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1. 发明授权

US09139503B2 Method for the production of dimethyl ether 有权
标题翻译：二甲醚生产方法
公开(公告)号：US09139503B2
公开(公告)日：2015-09-22
申请号：US11852923
申请日：2007-09-10
申请人： Lawrence A. Smith, Jr. , Abraham P. Gelbein , Christopher C. Boyer
发明人： Lawrence A. Smith, Jr. , Abraham P. Gelbein , Christopher C. Boyer
IPC分类号： C07C41/01 , C07C41/09
CPC分类号： C07C41/09 , Y02P20/127 , C07C43/043
摘要： A process for the production of dialkyl ether, the process including: feeding a stream comprising an alkyl alcohol to a distillation column reactor system; concurrently in the distillation column reactor system: i) contacting the alkyl alcohol with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the alkyl alcohol to form a corresponding dialkyl ether and water; and ii) fractionating the resulting dialkyl ether from the water; operating the distillation column reactor system to obtain substantially complete conversion of the alkyl alcohol to form the corresponding dialkyl ether and water; recovering the dialkyl ether from the distillation column reactor as an overheads fraction; recovering the water from the distillation column reactor as a bottoms fraction.
摘要翻译：一种制备二烷基醚的方法，该方法包括：将包含烷基醇的物流进料到蒸馏塔反应器系统; 在蒸馏塔反应器系统中同时进行：i）在蒸馏反应区中使烷基醇与催化蒸馏结构接触，从而使至少一部分烷基醇催化反应形成相应的二烷基醚和水; 和ii）从水中分馏得到的二烷基醚; 操作蒸馏塔反应器系统以获得烷基醇的基本上完全转化以形成相应的二烷基醚和水; 从塔顶反应器中回收二烷基醚作为塔顶馏分; 从蒸馏塔反应器中回收水作为塔底馏分。

2. 发明授权

US08153854B2 Gasoline alkylate RVP control 有权
标题翻译：汽油烷基化物RVP控制
公开(公告)号：US08153854B2
公开(公告)日：2012-04-10
申请号：US12134652
申请日：2008-06-06
申请人： Lawrence A. Smith, Jr. , Abraham P. Gelbein , William M. Cross, Jr.
发明人： Lawrence A. Smith, Jr. , Abraham P. Gelbein , William M. Cross, Jr.
IPC分类号： C07C2/02
CPC分类号： C07C9/02 , C07C2/62
摘要： A process for producing an alkylate having a low Reid vapor pressure, the process including: contacting a C6+-containing hydrocarbon stream with a mixture of isopentane and isobutane in the presence of an acid catalyst in an alkylation reactor to form a dilute alkylate product, wherein the C6+-containing hydrocarbon stream includes at least one of oligomers of C3 to C5 olefins and a dilute alkylate produced by contacting an isoparaffin with at least one of C3 to C5 olefins and oligomers of C3 to C5 olefins; fractionating the dilute alkylate product to form an isobutane-rich fraction, a n-butane-rich fraction, a fraction containing isopentane, and an alkylate product having a Reid vapor pressure less than 0.35 bar (5 psi); recycling at least a portion of the fraction containing isopentane to the alkylation reactor.
摘要翻译：一种制备具有低Reid蒸气压的烷基化物的方法，该方法包括：在烷基化反应器中，在酸催化剂存在下，将含C 6+的烃物流与异戊烷和异丁烷的混合物接触以形成稀烷基化物产物，其中含有C 6 +的烃物流包括C 3 -C 5烯烃的低聚物和通过使异链烷烃与C 3至C 5烯烃中的至少一种和C 3至C 5烯烃的低聚物接触而产生的稀烷基化物中的至少一种; 分馏稀烷基化产物以形成富含异丁烷的馏分，富含正丁烷的级分，含有异戊烷的级分和具有Reid蒸汽压小于0.35巴（5psi）的烷基化物产物; 将至少一部分含有异戊烷的级分再循环至烷基化反应器。

3. 发明授权

US08101810B2 Reformate benzene reduction via alkylation 有权
标题翻译：通过烷基化改性苯还原
公开(公告)号：US08101810B2
公开(公告)日：2012-01-24
申请号：US12195118
申请日：2008-08-20
申请人： Christopher C. Boyer , Lawrence A. Smith, Jr. , Arvids Judzis, Jr. , John R. Adams
发明人： Christopher C. Boyer , Lawrence A. Smith, Jr. , Arvids Judzis, Jr. , John R. Adams
IPC分类号： C07C2/52
CPC分类号： C07C2/66 , Y02P20/127 , C07C15/085 , C07C15/02
摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.
摘要翻译：一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。

4. 发明申请

US20100179362A1 SELECTIVATED ISOOLEFIN DIMERIZATION USING METALIZED RESINS 有权
标题翻译：使用金属化树脂的选择性ISOOLEFIN二维
公开(公告)号：US20100179362A1
公开(公告)日：2010-07-15
申请号：US12352198
申请日：2009-01-12
申请人： Lawrence A. Smith, JR. , William M. Cross, JR.
发明人： Lawrence A. Smith, JR. , William M. Cross, JR.
IPC分类号： C07C2/00
CPC分类号： C07C2/28 , B01J31/10 , B01J2231/20 , B01J2531/16 , C07C2527/173 , C07C2531/10 , C10G29/205 , Y02P20/127
摘要： A process for the dimerization of isoolefins, including: contacting an isoolefin with a solid catalyst composition passivated with at least one of an ether, an alcohol, and water; wherein the solid catalyst composition comprises at least one of a solid phosphoric acid catalyst and a resin of a macroporous matrix of polyvinyl aromatic compound crosslinked with a divinyl compound and having thereon from about 3 to 5 milli equivalents of sulfonic acid groups per gram of dry resin; and wherein at least 50% to less than 100% of acid groups in the solid catalyst composition are neutralized with a metal of Al, Fe, Zn, Cu, Ni, or mixtures thereof. The catalyst may be metalized prior to placement in a reactor or may be metalized in situ.
摘要翻译：一种异烯烃二聚的方法，包括：使异烯烃与用醚，醇和水中的至少一种钝化的固体催化剂组合物接触; 其中所述固体催化剂组合物包含固体磷酸催化剂和与二乙烯基化合物交联的聚乙烯基芳族化合物的大孔基体的树脂中的至少一种，并且其上具有约3至5毫当量的磺酸基团/克干树脂 ; 并且其中固体催化剂组合物中的至少50％至小于100％的酸基团被Al，Fe，Zn，Cu，Ni或其混合物的金属中和。催化剂可以在放置在反应器中之前被金属化，或者可以原位金属化。

5. 发明申请

US20090198091A1 H2SO4 ALKYLATION BY CONVERSION OF OLEFIN FEED TO OLIGOMERS AND SULFATE ESTERS 有权
标题翻译：通过向低聚物和硫酸酯转化烯烃的H2SO4烷基化
公开(公告)号：US20090198091A1
公开(公告)日：2009-08-06
申请号：US12023390
申请日：2008-01-31
申请人： Lawrence A. Smith, JR. , Abraham P. Gelbein , William M. Cross, JR.
发明人： Lawrence A. Smith, JR. , Abraham P. Gelbein , William M. Cross, JR.
IPC分类号： C07C2/56
CPC分类号： C07C2/08 , C07C2/58 , C07C7/17 , C07C7/171 , C07C17/08 , C07C303/24 , C10G29/205 , C07C9/16 , C07C19/08 , C07C305/06
摘要： A process for treating an alkylation feedstock comprising olefins, n-alkanes, and iso-alkanes, the process including: contacting at least a portion of the alkylation feedstock with sulfuric acid in a reaction zone under conditions to form sulfate esters of the olefins; separating the n-alkanes and the iso-alkanes from the sulfuric acid and the sulfate esters; recovering the n-alkanes and the iso-alkanes in a first product stream; and recovering the sulfate esters in a second product stream; wherein the sulfuric acid has a strength titrating as below 75 weight percent H2SO4/water mixtures.
摘要翻译：一种用于处理包含烯烃，正烷烃和异烷烃的烷基化原料的方法，该方法包括：在形成烯烃的硫酸酯的条件下，使反应区中至少一部分烷基化原料与硫酸接触; 从硫酸和硫酸酯分离正烷烃和异烷烃; 在第一产物流中回收正烷烃和异烷烃; 并在第二产物流中回收硫酸酯; 其中硫酸的浓度滴定低于75重量％的H 2 SO 4 /水混合物。

6. 发明申请

US20090076312A1 PROCESS FOR THE CONVERSION OF TERTIARY BUTYL ALCOHOL TO ETHYL TERTIARY BUTYL ETHER 有权
标题翻译：叔丁基醇向乙基叔丁基醚转化的方法
公开(公告)号：US20090076312A1
公开(公告)日：2009-03-19
申请号：US11857160
申请日：2007-09-18
申请人： Mitchell E. Loescher , Lawrence A. Smith, JR.
发明人： Mitchell E. Loescher , Lawrence A. Smith, JR.
IPC分类号： C07C41/09 , B01J8/02
CPC分类号： C07C41/06 , C07C43/046
摘要： A process for the conversion of tertiary butyl alcohol to ethyl tertiary butyl ether, including: dehydrating tertiary butyl alcohol to form a product stream comprising isobutylene and water; separating the product stream to form an isobutylene-rich fraction and a water-rich fraction; separating the water-rich fraction to recover a hydrocarbon fraction and a water fraction having less than 1 ppm hydrocarbon content; reacting isobutylene in the isobutylene-rich fraction with ethanol to form a reaction product comprising ethyl tertiary butyl ether; separating the reaction product to recover unreacted ethanol and an ethyl tertiary butyl ether stream; and recycling at least a portion of the unreacted ethanol to the reacting; wherein the ethyl tertiary butyl ether stream comprises at least 99 weight percent ethyl tertiary butyl ether.
摘要翻译：一种将叔丁醇转化为乙基叔丁基醚的方法，包括：脱水叔丁醇以形成包含异丁烯和水的产物流; 分离产物流以形成富含异丁烯的级分和富水级分; 分离富水馏分以回收烃馏分和具有小于1ppm烃含量的水馏分; 使富含异丁烯的馏分中的异丁烯与乙醇反应，形成包含乙基叔丁基醚的反应产物; 分离反应产物以回收未反应的乙醇和乙基叔丁基醚料流; 并将至少一部分未反应的乙醇再循环到反应中; 其中乙基叔丁基醚流包含至少99重量％的乙基叔丁基醚。

7. 发明授权

US07368617B2 Selective hydrogenation of acetylenes and dienes in a hydrocarbon stream 有权
标题翻译：在烃流中乙炔和二烯烃的选择性加氢
公开(公告)号：US07368617B2
公开(公告)日：2008-05-06
申请号：US10983433
申请日：2004-11-08
申请人： Abraham P. Gelbein , Lawrence A. Smith, Jr.
发明人： Abraham P. Gelbein , Lawrence A. Smith, Jr.
IPC分类号： C07C5/03
CPC分类号： C07C5/09 , C07C5/05 , C07C7/163 , C07C7/167 , C07C2523/44
摘要： Acetylenes and dienes in a stream containing hydrogen, methane, C2-C6 olefins and paraffins, C2-C6 acetylenes and dienes, benzene, toluene, xylenes, and other C6+ components are hydrogenated in a downflow boiling point reactor wherein the heat of reaction is absorbed by the liquid in the reactor which produces a vapor. Besides the feed to the reactor there is a recirculating stream which is fed at a rate sufficient to ensure that the catalyst particles within the reactor are wetted. A third stream, which is taken from a downstream distillation column, is fed to provide the make up mass corresponding to the mass evaporated in the reactor. The composition of the this third stream controls the steady state composition of the liquid flowing through the reactor.
摘要翻译：含有氢，甲烷，C 2 -C 6烯烃和链烷烃，C 2 -C 6烯烃的物流中的乙炔和二烯，乙炔和二烯，苯，甲苯，二甲苯和其它C 6+组分在下流沸点反应器中氢化，其中反应热被反应器中的液体吸收，产生汽。除了进料到反应器之外还有一个再循环流，其进料量足以确保反应器内的催化剂颗粒被润湿。进料从下游蒸馏塔获得的第三料流，以提供与在反应器中蒸发的物质相应的补充质量。该第三流的组成控制流过反应器的液体的稳态组成。

8. 发明授权

US07125484B2 Downflow process for hydrotreating naphtha 失效
标题翻译：加氢处理石脑油的下流过程
公开(公告)号：US07125484B2
公开(公告)日：2006-10-24
申请号：US10958857
申请日：2004-10-05
申请人： Lawrence A. Smith, Jr.
发明人： Lawrence A. Smith, Jr.
IPC分类号： C10G45/00 , C10G45/60
CPC分类号： C10G65/04 , C10G45/02 , C10G49/002 , C10G57/00 , C10G65/02 , C10G69/02 , C10G69/04 , C10G2300/4087
摘要： A process for the treatment of light naphtha hydrocarbon streams is disclosed wherein the mercaptans contained therein are reacted with diolefins simultaneous with fractionation into a light stream and a heavy stream. The heavy stream is then simultaneously treated at high temperatures and low pressures and fractionated. The naphtha is then stripped of the hydrogen sulfide in a final stripper.
摘要翻译：公开了一种处理轻石脑油烃流的方法，其中所含的硫醇与二烯烃反应，同时分馏成轻质流和重质流。然后在高温和低压下同时处理重质流并分馏。然后在最后的汽提塔中汽提石脑油。

9. 发明授权

US06169218A Selective hydrogenation of highly unsaturated compounds in hydrocarbon streams 失效
标题翻译：烃流中高度不饱和化合物的选择氢化
公开(公告)号：US06169218A
公开(公告)日：2001-01-02
申请号：US08978123
申请日：1997-11-25
申请人： Dennis Hearn , Robert P. Arganbright , Edward M. Jones, Jr. , Lawrence A. Smith, Jr. , Gary R. Gildert
发明人： Dennis Hearn , Robert P. Arganbright , Edward M. Jones, Jr. , Lawrence A. Smith, Jr. , Gary R. Gildert
IPC分类号： C07C503
CPC分类号： C10G70/02 , C07C7/163 , C07C2523/44 , C10G45/32 , Y02P20/127 , Y10S203/06 , C07C11/02
摘要： A process for the selective hydrogenation of the diolefins and acetylenic compounds in a olefin rich aliphatic hydrocarbon streams is disclosed wherein the selective hydrogenation is carried out at 40 to 300° F. under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig in a distillation column reactor containing a hydrogenation catalyst which serves as a component of a distillation structure, such as supported PdO encased in tubular wire mesh. Essentially no hydrogenation of the olefins occurs.
摘要翻译：公开了一种在富含烯烃的脂肪族烃流中选择性氢化二烯烃和炔属化合物的方法，其中选择性氢化在40至300°F的低氢分压下进行，其范围为约0.1psi至小于在含有氢化催化剂的蒸馏塔反应器中，在0至350psig下为70psia，其用作蒸馏结构的组分，例如包裹在管状丝网中的负载型PdO。基本上没有发生烯烃的氢化。

10. 发明授权

US5756872A Process for the treatment of FCCU off gas 失效
标题翻译： FCCU废气处理工艺
公开(公告)号：US5756872A
公开(公告)日：1998-05-26
申请号：US789650
申请日：1997-01-27
申请人： Lawrence A. Smith, Jr. , John R. Adams
发明人： Lawrence A. Smith, Jr. , John R. Adams
IPC分类号： B01D53/72 , C07C15/073 , C10G11/18 , C10G29/20 , C07C2/70 , C07C2/66 , C07C7/148
CPC分类号： B01D53/72 , C07C15/073 , C10G11/18 , C10G29/205 , C07C2527/173 , C07C2529/70
摘要： A process wherein an FCCU off gas is treated by first subjecting the off gas to an alkylation with a heavy reformat to remove the propylene and contaminants after which the gas is separated from the reformat and alkylated products by distillation to produce an ethylene feed suitable for the reaction with benzene to produce ethyl benzene.
摘要翻译：一种方法，其中通过首先使废气进行烷基化处理以除去丙烯和污染物，然后通过蒸馏将气体从重整塔和烷基化产物中分离出来，以生产适合于与苯反应生成乙苯。

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