C04B20/02
    • A process for treating thickened phosphatic clay suspensions, waste clay and phosphogypsum produced in the processing of phosphate ore by water beneficiation and chemical processing, the thickened phosphatic clay suspension having a solid content of from about 4 to about 40 percent by weight, includes mixing a sufficient amount of deflocculating agent with a thickened phosphatic clay suspension to cause deflocculation of the suspension to an extent sufficient to reduce the viscosity thereof to a value enabling the deflocculated suspension to be readily pumped from one location to another, the deflocculating agent comprising an alkali compound of a phosphorus oxide. The deflocculated suspension of reduced viscosity is pumped from one location to another and separated into a clay suspension and a phosphatic mineral and sand suspension. The non-clay minerals are dissolved in the phosphatic mineral and sand suspension in dilute sulfuric acid to separate a phosphatic fraction as phosphoric acid from a sand fraction. A cementitious material is produced by heating clay, phosphogypsum and sand in a kiln, and the cementitious material is mixed with the clay suspension and the sand fraction in an amount sufficient to cause the formation of large silicate molecules with resultant gelling and setting of the suspensions into an inert solid material.
    • 一种处理通过水精选和化学处理在磷酸盐矿石加工中产生的增稠的磷酸钙粘土悬浮液,废粘土和磷石膏的方法,固体含量为约4至约40重量%的增稠的磷酸粘土悬浮液包括混合 足够量的具有增稠的磷酸钙粘土悬浮液的抗絮凝剂以使悬浮液的抗絮凝程度足以将其粘度降低到能够使絮凝的悬浮液容易地从一个位置泵送到另一个位置的值,所述抗絮凝剂包含碱性化合物 的磷氧化物。 降低粘度的絮凝悬浮液从一个位置泵送到另一个位置,并分离成粘土悬浮液和磷矿物和砂悬浮液。 将非粘土矿物质溶解在稀硫酸中的磷酸矿物和砂悬浮液中,以从磷砂中分离磷酸盐级分。 通过在窑中加热粘土,磷石膏和砂子来生产水泥材料,并且将水泥质材料与粘土悬浮液和沙子组分混合,其量足以引起大的硅酸盐分子的形成,从而形成胶凝和凝固悬浮液 成为惰性固体材料。