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1. 发明授权

US4159991A Acyloxy-N,N'-diacylmalonamides and methods for their preparation 失效
标题翻译：酰氧基-N，N {40-二酰基丙二酰胺及其制备方法
公开(公告)号：US4159991A
公开(公告)日：1979-07-03
申请号：US826478
申请日：1977-08-22
申请人： Bernard Dubreux , Serve Y. Delavarenne , Jean-Pierre Schirmann
发明人： Bernard Dubreux , Serve Y. Delavarenne , Jean-Pierre Schirmann
IPC分类号： C07C309/59 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/14 , C07C233/90 , C07C235/88 , C07C301/00 , C07C313/00 , C07C315/04 , C07C317/00 , C07C317/44 , C07D20060101 , C09F5/00 , C11D20060101 , C11D1/28 , C11D3/39 , C11D3/395 , C11D7/54 , C07C143/90
CPC分类号： C07C255/00
摘要： .alpha.-Acyloxy-N,N'-diacylmalonamides of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, straight chain or branched alkyl radicals having from one to eleven carbon atoms, or hydrocarbon radicals with six to twelve carbon atoms and comprising at least one aromatic ring, are novel compounds prepared by the action of a mixture of carboxylic acids R.sub.3 COOH and R.sub.4 COOH upon an .alpha.-acyloxymalononitrile, R.sub.1 COO--C(CN).sub.2 --R.sub.2, in the presence of an acid catalyst and are useful as intermediates in organic synthesis and low temperature activators in bleaching or scouring compositions.
摘要翻译：式中，R 1，R 2，R 3和R 4相同或不同，为氢，具有1至11个碳原子的直链或支链烷基，或碳原子数为1〜7的α-甲酰氧基-N，N'-二酰基丙二酰胺具有6至12个碳原子并且包含至少一个芳环的基团是通过羧酸R 3 COOH和R 4 COOH的混合物在α-酰氧基丙二腈，R 1 COO-C（CN）2 -R 2）的作用下制备的新化合物的酸催化剂，可用作漂白或冲洗组合物中有机合成和低温活化剂的中间体。

2. 发明授权

US4221675A Percompound activators 失效
标题翻译：复合激活剂
公开(公告)号：US4221675A
公开(公告)日：1980-09-09
申请号：US908781
申请日：1978-05-23
申请人： Jean-Pierre Schirmann , Bernard Dubreux , Michel Bakes , Serge Y. Delavarenne , Marie-Christine Daude-Lagrave
发明人： Jean-Pierre Schirmann , Bernard Dubreux , Michel Bakes , Serge Y. Delavarenne , Marie-Christine Daude-Lagrave
IPC分类号： C07C235/88 , C11D3/39 , C09K3/00 , C07C69/02 , C07C69/12
CPC分类号： C11D3/3917
摘要： Percompound activators comprising .alpha.-acyloxy-N-acylacetamides having the formula ##STR1## where R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are hydrogen or hydrocarbon radicals optionally substituted by other groups, used to activate percompounds in oxidizing and bleaching of textile fibers, oils, fats, and waxes, for cosmetic hair and skin treatment, metal surface passivation, purification, disinfection, and sterilization, the activators providing more rapid action at a given temperature and being useful at lower temperatures.
摘要翻译：包含具有式“IMAGE”的α-酰氧基-N-酰基乙酰胺的化合物活化剂，其中R 1，R 2，R 3，R 4和R 5为氢或任选被其它基团取代的烃基，用于在纺织纤维的氧化和漂白中活化复合物，油，脂肪和蜡，用于美容毛发和皮肤处理，金属表面钝化，纯化，消毒和灭菌，活化剂在给定温度下提供更快速的作用并且在较低温度下有用。

3. 发明授权

US4913834A Storage stable fluid detergent formulations with bleaching action 失效
标题翻译：储存稳定的流体洗涤剂配方，具有漂白作用
公开(公告)号：US4913834A
公开(公告)日：1990-04-03
申请号：US652291
申请日：1984-09-18
申请人： Bernard Dubreux , Jean-Pierre Schirmann
发明人： Bernard Dubreux , Jean-Pierre Schirmann
IPC分类号： C11D3/395 , C01B15/017 , C11D3/39 , D06L1/04 , D06L3/02
CPC分类号： D06L3/026 , C01B15/017 , C11D3/3942 , C11D3/3947
摘要： Storage stable anhydrous fluid detergent formulation with bleaching action for textile comprising, in the anhydrous state, hydrogen peroxide and the process for the preparation of these formulations.
摘要翻译：用于纺织品的漂白作用的储存稳定的无水流体洗涤剂制剂包括无水状态的过氧化氢和用于制备这些制剂的方法。

4. 发明授权

US4552563A Composition for the alkaline bleaching of textiles containing peroxyamine 失效
标题翻译：用于含有过氧胺的纺织品的碱性漂白的组合物
公开(公告)号：US4552563A
公开(公告)日：1985-11-12
申请号：US650778
申请日：1984-09-13
申请人： Bernard Dubreux , Jackie Emeraud , Gerard Tatin , Jean-Pierre Schirmann
发明人： Bernard Dubreux , Jackie Emeraud , Gerard Tatin , Jean-Pierre Schirmann
IPC分类号： C11D3/395 , C07C67/00 , C07C407/00 , C07C409/40 , C11D3/39 , D06L3/02 , D06L3/00
CPC分类号： C11D3/3945 , D06L3/025
摘要： A composition for the alkaline bleaching of textiles during washing comprising a washing product and at least one peroxide derivative of the general formula: ##STR1## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are hydrogen, a linear alkyl radical containing from 1 to 12 carbon atoms, a cycloalkyl or branched alkyl radical containing from 3 to 12 carbon atoms, or an aromatic hydrocarbon radical having from 6 to 12 carbon atoms; said radicals being unsubstituted or substituted by chlorine, bromine, fluorine, a nitro group, hydroxy group, alkoxy group, ethylenic derivatives, or carboxylic ester and R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4, respectively, capable of forming only a single linear or branched radical having from 3 to 12 carbon atoms and the process of alkaline bleaching using the same.
摘要翻译：用于洗涤期间纺织品的碱性漂白的组合物包含洗涤产物和至少一种通式如下的过氧化物衍生物：其中R 1，R 2，R 3和R 4是氢，含有1个至12个碳原子，含有3至12个碳原子的环烷基或支链烷基或具有6至12个碳原子的芳族烃基; 所述自由基是未取代的或被氯，溴，氟，硝基，羟基，烷氧基，烯属衍生物或羧酸酯取代，R 1和R 2和/或R 3和R 4分别仅能形成单个直链或具有3至12个碳原子的支链基和使用其的碱性漂白过程。

5. 发明授权

US4128494A Activators for percompounds 失效
标题翻译：激活剂用于化合物
公开(公告)号：US4128494A
公开(公告)日：1978-12-05
申请号：US822145
申请日：1977-08-05
申请人： Jean-Pierre Schirmann , Bernard Dubreux , Michel Bakes , Serge-Yvon Delavarenne , Marie-Christine Daude-Lagrave
发明人： Jean-Pierre Schirmann , Bernard Dubreux , Michel Bakes , Serge-Yvon Delavarenne , Marie-Christine Daude-Lagrave
IPC分类号： A61K8/22 , A61K8/38 , A61K8/42 , A61Q5/08 , A61Q19/02 , C11D3/39 , C23C22/06 , C11D3/395 , C11D7/54 , D06L3/02
CPC分类号： A61Q19/02 , A61K8/22 , A61K8/38 , A61K8/42 , A61Q5/08 , C11D3/3917 , C23C22/06
摘要： Novel percompound activators having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are the same or different and are hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals, cycloalkyl radicals, or hydrocarbon radicals containing at least one aromatic ring, or R.sub.5 and/or R.sub.6 are COR.sub.7, where R.sub.7 is hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals or hydrocarbon radicals containing at least one aromatic ring, the activators producing more rapid bleaching or oxidation at a given temperature or the same bleaching effect at a lower temperature and being useful for bleaching textile fibers, oils, fats, and waxes; hair and skin treatment; metal surface passivation; or purifying, sterilizing and disinfecting techniques.
摘要翻译：具有式“IMAGE”的新型全合成活化剂，其中R 1，R 2，R 3，R 4，R 5和R 6相同或不同，为氢或某些取代或未取代的直链或支链烷基，环烷基或含有至少一个芳环，或R 5和/或R 6为COR 7，其中R 7为氢或某些取代或未取代的直链或支链烷基或含有至少一个芳环的烃基，所述活化剂在给定的条件下产生更快的漂白或氧化温度或在较低温度下具有相同的漂白效果，并且可用于漂白纺织纤维，油，脂肪和蜡; 头发和皮肤治疗; 金属表面钝化; 或净化，消毒和消毒技术。

6. 发明授权

US06482383B1 Method for preparing hydrazine hydrate 失效
标题翻译：水合肼的制备方法
公开(公告)号：US06482383B1
公开(公告)日：2002-11-19
申请号：US09674574
申请日：2000-10-31
申请人： Jean-Pierre Schirmann
发明人： Jean-Pierre Schirmann
IPC分类号： C01B2116
CPC分类号： C01B21/16
摘要： A method for preparing hydrazine hydrate comprising: (a) reacting ammonia, hydrogen peroxide and methyl ethyl ketone in a working solution to form an azine; (b) separating the working solution from a mixture comprising the azine, methyl ethyl ketone oxime and optionally the methyl ethyl ketone which had not reacted; (c) recycling the working solution to step (a) after an optional treatment; (d) hydrolyzing the azine to obtain hydrazine hydrate and regenerating the methyl ethyl ketone; (e) recycling to step (a) the methyl ethyl ketone. In step (d) the methyl ethyl ketone oxime is purged.
摘要翻译：一种制备水合肼的方法，包括：（a）在工作溶液中使氨，过氧化氢和甲基乙基酮反应形成吖嗪; （b）从包含吖嗪，甲基乙基酮肟和任选的未反应的甲基乙基酮的混合物中分离工作溶液; （c）在任选处理之后将工作溶液循环到步骤（a）; （d）水解吖嗪以获得水合肼并再生甲基乙基酮; （e）回收步骤（a）甲基乙基酮。在步骤（d）中，清除甲基乙基酮肟。

7. 发明授权

US6080893A Process for the manufacture of acrolein from propylene by a redox reaction and use of a solid mixed oxide composition as redox system in the said reaction 失效
标题翻译：通过氧化还原反应从丙烯制造丙烯醛的方法和在所述反应中使用固体混合氧化物组合物作为氧化还原体系
公开(公告)号：US6080893A
公开(公告)日：2000-06-27
申请号：US31665
申请日：1998-02-27
申请人： Gerard Hecquet , Jean-Pierre Schirmann , Michel Simon , Gilles Descat , Eric Etienne
发明人： Gerard Hecquet , Jean-Pierre Schirmann , Michel Simon , Gilles Descat , Eric Etienne
IPC分类号： B01J23/88 , C07B61/00 , C07C45/28 , C07C45/35 , C07C47/22 , B01J23/28 , B01J23/18 , B01J23/31 , B01J23/54
CPC分类号： C07C45/28
摘要： A mixed oxide solid composition of formula (I):Mo.sub.12 W.sub.a Bi.sub.b Fe.sub.c Co.sub.d Ni.sub.e Si.sub.f K.sub.g Sn.sub.h O.sub.x (I)where O.ltoreq.a.ltoreq.5, 0.5.ltoreq.b.ltoreq.5, 0.1.ltoreq.c.ltoreq.10, 0.5.ltoreq.d.ltoreq.10, 0.ltoreq.e.ltoreq.10, 0.ltoreq.f.ltoreq.15, 0.ltoreq.g.ltoreq.1, 0.ltoreq.h.ltoreq.2 and x is the quantity of oxygen bonded to the other elements and depends on their oxidation states, is used in the manufacture of acrolein by oxidizing propylene, the solid composition reacting with propylene according to the redox reaction (1):solid.sub.oxidized +propylene.fwdarw.solid.sub.reduced +acrolein(I)To manufacture acrolein, gaseous propylene is passed over a solid composition of formula (I), to conduct the redox reaction (1) by operating at a temperature of 200 to 600.degree. C., at a pressure of 1.01.times.10.sup.4 to 1.01 to 10.sup.6 Pa (0.1 to 10 atmospheres) and with a residence time of 0.01 second to 90 seconds, in the absence of molecular oxygen.
摘要翻译：式（I）的混合氧化物固体组合物：Mo12WaBibFecCodNieSifKgSnhOx（I）其中O 固体还原+丙烯醛（I ）为了制备丙烯醛，气态丙烯通过式（I）的固体组合物，通过在200至600℃的温度下操作，在1.01×10 4至1.01至106的压力下进行氧化还原反应（1） Pa（0.1〜10个大气压），停留时间为0.01秒〜90秒，不存在分子氧。

8. 发明授权

US5600039A Process for the preparation of 1,1,1,2-tetrafluoroethane 失效
标题翻译： 1,1,1,2-四氟乙烷的制备方法
公开(公告)号：US5600039A
公开(公告)日：1997-02-04
申请号：US363553
申请日：1994-12-23
申请人： Jean-Michel Galland , Emmanuel Guiraud , Jean-Pierre Schirmann
发明人： Jean-Michel Galland , Emmanuel Guiraud , Jean-Pierre Schirmann
IPC分类号： B01J23/26 , B01J27/053 , C07B61/00 , C07C17/20 , C07C19/08 , C07C17/08
CPC分类号： C07C17/206 , Y02P20/582
摘要： The subject of the invention is a continuous process for the preparation of 1,1,1,2-tetrafluoroethane (134a) from 2-chloro-1,1,1-trifluoroethane (133a) and hydrofluoric acid in the gaseous phase in the presence of a chromium-based catalysts.According to the invention, the flow of gas leaving the reactor is subjected to a distillation in order to separate at the top a flow containing almost all the HC1 and at least 90% of the 134a produced by the reaction and at the bottom a flow containing at least 90% of the unconverted reactants (133a and HF), and the latter flow is recycled directly to the reactor, without any purifying operation.
摘要翻译：本发明的主题是在2-氯-1,1,1-三氟乙烷（133a）中制备1,1,1,2-四氟乙烷（134a）和在气相中的氢氟酸的连续方法的铬基催化剂。根据本发明，离开反应器的气体流被进行蒸馏，以在顶部分离含有几乎所有的HC1和至少90％的通过反应产生的134a的流，并且在底部分离含有至少90％的未转化的反应物（133a和HF），后者的流体直接再循环到反应器中，而无需任何净化操作。

9. 发明授权

US4994583A Process for the preparation of epsilon-caprolactone 失效
标题翻译：制备ε-己内酯的方法
公开(公告)号：US4994583A
公开(公告)日：1991-02-19
申请号：US377806
申请日：1989-07-12
申请人： Michele Pralus , Jean-Claude Lecoq , Jean-Pierre Schirmann
发明人： Michele Pralus , Jean-Claude Lecoq , Jean-Pierre Schirmann
IPC分类号： C07D313/04 , B01J21/02 , C07B61/00 , C07D315/00
CPC分类号： C07D315/00 , Y02P20/582
摘要： Process for manufacturing .SIGMA.- caprolactone by oxidation of cyclohexanone by means of a crude C.sub.2 -C.sub.4 percarboxylic acid solution, resulting from the reaction of hydrogen peroxide on the corresponding carboxylic acid in the presence of a weak acid catalyst, with continuous elimination of water by azeotropic entrainment, characterized in that the molar ratio of cyclohexanone used to the percarboxylic acid is between about 0.50 to 0.99.
摘要翻译：通过在弱酸催化剂存在下由过氧化氢在相应的羧酸上反应产生的粗C2-C4过羧酸溶液来环己酮的氧化制备SIGMA-己内酯的方法，通过共沸连续消除水夹带，其特征在于使用的环己酮与过羧酸的摩尔比为约0.50至0.99。

10. 发明授权

US4459240A Process for the preparation of percarboxylic acids 失效
标题翻译：过羧酸的制备方法
公开(公告)号：US4459240A
公开(公告)日：1984-07-10
申请号：US450002
申请日：1982-12-15
申请人： Michele Pralus , Jean-Claude Lecoq , Jean-Pierre Schirmann
发明人： Michele Pralus , Jean-Claude Lecoq , Jean-Pierre Schirmann
IPC分类号： C07C409/10 , B01J21/02 , B01J27/02 , C07B61/00 , C07C67/00 , C07C407/00 , C07C409/24 , C07C409/26 , C07C179/10
CPC分类号： C07C407/00 , C07C407/003
摘要： Process of preparing substantially anhydrous solutions of percarboxylic acids which comprises reacting hydrogen peroxide contained in an aqueous solution with a water miscible carboxylic acid in the presence of a catalyst and an azeotropic organic solvent, continuously removing the water added with the hydrogen peroxide and formed during the reaction by azeotropic distillation by way of a distillation column, and continuously injecting water into the top of the distillation column during at least the major portion of the reaction time, the quantity of the injected water being less than the quantity of the water removed by azeotrope distillation.
摘要翻译：制备基本上无水的过羧酸溶液的方法，其包括在催化剂和共沸有机溶剂的存在下使包含在水溶液中的过氧化氢与水混溶性羧酸反应，连续除去加入过氧化氢并在通过蒸馏塔进行共沸蒸馏反应，并在反应时间的至少大部分期间将水连续注入蒸馏塔的顶部，注入的水的量小于通过共沸物除去的水量蒸馏。

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