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1. 发明授权

US5894076A Process for alkylation of benzene 失效
标题翻译：苯的烷基化方法
公开(公告)号：US5894076A
公开(公告)日：1999-04-13
申请号：US854731
申请日：1997-05-12
申请人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
发明人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
IPC分类号： B01D3/34 , B01D3/00 , C07C2/64 , C07C15/02 , C07C15/073 , C07C15/085 , C10G29/20 , C10G35/04 , C10G45/32 , C10G49/00 , C10G65/04 , C10G69/08 , C10G69/12 , C07C5/02 , C07C2/66 , C07C7/163 , C10G45/00
CPC分类号： C10G69/123 , B01D3/009 , C10G29/205 , C10G49/002 , C10G2400/02 , C10G2400/30 , Y10S203/06
摘要： A process for the alkylation of benzene contained in a mixed refinery stream is disclosed wherein the refinery stream is first subjected to hydrogenation of higher olefins prior to alkylation of the benzene with selected types and quantities of lower olefins. Streams containing sulfur compounds may be pretreated by hydrodesulfurization. All of the process steps are advantageously carried out in distillation column reactors to take advantage of that mode of operation.
摘要翻译：公开了一种在混合炼油厂物流中烷基化苯的方法，其中在选择类型和数量的低级烯烃的苯的烷基化之前，首先对炼油厂物流进行高级烯烃的氢化。含有硫化合物的流可以通过加氢脱硫进行预处理。所有的方法步骤有利地在蒸馏塔反应器中进行，以利用这种操作模式。

2. 发明授权

US5856602A Selective hydrogenation of aromatics contained in hydrocarbon streams 失效
标题翻译：碳氢化合物流中芳烃选择性加氢
公开(公告)号：US5856602A
公开(公告)日：1999-01-05
申请号：US711101
申请日：1996-09-09
申请人： Gary R. Gildert , Hugh M. Putman , Dennis Hearn
发明人： Gary R. Gildert , Hugh M. Putman , Dennis Hearn
IPC分类号： C07C5/10 , C07B61/00 , C07C7/04 , C07C13/18 , C10G45/44
CPC分类号： C10G45/44 , Y02P20/127 , Y10S203/06
摘要： A process for the hydrogenation of a selected aromatic, such as benzene contained in a naphtha stream to cyclohexane wherein the distillation column reactor is operated such that the portion of the naphtha containing the benzene is maintained in the catalyst bed such that essentially only benzene is hydrogenated. The reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed.
摘要翻译：将选择的芳族化合物（例如包含在石脑油中的苯）氢化成环己烷的方法，其中操作蒸馏塔反应器，使得含有苯的部分石脑油保持在催化剂床中，使得基本上仅苯被氢化。反应器在压力下操作，其中反应混合物在0至350psig下在约0.1psi至小于70psia的低氢分压下沸腾。提供催化剂作为催化蒸馏结构，使得反应同时进行蒸馏。塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。

3. 发明授权

US5792891A Integrated process for the production of tame 失效
标题翻译：整合生产温驯的过程
公开(公告)号：US5792891A
公开(公告)日：1998-08-11
申请号：US792980
申请日：1997-02-03
申请人： John R. Adams , Lawrence A. Smith, Jr. , Dennis Hearn , Edward M. Jones, Jr. , Robert P. Arganbright
发明人： John R. Adams , Lawrence A. Smith, Jr. , Dennis Hearn , Edward M. Jones, Jr. , Robert P. Arganbright
IPC分类号： B01D3/00 , B01D3/14 , C07C41/06 , C07C41/42
CPC分类号： C07C41/06 , B01D3/009 , B01D3/146 , C07C41/42 , Y02P20/125 , Y02P20/127
摘要： An alkene skeletal isomerization process is employed in an integrated process for the production of tertiary ether, e.g., tertiary amyl methyl ether (TAME) from the reaction of isoamylenes (iC.sub.5.sup.= 's) with methanol in the presence of an acid cation exchange resin. A light naphtha from a fluid catalytic cracking unit is used as the source of the iC.sub.5.sup.= 's in a process which separates the C.sub.5 containing fraction from the light naphtha, selectively hydrogenates the di-olefins contained in the C.sub.5 containing fraction, reacts the iC.sub.5.sup.= 's contained in the C.sub.5 containing fraction with methanol to form TAME, separates the TAME from the unreacted materials as a product, separates methanol from the unreacted materials, isomerizes a portion of the nC.sub.5.sup.= 's to iC.sub.5.sup.= 's , for example using a zeolite or an alumina treated with methanol, and use of the isomerization product as feed for a TAME reactor.
摘要翻译：烯烃骨架异构化方法用于在酸性阳离子交换树脂存在下，从异戊烯（iC5 = s）与甲醇的反应生产叔醚如叔戊基甲基醚（TAME）的一体化方法中。在将含C5馏分与轻石脑油分离的方法中，使用来自流化催化裂化装置的轻石脑油作为iC5 =的来源，选择性地氢化含C5馏分中所含的二烯烃，使iC5 包含在含甲醇的馏分中形成TAME，将TAME与未反应的物质作为产物分离，从未反应的物质中分离出甲醇，将nC5 =的一部分异构化为iC5 =，例如使用沸石或用甲醇处理的氧化铝，并使用异构化产物作为TAME反应器的进料。

4. 发明授权

US5629451A Reduction of nitrile contaminants by selective hydrogenation 失效
标题翻译：通过选择性氢化还原腈污染物
公开(公告)号：US5629451A
公开(公告)日：1997-05-13
申请号：US268811
申请日：1994-06-30
申请人： Dennis Hearn , Kyte H. Terhune
发明人： Dennis Hearn , Kyte H. Terhune
IPC分类号： C07C253/34 , C07C209/48
CPC分类号： C07C253/34
摘要： A process for selectively reducing nitrile contaminants in fluids such as water, methanol or hydrocarbon streams containing mono olefins and which contain minor amounts of contaminants comprising nitriles in the presence of hydrogen and a supported cobalt catalyst. In the olefin stream the nitrile contaminants are substantially reduced without substantial reduction of the mono olefins.
摘要翻译：选择性地还原流体中的腈污染物的方法，例如含有单烯烃的水，甲醇或烃流，并且在氢气和负载的钴催化剂的存在下含有少量的含有腈的污染物。在烯烃流中，腈污染物基本上减少，而单烯烃基本上不减少。

5. 发明授权

US4950834A Alkylation of organic aromatic compounds in a dual bed system 失效
标题翻译：有机芳族化合物在双床系统中的烷基化
公开(公告)号：US4950834A
公开(公告)日：1990-08-21
申请号：US385443
申请日：1989-07-26
申请人： Robert P. Arganbright , Dennis Hearn
发明人： Robert P. Arganbright , Dennis Hearn
IPC分类号： B01J29/08 , B01D3/00 , C07B61/00 , C07C2/66 , C07C7/04 , C07C15/085
CPC分类号： C07C15/085 , B01D3/009 , C07C2/66 , C07C2529/08 , C07C2529/70 , Y02P20/127 , Y02P20/52
摘要： Cumene is produced in a catalytic distillation column reactor having an upper bed of Omega type molecular sieve catalyst and a lower bed of Y type molecular sieve catalyst. Benzene and propylene are reacted in the upper bed where the Omega type sieve is more selective to cumene that the Y type sieve. Part of the reaction mixture flows down the column to the Y bed where benzene reacts with any unreacted propylene to produce cumene. Additionally, benzene reacts with dipropylbenzene in the Y bed to produce more cumene. Cumene is recovered as bottoms product and unreacted benzene recovered as overheads where it may be returned as reflux to the column to control the mole ratio of benzene to propylene.

6. 发明授权

US4447668A Process for producing high purity isoolefins and dimers thereof by dissociation of ethers 失效
标题翻译：通过醚解离生产高纯度异烯烃及其二聚体的方法
公开(公告)号：US4447668A
公开(公告)日：1984-05-08
申请号：US496983
申请日：1983-05-25
申请人： Lawrence A. Smith, Jr. , Edward M. Jones, Jr. , Dennis Hearn
发明人： Lawrence A. Smith, Jr. , Edward M. Jones, Jr. , Dennis Hearn
IPC分类号： C07C1/20 , C07C2/28 , C07C11/02 , C07C1/00
CPC分类号： C07C11/02 , C07C1/20 , C07C2/28 , C07C2531/08 , Y02P20/127
摘要： Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150.degree. to 250.degree. F. at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C.sub.3 to C.sub.6 and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom.
摘要翻译：烷基叔丁基醚或烷基叔戊基醚通过与阳离子酸性交换树脂在150至250°F的温度下以0.1至20的LHSV气相接触而解离，以产生由未反应的醚，异丁烯或异戊烯和对应于烷基的醇。在除去醇之后，可以分离乙醚/异烯烃流以获得高纯度异烯烃（99 +％），或者乙醚/异烯烃流可以与阳离子酸性交换树脂液相接触，以选择性地使异烯烃二聚高度放热反应，然后分馏二聚产物以产生高纯度二异氰酸酯（97 +％）。在烷基为C 3至C 6的情况下，并且在醚的解离时产生相应的醇，可以进行组合的解离 - 蒸馏，使得异烯烃为塔顶产物，醇为底部。

7. 发明授权

US06002058A Process for the alkylation of benzene 失效
标题翻译：苯烷基化方法
公开(公告)号：US06002058A
公开(公告)日：1999-12-14
申请号：US184171
申请日：1998-11-02
申请人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
发明人： Dennis Hearn , Robert P. Arganbright , Lawrence A. Smith, Jr. , John R. Adams
IPC分类号： B01D3/34 , B01D3/00 , C07C2/64 , C07C15/02 , C07C15/073 , C07C15/085 , C10G29/20 , C10G35/04 , C10G45/32 , C10G49/00 , C10G65/04 , C10G69/08 , C10G69/12 , C07C1/00 , C07C5/03 , C10G1/00 , C10G45/00
CPC分类号： C10G69/123 , B01D3/009 , C10G29/205 , C10G49/002 , C10G2400/02 , C10G2400/30 , Y10S203/06
摘要： A process for the alkylation of benzene contained in a mixed refinery stream is disclosed wherein the refinery stream is first subjected to hydrogenation of higher olefins prior to alkylation of the benzene with selected types and quantities of lower olefins. Streams containing sulfur compounds may be pretreated by hydrodesulfurization. All of the process steps are advantageously carried out in distillation column reactors to take advantage of that mode of operation.
摘要翻译：公开了一种在混合炼油厂物流中烷基化苯的方法，其中在选择类型和数量的低级烯烃的苯的烷基化之前，首先对炼油厂物流进行高级烯烃的氢化。含有硫化合物的流可以通过加氢脱硫进行预处理。所有的方法步骤有利地在蒸馏塔反应器中进行，以利用这种操作模式。

8. 发明授权

US5741930A Reduction of nitrite contaminants by selective hydrogenation 失效
标题翻译：通过选择性氢化还原亚硝酸盐污染物
公开(公告)号：US5741930A
公开(公告)日：1998-04-21
申请号：US796517
申请日：1997-04-28
申请人： Dennis Hearn , Kyte H. Terhune
发明人： Dennis Hearn , Kyte H. Terhune
IPC分类号： C07C253/34 , C07C209/48
CPC分类号： C07C253/34
摘要： A process for selectively reducing nitrile contaminants in fluids such as water, methanol or hydrocarbon streams containing mono olefins and which contain minor amounts of contaminants comprising nitriles in the presence of hydrogen and a supported cobalt catalyst. In the olefin stream the nitrile contaminants are substantially reduced without substantial reduction of the mono olefins.
摘要翻译：选择性地还原流体中的腈污染物的方法，例如含有单烯烃的水，甲醇或烃流，并且在氢气和负载的钴催化剂的存在下含有少量的含有腈的污染物。在烯烃流中，腈污染物基本上减少，而单烯烃基本上不减少。

9. 发明授权

US5595634A Process for selective hydrogenation of highly unsaturated compounds and isomerization of olefins in hydrocarbon streams 失效
标题翻译：高度不饱和化合物的选择性氢化和烃流中烯烃异构化的方法
公开(公告)号：US5595634A
公开(公告)日：1997-01-21
申请号：US500101
申请日：1995-07-10
申请人： Dennis Hearn , Gary R. Gildert , Hugh M. Putman
发明人： Dennis Hearn , Gary R. Gildert , Hugh M. Putman
IPC分类号： B01D3/00 , B01J8/04 , B01J23/56 , B01J23/755 , C07B61/00 , C07C5/13 , C07C7/163 , C07C7/167 , C07C11/02 , C10G45/06 , C10G45/10 , C10G45/40 , C10G65/00 , C10G65/06 , C10G67/02 , B01D3/34 , C01G7/00 , C07C5/22
CPC分类号： C07C7/167 , B01D3/009 , B01J8/0453 , C07C7/163 , C07C2523/44 , C07C2523/755 , C10G2300/4087 , C10G2400/02 , Y02P20/127 , Y10S203/06
摘要： A process for treating C.sub.3 to C.sub.12 petroleum fractions, such as a light cracked naphtha to be used as an etherification feed stock in which H.sub.2 S is removed by distillation of at least the C.sub.3 fraction and mercaptans and diolefins are removed simultaneously in a distillation column reactor using a dual catalyst bed. The mercaptans and H.sub.2 S are reacted with the diolefins in the presence of a reduced nickel catalyst to form sulfides which are higher boiling than the portion of the feed which is fractionated to an upper hydrogenation catalyst bed of palladium for hydrogenating diolefins and acetylenes. The higher boiling sulfides are removed as bottoms along with heavier materials. Any diolefins not converted to sulfides and acetylenes are selectively hydrogenated to mono-olefins in the presence of a palladium oxide catalyst in an upper bed, producing overheads, substantially free of sulfur compounds, diolefins and acetylenes.
摘要翻译：一种用于处理C3至C12石油馏分的方法，例如用作通过蒸馏至少C3馏分和硫醇和二烯烃除去H 2 S的醚化原料的轻质裂化石脑油，在蒸馏塔反应器中同时除去，使用双催化剂床。在还原的镍催化剂的存在下，硫醇和H 2 S与二烯烃反应形成沸点高于进料的部分沸点的硫化物，该部分被分馏到用于氢化二烯烃和乙炔的钯的上加氢催化剂床。较高沸点的硫化物作为底部以及更重的材料被去除。任何未转化为硫化物和炔烃的二烯烃在上层床中在氧化钯催化剂存在下选择性氢化成单烯烃，产生基本上不含硫化合物，二烯烃和炔烃的塔顶馏出物。

10. 发明授权

US5431890A Catalytic distillation structure 失效
标题翻译：催化蒸馏结构
公开(公告)号：US5431890A
公开(公告)日：1995-07-11
申请号：US188803
申请日：1994-01-31
申请人： Clifford S. Crossland , Gary R. Gildert , Dennis Hearn
发明人： Clifford S. Crossland , Gary R. Gildert , Dennis Hearn
IPC分类号： B01D3/16 , B01D3/00 , B01J8/00 , B01J8/02 , B01J19/30 , B01J19/32 , B01J35/02 , B01J35/04 , B01J35/06 , B01J8/06
CPC分类号： B01J35/02 , B01D3/009 , B01J19/32 , B01J35/04 , B01J35/06 , B01J8/008 , B01J2208/0069 , B01J2219/32279 , B01J2219/32408 , B01J2219/32466 , Y10S203/06
摘要： A bale shaped catalytic distillation structure formed by placing multiple link or continuous tube shaped structures on top of a wire mesh screen, such as demister wire, arrayed at an angle to the longitudinal axis of the bale, such that when the wire mesh screen is rolled up, the rolled structure provides a catalytic distillation structure. The tube comprises flexible, semi-rigid open mesh tubular element filled with a particulate catalytic material, the tube shaped structure having a fastener every 1-12 inches in length to form a multiple link.
摘要翻译：一种捆包形催化蒸馏结构，其通过将多个连接或连续的管状结构放置在与捆包的纵向轴线成一定角度排列的丝网筛（例如除雾丝）的顶部上，使得当丝网筛被轧制时轧制结构提供催化蒸馏结构。该管包括填充有颗粒催化材料的柔性半刚性开式网状管状元件，该管状结构具有每1-12英寸长的紧固件以形成多个连接。

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