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    • 8. 发明授权
    • Supercritical selective extraction of hydrocarbons from asphaltic
petroleum oils
    • 从沥青油中超临界选择性​​提取碳氢化合物
    • US4354928A
    • 1982-10-19
    • US157728
    • 1980-06-09
    • Costandi A. AudehTsoung Y. Yan
    • Costandi A. AudehTsoung Y. Yan
    • B01D11/02C10C3/08C10G1/04C10C3/00
    • C10C3/08B01D11/0203C10G1/04
    • An asphalt containing petroleum oil is deasphalted and extracted by contacting the oil with a solvent maintained at its critical temperature and pressure. With the solvent at its critical temperature and pressure, extraction of the valuable hydrocarbon oils present in the asphaltic feedstock is effected by way of vapor-liquid phase separation which serves to decompose the metal complexes present in the feedstock, thus reducing the metal content of the extracted hydrocarbon oil. Examples of solvents employed in the process of the invention include C.sub.4 -C.sub.10 cuts of typical refinery streams, benzene, toluene, ethylene glycols and the like. In one process embodiment, promoters or catalyst are employed to further reduce the metal content of the extracted hydrocarbon oil.
    • 含有石油的沥青通过使油与保持在其临界温度和压力下的溶剂接触而脱沥青并提取。 在溶剂处于临界温度和压力下,沥青原料中存在的有价值烃油的萃取是通过汽相 - 液相分离进行的,这种气相分离用于分解存在于原料中的金属络合物,从而降低了原料中金属含量 提取烃油。 在本发明方法中使用的溶剂的实例包括典型的炼油厂物流的C4-C10馏分,苯,甲苯,乙二醇等。 在一个方法实施方案中,使用促进剂或催化剂进一步降低提取的烃油的金属含量。