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    • 1. 发明授权
    • Solid state thermal conversion of polycrystalline alumina to sapphire
using a seed crystal
    • 使用晶种将多晶氧化铝固体热转化为蓝宝石
    • US5549746A
    • 1996-08-27
    • US126628
    • 1993-09-24
    • Curtis E. ScottJack M. StrokLionel M. Levinson
    • Curtis E. ScottJack M. StrokLionel M. Levinson
    • C30B1/02C30B29/20C30B33/02
    • C30B1/02C30B29/20
    • A solid state seed crystal process for bulk conversion of a polycrystalline ceramic body to a single crystal body (of the same chemical composition) having the same crystal orientation as the seed crystal. The process comprises heating said body to form a monolithic join between the body and the seed crystal, heating the joined structure to reduce grain growth inhibitors and further heating the joined structure above the minimum temperature required for crystallite growth of the crystalline material, but not hot enough to melt and distort the original shape of the polycrystalline ceramic body during its conversion to a single crystal. This process has been used to convert polycrystalline alumina (PCA) bodies to sapphire having the same crystal orientation as the seed crystal by heating the PCA body, monolithically joined to a sapphire seed crystal, at a temperature above 1700.degree. C. without melting the body.
    • 用于将多晶陶瓷体大量转化成具有与晶种相同的晶体取向的单晶体(相同的化学组成)的固态晶种方法。 该方法包括加热所述主体以在主体和晶种之间形成整体连接,加热接合的结构以减少晶粒生长抑制剂并进一步加热接合结构高于结晶材料微晶生长所需的最低温度,但不热 足以熔化和扭曲多晶陶瓷体在其转变成单晶时的原始形状。 已经使用该方法将多晶氧化铝(PCA)体转变为具有与晶种相同的晶体取向的蓝宝石,通过加热在1700℃以上的温度下单体连接到蓝宝石晶种的PCA体,而不熔化本体 。
    • 3. 发明授权
    • Conversion of doped polycrystalline material to single crystal material
    • 掺杂多晶材料转化为单晶材料
    • US5588992A
    • 1996-12-31
    • US552700
    • 1995-11-03
    • Curtis E. ScottMary Sue KaliszewskiLionel M. Levinson
    • Curtis E. ScottMary Sue KaliszewskiLionel M. Levinson
    • C30B1/02C30B1/00C30B29/20C30B1/06
    • C30B1/00C30B29/20
    • A solid state method of converting a polycrystalline ceramic body to a single crystal body includes the steps of doping the polycrystalline ceramic material with a conversion-enhancing dopant and then heating the polycrystalline body at a selected temperature for a selected time sufficient to convert the polycrystalline body to a single crystal. The selected temperature is less than the melting temperature of the polycrystalline material and greater than about one-half the melting temperature of the material. In the conversion of polycrystalline alumina to single crystal alumina (sapphire), examples of conversion-enhancing dopants include cations having a +3 valence, such as chromium, gallium, and titanium. The polycrystalline body further can be inhomogeneously doped to form a first portion of the polycrystalline body that is doped to the selected level of the conversion-enhancing dopant and a second portion that is not doped such that heating the doped polycrystalline body causes conversion of first portion to a single crystal structure and the second portion retains a polycrystalline structure.
    • 将多晶陶瓷体转换为单晶体的固态方法包括以下步骤:用转化增强掺杂剂掺杂多晶陶瓷材料,然后在所选择的温度下加热多晶体一段足以将多晶体转变的选定时间 到单晶。 所选择的温度小于多晶材料的熔化温度并且大于材料的熔融温度的约一半。 在将多晶氧化铝转化为单晶氧化铝(蓝宝石)时,转化增强掺杂剂的实例包括具有+3价的阳离子,例如铬,镓和钛。 多晶体还可以不均匀地掺杂以形成掺杂到转化增强掺杂剂的选定水平的多晶体的第一部分和不掺杂的第二部分,使得加热掺杂的多晶体导致第一部分的转化 到单晶结构,第二部分保留多晶结构。
    • 4. 发明授权
    • Conversion of doped polycrystalline material to single crystal
    • 掺杂多晶材料转化为单晶
    • US5487353A
    • 1996-01-30
    • US195187
    • 1994-02-14
    • Curtis E. ScottMary Sue KaliszewskiLionel M. Levinson
    • Curtis E. ScottMary Sue KaliszewskiLionel M. Levinson
    • C30B1/02C30B1/00C30B29/20C30B21/04
    • C30B1/00C30B29/20
    • A solid state method of converting a polycrystalline ceramic body to a single crystal body includes the steps of doping the polycrystalline ceramic material with a conversion-enhancing dopant and then heating the polycrystalline body at a selected temperature for a selected time sufficient to convert the polycrystalline body to a single crystal. The selected temperature is less than the melting temperature of the polycrystalline material and greater than about one-half the melting temperature of the material. In the conversion of polycrystalline alumina to single crystal alumina (sapphire), examples of conversion-enhancing dopants include cations having a +3 valence, such as chromium, gallium, and titanium. The polycrystalline body further can be inhomogeneously doped to form a first portion of the polycrystalline body that is doped to the selected level of the conversion-enhancing dopant and a second portion that is not doped such that heating the doped polycrystalline body causes conversion of first portion to a single crystal structure and the second portion retains a polycrystalline structure.
    • 将多晶陶瓷体转换为单晶体的固态方法包括以下步骤:用转化增强掺杂剂掺杂多晶陶瓷材料,然后在所选择的温度下加热多晶体一段足以将多晶体转变的选定时间 到单晶。 所选择的温度小于多晶材料的熔化温度并且大于材料的熔融温度的约一半。 在将多晶氧化铝转化为单晶氧化铝(蓝宝石)时,转化增强掺杂剂的实例包括具有+3价的阳离子,例如铬,镓和钛。 多晶体还可以不均匀地掺杂以形成掺杂到转化增强掺杂剂的选定水平的多晶体的第一部分和不掺杂的第二部分,使得加热掺杂的多晶体导致第一部分的转化 到单晶结构,第二部分保留多晶结构。
    • 6. 发明授权
    • Conversion of polycrystalline material to single crystal material using
bodies having a selected surface topography
    • 使用具有选定表面形貌的主体将多晶材料转化为单晶材料
    • US5540182A
    • 1996-07-30
    • US126830
    • 1993-09-24
    • Lionel M. LevinsonCurtis E. Scott
    • Lionel M. LevinsonCurtis E. Scott
    • C30B1/02C30B1/00C30B29/20
    • C30B1/00C30B29/20
    • A solid step process for convening a polycrystalline body to a single crystal body includes the steps of forming a selected surface topography on the body and then heating the body at a temperature below its melting temperature for a time sufficient to substantially convert the polycrystalline material to single crystal material. The surface topography includes depressions or protrusions from the body having sidewalls of the polycrystalline material that are disposed to intersect one another at junctions forming relatively sharp corners, and the dimensions of the sidewalls are greater than the average grain size of the polycrystalline material. Typically alumina is the polycrystalline material and surface features include grooves or the like. The patterned alumina body with the selected surface topography is heated to a temperature between 1800.degree. and 2000.degree. C. in one or more cycles to convert the polycrystalline alumina to sapphire.
    • 用于将多晶体聚合到单晶体的固体步骤包括以下步骤:在体上形成所选择的表面形貌,然后在低于其熔融温度的温度下加热体,所述时间足以将多晶材料基本上转化为单 水晶材料。 表面形貌包括来自具有多晶材料侧壁的主体的凹陷或突起,所述侧壁设置成在形成相对尖锐的拐角处的接合处彼此相交,并且侧壁的尺寸大于多晶材料的平均晶粒尺寸。 通常,氧化铝是多晶材料,表面特征包括凹槽等。 将具有所选表面形貌的图案化氧化铝体在一个或多个循环中加热至1800℃至2000℃的温度以将多晶氧化铝转化为蓝宝石。