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    • 6. 发明授权
    • Method of recovering metals and producing a secondary slag from base
metal smelter slag
    • 从金属冶炼炉渣中回收金属和生产二次炉渣的方法
    • US5626646A
    • 1997-05-06
    • US663724
    • 1996-06-14
    • David Krofchak
    • David Krofchak
    • C04B5/06C04B7/147C04B7/19C04B18/14C04B28/02C21B3/04C21B3/06C22B7/04C21B15/00
    • C04B28/02C04B18/144C04B5/06C04B7/147C04B7/19C21B3/04C21B3/06C22B7/04Y02P10/212Y02P40/143Y02W30/542Y02W30/543Y02W30/94
    • A method of recovering metals and producing a secondary slag from base metal smelter slag produced by a copper or nickel smelter includes mixing the smelter slag with at least one reducing agent selected from the group consisting of carbon and aluminum, said carbon (if present) being from about 1% to about 10% by weight of the slag and said aluminum (if present) being from about 5 to about 30% by weight of the slag, and with from zero to about 60% calcium oxide by weight of the slag. The mixture is heated above the eutectic melting point thereof directly and to ignition temperature aluminothermically (if aluminum is present as reducing agent) to reduce the iron silicate to ferrosilicon containing substantially all the copper, nickel and cobalt which was in the smelter slag and form a secondary slag comprising at least one compound selected from the group consisting of calcium silicate, calcium aluminate and calcium iron aluminum silicate. The ferrosilicon is then separated from the secondary slag.
    • 回收金属并由铜或镍冶炼炉生产的贱金属冶炼炉渣生产二次炉渣的方法包括将冶炼炉渣与至少一种选自碳和铝的还原剂混合,所述碳(如果存在)为 炉渣的重量的约1%至约10%,所述铝(如果存在)为炉渣的约5至约30重量%,并且以炉渣重量计为零至约60%的氧化钙。 将混合物直接加热到高于其共晶熔点的地方,并将铝热成型(如果铝以还原剂的形式存在),以将铁硅酸盐还原成含有基本上所有的在冶炼炉渣中的所有铜,镍和钴的硅铁,并形成 包含至少一种选自硅酸钙,铝酸钙和硅酸钙铁铝的化合物的二次炉渣。 然后将硅铁与二次炉渣分离。