专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5942456A Multi-functional catalytic distillation structure 失效
标题翻译：多功能催化蒸馏结构
公开(公告)号：US5942456A
公开(公告)日：1999-08-24
申请号：US762323
申请日：1996-12-09
申请人： Clifford S. Crossland , John R. Adams
发明人： Clifford S. Crossland , John R. Adams
IPC分类号： B01D3/00 , B01J8/00 , B01J8/02 , B01J8/06 , B01J19/32 , B01J35/02 , B01J35/04 , B01J33/02
CPC分类号： B01J8/02 , B01D3/009 , B01J19/32 , B01J35/02 , B01J35/04 , B01J8/008 , B01J8/06 , B01J2208/0069 , B01J2208/00814 , B01J2219/32279 , B01J2219/32282 , B01J2219/32466
摘要： A catalytic distillation structure containing (1) a solid catalytic material comprising a catalyst component and (2) a structure. The total volume of open space for the catalytic distillation structure should be at least 10 volume % and preferably at least 20 volume % up to about 65 volume %. The catalytic material may be a mixture of two or more catalysts or the individual catalyst may occupy separate and distinct areas of the structure without physical mixing of the catalysts. The structural element may contain substantially rigid elements and porous containers which contain the catalytic material. The structural element may be comprised of the porous containers. Other catalytic distillation structures may comprises the porous containers for the catalysts and a resilient material such as demister wire.
摘要翻译：一种催化蒸馏结构，其包含（1）包含催化剂组分的固体催化材料和（2）结构。催化蒸馏结构的开放空间的总体积应为至少10体积％，优选至少20体积％至多约65体积％。催化材料可以是两种或更多种催化剂的混合物，或者单独的催化剂可以占据该结构的单独且不同的区域，而不会使催化剂物理混合。结构元件可以包含基本上刚性的元件和含有催化材料的多孔容器。结构元件可以由多孔容器组成。其他催化蒸馏结构可以包括用于催化剂的多孔容器和诸如除雾丝的弹性材料。

2. 发明授权

US5346676A Apparatus of alkylation using alkanes and olefins 失效
标题翻译：使用烷烃和烯烃进行烷基化的设备
公开(公告)号：US5346676A
公开(公告)日：1994-09-13
申请号：US82517
申请日：1993-06-25
申请人： Clifford S. Crossland , Alan Johnson , John Woods , Elliot G. Pitt
发明人： Clifford S. Crossland , Alan Johnson , John Woods , Elliot G. Pitt
IPC分类号： C07C2/08 , B01J8/22 , B01J27/12 , C07B61/00 , C07C2/58 , C07C2/60 , C07C2/62 , C07C9/16 , B01J8/08
CPC分类号： C07C2/60 , B01J27/12 , B01J8/228 , C07C2/58 , C07C2521/08 , C07C2527/133
摘要： Paraffin alkylation using solid, particulate catalyst is carried out by preparing an alkane-catalyst mixture in a wash zone, passing the alkane-catalyst mixture to a plug flow reactor where a minor amount of olefin is introduced to contact the alkane-catalyst mixture and react to form alkylate and the alkane-catalyst-alkylate mixture is passed through the reactor with a minimum of back mixing to restrict the reaction of alkylate with olefin, thus substantially preventing polymerization. The alkane-catalyst-alkylate mixture, substantially free of olefin is passed to a disengaging zone where the liquid is removed and the solid particulate catalyst is recovered and returned to the wash zone for recycle. The alkane is present in the reactor in sufficient molar excess to react substantially all of the olefin. Any unreacted isoalkane is recycled to the reactor with make-up isoalkane added to maintain the molar excess. The preferred catalyst is an acid washed silica treated with antimony pentafluoride and more preferably treated with alkane at low temperature, e.g. -30.degree. to -160.degree. C.
摘要翻译：使用固体颗粒催化剂的石蜡烷基化通过在洗涤区中制备烷烃 - 催化剂混合物进行，将烷烃 - 催化剂混合物通过活塞流反应器，其中引入少量的烯烃以接触烷烃 - 催化剂混合物并反应以形成烷基化物，烷烃 - 催化剂 - 烷基化物混合物以最少的反混合通过反应器以限制烷基化物与烯烃的反应，从而基本上防止聚合。基本上不含烯烃的烷烃 - 催化剂 - 烷基化物混合物被传送到去除液体的脱离区域，并且将固体颗粒催化剂回收并返回到洗涤区域进行再循环。烷烃以足够的摩尔过量存在于反应器中以使基本上所有的烯烃反应。任何未反应的异烷烃被再循环到反应器中，加入补充的异烷烃以保持摩尔过量。优选的催化剂是用五氟化锑处理的酸洗二氧化硅，更优选在低温下用烷烃处理，例如， -30℃至-160℃

3. 发明授权

US06659434B1 Collapsible sparger 失效
标题翻译：可折叠式喷雾器
公开(公告)号：US06659434B1
公开(公告)日：2003-12-09
申请号：US10044617
申请日：2002-01-11
申请人： Ralph E. Casas , Henry J. Semerak , Rodney D. Chevalier , Willibrord A. Groten , Clifford S. Crossland
发明人： Ralph E. Casas , Henry J. Semerak , Rodney D. Chevalier , Willibrord A. Groten , Clifford S. Crossland
IPC分类号： B01F304
CPC分类号： B01D47/16 , Y10T29/49716
摘要： A collapsible sparger for insertion into a vessel through a flanged opening is disclosed having a central tubular conduit having a plurality of rotatable members along its length. The rotatable members may be rotated and secured into position after insertion.
摘要翻译：公开了一种用于通过法兰开口插入容器的可折叠式分布器，其具有沿着其长度具有多个可旋转构件的中心管状导管。可旋转构件可以在插入之后旋转并固定到位。

4. 发明授权

US5043506A Process for the alkylation of organic aromtic compounds in the presence of inert aliphatic compounds 失效
标题翻译：在惰性脂族化合物存在下烷基化有机芳族化合物的方法
公开(公告)号：US5043506A
公开(公告)日：1991-08-27
申请号：US583161
申请日：1990-09-17
申请人： Clifford S. Crossland
发明人： Clifford S. Crossland
IPC分类号： B01D3/00 , C07C15/073 , C07C15/085
CPC分类号： C07C15/073 , B01D3/009 , C07C15/085 , Y02P20/127 , Y10S203/06
摘要： An improvement in the operation to a catalytic distillation process for the alkylation of organic aromatic compounds with an olefin contained wherein aliphatic compounds are contained in either the olefin feed stream, the aromatic feed stream or both is disclosed. Aliphatic compounds are added to the upper portion of a secondary distillation column reactor wherein aromatic is being reacted with unreacted olefin from a primary distillation column reactor to polish the conversion of olefin. The additional aliphatic compound produces an equilibrium in the secondary column wherein unreacted aromatic and alkylation product are recovered as bottoms which may be recycled to the primary distillation column reactor.
摘要翻译：公开了对烯烃进料流，芳烃进料流或二者中含有脂族化合物的烯烃烷基化有机芳族化合物的催化蒸馏方法的改进。将脂族化合物加入到二级蒸馏塔反应器的上部，其中芳族化合物与来自一级蒸馏塔反应器的未反应的烯烃反应，以研磨烯烃的转化率。另外的脂肪族化合物在第二塔中产生平衡，其中将未反应的芳族和烷基化产物作为塔底产物回收，其可以再循环到一次蒸馏塔反应器中。

5. 发明授权

US5837130A Catalytic distillation refining 失效
标题翻译：催化精馏
公开(公告)号：US5837130A
公开(公告)日：1998-11-17
申请号：US735234
申请日：1996-10-22
申请人： Clifford S. Crossland
发明人： Clifford S. Crossland
IPC分类号： C10G65/00 , C10G65/16 , C10G25/00
CPC分类号： C10G65/16 , C10G65/00 , C10G2300/4087
摘要： A process for hydrotreating petroleum fractions early in the refining process by employing catalyst prepared as components of distillation structures or as contained beds of catalyst in atmospheric distillation columns and or side draw columns. For example, a crude petroleum is hydrotreated by taking side streams from an atmospheric distillation column and the vacuum gas oil from a vacuum distillation column which are individually fed to separate desulfurizations, preferably in distillation column reactors containing a hydrodesulfurization catalyst. The overheads from each of the distillation column reactors is returned to the atmospheric column and the bottoms from each distillation column reactor is withdrawn as hydrotreated product. The process may also be used for upgrading the effluent from a fluid catalytic cracking unit, preferably operated as a catalytic distillation reactor.
摘要翻译：一种在精炼过程早期加氢处理石油馏分的方法，其中采用制备为蒸馏结构的组分的催化剂或作为常压蒸馏塔和/或侧馏分塔中的催化剂床。例如，通过将来自常压蒸馏塔的侧流和来自真空蒸馏塔的减压瓦斯油，分别进料到单独的脱硫，优选在含有加氢脱硫催化剂的蒸馏塔反应器中，将粗油加氢处理。将每个蒸馏塔反应器的塔顶馏出物返回至大气柱，并将来自每个蒸馏塔反应器的塔底物作为加氢处理产物取出。该方法还可用于将来自流化催化裂化装置的流出物升级，优选作为催化蒸馏反应器操作。

6. 发明授权

US5431890A Catalytic distillation structure 失效
标题翻译：催化蒸馏结构
公开(公告)号：US5431890A
公开(公告)日：1995-07-11
申请号：US188803
申请日：1994-01-31
申请人： Clifford S. Crossland , Gary R. Gildert , Dennis Hearn
发明人： Clifford S. Crossland , Gary R. Gildert , Dennis Hearn
IPC分类号： B01D3/16 , B01D3/00 , B01J8/00 , B01J8/02 , B01J19/30 , B01J19/32 , B01J35/02 , B01J35/04 , B01J35/06 , B01J8/06
CPC分类号： B01J35/02 , B01D3/009 , B01J19/32 , B01J35/04 , B01J35/06 , B01J8/008 , B01J2208/0069 , B01J2219/32279 , B01J2219/32408 , B01J2219/32466 , Y10S203/06
摘要： A bale shaped catalytic distillation structure formed by placing multiple link or continuous tube shaped structures on top of a wire mesh screen, such as demister wire, arrayed at an angle to the longitudinal axis of the bale, such that when the wire mesh screen is rolled up, the rolled structure provides a catalytic distillation structure. The tube comprises flexible, semi-rigid open mesh tubular element filled with a particulate catalytic material, the tube shaped structure having a fastener every 1-12 inches in length to form a multiple link.
摘要翻译：一种捆包形催化蒸馏结构，其通过将多个连接或连续的管状结构放置在与捆包的纵向轴线成一定角度排列的丝网筛（例如除雾丝）的顶部上，使得当丝网筛被轧制时轧制结构提供催化蒸馏结构。该管包括填充有颗粒催化材料的柔性半刚性开式网状管状元件，该管状结构具有每1-12英寸长的紧固件以形成多个连接。

7. 发明授权

US5190904A Paraffin alkylation catalyst 失效
标题翻译：石蜡烷基化催化剂
公开(公告)号：US5190904A
公开(公告)日：1993-03-02
申请号：US791106
申请日：1991-11-12
申请人： Clifford S. Crossland , Alan Johnson , John Woods , Elliot G. Pitt
发明人： Clifford S. Crossland , Alan Johnson , John Woods , Elliot G. Pitt
IPC分类号： B01J8/22 , B01J27/12 , C07C2/58 , C07C2/60
CPC分类号： C07C2/60 , B01J27/12 , B01J8/228 , C07C2/58 , C07C2521/08 , C07C2527/133
摘要： Paraffin alkylation using solid, particulate catalyst is carried out by preparing an alkane-catalyst mixture in a wash zone, passing the alkane-catalyst mixture to a plug flow reactor where a minor amount of olefin is introduced to contact the alkane-catalyst mixture and react to form alkylate and the alkane-catalyst-alkylate mixture is passed through the reactor with a minimum of back mixing to restrict the reaction of alkylate with olefin, thus substantially preventing polymerization. The alkane-catalyst-alkylate mixture, substantially free of olefin is passed to a disengaging zone where the liquid is removed and the solid particulate catalyst is recovered and returned to the wash zone for recycle. The alkane is present in the reactor in sufficient molar excess to react substantially all of the olefin. Any unreacted isoalkane is recycled to the reactor with make-up isoalkane added to maintain the molar excess. The preferred catalyst is an acid washed silica treated with antimony pentafluoride and more preferably treated with alkane at low temperature, e.g. -30.degree. to -160.degree. C.
摘要翻译：使用固体颗粒催化剂的石蜡烷基化通过在洗涤区中制备烷烃 - 催化剂混合物来进行，将烷烃 - 催化剂混合物通过活塞流反应器，其中引入少量烯烃与烷烃 - 催化剂混合物接触并反应以形成烷基化物，烷烃 - 催化剂 - 烷基化物混合物以最少的反混合通过反应器以限制烷基化物与烯烃的反应，从而基本上防止聚合。基本上不含烯烃的烷烃 - 催化剂 - 烷基化物混合物被传送到去除液体的脱离区域，并且将固体颗粒催化剂回收并返回到洗涤区域进行再循环。烷烃以足够的摩尔过量存在于反应器中以使基本上所有的烯烃反应。任何未反应的异烷烃被再循环到反应器中，加入补充的异烷烃以保持摩尔过量。优选的催化剂是用五氟化锑处理的酸洗二氧化硅，更优选在低温下用烷烃处理，例如， -30℃至-160℃

8. 发明授权

US06583325B1 Process for the production of tertiary alkyl ethers 失效
标题翻译：生产叔烷基醚的方法
公开(公告)号：US06583325B1
公开(公告)日：2003-06-24
申请号：US10087371
申请日：2002-03-01
申请人： Lawrence A. Smith, Jr. , Hugh M. Putman , Henry J. Semerak , Clifford S. Crossland
发明人： Lawrence A. Smith, Jr. , Hugh M. Putman , Henry J. Semerak , Clifford S. Crossland
IPC分类号： C07C4100
CPC分类号： B01D3/009 , B01D3/146 , C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/046
摘要： A process for the production of tertiary ethers from the reaction of isoolefins with lower alcohols, such as methanol, uses two distillation column reactors in series to maximize conversion, especially for isopentenes and isohexenes. The second distillation column reactor may be concurrently used as a C5 polishing reactor and a reactor for producing MTBE or ETBE from isobutene, for example.
摘要翻译：从异烯烃与低级醇如甲醇的反应生产叔醚的方法使用两个串联的蒸馏塔反应器，以使转化率最大化，特别是对于异戊烯和异己烯。第二蒸馏塔反应器可以同时用作C5抛光反应器和用于从异丁烯生产MTBE或ETBE的反应器。

9. 发明授权

US5730843A Catalytic distillation structure 失效
标题翻译：催化蒸馏结构
公开(公告)号：US5730843A
公开(公告)日：1998-03-24
申请号：US580822
申请日：1995-12-29
申请人： Willibrord A. Groten , Derwyn Booker , Clifford S. Crossland
发明人： Willibrord A. Groten , Derwyn Booker , Clifford S. Crossland
IPC分类号： B01D3/14 , B01D3/00 , B01D3/26 , B01J8/02 , B01J19/32 , B01J35/02 , B01J35/06
CPC分类号： B01J35/06 , B01D3/009 , B01J19/32 , B01J35/02 , B01J8/02 , B01J2208/00814 , B01J2219/32279 , B01J2219/32296 , B01J2219/32408 , B01J2219/32425 , B01J2219/32466 , B01J2219/326
摘要： A contact structure, useful as a distillation structure, has a rigid frame made of two substantially vertical duplicate grids spaced apart and held rigid by a plurality of substantially horizontal rigid members and a plurality of substantially horizontal wire mesh tubes mounted to the grids to form a plurality of fluid pathways among the tubes. For use as a catalytic distillation structure, which serves as both the distillation structure and the catalyst, at least a portion of the wire mesh tubes contain a particulate catalytic material. The catalyst within the tubes provides a reaction zone where catalytic reactions may occur and the wire mesh provides mass transfer surfaces to effect a fractional distillation. The spacing elements provide for a variation of the catalyst density and loading and structural integrity.
摘要翻译：用作蒸馏结构的接触结构具有刚性框架，该刚性框架由两个基本上垂直的重叠格栅构成，该两个栅格由多个基本上水平的刚性构件间隔开并保持刚性，并且多个基本上水平的丝网管安装到栅格以形成管中的多个流体通路。为了用作催化蒸馏结构，其用作蒸馏结构和催化剂，至少一部分丝网管含有颗粒催化材料。管内的催化剂提供了可能发生催化反应的反应区，并且丝网提供传质表面以进行分馏。间隔元件提供催化剂密度和负载和结构完整性的变化。

10. 发明授权

US5157196A Paraffin alkylation process 失效
标题翻译： PARAFFIN烷基化方法
公开(公告)号：US5157196A
公开(公告)日：1992-10-20
申请号：US632478
申请日：1990-12-24
申请人： Clifford S. Crossland , Alan Johnson , John Woods , Elliot G. Pitt
发明人： Clifford S. Crossland , Alan Johnson , John Woods , Elliot G. Pitt
IPC分类号： C07C2/08 , B01J8/22 , B01J27/12 , C07B61/00 , C07C2/58 , C07C2/60 , C07C2/62 , C07C9/16
CPC分类号： C07C2/60 , B01J27/12 , B01J8/228 , C07C2/58 , C07C2521/08 , C07C2527/133
摘要： Paraffin alkylation using solid, particulate catalyst is carried out by preparing an alkane-catalyst mixture in a wash zone, passing the alkane-catalyst mixture to a plug flow reactor where a minor amount of olefin is introduced to contact the alkane-catalyst mixture and react to form alkylate and the alkane-catalyst-alkylate mixture is passed through the reactor with a minimum of back mixing to restrict the reaction of alkylate with olefin, thus substantially preventing polymerization. The alkane-catalyst-alkylate mixture, substantially free of olefin is passed to a disengaging zone where the liquid is removed and the solid particulate catalyst is recovered and returned to the wash zone for recycle. The alkane is present in the reactor in sufficient molar excess to react substantially all of the olefin. Any unreacted isoalkane is recycled to the reactor with make-up isoalkane added to maintain the molar excess. The preferred catalyst is an acid washed silica treated with antimony pentafluoride and more preferably treated with alkane at low temperature, e.g. -30.degree. to -160.degree. C.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式