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1. 发明授权

US5082642A Method for catalyzing oxidation/reduction reactions of simple molecules 失效
标题翻译：催化简单分子的氧化/还原反应的方法
公开(公告)号：US5082642A
公开(公告)日：1992-01-21
申请号：US607634
申请日：1990-10-31
申请人： David Bickar , Celia Bonaventura , Joseph Bonaventura
发明人： David Bickar , Celia Bonaventura , Joseph Bonaventura
IPC分类号： C01B21/087 , C01B21/22 , C01B21/36 , C01B31/18 , C01B31/20 , C01B31/26
CPC分类号： C01B21/36 , C01B31/18 , C01B31/20 , C01B31/262 , C01B31/267
摘要： This invention relates to a method for catalyzing the reactionsQZ+H.sub.2 X?QZX (1)andQZX?QZ+H.sub.2 X (2)whereinQ=C or N;Z=O or S;X=O, S, NH or NR;R=C.sub.1 to C.sub.8 alkyl which may be linear, branched or cyclized,which comprises:contacting at least one polydentate nitrogen-containing chelating agent complexed with a metal atom with the reactants of one of said reactions, wherein said contacting takes place in the presence of a means for oxidizing when reaction (1) is catalyzed and in the presence of a means for reducing when reaction (2) is catalyzed. A particular reaction is the conversion of NO to NO.sub.2 using water and supported porphines, hemes, phthalocyanines, ethioporphrins sirohemes, particularly heme and heme compounds or derivatives such as methemoglobin, myoglobin, or hemin.
摘要翻译：本发明涉及催化反应QZ + H2X→QZX（1）和QZX→QZ + H2X（2）的方法，其中Q = C或N; Z = O或S; X = O，S，NH或NR; R = C1至C8烷基，其可以是直链，支链或环化的，其包括：使与金属原子络合的至少一种多齿含氮螯合剂与所述反应之一的反应物接触，其中所述接触在存在下进行当催化反应（1）时和在反应（2）被催化时还原反应的手段的存在下，氧化的手段。特别的反应是使用水和负载的卟吩，海马，酞菁，乙孢子卟啉，特别是血红素和血红素化合物或衍生物如高铁血红蛋白，肌红蛋白或血红素，将NO转化为NO2。

2. 发明授权

US4751068A Method for catalyzing oxidation/reduction reactions of simple molecules 失效
标题翻译：催化简单分子的氧化/还原反应的方法
公开(公告)号：US4751068A
公开(公告)日：1988-06-14
申请号：US648952
申请日：1984-09-10
申请人： David Bickar , Celia Bonaventura , Joseph Bonaventura
发明人： David Bickar , Celia Bonaventura , Joseph Bonaventura
IPC分类号： C01B21/087 , C01B21/36 , C01B31/18 , C01B31/20 , C01B31/26 , B01J31/00
CPC分类号： C01B21/087 , C01B21/36 , C01B31/18 , C01B31/20 , C01B31/262 , C01B31/267
摘要： This invention relates to a method for catalyzing the reactionsQZ+H.sub.2 X.fwdarw.QZX (1) psandQZX.fwdarw.QZ+H.sub.2 X (2)wherein Q=C or N;Z=O or S;X=O, S, NH or NR;R=C.sub.1 to C.sub.8 alkyl which may be linear, branched or cyclized,which comprises:contacting at least one polydentate nitrogen-containing chelating agent complexed with a metal atom with the reactants of one of said reactions, wherein said contacting takes place in the presence of a means for oxidizing when reaction (1) is catalyzed and in the presence of a means for reducing when reaction (2) is catalyzed.
摘要翻译：本发明涉及一种催化反应QZ + H2X→QZX（1）ps和QZX→QZ + H2X（2）的方法，其中Q = C或N; Z = O或S; X = O，S，NH或NR; R = C1至C8烷基，其可以是直链，支链或环化的，其包括：使与金属原子络合的至少一种多齿含氮螯合剂与所述反应之一的反应物接触，其中所述接触在存在下进行当催化反应（1）时和在反应（2）被催化时还原反应的手段的存在下，氧化的手段。

3. 发明授权

US4629544A Apparatus and method for reversibly removing ligands from carriers 失效
标题翻译：从载体上可逆地除去配体的装置和方法
公开(公告)号：US4629544A
公开(公告)日：1986-12-16
申请号：US653729
申请日：1984-09-24
申请人： Joseph Bonaventura , Celia Bonaventura , C. William Anderson
发明人： Joseph Bonaventura , Celia Bonaventura , C. William Anderson
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18
CPC分类号： C01B13/0251 , C01B13/0255 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528 , Y10S204/04
摘要： A method for reversibly removing a ligand from a ligand carrier, which comprises:(1) contacting a fluid containing a binding-state ligand carrier to which said ligand is bound with a first electrochemical electrode wherein said binding-state ligand carrier undergoes a redox reaction to form a nonbinding-state ligand carrier and free ligand;(2) removing free ligand from the fluid obtained in step (1);(3) contacting the fluid obtained from step (2) containing said nonbinding-state ligand carrier with a second electrochemical electrode wherein said nonbinding-state ligand carrier undergoes a redox reaction to reform said binding-state ligand carrier;(4) contacting the fluid obtained from step (3) containing said binding-state ligand carrier with a ligand source, whereby said ligand binds to said binding-state ligand carrier; and(5) repeating steps (1)-(4),is disclosed along with an apparatus useful in conducting this invention.
摘要翻译：一种从配体载体中可逆地除去配体的方法，其包括：（1）将含有所述配体结合的结合状态配体载体的流体与第一电化学电极接触，其中所述结合状态配体载体经历氧化还原反应以形成非结合态配体载体和游离配体; （2）从步骤（1）中获得的流体中除去游离配体; （3）将含有所述非结合态配体载体的步骤（2）获得的流体与第二电化学电极接触，其中所述非结合态配体载体经历氧化还原反应以重整所述结合状态配体载体; （4）将含有所述结合状态配体载体的步骤（3）获得的流体与配体源接触，由此所述配体结合所述结合状态配体载体; 和（5）重复步骤（1） - （4），以及可用于实施本发明的装置。

4. 发明授权

US4609383A Apparatus and method for extracting oxygen from fluids 失效
标题翻译：从流体中提取氧气的装置和方法
公开(公告)号：US4609383A
公开(公告)日：1986-09-02
申请号：US653549
申请日：1984-09-24
申请人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner
发明人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18 , B01D53/22
CPC分类号： C01B13/0255 , C01B13/0251 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528
摘要： An apparatus for extracting oxygen from an environment surrounding the apparatus, which comprises a container having an interior space isolated from physical contact with the environment at least in part by a gas permeable membrane having a first and a second side, wherein the membrane contacts the environment on the first side of the membrane, a carrier fluid in contact with the second side of the membrane in the first container, and a non-proteinaceous oxygen binding compound contained in the carrier fluid, wherein the compound comprises a tetradentate chelating molecule, a metal ion chelated in the molecule, and a nitrogenous base chelated to the metal ion, is disclosed along with a method for extracting oxygen from environmental fluids.
摘要翻译：一种用于从设备周围的环境中提取氧气的装置，其包括具有至少部分由具有第一和第二侧的透气膜与物体与环境物理接触隔离的内部空间的容器，其中膜接触环境在膜的第一侧上，与第一容器中的膜的第二侧接触的载体流体和载体流体中所含的非蛋白质氧结合化合物，其中所述化合物包含四齿螯合分子，金属离子螯合在分子中，并且与金属离子螯合的含氮碱基与从环境流体中提取氧的方法一起公开。

5. 发明授权

US4427416A Processes for extracting oxygen from fluids using immobilized hemoglobin 失效
标题翻译：使用固定化血红蛋白从流体中提取氧气的方法
公开(公告)号：US4427416A
公开(公告)日：1984-01-24
申请号：US372338
申请日：1982-04-27
申请人： Joseph Bonaventura , Celia Bonaventura
发明人： Joseph Bonaventura , Celia Bonaventura
IPC分类号： A61K38/00 , C01B13/02 , C07K14/805 , C01B13/00
CPC分类号： C01B13/0285 , C01B13/0262 , C07K14/805 , A61K38/00 , C01B2210/0046 , C01B2210/0062
摘要： An oxygen carrier, capable of reversibly binding and releasing oxygen, immobilized in a polymer matrix and a method of recovering dissolved oxygen from fluids utilizing the same.
摘要翻译：固定在聚合物基质中的能够可逆地结合和释放氧的氧载体，以及利用该载体从溶液中回收溶解氧的方法。

6. 发明授权

US4343715A Immobilized hemoglobin, and processes for extracting oxygen from fluids using the same 失效
标题翻译：固定化血红蛋白，以及使用其从流体中提取氧气的方法
公开(公告)号：US4343715A
公开(公告)日：1982-08-10
申请号：US196036
申请日：1980-10-10
申请人： Joseph Bonaventura , Celia Bonaventura
发明人： Joseph Bonaventura , Celia Bonaventura
IPC分类号： A61K38/00 , B01J20/28 , C01B13/02 , C07K14/805 , C01B13/00 , A61M16/00
CPC分类号： B01J20/28026 , B01J20/28004 , B01J20/28016 , B01J20/28045 , B01J20/28047 , C01B13/0262 , C01B13/0285 , C07K14/805 , A61K38/00 , C01B2210/0046 , C01B2210/0062
摘要： An oxygen carrier, capable of reversibly binding and releasing oxygen, immobilized in a polymer matrix and a method of recovering dissolved oxygen from fluids utilizing the same.
摘要翻译：固定在聚合物基质中的能够可逆地结合和释放氧的氧载体，以及利用该载体从溶液中回收溶解氧的方法。

7. 发明授权

US5998200A Anti-fouling methods using enzyme coatings 失效
标题翻译：使用酶涂层的防污方法
公开(公告)号：US5998200A
公开(公告)日：1999-12-07
申请号：US683130
申请日：1991-04-10
申请人： Celia Bonaventura , Joseph Bonaventura , Irving R. Hooper
发明人： Celia Bonaventura , Joseph Bonaventura , Irving R. Hooper
IPC分类号： A01N41/08 , A01N43/16 , A01N59/12 , A01N61/00 , A01N63/00 , A01N63/02 , A01N65/00 , C09D5/16 , C12S9/00
CPC分类号： A01N65/00 , A01N41/08 , A01N43/16 , A01N59/12 , A01N61/00 , A01N63/00 , A01N63/02 , A01N65/08 , C09D5/1625 , C09D5/1637
摘要： A method for preventing fouling of an aquatic apparatus by an aquatic organism which comprises affixing a biologically active chemical to a surface intended for use in contact with an aquatic environment containing the organism, wherein the chemical is an enzyme, repellant, chelating agent, enzyme inhibitor, or non-metallic toxicant capable of hindering the attachment of the organism to the surface while affixed to the surface, is disclosed along with improved apparatuses which are produced using the method.
摘要翻译：一种防止水生生物污染水生生物的方法，其包括将生物活性化学品固定在与包含生物体的水生环境接触的表面上，其中所述化学物质是酶，驱避剂，螯合剂，酶抑制剂或能够阻碍生物体附着于表面而附着在表面上的非金属毒素，以及使用该方法生产的改进的装置。

8. 发明授权

US4761209A System for the extraction and utilization of oxygen from fluids 失效
标题翻译：从流体中提取和利用氧气的系统
公开(公告)号：US4761209A
公开(公告)日：1988-08-02
申请号：US855706
申请日：1986-04-25
申请人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
发明人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18
CPC分类号： H01M8/0656 , C01B13/0251 , C01B13/0255 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528 , Y10S123/13 , Y10S204/04 , Y10S261/28
摘要： A method for extracting oxygen from a fluid environment, which comprises the steps of (1) contacting a first fluid environment containing oxygen with a first surface of a first oxygen permeable membrane having a first and a second surface, wherein the membrane separates the environment from an interior space of a closed container, (2) transporting a carrier fluid into contact with the second surface of the membrane, wherein the carrier fluid is confined in the closed container and the carrier fluid contains a binding-state oxygen carrier, whereby oxygen which diffuses through the membrane binds to the carrier to give a bound oxygen complex, (3) transporting the carrier fluid containing the bound oxygen complex to a first electrode compartment of an electrochemical cell which forms a second portion of the closed container, (4) electrochemically modifying the binding-state oxygen carrier to an oxidation state having less binding affinity for oxygen, thereby releasing free oxygen into the carrier fluid and producing a nonbinding-state oxygen carrier, (5) removing oxygen from the carrier fluid, (6) transporting the carrier fluid containing the nonbinding-state oxygen carrier to a second electrode compartment of an electrochemical cell which forms a third portion of the closed container, and (7) electrochemically modifying the nonbinding-state oxygen carrier to the binding-state oxygen carrier, is disclosed along with an apparatus useful for carrying out the method of the invention.
摘要翻译：一种用于从流体环境中提取氧气的方法，其包括以下步骤：（1）使含有氧的第一流体环境与具有第一和第二表面的第一透氧膜的第一表面接触，其中所述膜将环境与密封容器的内部空间，（2）将载体流体输送到膜的第二表面接触，其中载体流体被限制在密闭容器中，并且载体流体含有结合态氧载体，通过膜的扩散与载体结合以产生结合的氧络合物，（3）将含有结合的氧络合物的载体流体输送到形成密闭容器的第二部分的电化学电池的第一电极室，（4）电化学将结合态氧载体改性为具有对氧的结合亲和力较小的氧化态，从而将游离氧释放到其中制造非结合态氧载体，（5）从载体流体中除去氧气，（6）将含有非结合态氧载体的载体流体输送到形成第三部分的电化学电池的第二电极室封闭的容器，以及（7）将非结合状态的氧载体电化学修饰为结合态氧载体，以及用于实施本发明方法的装置。

9. 发明授权

US4602987A System for the extraction and utilization of oxygen from fluids 失效
公开(公告)号：US4602987A
公开(公告)日：1986-07-29
申请号：US653850
申请日：1984-09-24
申请人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
发明人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18
CPC分类号： H01M8/0656 , C01B13/0251 , C01B13/0255 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528 , Y10S123/13 , Y10S204/04 , Y10S261/28
摘要： A method for extracting oxygen from a fluid environment, which comprises the steps of (1) contacting a first fluid environment containing oxygen with a first surface of a first oxygen permeable membrane having a first and a second surface, wherein the membrane separates the environment from an interior space of a closed container, (2) transporting a carrier fluid into contact with the second surface of the membrane, wherein the carrier fluid is confined in the closed container and the carrier fluid contains a binding-state oxygen carrier, whereby oxygen which diffuses through the membrane binds to the carrier to give a bound oxygen complex, (3) transporting the carrier fluid containing the bound oxygen complex to a first electrode compartment of an electrochemical cell which forms a second portion of the closed container, (4) electrochemically modifying the binding-state oxygen carrier to an oxidation state having less binding affinity for oxygen, thereby releasing free oxygen into the carrier fluid and producing a nonbinding-state oxygen carrier, (5) removing oxygen from the carrier fluid, (6) transporting the carrier fluid containing the nonbinding-state oxygen carrier to a second electrode compartment of an electrochemical cell which forms a third portion of the closed container, and (7) electrochemically modifying the nonbinding-state oxygen carrier to the binding-state oxygen carrier, is disclosed along with an apparatus useful for carrying out the method of the invention.

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