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1. 发明申请

US20070243999A1 Method of Forming a Carbon-Heteroatom Bond 失效
标题翻译：形成碳杂原子键的方法
公开(公告)号：US20070243999A1
公开(公告)日：2007-10-18
申请号：US10556849
申请日：2004-05-12
申请人： Christelle Mauger , Gerard Mignani
发明人： Christelle Mauger , Gerard Mignani
IPC分类号： B01J21/00
CPC分类号： C07C249/16 , C07C251/86
摘要： The present invention relates to a method of creating a carbon-heteroatom bond, and preferably a carbon-nitrogen bond, by reacting a leaving group-bearing unsaturated compound and a nucleophilic compound. In particular, the invention relates to the creation of a carbon-nitrogen bond, using a method involving the arylation of nitrogenous organic derivatives; the inventive method consists in creating a carbon-heteroatom bond by reacting a leaving group-bearing unsaturated compound and a nucleophilic compound introducing a heteroatom which can be substituted for the leaving group, thereby creating a carbon-heteroatom bond, in the presence of a palladium-based catalyst, optionally a ligand. The invention is characterized in that the reaction takes place in the presence of an effective quantity of a metal hydroxide or ammonium hydroxide which is associated with an alcohol-type solvent.
摘要翻译：本发明涉及通过使含离去基团的不饱和化合物与亲核性化合物反应而产生碳 - 杂原子键，优选碳 - 氮键的方法。特别地，本发明涉及使用涉及含氮有机衍生物的芳基化的方法产生碳 - 氮键; 本发明的方法包括通过使带有离去基团的不饱和化合物和引入可被取代离去基团的杂原子的亲核化合物反应产生碳 - 杂原子键，从而在钯的存在下产生碳 - 杂原子键的催化剂，任选的配体。本发明的特征在于反应在有效量的与醇型溶剂相关的金属氢氧化物或氢氧化铵存在下进行。

2. 发明申请

US20100113800A1 Formation of Carbon-nitrogen bond 审中-公开
标题翻译：形成碳 - 氮键
公开(公告)号：US20100113800A1
公开(公告)日：2010-05-06
申请号：US11990012
申请日：2006-08-04
申请人： Christelle Mauger , Gerard Mignani , Roland Jacquot
发明人： Christelle Mauger , Gerard Mignani , Roland Jacquot
IPC分类号： C07D233/00
CPC分类号： C07D233/56
摘要： The present invention relates to a process to create a carbon-nitrogen bond by the reaction of an aromatic compound carrying at least one electro attractive group with one nitrogenous heterocyclic type nucleophile compound. The invention aims, in particular, at a link reaction between an aromatic compound carrying at least one electro attractive group and an imidazole heterocycle type. The invention process, consisting of the reaction of an aromatic compound carrying one leaving group and at least one electro attractive group and a nitrogenous heterocyclic type nucleophile compound comprising a N—H pattern likely to substitute the leaving group, thereby creating a carbon-nitrogen bond in the presence of a copper catalyst, of a base in an organic solvent, is characterized by the fact that the said nitrogenous heterocycle reacts with an aromatic type electrophile compound carrying one leaving group (Y) chosen from bromine, chlorine or sulfonic ester and at least one electro attractive group (Z1), in the presence of a copper catalyst, of a mineral or organic base, of an extracting agent selected from aliphatic diamines, aliphatic amino alcohols and diols in a polar aprotic organic solvent with a dielectric constant less than about 20 and a basicity such that its “donor number” is less than about 25.
摘要翻译：本发明涉及通过携带至少一个电吸引基团的芳族化合物与一种含氮杂环型亲核化合物的反应产生碳 - 氮键的方法。本发明特别涉及携带至少一个电吸引基团的芳族化合物和咪唑杂环类型之间的连接反应。本发明方法由携带一个离去基团的芳族化合物和至少一个电吸引基团和含氮杂环型亲核化合物的反应组成，该化合物包含可能代替离去基团的N-H型，从而产生碳 - 氮键在铜催化剂存在下，在有机溶剂中存在碱，其特征在于所述含氮杂环与携带选自溴，氯或磺酸酯的一个离去基团（Y）的芳香族亲电子试剂反应，并且在在铜催化剂存在下，在介电常数小于或等于的极性非质子有机溶剂中的选自脂族二胺，脂族氨基醇和二醇的萃取剂的至少一个电吸引组（Z1）大约20岁，并且其“捐赠人数”小于约25的碱度。

3. 发明申请

US20110046301A1 SYNTHESIS OF URETHANES AND POLYURETHANES CATALYSED BY CARBENES 有权
标题翻译：由碳酸酯催化的尿素和聚氨酯的合成
公开(公告)号：US20110046301A1
公开(公告)日：2011-02-24
申请号：US12670298
申请日：2008-07-25
申请人： Gerard Mignani , Mathias Destarac , Daniel Taton , Yves Gnanou , Antoine Baceiredo , Tsuyoshi Kato , Fabian Bonnette , Gopakumar Sivasankarapillai
发明人： Gerard Mignani , Mathias Destarac , Daniel Taton , Yves Gnanou , Antoine Baceiredo , Tsuyoshi Kato , Fabian Bonnette , Gopakumar Sivasankarapillai
IPC分类号： C09D175/04 , C08G18/16
CPC分类号： B01J31/0239 , B01J31/006 , B01J31/0247 , B01J31/0267 , B01J2231/14 , C08G18/2018 , C08G18/2027 , C08G18/209 , C08G18/3206 , C08G18/4833
摘要： The present invention relates to a process for preparing a compound comprising at least a urethane group —HN—C(═O)—O, said process comprising a step (E) in which a compound (I) comprising at least an isocyanate functional group —N═C═O is reacted with an organic compound (II) carrying at least a hydroxyl group —OH, said reaction being carried out in a presence of a carbene (III) used as a catalyst.
摘要翻译：本发明涉及至少包含氨基甲酸酯基-HN-C（= O）-O的化合物的制备方法，所述方法包括步骤（E），其中至少包含异氰酸酯官能团的化合物（I） -N = C = O与至少含有羟基-OH的有机化合物（II）反应，所述反应在用作催化剂的卡宾（III）存在下进行。

4. 发明申请

US20080255322A1 METHOD FOR PREPARING FUNCTIONALIZED POLYORGANOSILOXANE RESINS BY REDISTRIBUTION IN THE PRESENCE OF AT LEAST ONE TRIFLIC ACID DERIVATIVE 审中-公开
标题翻译：通过重新分配在至少一种三聚酸衍生物存在下制备官能化聚硅氧烷树脂的方法
公开(公告)号：US20080255322A1
公开(公告)日：2008-10-16
申请号：US12142384
申请日：2008-06-19
申请人： Fernande BOISSON , Gerard Mignani
发明人： Fernande BOISSON , Gerard Mignani
IPC分类号： C08G77/38
CPC分类号： C08G77/08 , C08G77/10
摘要： The present invention relates to a process for preparing functionalized polyorganosiloxane (POS) resins comprising units M: (R3SiO1/2) Q: (SiO4/2) and M′: (YaR3−aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), with, in these units: R=C1-C10 alkyl or a C8-C12 aryl and Y a functional group (e.g.: Si—H),by redistribution of POS resins using POSf bearing functional units M′ and/or D′ and/or in the presence of an acid catalyst of the trifluoromethane-sulfonimide (TFSI) type.The present invention also relates to the aforementioned catalyst system.
摘要翻译：本发明涉及一种制备官能化聚有机硅氧烷（POS）树脂的方法，其包含单元M：（R 3 SiO 2 1/2）Q：（SiO 4 / 2）和M'：（Y a a R 3-a SiO 1/2）和任选的D：（R' 和/或D'：（RYSiO 2/2）和T：（RS 3 O 3/2） / /> T'：（YSiO 3/2/2），在这些单元中：R = C 1 -C 10 >烷基或C 8 -C 12芳基，Y是官能团（例如：Si-H），通过使用POSf承载功能单元M'重新分配POS树脂， /或D'和/或在三氟甲烷 - 磺酰亚胺（TFSI）型的酸催化剂存在下进行。本发明还涉及上述催化剂体系。

5. 发明申请

US20050032949A1 Tire rubber composition comprising a coupling agent having a polythiosulfenamide function 有权
标题翻译：轮胎橡胶组合物，其包含具有聚亚硫酰胺功能的偶联剂
公开(公告)号：US20050032949A1
公开(公告)日：2005-02-10
申请号：US10870999
申请日：2004-06-21
申请人： Carlos Araujo Da Silva , Christiane Blanchard , Gerard Mignani , Salvatore Pagano , Jean-Claude Tardivat
发明人： Carlos Araujo Da Silva , Christiane Blanchard , Gerard Mignani , Salvatore Pagano , Jean-Claude Tardivat
IPC分类号： B60C1/00 , B60C15/06 , C08J3/20 , C08K3/00 , C08K5/548 , C08L21/00 , C08K3/34 , C08K5/24
CPC分类号： B60C15/06 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , C08K5/548 , C08L21/00
摘要： An elastomeric composition usable for the manufacture of tires, based on at least (i) a diene elastomer, (ii) an inorganic filler as reinforcing filler and (iii), as (inorganic filler/diene elastomer) coupling agent, a organosilicon compound which is at least bifunctional and can be grafted on to the elastomer by means of a sulfur group having a polythiosulfenamide function, of formula: ≡Si-A-Sx—NR1R2, (I) in which: A is a divalent bond group, whether straight-chain or branched, which makes it possible to join the polythiosulfenamide group to a silicon atom of the organosilicon compound; x is an integer or fractional number of from 2 to 4; R1 represents hydrogen or a monovalent hydrocarbon group; R2 represents a monovalent hydrocarbon group selected from among C3-C8 alkyls, whether straight-chain or branched, C5-C10 cycloalkyls, C6-C18 aryls and (C6-C18)aryl-(C1-C8)alkyls; R1 and R2 possibly forming together and with the nitrogen atom to which they are bonded a single hydrocarbon ring. Tires and tire treads comprising a composition of this type.
摘要翻译：可用于制造轮胎的弹性体组合物，至少基于（i）二烯弹性体，（ii）作为增强填料的无机填料和（iii）作为（无机填料/二烯弹性体）偶联剂的有机硅化合物，至少是双官能的，并且可以通过具有式：Si-A-Sx-NR 1 R 2，（I）的具有聚亚硫酰胺官能团的硫基接枝到弹性体上，其中：A是无论是直链还是支链的二价键基团，这使得可以将多亚硫酰胺基团连接到有机硅化合物的硅原子; x是2到4的整数或小数; R 1表示氢或一价烃基; R 2表示选自C 3 -C 8烷基，无论是直链还是支链，C5-C10环烷基，C6-C18芳基和（C6-C18）芳基 - （C1-C8）烷基的一价烃基; R 1和R 2可以一起形成，并与它们所键合的氮原子形成单个烃环。包括这种类型的组合物的轮胎和轮胎胎面。

6. 发明授权

US5324827A Optionally oriented, monomeric and polymeric nonlinearly optically active materials and derivatives thereof 失效
标题翻译：任选取向的单体和聚合物非线性光学活性材料及其衍生物
公开(公告)号：US5324827A
公开(公告)日：1994-06-28
申请号：US118286
申请日：1993-09-09
申请人： Yves Camberlin , Gerard Mignani , Remi Meyrueix , Gilles Tapolsky
发明人： Yves Camberlin , Gerard Mignani , Remi Meyrueix , Gilles Tapolsky
IPC分类号： C08F20/60 , C07D207/44 , C07D207/452 , C07D207/456 , C08F20/52 , C08F22/36 , C08F22/40 , C08G73/10 , C08G73/14 , G02F1/35 , G02F1/355 , G02F1/361 , G03F7/027 , C07C245/06
CPC分类号： C07D207/452 , C07D207/456 , C08G73/1067 , C08G73/14 , G02F1/361 , G03F7/027
摘要： Nonlinearly optically active monomer species comprising at least two carbon-carbon activated double bonds, i.e., the polymerization of which is facilitated by the presence of an electron attracting function, and a non-centrosymmetric system of pi (.pi.) conjugated bonds bearing at least one electron attracting group on one terminal thereof and at least one electron donor group on the other terminal, are readily (co)polymerized and optionally oriented and crosslinked into shaped articles well adopted for the manufacture of a variety of electrooptical devices; such monomer species can have, for example, the following structural formula (I): ##STR1##
摘要翻译：包含至少两个碳 - 碳活化双键的非线性光学活性单体物质，即其聚合通过存在吸电子功能而促进，以及带有至少一个的π（π）共轭键的非中心对称体系其一端上的吸电子基团和另一个末端上的至少一个电子给体基团容易（共）聚合并任选取向并交联成良好地用于制造各种电光器件的成形制品; 这样的单体物质可以具有例如以下结构式（I）：其中（I）

7. 发明授权

US5214176A Organosilicon compounds 失效
标题翻译：有机硅化合物
公开(公告)号：US5214176A
公开(公告)日：1993-05-25
申请号：US340778
申请日：1989-04-20
申请人： Gerard Soula , Gerard Mignani
发明人： Gerard Soula , Gerard Mignani
IPC分类号： G02F1/35 , C07F7/08 , C07F7/10 , C07F7/12 , C07F9/40 , G02F1/355 , G02F1/361
CPC分类号： G02F1/3619 , C07F7/0821
摘要： Novel organosilicon compounds having a second order hyperpolarizability coefficient .beta. greater than zero, well suited for use in the field of nonlinear optics, e.g., in telecommunication devices, have the general formula: ##STR1## which n is an integer ranging from 1 to 20; R.sub.1 is an electron donating group; R.sub.2 is an electron accepting group; R.sub.3 is an alkyl radical having from 1 to 8 carbon atoms, a hydrogen atom, an aryl radical, or an R.sub.1 or R.sub.2 radical; and R.sub.4 is an alkyl radical having from 1 to 8 carbon atoms, a hydrogen atom, an aryl radical, or an R.sub.1 radical when R.sub.3 is not an R.sub.2 radical or an R.sub.2 radical when R.sub.3 is not an R.sub.1 radical.
摘要翻译：具有二阶超极化率系数β大于零的新型有机硅化合物，非常适合用于非线性光学领域，例如在电信设备中，具有以下通式：其中n是1至20的整数; R1是给电子基团; R2是电子接受基团; R3是具有1至8个碳原子的烷基，氢原子，芳基或R1或R2基团; 当R 3不是R 1基团时，当R 3不是R 2基团或R 2基团时，R 4是具有1至8个碳原子的烷基，氢原子，芳基或R 1基团。

8. 发明授权

US5145917A Boron/nitrogen/silicon preceramic polymers and boron nitride ceramic materials produced therefrom 失效
标题翻译： BORON / NITROGEN / SILICON PRECERAMIC POLYMERS和BORON NITRIDE CERAMIC MATERIALS PRODUCER THEREFROM
公开(公告)号：US5145917A
公开(公告)日：1992-09-08
申请号：US565455
申请日：1990-08-10
申请人： Pierre Ardaud , Gerard Mignani
发明人： Pierre Ardaud , Gerard Mignani
IPC分类号： C04B35/583 , C08G79/00 , C08G79/08 , D01F9/10
CPC分类号： C04B35/583 , C08G79/08
摘要： Boron/nitrogen/silicon preceramic polymers are prepared by copolymerizing at least one trihaloborane with at least one disilazane and at least one B-trichloroborazine; the resulting polymers, advantageously in fibrous form, are then facilely crosslinked and pyrolyzed into boron nitride ceramic materials.
摘要翻译：通过使至少一种三卤代硼烷与至少一种二硅氮烷和至少一种B-三氯硼烷共聚制备硼/氮/硅预陶瓷聚合物; 所得聚合物有利地是纤维状的，然后易于交联并热解成氮化硼陶瓷材料。

9. 发明授权

US5021371A Low carbon/high purity boron nitride 失效
标题翻译：低碳/高纯度氮化硼
公开(公告)号：US5021371A
公开(公告)日：1991-06-04
申请号：US482073
申请日：1990-02-20
申请人： Gerard Mignani , Pierre Ardaud , Roger Trichon
发明人： Gerard Mignani , Pierre Ardaud , Roger Trichon
IPC分类号： C01B21/064 , C04B35/583 , C08G79/08 , D01F9/10
CPC分类号： C08G79/08 , C01B21/064 , C01B21/0646 , C04B35/583
摘要： Highly pure boron nitride ceramic material, devoid of silicon values and having low carbon content, is prepared by pyrolyzing, under an atmosphere of ammonia, the product of the reaction between (i) at least one B-trihalogeno-borazole having the formula: ##STR1## and (ii) at least one primary amine having the formula:H.sub.2 N--Rin which formulae X is a halogen atom and R is an optionally substituted hydrocarbon radical having from 1 to 6 carbon atoms.
摘要翻译：通过在氨气氛下热解（i）至少一种具有下列结构式的β-三卤代 - 硼唑之间的反应产物，制备无纯硅含量低的碳氮化硼陶瓷材料：和（ii）至少一种具有下式的伯胺：其中式X是卤素原子，R是具有1至6个碳原子的任选取代的烃基。

10. 发明授权

US4806280A Process for the preparation of unsaturated compound .alpha.-chlorinated with respect to two electron-attracting groups in a .beta.-position 失效
标题翻译：制备相对于β-位中的两个吸电子基团的α-氯化不饱和化合物的方法
公开(公告)号：US4806280A
公开(公告)日：1989-02-21
申请号：US81634
申请日：1987-08-03
申请人： Gerard Mignani , Didier Morel
发明人： Gerard Mignani , Didier Morel
IPC分类号： C07C45/63 , C07C45/00 , C07C45/65 , C07C45/67 , C07C47/24 , C07C49/203 , C07C49/227 , C07C49/258 , C07C67/00 , C07C67/307 , C07C69/587 , C07C69/73 , C07C69/738 , C07C201/00 , C07C201/12 , C07C205/09 , C07C231/00 , C07C231/12 , C07C233/09 , C07C253/00 , C07C253/30 , C07C255/10 , C07C255/17 , C07C269/06 , C07C271/18 , C07C313/00 , C07C315/04 , C07C317/04 , C07C317/24 , C07C317/44 , C07C69/60 , C11C3/00
CPC分类号： C07C49/227 , C07C45/65 , C07C45/673 , C07C45/676 , C07C49/203
摘要： Compounds of formula ##STR1## in which n denotes an integer from 1 to 10 and X and Y, which are identical or different, each denote an electron-attracting group, are made by reacting a halogenating agent with a compound of formula ##STR2## in which R, X and Y are as hereinbefore defined, anionized by a base.
摘要翻译：其中n表示1至10的整数并且相同或不同的X和Y各自表示吸电子基团的式（Ia）或（IMA）化合物或其中n表示电子吸引基团，卤化剂与式（IIa）化合物或式（IIb）化合物反应，其中R，X和Y如上所定义，被碱阴离子化。

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