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1. 发明授权

US4609383A Apparatus and method for extracting oxygen from fluids 失效
标题翻译：从流体中提取氧气的装置和方法
公开(公告)号：US4609383A
公开(公告)日：1986-09-02
申请号：US653549
申请日：1984-09-24
申请人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner
发明人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18 , B01D53/22
CPC分类号： C01B13/0255 , C01B13/0251 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528
摘要： An apparatus for extracting oxygen from an environment surrounding the apparatus, which comprises a container having an interior space isolated from physical contact with the environment at least in part by a gas permeable membrane having a first and a second side, wherein the membrane contacts the environment on the first side of the membrane, a carrier fluid in contact with the second side of the membrane in the first container, and a non-proteinaceous oxygen binding compound contained in the carrier fluid, wherein the compound comprises a tetradentate chelating molecule, a metal ion chelated in the molecule, and a nitrogenous base chelated to the metal ion, is disclosed along with a method for extracting oxygen from environmental fluids.
摘要翻译：一种用于从设备周围的环境中提取氧气的装置，其包括具有至少部分由具有第一和第二侧的透气膜与物体与环境物理接触隔离的内部空间的容器，其中膜接触环境在膜的第一侧上，与第一容器中的膜的第二侧接触的载体流体和载体流体中所含的非蛋白质氧结合化合物，其中所述化合物包含四齿螯合分子，金属离子螯合在分子中，并且与金属离子螯合的含氮碱基与从环境流体中提取氧的方法一起公开。

2. 发明授权

US06709724B1 Metal catalyzed ascorbate compounds as oxygen scavengers 失效
标题翻译：金属催化的抗坏血酸化合物作为除氧剂
公开(公告)号：US06709724B1
公开(公告)日：2004-03-23
申请号：US08783714
申请日：1997-01-16
申请人： Fred N. Teumac , Bruce D. Zenner , Bert A. Ross , Larrie A. Deardurff , Mahmood R. Rassouli
发明人： Fred N. Teumac , Bruce D. Zenner , Bert A. Ross , Larrie A. Deardurff , Mahmood R. Rassouli
IPC分类号： C09K1500
CPC分类号： C09K15/16 , B65D81/266 , C08K3/24 , C08K5/0091 , C08K5/098 , Y10T428/13 , Y10T428/215
摘要： An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. Also, a catalyzing agent is included in an amount sufficient to increase the rate of oxygen scavenging by the organic compound. The organic compound and catalyzing agent are preferably maintained in a dry state by freeze drying or microencapsulation until the organic compound is activated for oxygen scavenging by contact with water or water vapor.
摘要翻译：可透过氧气和水或水蒸气的载体如聚合物的氧气清除组合物和有机化合物或其盐的氧清除化合物相对均匀地分散在整个聚合物中，其量有效地用作除氧剂氧清除化合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。而且，催化剂的含量足以提高有机化合物的氧清除速率。有机化合物和催化剂优选通过冷冻干燥或微胶囊化将其保持在干燥状态，直到有机化合物通过与水或水蒸汽接触而被氧化除氧。

3. 发明授权

US06656383B1 Oxygen scavenging compositions from concentrates 失效
标题翻译：浓缩氧气清除组合物
公开(公告)号：US06656383B1
公开(公告)日：2003-12-02
申请号：US08783752
申请日：1997-01-16
申请人： Bruce D. Zenner , Charles S. Benedict
发明人： Bruce D. Zenner , Charles S. Benedict
IPC分类号： C08K5092
CPC分类号： C08K5/09 , B65D81/266 , C08K3/24 , C08K5/0091 , C08K5/098 , C09K15/16 , Y10T428/1352 , C08L23/02 , C08L27/06
摘要： An oxygen scavenging composition or concentrate of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound may be an ascorbate compound or a polycarboxylic or salicylic acid chelate or complex of a transition metal or a salt thereof. The oxygen scavenging composition is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. A catalyzing agent is included in an amount sufficient to increase the rate of oxygen scavenging by the ascorbate compound. The oxygen scavenging compound may be added to the composition in a dry state, and is inactive until activated by contact with water or water vapor.
摘要翻译：一种氧气清除组合物或诸如聚合物的氧化物和水或水蒸汽可渗透的载体的氧清除组合物或浓缩物，以及有机化合物或其盐的氧清除化合物以有效作用的量相对均匀地分散在整个聚合物中作为除氧剂。除氧化合物可以是抗坏血酸盐化合物或过渡金属或其盐的多羧酸或水杨酸螯合物或络合物。氧清除组合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。以足以增加抗坏血酸化合物的氧清除速率的量包含催化剂。氧清除化合物可以在干燥状态下加入到组合物中，并且通过与水或水蒸气接触而活化。

4. 发明授权

US06465065B1 Metal catalyzed ascorbate compounds as oxygen scavengers 失效
标题翻译：金属催化的抗坏血酸化合物作为除氧剂
公开(公告)号：US06465065B1
公开(公告)日：2002-10-15
申请号：US08783784
申请日：1997-01-15
申请人： Fred N. Teumac , Bruce D. Zenner , Bert A. Ross , Larrie A. Deardurff , Mahmood R. Rassouli
发明人： Fred N. Teumac , Bruce D. Zenner , Bert A. Ross , Larrie A. Deardurff , Mahmood R. Rassouli
IPC分类号： C09K1500
CPC分类号： B65D81/266 , C08K3/24 , C08K5/0091 , C08K5/098 , C09K15/16 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355
摘要： An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. Also, a catalyzing agent is included in an amount sufficient to increase the rate of oxygen scavenging by the organic compound. The organic compound and catalyzing agent are preferably maintained in a dry state by freeze drying or microencapsulation until the organic compound is activated for oxygen scavenging by contact with water or water vapor.
摘要翻译：可透过氧气和水或水蒸气的载体如聚合物的氧气清除组合物和有机化合物或其盐的氧清除化合物相对均匀地分散在整个聚合物中，其量有效地用作除氧剂氧清除化合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。而且，催化剂的含量足以提高有机化合物的氧清除速率。有机化合物和催化剂优选通过冷冻干燥或微胶囊化将其保持在干燥状态，直到有机化合物通过与水或水蒸汽接触而被氧化除氧。

5. 发明授权

US5492742A Packages and containers comprising salicylic acid chelates as oxygen scavengers 失效
标题翻译：包含水杨酸螯合物作为除氧剂的包装和容器
公开(公告)号：US5492742A
公开(公告)日：1996-02-20
申请号：US296761
申请日：1994-08-26
申请人： Bruce D. Zenner , Fred N. Teumac , Larrie A. Deardurff , Bert A. Ross
发明人： Bruce D. Zenner , Fred N. Teumac , Larrie A. Deardurff , Bert A. Ross
IPC分类号： A23L3/3436 , B65D51/24 , B65D81/26 , C08K5/00 , C09K15/04 , B32B1/00 , B29D22/00
CPC分类号： C09K15/04 , A23L3/3436 , B65D51/244 , B65D81/266 , C08K5/0091 , Y10T428/1334 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： An oxygen scavenging packages and containers which comprise a composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is a salicylic acid chelate or complex of a transition metal or a salt thereof. The oxygen scavenging composition is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. A reducing agent of an ascorbate compound may be added to enhance the performance of the salicylic acid chelate or complex. The oxygen scavenging compound may be added to the composition in a dry state, and is inactive until activated for oxygen scavenging by contact with water or water vapor.
摘要翻译：包含氧清除包装和容器，其包含可透过氧气和水或水蒸气的载体如聚合物的组合物，以及有机化合物或其盐的氧清除化合物相对均匀地分散在整个聚合物中有效地用作除氧剂。除氧化合物是过渡金属或其盐的水杨酸螯合物或络合物。氧清除组合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。可以加入抗坏血酸盐化合物的还原剂以增强水杨酸螯合物或络合物的性能。氧清除化合物可以在干燥状态下加入到组合物中，并且通过与水或水蒸汽接触而活化，直到被氧气清除为止。

6. 发明授权

US06391406B1 Polymer compositions containing oxygen scavenging compounds 失效
标题翻译：含氧清除化合物的聚合物组合物
公开(公告)号：US06391406B1
公开(公告)日：2002-05-21
申请号：US08783780
申请日：1997-01-15
申请人： Bruce D. Zenner , Charles S. Benedict
发明人： Bruce D. Zenner , Charles S. Benedict
IPC分类号： C09K1506
CPC分类号： C08K5/09 , B65D81/266 , C08K3/24 , C08K5/0091 , C08K5/098 , C09K15/16 , Y10T428/1352 , C08L23/02 , C08L27/06
摘要： An oxygen scavenging composition or concentrate of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound may be an ascorbate compound or a polycarboxylic or salicylic acid chelate or complex of a transition metal or a salt thereof. The oxygen scavenging composition is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier.
摘要翻译：一种氧气清除组合物或诸如聚合物的氧化物和水或水蒸汽可渗透的载体的氧气清除组合物或浓缩物，以及有机化合物或其盐的氧清除化合物以有效作用的量相对均匀地分散在整个聚合物中作为除氧剂。除氧化合物可以是抗坏血酸盐化合物或过渡金属或其盐的多羧酸或水杨酸螯合物或络合物。氧清除组合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。

7. 发明授权

US5364555A Polymer compositions containing salicylic acid chelates as oxygen scavengers 失效
标题翻译：包含水杨酸螯合物作为除氧剂的聚合物组合物
公开(公告)号：US5364555A
公开(公告)日：1994-11-15
申请号：US124993
申请日：1993-09-21
申请人： Bruce D. Zenner , Fred N. Teumac , Larrie A. Deardurff , Bert A. Ross
发明人： Bruce D. Zenner , Fred N. Teumac , Larrie A. Deardurff , Bert A. Ross
IPC分类号： A23L3/3436 , B65D51/24 , B65D81/26 , C08K5/00 , C09K15/04
CPC分类号： C09K15/04 , A23L3/3436 , B65D51/244 , B65D81/266 , C08K5/0091 , Y10T428/1334 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is a salicylic acid chelate or complex of a transition metal or a salt thereof. The oxygen scavenging composition is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. A reducing agent of an ascorbate compound may be added to enhance the performance of the salicylic acid chelate or complex. The oxygen scavenging compound may be added to the composition in a dry state, and is inactive until activated for oxygen scavenging by contact with water or water vapor.
摘要翻译：可透过氧气和水或水蒸气的载体如聚合物的氧气清除组合物和有机化合物或其盐的氧清除化合物相对均匀地分散在整个聚合物中，其量有效地用作除氧剂除氧化合物是过渡金属或其盐的水杨酸螯合物或络合物。氧清除组合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。可以加入抗坏血酸盐化合物的还原剂以增强水杨酸螯合物或络合物的性能。氧清除化合物可以在干燥状态下加入到组合物中，并且通过与水或水蒸汽接触而活化，直到被氧气清除为止。

8. 发明授权

US5202052A Amino polycarboxylic acid compounds as oxygen scavengers 失效
标题翻译：氨基多羧酸化合物作为除氧剂
公开(公告)号：US5202052A
公开(公告)日：1993-04-13
申请号：US581507
申请日：1990-09-12
申请人： Bruce D. Zenner , Fred N. Teumac , Larrie A. Deardurff , Bert A. Ross
发明人： Bruce D. Zenner , Fred N. Teumac , Larrie A. Deardurff , Bert A. Ross
IPC分类号： B65D81/26 , C08K3/24 , C08K5/00 , C08K5/098 , C09K15/16
CPC分类号： C08K5/0091 , B65D81/266 , C08K3/24 , C08K5/098 , C09K15/16
摘要： An oxygen scavenging composition of a polymer which is permeable to both oxygen and water or water vapor, and an oxygen scavenging material of an amino polycarboxylic acid chelate or complex of a transition metal, or salt thereof, dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger when activated for scavenging oxygen by contact with water or water vapor which permeates the polymer. A preferred oxygen scavenging compound is ferrous EDTA or salts thereof. Also, an ascorbate compound may be used as a preservative or augmenter for the oxygen scavenging compound.
摘要翻译：能够透过氧气和水或水蒸汽的聚合物的氧气清除组合物以及过渡金属或其盐的氨基多羧酸螯合物或络合物的氧清除材料以相对均匀地分散在整个聚合物中的量当通过与渗透聚合物的水或水蒸气接触而被氧化除氧时被有效地用作除氧剂。优选的除氧化合物是亚铁EDTA或其盐。此外，还可以使用抗坏血酸盐化合物作为除氧化合物的防腐剂或增强剂。

9. 发明授权

US4761209A System for the extraction and utilization of oxygen from fluids 失效
标题翻译：从流体中提取和利用氧气的系统
公开(公告)号：US4761209A
公开(公告)日：1988-08-02
申请号：US855706
申请日：1986-04-25
申请人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
发明人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18
CPC分类号： H01M8/0656 , C01B13/0251 , C01B13/0255 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528 , Y10S123/13 , Y10S204/04 , Y10S261/28
摘要： A method for extracting oxygen from a fluid environment, which comprises the steps of (1) contacting a first fluid environment containing oxygen with a first surface of a first oxygen permeable membrane having a first and a second surface, wherein the membrane separates the environment from an interior space of a closed container, (2) transporting a carrier fluid into contact with the second surface of the membrane, wherein the carrier fluid is confined in the closed container and the carrier fluid contains a binding-state oxygen carrier, whereby oxygen which diffuses through the membrane binds to the carrier to give a bound oxygen complex, (3) transporting the carrier fluid containing the bound oxygen complex to a first electrode compartment of an electrochemical cell which forms a second portion of the closed container, (4) electrochemically modifying the binding-state oxygen carrier to an oxidation state having less binding affinity for oxygen, thereby releasing free oxygen into the carrier fluid and producing a nonbinding-state oxygen carrier, (5) removing oxygen from the carrier fluid, (6) transporting the carrier fluid containing the nonbinding-state oxygen carrier to a second electrode compartment of an electrochemical cell which forms a third portion of the closed container, and (7) electrochemically modifying the nonbinding-state oxygen carrier to the binding-state oxygen carrier, is disclosed along with an apparatus useful for carrying out the method of the invention.
摘要翻译：一种用于从流体环境中提取氧气的方法，其包括以下步骤：（1）使含有氧的第一流体环境与具有第一和第二表面的第一透氧膜的第一表面接触，其中所述膜将环境与密封容器的内部空间，（2）将载体流体输送到膜的第二表面接触，其中载体流体被限制在密闭容器中，并且载体流体含有结合态氧载体，通过膜的扩散与载体结合以产生结合的氧络合物，（3）将含有结合的氧络合物的载体流体输送到形成密闭容器的第二部分的电化学电池的第一电极室，（4）电化学将结合态氧载体改性为具有对氧的结合亲和力较小的氧化态，从而将游离氧释放到其中制造非结合态氧载体，（5）从载体流体中除去氧气，（6）将含有非结合态氧载体的载体流体输送到形成第三部分的电化学电池的第二电极室封闭的容器，以及（7）将非结合状态的氧载体电化学修饰为结合态氧载体，以及用于实施本发明方法的装置。

10. 发明授权

US4602987A System for the extraction and utilization of oxygen from fluids 失效
公开(公告)号：US4602987A
公开(公告)日：1986-07-29
申请号：US653850
申请日：1984-09-24
申请人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
发明人： Joseph Bonaventura , Celia Bonaventura , Joseph C. Van Ryzin , Bruce D. Zenner , C. William Anderson
IPC分类号： C01B13/02 , C25B1/02 , H01M8/06 , H01M8/18
CPC分类号： H01M8/0656 , C01B13/0251 , C01B13/0255 , C01B13/0285 , C25B1/02 , H01M8/06 , H01M8/18 , C01B2210/005 , Y02E60/528 , Y10S123/13 , Y10S204/04 , Y10S261/28
摘要： A method for extracting oxygen from a fluid environment, which comprises the steps of (1) contacting a first fluid environment containing oxygen with a first surface of a first oxygen permeable membrane having a first and a second surface, wherein the membrane separates the environment from an interior space of a closed container, (2) transporting a carrier fluid into contact with the second surface of the membrane, wherein the carrier fluid is confined in the closed container and the carrier fluid contains a binding-state oxygen carrier, whereby oxygen which diffuses through the membrane binds to the carrier to give a bound oxygen complex, (3) transporting the carrier fluid containing the bound oxygen complex to a first electrode compartment of an electrochemical cell which forms a second portion of the closed container, (4) electrochemically modifying the binding-state oxygen carrier to an oxidation state having less binding affinity for oxygen, thereby releasing free oxygen into the carrier fluid and producing a nonbinding-state oxygen carrier, (5) removing oxygen from the carrier fluid, (6) transporting the carrier fluid containing the nonbinding-state oxygen carrier to a second electrode compartment of an electrochemical cell which forms a third portion of the closed container, and (7) electrochemically modifying the nonbinding-state oxygen carrier to the binding-state oxygen carrier, is disclosed along with an apparatus useful for carrying out the method of the invention.

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