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1. 发明授权

US4828927A Sheet or web carrying an antistatic layer 失效
标题翻译：带有抗静电层的板或网
公开(公告)号：US4828927A
公开(公告)日：1989-05-09
申请号：US40822
申请日：1987-04-21
申请人： Daniel M. Timmerman , August M. Marien , Jan E. Van Havenbergh , Etienne A. Van Thillo
发明人： Daniel M. Timmerman , August M. Marien , Jan E. Van Havenbergh , Etienne A. Van Thillo
IPC分类号： H05F1/02 , C09K3/16 , G03C1/85 , G03C1/89
CPC分类号： G03C1/895 , C09K3/16 , Y10S428/913 , Y10T428/31786 , Y10T428/31797
摘要： A sheet or web comprising a substrate which is composed of or coated with a hydrophobic resin and carries an antistatic layer, characterized in that the antistatic layer consists essentially of a blockcopolyetherester of dibasic carboxylic acid(s) esterified with ethylene glycol and with a polyoxyethylene glycol having an average molecular weight in the range 1,000 to 10,000, at least 20% by weight of such blockcopolyetherester being constituted by polyoxyethylene-ester chain parts.

2. 发明授权

US5252445A Element containing solvent-resistant polymer beads 失效
标题翻译：含有耐溶剂聚合物珠的元素
公开(公告)号：US5252445A
公开(公告)日：1993-10-12
申请号：US730479
申请日：1991-07-16
申请人： Daniel M. Timmerman , Etienne A. Van Thillo , Bavo A. Muys
发明人： Daniel M. Timmerman , Etienne A. Van Thillo , Bavo A. Muys
IPC分类号： C08F2/06 , C08F2/04 , C08F2/44 , C08F8/14 , C08F291/00 , G03C1/89 , G03C1/95 , G03C1/85
CPC分类号： C08F8/14 , C08F291/00 , G03C1/89 , G03C1/95 , C08F2810/20 , Y10S428/913 , Y10S430/151 , Y10T428/31786 , Y10T428/31797
摘要： Method of preparing solvent-resistant polymer beads sizing 0.5-5 pm and having a glass transition temperature of at least 40.degree. C. by dissolving in a solvent mixture of water and water-miscible polar organic solvent an Alpha, Beta-ethylenically unsaturated monomer (1) capable of forming a polymer that is soluble in the monomer(s) present in said solvent mixture but which is insoluble in said solvent mixture, a monomer (2) carrying COOH group(s), a monomer (3) carrying halogen atom(s), a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution obtained to a temperature from 50.degree. C. to the reflux temperature thereof with stirring to form said beads, converting said COOH group(s) by reaction with a hydroxide into a carboxylic acid salt group, and causing said carboxylic acid salt group to react with said halogen atom to form ester cross-linkages. The beads can be used as spacing agents in a sheet or web material.

3. 发明授权

US5472832A Silver halide photographic element containing antistatic hydrophilic colloid binder layer 失效
标题翻译：含有抗静电亲水胶体粘合剂层的卤化银照相元件
公开(公告)号：US5472832A
公开(公告)日：1995-12-05
申请号：US69675
申请日：1993-06-01
申请人： Daniel M. Timmerman , Filip B. E. Byl , Frank G. De Voeght
发明人： Daniel M. Timmerman , Filip B. E. Byl , Frank G. De Voeght
IPC分类号： C08L33/08 , C08L33/04 , C09K3/16 , G03C1/04 , G03C1/89 , G03C8/26 , G03C1/85
CPC分类号： G03C1/89
摘要： A recording material comprising a sheet, ribbon or web support and a hydrophilic colloid binder layer incorporating an ionic polymer in the form of dispersed particulate material providing to said material an antistatic character, characterized in that (i) said ionic polymer is a cross-linked copolymer of an acrylic and/or methacrylic acid ester including 90-99 mole % of acrylate and/or methacrylate and 1 to 10 mole % of tetraallyloxyethane as polyfunctional crosslinking monomer, wherein in said copolymer at least 75% of the ester groups have been transformed into alkali metal carboxylate groups (ii) said ionic polymer is coated at a coverage of at least 14 g/m.sup.2, and (iii) said ionic polymer is present in admixture with said hydrophilic colloid binder in a weight ratio of at least 10/90.
摘要翻译：一种记录材料，包括片材，带或网状物支撑体和亲水胶体粘合剂层，所述亲水胶体粘合剂层包含提供给所述材料的抗分散颗粒材料形式的离子聚合物，其特征在于：（i）所述离子聚合物是交联的丙烯酸和/或甲基丙烯酸酯的共聚物，其包含90-99摩尔％的丙烯酸酯和/或甲基丙烯酸酯和1至10摩尔％的四烯丙氧基乙烷作为多官能交联单体，其中在所述共聚物中至少75％的酯基已经被转化（ii）所述离子聚合物以至少14g / m 2的覆盖层被涂覆，和（iii）所述离子聚合物与所述亲水胶体粘合剂的混合物以至少10/90的重量比存在。

4. 发明授权

US4855211A Polymeric phosphonium mordant and photographic element containing the same 失效
标题翻译：聚合物絮凝剂和含有它们的摄影元素
公开(公告)号：US4855211A
公开(公告)日：1989-08-08
申请号：US228173
申请日：1988-08-04
申请人： Wilhelmus Janssens , Daniel M. Timmerman , Daniel A. Claeys
发明人： Wilhelmus Janssens , Daniel M. Timmerman , Daniel A. Claeys
IPC分类号： C08F212/14 , C07F9/54 , C08F12/00 , C08F30/02 , C08F230/02 , G03C8/56
CPC分类号： G03C8/56 , C07F9/5456 , C08F30/02 , Y10S430/142 , Y10S525/916
摘要： Phosphonium mordanting polymer, that is capable of fixing acid dyes and that comprises randomly distributed recurring units corresponding to the general formula (I) ##STR1## wherein: A represents a unit that is derived from a copolymerizable monomer capable of quenching singlet oxygen e.g. N-vinylimidazole or 2-methyl-1-vinylimidazole;B represents a unit that is derived from a copolymerizable monomer having a hydrophobic character e.g. acrylonitrile or methacrylonitrile;n represents an integer of from 1 to about 12;each of R.sub.1, R.sub.2 and R.sub.3 (same or different) represents a C.sub.1 -C.sub.8 alkyl group e.g. n-butyl, a substituted C.sub.1 -C.sub.8 alkyl group e.g. a methylol group, a cyanoethyl group or an aralkyl group, a cycloalkyl group, an aryl group e.g. phenyl, or a substituted aryl group;X.sup.- represents an acid anion e.g. a halogen anion e.g. Cl.sup.-, Br.sup.- or I.sup.-, or an anion derived from an inorganic acid e.g. NO.sub.3.sup.-, HSO.sub.4.sup.-, SO.sub.4.sup.--, H.sub.2 PO.sub.4.sup.-, HPO.sub.4.sup.-- or PO.sub.4.sup.---;x represents from about 5 mole % to about 80 mole %;y represents from about 20 mole % to about 95 mole % andz represents from about 0 mole % to about 65 mole %.
摘要翻译：鏻媒染聚合物，其能够固定酸性染料并且包含对应于通式（I）的无规分布的重复单元其中：A表示衍生自能够淬灭单线态氧的可共聚单体的单元例如 N-乙烯基咪唑或2-甲基-1-乙烯基咪唑; B表示衍生自具有疏水性的可共聚单体的单元，丙烯腈或甲基丙烯腈; n表示1〜12的整数， R 1，R 2和R 3（相同或不同）各自表示C 1 -C 8烷基。正丁基，取代的C 1 -C 8烷基，例如羟甲基，氰乙基或芳烷基，环烷基，芳基例如。苯基或取代的芳基; X-表示酸性阴离子例如卤素阴离子 Cl-，Br-或I-，或衍生自无机酸的阴离子例如。 NO331，HSO4-，SO4-，H 2 PO 4 - ，HPO 4 - 或PO 4 - ; x表示约5摩尔％至约80摩尔％; y表示约20摩尔％至约95摩尔％，z表示约0摩尔％至约65摩尔％。

5. 发明授权

US4820608A Dye diffusion transfer imaging process and image receptor used therein 失效
标题翻译：染料扩散转移成像过程和图像受体
公开(公告)号：US4820608A
公开(公告)日：1989-04-11
申请号：US110797
申请日：1987-10-21
申请人： Daniel A. Claeys , Daniel M. Timmerman , Antonius A. Rutges , Eddy A. Michiels , Luc J. Vanmaele , Piet Kok
发明人： Daniel A. Claeys , Daniel M. Timmerman , Antonius A. Rutges , Eddy A. Michiels , Luc J. Vanmaele , Piet Kok
IPC分类号： G03C8/56 , G03C8/00 , G03C8/26 , G03C5/54
CPC分类号： G03C8/26 , G03C8/00 , Y10S430/142
摘要： The present invention provides a dye diffusion transfer imaging process comprising transferring image-wise by diffusion an acid dye to an image-receiving layer incorporating a non-polymeric phosphonium mordanting agent and a copolymer latex comprising free weak acid groups as a stabilizer for the mordanting agent, wherein the image-wise transfer of said acid dye is performed in the presence of a heterocyclic compound corresponding to one of the following general formulae I, II, and III: ##STR1## wherein: Y represents the non-metallic atoms needed to complete a saturated or unsaturated 5- or 6-membered heterocyclic nucleus, which may carry a fused-on aromatic ring system, and M represents hydrogen, an alkali metal atom, a quaternary ammonium group, or a negative charge forming an inner salt with a quaternized nitrogen atom of the heterocyclic compound. The invention also provides an image receptor element for dye diffusion transfer imaging processes comprising a support and such image-receiving layer.

6. 发明授权

US4266044A Novel polymeric mordanting agents for anionic compounds 失效
标题翻译：用于阴离子化合物的新型聚合物媒染剂
公开(公告)号：US4266044A
公开(公告)日：1981-05-05
申请号：US968175
申请日：1978-12-11
申请人： Daniel M. Timmerman , Walter F. De Winter , Albert E. Van Hoof
发明人： Daniel M. Timmerman , Walter F. De Winter , Albert E. Van Hoof
IPC分类号： G03C1/835 , G03C7/25 , C08C19/22 , C08F26/00 , C08F220/60 , C08F226/00
CPC分类号： G03C1/835 , G03C7/25 , Y10S430/142 , Y10S526/923
摘要： Mordanting agents for anionic organic compounds are described which comprise recurring units of the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; A is methylene or methylene substituted by C.sub.1 -C.sub.5 alkyl;n is 0 or 1;R.sub.2 is alkyl, andX is an acid radical.They are particularly suitable for hindering diffusion of dyes in hydrophilic colloid media e.g. hydrophilic colloid layers of a photographic silver halide element, for hindering diffusion of color couplers in such layers e.g. layers of a radiographic silver halide color element and for the formation of color images by the relief imbibition process.
摘要翻译：描述了阴离子有机化合物的媒染剂，其包含下式的重复单元：其中R 1是氢或甲基; A是被C1-C5烷基取代的亚甲基或亚甲基; n为0或1; R2是烷基，X是酸基。它们特别适用于阻止染料在亲水胶体介质中的扩散，例如照相卤化银元素的亲水胶体层，用于阻止彩色成色剂在这种层中的扩散。一层放射摄影卤化银色素，并通过浮雕吸收过程形成彩色图像。

7. 发明授权

US4145220A Silver halide element with polymeric mordanting agents for anionic compounds 失效
标题翻译：卤化银元素与阴离子化合物的聚合物媒染剂
公开(公告)号：US4145220A
公开(公告)日：1979-03-20
申请号：US213990
申请日：1971-12-30
申请人： Daniel M. Timmerman , Walter F. De Winter , Albert E. Van Hoof
发明人： Daniel M. Timmerman , Walter F. De Winter , Albert E. Van Hoof
IPC分类号： G03C1/835 , G03C7/25 , G03C1/84 , G03C1/10
CPC分类号： G03C1/835 , G03C7/25 , Y10S430/142 , Y10S526/923
摘要： Mordanting agents for anionic organic compounds are described which comprise recurring units of the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; A is methylene or methylene sustituted by C.sub.1 -C.sub.5 alkyl; N is 0 or 1; R.sub.2 is alkyl, and X is an acid radical. They are particularly suitable for hindering diffusion of dyes in hydrophilic colloid media e.g. hydrophilic colloid layers of a photographic silver halide element, for hindering diffusion of color couplers in such layers e.g. layers of a radiographic silver halide color element and for the formation of color images by the relief imbibition process.
摘要翻译：描述了阴离子有机化合物的媒染剂，其包含下式的重复单元：其中R 1是氢或甲基; A是由C 1 -C 5烷基取代的亚甲基或亚甲基; N IS 0或1; R2是烷基，X是酸基。

8. 发明授权

US5254434A Method of forming thermal transfer dye images 失效
标题翻译：形成热转印染料图像的方法
公开(公告)号：US5254434A
公开(公告)日：1993-10-19
申请号：US783243
申请日：1991-10-28
申请人： Herman J. Uytterhoeven , Joan T. Vermeersch , Daniel M. Timmerman , Marcel J. Monbaliu
发明人： Herman J. Uytterhoeven , Joan T. Vermeersch , Daniel M. Timmerman , Marcel J. Monbaliu
IPC分类号： B41M5/382 , B41M5/392 , B41M5/50 , B41M5/52 , G03F7/027 , G03F7/34
CPC分类号： G03F7/027 , G03F7/34
摘要： Method of forming thermal transfer dye images comprising exposing a recording element comprising at least one layer of an organic photochemical imaging composition comprising a heat-diffusible dye (precursor) monomer, said layer being permeable to said dye (precursor) monomer, to an image-wise distribution of actinic radiation to create a change in its permeability corresponding to said image-wise distribution of actinic radiation, wherein said change in permeability is brought about by the radiation-induced polymerization or crosslinking reaction of said organic photochemical imaging composition combined with a concurrent copolymerization or crosslinking reaction of said heat-diffusible dye (precursor) monomer, bringing said recording element in contact with an image-receiving element, overall heating at least one of said contacting elements to cause diffusion of the heat-diffusible dye (precursor) monomer from the areas having unchanged permeability and transfer to said image-receiving element, causing in the case of said dye precursor monomer reaction of said transferred dye precursor monomer with a reagent present in said recording element, in said image-receiving element, or in a fluid medium applied to said image-receiving element, to convert said transferred dye precursor monomer into a dye. The invention also provides a recording element for use according to this method.

9. 发明授权

US4614708A Method for the preparation of stable aqueous dispersions of polymer beads and the use of these dispersions in photographic elements 失效
标题翻译：用于制备聚合物珠的稳定水分散体的方法以及这些分散体在照相元件中的应用
公开(公告)号：US4614708A
公开(公告)日：1986-09-30
申请号：US580272
申请日：1984-02-16
申请人： Daniel M. Timmerman , Jan J. Priem , Jan H. Janssens
发明人： Daniel M. Timmerman , Jan J. Priem , Jan H. Janssens
IPC分类号： G03C1/32 , C08F2/00 , C08F2/16 , C08F2/18 , C08F257/02 , C08F267/02 , C08F291/00 , G03C1/825 , G03C1/89 , G03C1/95 , G03C1/84 , G03C1/02
CPC分类号： C08F257/02 , C08F267/02 , G03C1/825 , G03C1/89 , G03C1/95 , Y10S430/132 , Y10S430/151 , Y10S430/162
摘要： Method for the preparation of stable aqueous dispersions of finely divided solid spherical polymer beads having an average particle size between about 0.5 and about 5 .mu.m and having a glass transition temperature of at least 40.degree. C. by dissolving in an aqueous solvent mixture at least one .alpha.,.beta.-ethylenically unsaturated monomer capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in said aqueous solvent mixture, a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution to a temperature from 50.degree. C. to the reflux temperature thereof with stirring so as to form said polymer beads. The polymer beads can be used in an antifriction surface layer, an antihalation surface layer, an antistatic surface layer, or in a protective surface layer of a photographic element or in a top layer of a drafting film containing a photosensitive layer.
摘要翻译：制备平均粒径为约0.5至约5μm的玻璃化转变温度为至少40℃的细分固体球形聚合物珠粒的稳定水分散体的方法，通过将至少能够形成可溶于所述水性溶剂混合物中存在但不溶于所述水性溶剂混合物中的单体的聚合物的一种α，β-烯属不饱和单体，自由基形成聚合引发剂和接枝 - 含有亲水基团的可聚合聚合物，在搅拌下将溶液加热至50℃至其回流温度，以形成所述聚合物珠粒。聚合物珠可以用于减摩表面层，防光晕表面层，抗静电表面层，或照相元件的保护表面层或含有感光层的牵伸膜的顶层中。

10. 发明授权

US4186010A Silver halide elements with polymers containing ketoiminoguanidinium groups 失效
标题翻译：卤化银元素与含有酮基鸟嘌呤基团的聚合物
公开(公告)号：US4186010A
公开(公告)日：1980-01-29
申请号：US567109
申请日：1975-04-11
申请人： Raymond L. Florens , Daniel M. Timmerman
发明人： Raymond L. Florens , Daniel M. Timmerman
IPC分类号： G03C1/34 , C08F246/00 , G03C1/053 , G03C5/30 , G03C1/72
CPC分类号： G03C1/053 , Y10S430/164
摘要： A photographic element is described comprising an emulsion layer of low gelatin to silver halide ratio, the emulsion comprising a polymeric compound containing recurring units with ketoiminoguanidinium groups in the side chain to reduce formation of pressure marks.
摘要翻译：描述了一种照相元件，其包含低明胶与卤化银比例的乳剂层，该乳液包含在侧链中含有酮亚胺基团的重复单元的聚合物，以减少形成压痕。

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