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    • 3. 发明授权
    • Polymer particles
    • 聚合物颗粒
    • US09339781B2
    • 2016-05-17
    • US14122700
    • 2012-05-31
    • Matthew Paul BakerTimothy Warren DaveyBrian Stanley HawkettDuc Ngoc NguyenChristopher Henry Such
    • Matthew Paul BakerTimothy Warren DaveyBrian Stanley HawkettDuc Ngoc NguyenChristopher Henry Such
    • B01J13/18B01J13/22
    • B01J13/18B01J13/22C01P2002/88C01P2004/04C08F2/18C08F2/44C09B67/0013C09C1/3676Y10T428/2989
    • The present invention relates to a method of preparing an aqueous dispersion of polymer encapsulated particulate material, the method comprising: providing a dispersion of the particulate material in a continuous aqueous phase, the dispersion comprising ethylenically unsaturated monomer and a stabilizer for the particulate material; and polymerizing the ethylenically unsaturated monomer by non-living free radical polymerization to form polymer that encapsulates the particulate material, thereby providing the aqueous dispersion of polymer encapsulated particulate material; wherein polymerization of the ethylenically unsaturated monomer comprises: (a) polymerizing a monomer composition that includes ionizable ethylenically unsaturated monomer so as to form a base responsive water swellable non-living polymer layer that encapsulates the particulate material; and (b) polymerizing a monomer composition that includes non-ionizable ethylenically unsaturated monomer so as to form an extensible, water and base permeable non-living polymer layer that encapsulates the base responsive water swellable polymer layer.
    • 本发明涉及一种制备聚合物包封的颗粒材料的水分散体的方法,所述方法包括:提供颗粒材料在连续水相中的分散体,所述分散体包含烯键式不饱和单体和用于颗粒材料的稳定剂; 并通过非活性自由基聚合使烯属不饱和单体聚合形成包封颗粒材料的聚合物,从而提供聚合物包封的颗粒材料的水性分散体; 其中所述烯键式不饱和单体的聚合包括:(a)聚合包含可离子化的烯属不饱和单体的单体组合物,以便形成包封所述颗粒材料的碱性响应性水溶胀性非活性聚合物层; 和(b)使包含不可离子化的烯属不饱和单体的单体组合物聚合,以便形成包封碱性响应性水溶胀性聚合物层的可延伸的水和基底可渗透的非活性聚合物层。
    • 4. 发明申请
    • POLYMER PARTICLES
    • 聚合物颗粒
    • US20140329932A1
    • 2014-11-06
    • US14122700
    • 2012-05-31
    • Matthew Paul BakerTimothy Warren DaveyBrian Stanley HawkettDuc Ngoc NguyenChristopher Henry Such
    • Matthew Paul BakerTimothy Warren DaveyBrian Stanley HawkettDuc Ngoc NguyenChristopher Henry Such
    • B01J13/18B01J13/22
    • B01J13/18B01J13/22C01P2002/88C01P2004/04C08F2/18C08F2/44C09B67/0013C09C1/3676Y10T428/2989
    • The present invention relates to a method of preparing an aqueous dispersion of polymer encapsulated particulate material, the method comprising: providing a dispersion of the particulate material in a continuous aqueous phase, the dispersion comprising ethylenically unsaturated monomer and a stabiliser for the particulate material; and polymerising the ethylenically unsaturated monomer by non-living free radical polymerisation to form polymer that encapsulates the particulate material, thereby providing the aqueous dispersion of polymer encapsulated particulate material; wherein polymerisation of the ethylenically unsaturated monomer comprises: (a) polymerising a monomer composition that includes ionisable ethylenically unsaturated monomer so as to form a base responsive water swellable non-living polymer layer that encapsulates the particulate material; and (b) polymerising a monomer composition that includes non-ionisable ethylenically unsaturated monomer so as to form an extensible, water and base permeable non-living polymer layer that encapsulates the base responsive water swellable polymer layer.
    • 本发明涉及一种制备聚合物包封的颗粒材料的水分散体的方法,所述方法包括:提供颗粒材料在连续水相中的分散体,所述分散体包含烯键式不饱和单体和用于颗粒材料的稳定剂; 并通过非活性自由基聚合使烯属不饱和单体聚合以形成包封颗粒材料的聚合物,由此提供聚合物包封的颗粒材料的水分散体; 其中所述烯键式不饱和单体的聚合包括:(a)聚合包含可离子化烯键式不饱和单体的单体组合物,以形成包封所述颗粒材料的碱性响应性水可溶胀非活性聚合物层; 和(b)聚合包含不可离子化的烯键式不饱和单体的单体组合物,以便形成包封碱性响应性水溶胀性聚合物层的可延伸的水和可渗透的非活性聚合物层。
    • 10. 发明授权
    • Aqueous polymer dispersion
    • 聚合物水分散体
    • US07858695B2
    • 2010-12-28
    • US10565218
    • 2004-07-23
    • Amanda Jane ChalmersJason Michael FarrugiaElizabeth Ann SalterChristopher Henry SuchOlga Maree MacKinnon
    • Amanda Jane ChalmersJason Michael FarrugiaElizabeth Ann SalterChristopher Henry SuchOlga Maree MacKinnon
    • C08F8/30
    • C09D151/003C08F2/22C08F265/04C08F265/06C08F285/00C08L51/003C08L2666/02C09D7/43C09J151/003
    • The invention provides a process for preparing an aqueous dispersion of water insoluble heteropolymeric particles comprising polymerising in an aqueous reaction medium ethylenically unsaturated monomers, said ethylenically unsaturated monomers comprising ionisable ethylenically unsaturated monomers and non-ionisable hydrophilic ethylenically unsaturated monomers, to form said heteropolymeric particles dispersed in said aqueous reaction medium, wherein the monomers in said reaction medium at any point in time comprise less than 5 weight % of ionisable ethylenically unsaturated monomer, wherein for at least a part of the polymerisation the monomers in said reaction medium have a composition which is maintained with an ionisable ethylenically unsaturated monomer content of from 0.5 to less than 5 weight % throughout polymerisation of at least 30 weight % of the total amount of monomers polymerised to form the heteropolymeric particles, and wherein the total amount of non-ionisable hydrophilic ethylenically unsaturated monomers and ionisable ethylenically unsaturated monomers polymerised constitutes at least 75 weight % of the total amount of monomers polymerised to form the heteropolymeric particles, a method of preparing a paint comprising conventional paint additives and the aqueous dispersion of water insoluble heteropolymeric particles of the invention, and a novel aqueous dispersion of water insoluble heteropolymeric particles.
    • 本发明提供了一种制备水不溶性杂聚颗粒的水性分散体的方法,包括在水性反应介质中聚合烯键式不饱和单体,所述烯键式不饱和单体包含可离子化的烯属不饱和单体和不可离子化的亲水性烯键式不饱和单体,以形成分散的所述杂聚颗粒 在所述水性反应介质中,其中所述反应介质中的任何时间点上的单体包含小于5重量%的可离子化烯属不饱和单体,其中对于至少一部分聚合,所述反应介质中的单体具有 在聚合过程中保持0.5至小于5重量%的可离子化的烯键式不饱和单体的含量,其至少为聚合形成杂聚颗粒的单体总量的至少30重量%,并且其中不可离子化的亲水 聚合的非烯属不饱和单体和可离子化烯键式不饱和单体构成聚合形成异聚颗粒的单体总量的至少75重量%,制备包含常规涂料添加剂的涂料的方法和水不溶性杂聚颗粒的水分散体 发明和水不溶性异聚合物颗粒的新型水性分散体。