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    • 3. 发明授权
    • Color motion picture print film with desaturated color space
    • 彩色运动图像打印带有不饱和色彩空间的影片
    • US5985529A
    • 1999-11-16
    • US219697
    • 1998-12-23
    • Mitchell J. BogdanowiczJames P. MerrillCharles P. Hagmaier
    • Mitchell J. BogdanowiczJames P. MerrillCharles P. Hagmaier
    • G03C1/035G03C7/30
    • G03C1/035G03C7/3029G03C2007/3015G03C2007/3034G03C2007/3037G03C7/3022G03C7/3041Y10S430/135
    • A silver halide light sensitive motion picture photographic color print element is disclosed comprising a support bearing on one side thereof: a primary blue sensitive and secondary green and red sensitive yellow dye image-forming unit comprising at least one light sensitive silver halide emulsion layer having associated therewith yellow dye-forming coupler; a primary red sensitive and secondary green and blue sensitive cyan dye image-forming unit comprising at least one light sensitive silver halide emulsion layer having associated therewith cyan dye-forming coupler; and a primary green sensitive and secondary blue and red sensitive magenta dye image-forming unit comprising at least one light sensitive silver halide emulsion layer having associated therewith magenta dye-forming coupler; wherein the primary and secondary light sensitivities in each of the dye image-forming units result in ratios of the primary color linear sensitivity of the unit to the same color secondary linear sensitivity of each of the other dye image-forming units of from 30:1 to 3:2. Color print film silver halide photographic elements with crossed blue, green and red sensitization in each of the yellow, magenta and cyan dye image-forming units thereof enable the production of projected images having desired black densities and colored images having desired degrees of color saturation.
    • 公开了一种卤化银光敏电影照相彩色印刷元件,其包括在其一侧上的支撑轴承:初级蓝色敏感性和次级绿色和红色敏感性黄色染料图像形成单元,其包含至少一种具有相关联的感光卤化银乳剂层 由此形成黄色染料成色剂; 初级红色敏感性和次级绿色和蓝色感光青色染料成像单元,其包含至少一种具有与其形成青色染料的成色剂相关联的感光卤化银乳剂层; 和主要的绿色敏感和次级蓝色和红色敏感的品红色染料成像单元,其包括至少一种具有与品红成色成色剂相关联的感光卤化银乳剂层; 其中每个染料成像单元中的初级和次级光敏度导致单位的原色线性灵敏度与每种其它染料成像单元的相同颜色次级线性灵敏度的比例为30:1 至3:2。 在其黄色,品红色和青色染料成像单元中的每一个中具有交叉的蓝色,绿色和红色致敏的彩色印刷膜卤化银照相元件能够产生具有所需黑色浓度的投影图像和具有期望色彩饱和度的彩色图像。
    • 5. 发明授权
    • Photographic elements containing certain acylacetanilide couplers in
combination with development inhibitor releasing couplers
    • 含有某些酰基乙酰苯胺成色剂与显影抑制剂释放成色剂的摄影元件
    • US5451492A
    • 1995-09-19
    • US214722
    • 1994-03-17
    • Paul B. MerkelJerrold N. PoslusnyJames P. MerrillBernard A. ClarkPaul L. R. Stanley
    • Paul B. MerkelJerrold N. PoslusnyJames P. MerrillBernard A. ClarkPaul L. R. Stanley
    • G03C7/00G03C7/305G03C7/36G03C1/46
    • G03C7/30535G03C7/367Y10S430/158
    • The present invention provides a photographic element comprising a support bearing a blue light sensitive silver halide emulsion layer containing an acylacetanilide yellow image dye-forming coupler having formula I: ##STR1## wherein: R.sub.a is a substituted or unsubstituted alkyl, alkoxy, or aryloxy group;R.sub.b is a substituted or unsubstituted alkyl or aryl group;R.sub.c is hydrogen or a substituted or unsubstituted alkyl group;R.sub.1 is a substituent;R.sub.2 is selected from the group consisting of halogen, trifluoromethyl, and substituted or unsubstituted alkoxy and aryloxy;each R.sub.3 is bonded at the 4- or 5- position relative to the anilino nitrogen and is independently a substituent selected from the group consisting of halogen, alkoxycarbonyl (--CO.sub.2 R), carbamoyl (--CONRR'), sulfonate (--OSO.sub.2 R), sulfamoyl (--SO.sub.2 NRR'), sulfonyl (--SO.sub.2 R), trifluoromethyl, cyano, and sulfonamido (--NRSO.sub.2 R'), in which each R and R' is independently hydrogen or a substituent;q is 1 or 2;R.sub.4 and R.sub.5 are independently hydrogen or an alkyl group; andR.sub.6 is a substituent;n is an integer from 0 to (3-q);wherein the blue light sensitive silver halide emulsion layer has associated therewith a development inhibitor releasing coupler. The invention also provides a method of forming an image in such an element.
    • 本发明提供了一种照相元件,其包含支持蓝色感光卤化银乳剂层的载体,其含有具有式I的酰基乙酰替苯胺黄色成像剂:其中:R a是取代或未取代的烷基,烷氧基或芳氧基 组; Rb是取代或未取代的烷基或芳基; Rc是氢或取代或未取代的烷基; R1是取代基; R2选自卤素,三氟甲基和取代或未取代的烷氧基和芳氧基; 每个R 3相对于苯胺基氮键在4-或5-位,并且独立地是选自卤素,烷氧基羰基(-CO 2 R),氨基甲酰基(-CONRR'),磺酸酯(-OSO 2 R),氨磺酰基 (-SO 2 NRR'),磺酰基(-SO 2 R),三氟甲基,氰基和亚磺酰氨基(-NRSO 2 R'),其中R和R'各自独立地为氢或取代基; q为1或2; R4和R5独立地是氢或烷基; R6为取代基; n是从0到(3-q)的整数; 其中所述蓝光感光卤化银乳剂层与其形成显影抑制剂释放成色剂。 本发明还提供了一种在这种元件中形成图像的方法。
    • 7. 发明授权
    • Color motion picture print film for use with digital output
    • US5891607A
    • 1999-04-06
    • US929962
    • 1997-09-15
    • John C. BrewerJames P. Merrill
    • John C. BrewerJames P. Merrill
    • G03C7/20G03C7/22G03C7/30G03C1/46G03C7/407G03C5/12
    • G03C7/3041
    • One embodiment of the invention comprises a silver halide light sensitive photographic print element comprising a support bearing on one side thereof: a blue color sensitive record comprising at least one blue-sensitive silver halide emulsion yellow-image forming layer, a red color sensitive record comprising at least one red-sensitive silver halide emulsion cyan-image forming layer, and a green color sensitive record comprising at least one green-sensitive silver halide emulsion magenta-image forming layer; wherein the overall contrast (OC) of the green record is greater than 1.9, and the mid-scale contrast (MSC) of the green record is about 3.2 or more, wherein the parameters OC and MSC are as defined herein. A further embodiment of the invention comprises a process of forming an image in a motion picture silver halide light sensitive color photographic print element comprising: (a) digitally exposing a photographic light sensitive element according to digital image data using a digital film recording device to form a color negative film record, and printing the negative film record on the silver halide light sensitive photographic print element to form an exposed print element, or (b) directly exposing the silver halide light sensitive photographic print element according to digital image data with a digital film recording device; and processing the exposed photographic print element resulting from (a) or (b) to form a developed image; wherein the overall contrast (OC) of the green record of the print element is greater than 1.9. Preferably, the elements of the invention and the elements used in the process ol the invention have corresponding red and blue OC values which are at least 90% of the green values, and MSC values within .+-.10% of the green values, enabling the production of outstanding projected images having black densities and with digital assistance, optimal mid-scale contrasts which together cannot be easily obtained with traditionally designed color print films.
    • 8. 发明授权
    • Color motion picture print film
    • 彩色动态影像打印胶卷
    • US5888706A
    • 1999-03-30
    • US931010
    • 1997-09-15
    • James P. MerrillJohn C. BrewerLeslie Gutierrez
    • James P. MerrillJohn C. BrewerLeslie Gutierrez
    • G03C7/20G03C7/22G03C7/30G03C1/46G03C7/407G03C5/12
    • G03C7/3041
    • A silver halide light sensitive photographic print element is disclosed comprising a support bearing on one side thereof: a blue color sensitive record comprising at least one blue-sensitive silver halide emulsion yellow-image forming layer, a red color sensitive record comprising at least one red-sensitive silver halide emulsion cyan-image forming layer, and a green color sensitive record comprising at least one green-sensitive silver halide emulsion magenta-image forming layer; wherein the overall contrast (OC) of the green record is greater than 1.9, the mid-scale contrast (MSC) of the green record is less than 3.2, and the upper-scale contrast (USC) of the green record is greater than 3.2, wherein the parameters OC, MSC and USC are as defined herein. A process of forming an image in a motion picture silver halide light sensitive photographic print element as described above comprises exposing the silver halide light sensitive photographic print element to a color negative film record, and processing the exposed photographic print element to form a developed image having maximum green Equivalent Neutral Densities of at least 3.8. In accordance with preferred embodiments, the elements are exposed and processed to form images with red and blue maximum Equivalent Neutral Densities which are also at least 3.8. Preferably, the elements of the invention and the elements used in the process of the invention have corresponding red and blue OC and USC values which are at least 90% of the green values, and MSC values within .+-.10% of the green values, enabling the production of outstanding projected images having high black densities and optimal mid-scale contrasts.
    • 公开了一种卤化银感光照相印刷元件,其包括在其一侧上的支撑轴承:蓝色感光记录,其包括至少一种感蓝卤化银乳剂黄色图像形成层,红色敏感记录,其包含至少一种红色 感光卤化银乳剂青色图像形成层和包含至少一种感绿卤化银乳剂品红色图像形成层的绿色感知记录; 其中绿色记录的总体对比度(OC)大于1.9,绿色记录的中等尺度对比度(MSC)小于3.2,绿色记录的上限对比度(USC)大于3.2 其中参数OC,MSC和USC如本文所定义。 在如上所述的电影照相卤化银感光照相打印元件中形成图像的过程包括将卤化银感光照相打印元件暴露于彩色底片记录,以及处理曝光的照相打印元件,以形成具有 最大绿色等效中性密度至少3.8。 根据优选实施例,元件被曝光和处理以形成具有红色和蓝色最大等效中性密度的图像,其也为至少3.8。 优选地,本发明的元件和在本发明的方法中使用的元件具有相应的红色和蓝色OC和USC值,其为绿色值的至少90%,并且MSC值在绿色值的+/- 10%内 ,使得能够生产具有高黑色密度和最佳中等尺寸对比度的突出投影图像。
    • 10. 发明授权
    • Photographic element containing certain azoaniline dyes
    • 含有某些偶氮苯胺染料的摄影元素
    • US5532117A
    • 1996-07-02
    • US431234
    • 1995-04-28
    • Paul B. MerkelJames P. MerrillJeffrey W. SchmoegerJared B. Mooberry
    • Paul B. MerkelJames P. MerrillJeffrey W. SchmoegerJared B. Mooberry
    • G03C7/00G03C1/40G03C1/83G03C7/20G03C1/46
    • G03C1/831
    • The invention provides a multicolor negative photographic element which contains a layer containing a yellow or orange-yellow azoaniline dye of structure I ##STR1## wherein: R.sub.1 is an alkyl group or a phenyl group;R.sub.2 is hydrogen or an alkyl group;R.sub.3 is an alkoxy, aryloxy or alkyl group when R.sub.2 is hydrogen, or is hydrogen when R.sub.2 is an alkyl group;R.sub.1 and R.sub.2 or R.sub.1 and R.sub.3 may join to form a ring;R.sub.4, which may be in the para or meta position relative to the azo group, is an electron-withdrawing group selected from the group consisting of trifluoromethyl, cyano, halogen, and from alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido, sulfonamido, carbamoyl, sulfamoyl, alkylsulfonyl, arylsulfonyl, sulfonyloxy (--OSO.sub.3 R), alkoxysulfonyl, aryloxysulfonyl, and sulfoxide groups;R.sub.5 is hydrogen or, can be a chlorine in the meta position when R.sub.4 is a chlorine in the para position; andthe total number of carbon atoms in R.sub.1, R.sub.2, R.sub.3, and R.sub.4 taken together is at least 9;wherein neither a layer sensitive to blue light nor a layer sensitive to green light is located between the support and the layer in which the azoaniline dye is located. The invention also provides a method of forming an image in an element of the invention.
    • 本发明提供一种多色负片照相元件,其含有含有结构I的黄色或橙色 - 黄色偶氮苯胺染料的层,其中:R1是烷基或苯基; R2是氢或烷基; 当R 2为氢时,R 3为烷氧基,芳氧基或烷基,或当R 2为烷基时为R 3; R1和R2或R1和R3可以连接形成环; R4可以相对于偶氮基在对位或间位,是从三氟甲基,氰基,卤素和烷氧基羰基,芳氧基羰基,酰氧基,碳酰氨基,亚磺酰氨基,氨基甲酰基,氨磺酰基中的吸电子基团 ,烷基磺酰基,芳基磺酰基,磺酰氧基(-OSO 3 R),烷氧基磺酰基,芳氧基磺酰基和亚砜基团; 当R4是对位的氯时,R5是氢或可以是间位的氯; R 1,R 2,R 3和R 4中的碳原子总数合计为9以上。 其中对蓝色光敏感的层和对绿色光敏感的层都不位于载体和偶氮苯胺染料所在的层之间。 本发明还提供了一种在本发明的元件中形成图像的方法。