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    • 5. 发明申请
    • Solvating component and solvent system for mesophase pitch
    • 溶剂组分和溶剂体系用于中间相沥青
    • US20020011427A1
    • 2002-01-31
    • US09873754
    • 2001-06-04
    • H. Ernest RomineJohn A. RodgersW. Mark SouthardEdward J. Nanni
    • C10C003/08C08L095/00
    • D01F9/145C10C3/00C10C3/08C10G2400/30
    • A solvating component for a solvated mesophase pitch. The solvated component includes a mixture of aromatic hydrocarbons having boiling points in the atmospheric equivalent boiling point range of about 285null to about 460null C. (about 550null F.-932null F.). At least 80% of the carbon atoms of the hydrocarbons are aromatic as characterized by carbon 13 NMR. The aromatic hydrocarbons are selected from a group consisting of aromatic compounds having 2 to 5 aromatic rings, substituted aromatic compounds having 2 to 5 aromatic rings wherein said substituents are alkyl groups having 1 to 3 carbons, hydroaromatic compounds having 2 to 5 rings, substituted aromatic compounds having 2 to 5 rings wherein said substituents are alkyl groups having 1 to 3 carbons, and mixtures thereof.
    • 溶剂化中间相沥青的溶剂组分。 溶剂化组分包括沸点在约285℃至约460℃(约550°F-932°F)的大气当量沸点范围内的芳族烃的混合物。 烃的至少80%的碳原子是芳族的,由碳13 NMR表征。 芳烃选自具有2-5个芳环的芳族化合物,具有2至5个芳环的取代芳族化合物,其中所述取代基是具有1至3个碳原子的烷基,具有2至5个环的芳族化合物,取代的芳族 具有2至5个环的化合物,其中所述取代基是具有1至3个碳原子的烷基,以及它们的混合物。
    • 7. 发明授权
    • Process for the production of mesophase
    • 中间相生产工艺
    • US4892642A
    • 1990-01-09
    • US298536
    • 1989-01-17
    • Hugh E. RomineTa-Wei Fu
    • Hugh E. RomineTa-Wei Fu
    • C10C3/00C10C3/04C10C3/08C10C3/10D01F9/145
    • C10C3/08C10C3/002C10C3/04
    • An improved process for producing an anisotropic pitch product suitable for carbon fiber manufacture. A carbonaceous feedstock substantially free of mesophase pitch is heated at elevated temperature while passing an oxidatively reactive sparging gas such as air through the feedstock. The oxidatively treated feedstock, which contains isotropic pitch, is solvent fractionated to recover a solid pitch which on fusion becomes an anisotropic pitch product having from 50 to 100 percent by volume mesophase. In one aspect of the invention the carbonaceous feedstock is oxidatively treated in a melt phase at a lower temperature and the resulting isotropic pitch is then heated at a higher temperature in a melt phase in the presence or absence of a non-oxidative sparging gas prior to solvent fractionation.
    • 一种用于生产适用于碳纤维制造的各向异性沥青产品的改进方法。 基本上不含中间相沥青的碳质原料在升高的温度下加热,同时使氧化反应性的鼓泡气体如空气通过原料。 包含各向同性沥青的经氧化处理的原料被溶剂分馏以回收固体沥青,其在熔化时成为具有50至100体积%中间相的各向异性沥青产物。 在本发明的一个方面,碳质原料在较低温度下在熔融相中进行氧化处理,然后在存在或不存在非氧化性鼓泡气体的情况下,在熔融相中将所得各向同性沥青加热, 溶剂分馏。