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1. 发明授权

US5401393A Reactive adsorbent and method for removing mercury from hydrocarbon fluids 失效
标题翻译：活性吸附剂和从烃类流体中去除汞的方法
公开(公告)号：US5401393A
公开(公告)日：1995-03-28
申请号：US120505
申请日：1993-09-14
申请人： Darrell D. Whitehurst , Tsoung Y. Yan
发明人： Darrell D. Whitehurst , Tsoung Y. Yan
IPC分类号： B01J20/26 , B01J20/32 , C10G25/02 , C10G17/00
CPC分类号： B01J20/264 , B01J20/0266 , B01J20/265 , B01J20/267 , B01J20/28004 , B01J20/28016 , B01J20/28057 , B01J20/3078 , B01J20/321 , B01J20/3234 , C10G25/02 , B01J2220/46
摘要： A method is disclosed for synthesizing a reactive sulfur-containing adsorbent material for removing metals, preferably mercury, from hydrocarbon fluids. The method includes impregnating a porous polystyrene resin with elemental sulfur, and heating the impregnated resin/sulfur mixture to chemically fix the sulfur to the resin. The elemental sulfur may be in solid, liquid, or vapor phase under conditions of contact with the resin. Also disclosed is the reactive adsorbent synthesized by this method. Also, a process is disclosed for removing mercury from hydrocarbon fluids by using a reactive adsorbent of the invention.
摘要翻译：公开了一种合成用于从烃流体中除去金属（优选汞）的反应性含硫吸附剂材料的方法。该方法包括用元素硫浸渍多孔聚苯乙烯树脂，并加热浸渍的树脂/硫混合物以将硫化学固定在树脂上。在与树脂接触的条件下，元素硫可以是固体，液体或气相。还公开了通过该方法合成的反应性吸附剂。此外，公开了通过使用本发明的反应性吸附剂从烃流体中除去汞的方法。

2. 发明授权

US5338463A Wastewater treatment by catalytic oxidation 失效
标题翻译：通过催化氧化处理废水
公开(公告)号：US5338463A
公开(公告)日：1994-08-16
申请号：US61127
申请日：1990-05-12
申请人： Tsoung Y. Yan
发明人： Tsoung Y. Yan
IPC分类号： C02F1/28 , C02F1/58 , C02F1/72 , C02F1/74
CPC分类号： C02F1/74 , C02F1/281 , C02F1/283 , C02F1/586 , C02F1/725 , Y10S210/916
摘要： Waste water chemical oxygen demand is reduced from a waste water by passing the water in the presence of an oxidizing agent through an adsorbent porous solid substrate, preferably zeolite A, zeolite X, zeolite Y, ZSM-5, erionite, chabasite or activated carbon which has been partially ion exchanged with a water insoluble metal compound, preferably copper (Cu), that facilitates oxidation of the components in the waste water that increase its chemical oxygen demand, such as sulfide, thiosulfate, sulfite, mercaptan, or disulfide. The preferred oxidizing agent is air.
摘要翻译：通过在氧化剂存在下使水通过吸附剂多孔固体基质，优选沸石A，沸石X，沸石Y，ZSM-5，毛沸石，菱镁石或活性炭，从废水中减少化学需氧量。已经部分地与水不溶性金属化合物（优选铜（Cu））离子交换，这促进了废水中的组分的氧化，这增加了其化学需氧量，例如硫化物，硫代硫酸盐，亚硫酸盐，硫醇或二硫化物。优选的氧化剂是空气。

3. 发明授权

US5107060A Thermal cracking of mercury-containing hydrocarbon 失效
标题翻译：含汞烃的热裂解
公开(公告)号：US5107060A
公开(公告)日：1992-04-21
申请号：US599200
申请日：1990-10-17
申请人： Tsoung Y. Yan
发明人： Tsoung Y. Yan
IPC分类号： C10G55/04
CPC分类号： C10G55/04
摘要： A method is provided for high temperature conversion of mercutry-containing hydrocarbon feedstocks to produce a product stream with a negligible mercury level and to protect cryogenic heat exchangers from mercury damage. The feed is treated with adsorbent at high temperatures to remove up to 99% of the mercury. After high temperature conversion, the product stream is treated over a second adsorbent composition to remove any residual mercury and water before the product is cooled and collected.
摘要翻译：提供了一种用于高含量含烃烃原料的高温转化以产生具有可忽略的汞含量的产物流并保护低温热交换器免受汞损害的方法。饲料在高温下用吸附剂处理，以除去高达99％的汞。在高温转化后，在冷却和收集产品之前，通过第二吸附剂组合物处理产物流以除去任何残留的汞和水。

4. 发明授权

US5106799A Fluidized bed combustion process 失效
标题翻译：流化床燃烧过程
公开(公告)号：US5106799A
公开(公告)日：1992-04-21
申请号：US646911
申请日：1991-01-28
申请人： Gary J. Green , Tsoung Y. Yan
发明人： Gary J. Green , Tsoung Y. Yan
IPC分类号： B01J8/28 , B01J38/30 , C10G11/18 , F23C10/00
CPC分类号： F23C10/002 , B01J38/30 , B01J8/28 , C10G11/182
摘要： A process and apparatus for fluidized bed combustion using a dense phase combustion zone over a dilute phase combustion zone. When used to regenerate FCC catalyst containing coke with relatively large amounts of NO.sub.x precursors, the catalyst is added to and partially regenerated in the dense phase zone and then falls down into the dilute phase zone. Most of the combustion air is added to the dilute phase and rises into and fluidizes the dense phase zone. NO.sub.x formed in the dilute phase is reduced to N.sub.2 in the dense phase.
摘要翻译：一种用于在稀相燃烧区上使用密相燃烧区的流化床燃烧的方法和装置。当用于再生具有相当大量的NOx前体的含有FCC的FCC催化剂时，将催化剂加入并在密相区域中部分再生，然后落入稀相区。大部分燃烧空气被加入到稀相中并且上升并使稠相区流化。在稀相中形成的NOx在密相中降低到N2。

5. 发明授权

US5096673A Natural gas treating system including mercury trap 失效
标题翻译：包括汞捕集器在内的天然气处理系统
公开(公告)号：US5096673A
公开(公告)日：1992-03-17
申请号：US559877
申请日：1990-07-27
申请人： Douglas J. Gammie , Tsoung Y. Yan
发明人： Douglas J. Gammie , Tsoung Y. Yan
IPC分类号： B01D8/00 , C10L3/10 , F25J1/02
CPC分类号： F25J1/0022 , B01D8/00 , C10L3/10 , F25J2205/02 , F25J2220/60 , F25J2220/64 , F25J2290/42 , F25J2290/44
摘要： A system for mechanically removing mercury from natural gas is provided. A mercury trap is positioned at substantially the coldest point in the system before a main heat exchanger. The trap includes a bend in the natural gas flow path, baffles, a demister and/or a perforated cylinder for changing the direction of the flow path and causing mercury to be deposited therein.
摘要翻译：提供了一种从天然气中机械去除汞的系统。在主热交换器之前，汞阱位于系统中的最冷点处。捕集器包括天然气流路中的弯曲部，挡板，除雾器和/或穿孔圆筒，用于改变流路的方向并使汞沉积在其中。

6. 发明授权

US5053209A Removal of mercury from natural gas and liquid hydrocarbons utilizing silver on alumina adsorbent 失效
标题翻译：使用氧化铝吸附剂上的银，从天然气和液体烃中去除汞
公开(公告)号：US5053209A
公开(公告)日：1991-10-01
申请号：US332149
申请日：1989-04-03
申请人： Tsoung Y. Yan
发明人： Tsoung Y. Yan
IPC分类号： C07C7/00 , C10G25/00 , C10G53/08 , C10L3/10
CPC分类号： C10G25/003 , C07C7/00 , C10G53/08 , C10L3/10
摘要： Hydrocarbon liquids and gas, particularly gas to be processed in LNG plants, is treated to remove mercury by contacting it with free silver preferably on an activated carbon or gamma alumina support. The mercury amalgamates onto the metal. The gas can previously have been treated by contact with free sulfur to remove mercury.
摘要翻译：碳氢化合物液体和气体，特别是在LNG装置中处理的气体，通过与游离的银接触，优选在活性炭或γ氧化铝载体上进行处理以除去汞。汞合并到金属上。气体可以预先通过与游离硫接触来去除汞。

7. 发明授权

US4991521A Fluidized bed combustion process and apparatus 失效
标题翻译：流化床燃烧过程和装置
公开(公告)号：US4991521A
公开(公告)日：1991-02-12
申请号：US180755
申请日：1988-04-12
申请人： Gary J. Green , Tsoung Y. Yan
发明人： Gary J. Green , Tsoung Y. Yan
IPC分类号： B01J8/28 , F23C10/00
CPC分类号： F23C10/002 , B01J8/28
摘要： A process and apparatus for fluidized bed combustion using a dense phase combustion zone over a dilute phase combustion zone. When used to regenerate FCC catalyst containing coke with relatively large amounts of NO.sub.x precursors, the catalyst is added to and partially regenerated in the dense phase zone and then falls down into the dilute phase zone. Most of the combustion air is added to the dilute phase and rises into and fluidizes the dense phase zone. NO.sub.x formed in the dilute phase is reduced to N.sub.2 in the dense phase.
摘要翻译：一种用于在稀相燃烧区上使用密相燃烧区的流化床燃烧的方法和装置。当用于再生具有相当大量的NOx前体的含有FCC的FCC催化剂时，将催化剂加入并在密相区域中部分再生，然后落入稀相区。大部分燃烧空气被加入到稀相中并且上升并使稠相区流化。在稀相中形成的NOx在密相中降低到N2。

8. 发明授权

US4982050A Natural gas treating system including mercury trap 失效
标题翻译：包括汞捕集器在内的天然气处理系统
公开(公告)号：US4982050A
公开(公告)日：1991-01-01
申请号：US224595
申请日：1988-07-25
申请人： Douglas J. Gammie , Tsoung Y. Yan
发明人： Douglas J. Gammie , Tsoung Y. Yan
IPC分类号： B01D8/00 , C10L3/10
CPC分类号： B01D8/00 , C10L3/10 , B01D2257/602 , B01D53/64 , Y10S55/15
摘要： A method and system for mechanically removing mercury from natural gas are provided. A mercury trap is positioned at substantially the coldest point in the system before a main heat exhanger. The trap includes a bend in the natural gas flow path, baffles, a demister and/or a perforated cylinder for changing the direction of the flow path and causing mercury to be deposited therein.
摘要翻译：提供了一种从天然气中机械去除汞的方法和系统。在主换热器之前，汞阱位于系统中的最冷点处。捕集器包括天然气流路中的弯曲部，挡板，除雾器和/或穿孔圆筒，用于改变流路的方向并使汞沉积在其中。

9. 发明授权

US4980052A Catalytic cracking of hydrocarbons 失效
标题翻译：碳氢化合物的催化裂化
公开(公告)号：US4980052A
公开(公告)日：1990-12-25
申请号：US433407
申请日：1989-11-03
申请人： Gary J. Green , David S. Shihabi , Tsoung Y. Yan
发明人： Gary J. Green , David S. Shihabi , Tsoung Y. Yan
IPC分类号： B01J29/072 , B01J37/04 , C10G11/05 , C10G11/18
CPC分类号： C10G11/05 , B01J29/072 , B01J37/04 , C10G11/18
摘要： Emission of noxious nitrogen oxides with the flue gas from the regenerator of a fluid catalytic cracking plant are reduced by incorporating into the circulating inventory of cracking catalyst separate additive particles that contain a copper-loaded zeolite. A particularly effective additive is provided by ion-exchanging ZSM-5 zeolite with cupric ion. With such preferred additive, CO emissions also are reduced, and the recovered gasoline has enhanced octane number.
摘要翻译：通过将含有负载铜的沸石的裂化催化剂分离的添加剂颗粒结合到循环库存中，减少了来自流化催化裂化装置的再生器的烟道气的有害氮氧化物的排放。通过离子交换ZSM-5沸石与铜离子提供特别有效的添加剂。使用这种优选的添加剂，CO排放也减少，回收的汽油具有增强的辛烷值。

10. 发明授权

US4980050A Catalytic cracking process with partial CO combustion 失效
标题翻译：催化裂化过程与部分CO燃烧
公开(公告)号：US4980050A
公开(公告)日：1990-12-25
申请号：US206241
申请日：1988-06-10
申请人： Billy K. Huh , Tsoung Y. Yan
发明人： Billy K. Huh , Tsoung Y. Yan
IPC分类号： C10G11/05 , C10G11/18
CPC分类号： C10G11/05 , C10G11/18
摘要： A catalytic cracking process for converting heavy, metals laden feed to lighter products is disclosed. The catalyst regenerator is operated under relatively reducing conditions, to produce a flue gas containing at least 1 mole % carbon monoxide. An additive, preferably alumina, is added to the circulating catalyst inventory to selectively sorb metal contaminants in the feed. The reducing conditions in the catalyst regenerator minimize formation of highly oxidized forms of vanadium, permitting higher vanadium levels to be tolerated on the cracking catalyst. The additive material has a greater affinity for vanadium than the cracking catalyst, and absorbs a disproportionate amount of metals in the feed. Preferably a soft, friable, alumina additive is used which results in the production of alumina fines rich in vanadium, which are discharged from the unit with catalyst fines. The process works especially well in fluidized catalytic cracking processes, with removal of vanadium laden alumina fines from the FCC regenerator with the regenerator flue gas.
摘要翻译：公开了一种将重金属负载物转化为轻质产品的催化裂化方法。催化剂再生器在相对减少的条件下运行，以产生含有至少1摩尔％一氧化碳的烟道气。将添加剂，优选氧化铝加入到循环催化剂库存中，以选择性地吸附进料中的金属污染物。催化剂再生器中的还原条件最小化高度氧化形式的钒的形成，允许在裂化催化剂上耐受更高的钒水平。添加剂材料对钒的亲和力高于裂化催化剂，并且吸收进料中不成比例的金属。优选地，使用柔软的，易碎的氧化铝添加剂，其导致富含钒的氧化铝细粉的生产，其从催化剂细粉中排出。该方法在流化催化裂化过程中特别好，通过再生器烟气从FCC再生器中除去含钒的氧化铝细粉。

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