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1. 发明授权

US08436118B2 Synthesis of acylarylenes and hyperbranched poly(aclarylene)s by metal-free cyclotrimerization of alkynes 有权
标题翻译：通过不含金属的炔炔环化三聚法合成酰基亚芳基和超支化聚（亚丙烯基）
公开(公告)号：US08436118B2
公开(公告)日：2013-05-07
申请号：US12451527
申请日：2008-03-04
申请人： Benzhong Tang , Ka Wai Jim , Anjun Qin , Matthias Haeussler , Wing Yip Lam
发明人： Benzhong Tang , Ka Wai Jim , Anjun Qin , Matthias Haeussler , Wing Yip Lam
IPC分类号： C08F138/00 , C08F38/00 , C07C15/00 , C07C15/02
CPC分类号： C08G63/20 , C08G63/00
摘要： The present invention provides a new metal-free cyclotrimerization reaction of alkynes to produce a 1,3,5-triacylarylene or 1,3,5-triacylbenzene. This reaction is catalyzed by secondary amines, is strictly regioselective, highly functionality-tolerant, and the resulting product can be obtained in high yields. This reaction can be further applied for the preparation of novel branched (co)polymers bearing the triacylarylenes as structural units. The preparation of the (co)polymers is carried out as a one-pot single-step reaction procedure, giving branched oligomers and polymers in high yields up to 90%. The produced (co)polymers are also processible, easily film-forming, and thermally stable.
摘要翻译：本发明提供了一种新的无金属的炔炔环化三聚反应，产生1,3,5-三酰基亚芳基或1,3,5-三酰基苯。该反应由仲胺催化，是严格区域选择性的，具有高度的官能度 - 耐受性，所得产物可以高产率获得。该反应可以进一步用于制备具有三酰基亚芳基作为结构单元的新型支链（共）聚合物。（共）聚合物的制备是作为一锅一步反应方法进行的，以高产率提供高达90％的支链低聚物和聚合物。生产的（共）聚合物也是可加工的，容易成膜和热稳定的。

2. 发明授权

US07772358B2 Polytriazoles constructed by 1,3-dipolar cycloaddition 有权
标题翻译：由1,3-偶极环加成构成的三叉唑
公开(公告)号：US07772358B2
公开(公告)日：2010-08-10
申请号：US11896675
申请日：2007-09-05
申请人： Benzhong Tang , Anjun Qin , Matthias Haeussler
发明人： Benzhong Tang , Anjun Qin , Matthias Haeussler
IPC分类号： C08G73/08 , C07C247/02 , C07C247/16
CPC分类号： C08F24/00 , C08F26/06 , C08F30/04
摘要： A process of synthesizing hyperbranched polytriazoles, linear and hyperbranched poly(aroyltriazoles) by Huisgen 1,3-dipolar cycloaddition. The polytriazoles were prepared by A2+B3 method to avoid self-polymerization during monomer preparation and storage. The polymers are light emissive and can be crosslinked to generate well-resolution photopatterns upon UV irradiation. White light emission patterns were observed with fluorescence microscopy. The high molecular weight poly(aroyltriazoles) (up to 26000 Da) are prepared in high yields (up to 92.0%) and with high regioselectivity (the ratio of 1,4- and 1,5-disubstituted 1,2,3-triazole is equal or larger than 9:1). The polycyclomerization is not moisture or oxygen sensitive and therefore, no special precautions are necessary before and during the reaction. All the polymers are processible, easily film-forming, and curable into thermosets by heat or irradiation. The hyperbranched polymers can act as fluorescent adhesive materials with large tensile strength.
摘要翻译：通过Huisgen 1,3-偶极环加成合成超支化聚三唑，线性和超支化聚（芳酰基三唑）的方法。通过A2 + B3方法制备聚三唑，以避免单体制备和储存过程中的自聚合。聚合物是发光的并且可以交联以在UV照射时产生良好分辨率的光图案。用荧光显微镜观察白光发射模式。高分子量聚（芳基三唑）（高达26000Da）以高产率（高达92.0％）和高分辨率选择性（1,4和1,5-二取代的1,2,3-三唑的比例等于或大于9：1）。多重环化不是水分或氧气敏感的，因此在反应之前和期间都不需要特别的预防措施。所有的聚合物都是可加工的，易成膜的，并且通过热或照射可固化成热固性材料。超支化聚合物可以作为具有大拉伸强度的荧光粘合剂材料。

3. 发明申请

US20100129757A1 SYNTHESIS OF ACYLARYLENES AND HYPERBRANCHED POLY(ACLARYLENE)S BY METAL-FREE CYCLOTRIMERIZATION OF ALKYNES 有权
标题翻译：通过金属无环烷基化方法合成乙烯和高分子聚（丙烯）
公开(公告)号：US20100129757A1
公开(公告)日：2010-05-27
申请号：US12451527
申请日：2008-03-04
申请人： Benzhong Tang , Ka Wai Jim , Anjun Qin , Matthias Haeussler , Wing Yip Lam
发明人： Benzhong Tang , Ka Wai Jim , Anjun Qin , Matthias Haeussler , Wing Yip Lam
IPC分类号： G03F7/20 , C08G63/78 , C08G63/00 , C08G73/00
CPC分类号： C08G63/20 , C08G63/00
摘要： The present invention provides a new metal-free cyclotrimerization reaction of alkynes to produce a 1,3,5-triacylarylene or 1,3,5-triacylbenzene. This reaction is catalyzed by secondary amines, is strictly regioselective, highly functionality-tolerant, and the resulting product can be obtained in high yields. This reaction can be further applied for the preparation of novel branched (co)polymers bearing the triacylarylenes as structural units. The preparation of the (co)polymers is carried out as a one-pot single-step reaction procedure, giving branched oligomers and polymers in high yields up to 90%. The produced (co)polymers are also processible, easily film-forming, and thermally stable.
摘要翻译：本发明提供了一种新的无金属的炔炔环化三聚反应，产生1,3,5-三酰基亚芳基或1,3,5-三酰基苯。该反应由仲胺催化，是严格区域选择性的，具有高度的官能度 - 耐受性，所得产物可以高产率获得。该反应可以进一步用于制备具有三酰基亚芳基作为结构单元的新型支链（共）聚合物。（共）聚合物的制备是作为一锅一步反应方法进行的，以高产率提供高达90％的支链低聚物和聚合物。生产的（共）聚合物也是可加工的，容易成膜和热稳定的。

4. 发明申请

US20080103273A1 Polytriazoles constructed by 1, 3-dipolar cycloaddition 有权
标题翻译：通过1,3-偶极环加成构成的三叉唑
公开(公告)号：US20080103273A1
公开(公告)日：2008-05-01
申请号：US11896675
申请日：2007-09-05
申请人： Benzhong Tang , Anjun Qin , Matthias Haeussler
发明人： Benzhong Tang , Anjun Qin , Matthias Haeussler
IPC分类号： C08F38/00 , C08F24/00 , C08F26/06 , C08F30/04
CPC分类号： C08F24/00 , C08F26/06 , C08F30/04
摘要： A process of synthesizing hyperbranched polytriazoles, linear and hyperbranched poly(aroyltriazoles) by Huisgen 1,3-dipolar cycloaddition. The polytriazoles were prepared by A2+B3 method to avoid self-polymerization during monomer preparation and storage. The polymers are light emissive and can be crosslinked to generate well-resolution photopatterns upon UV irradiation. White light emission patterns were observed with fluorescence microscopy. The high molecular weight poly(aroyltriazoles) (up to 26000 Da) are prepared in high yields (up to 92.0%) and with high regioselectivity (the ratio of 1,4- and 1,5-disubstituted 1,2,3-triazole is equal or larger than 9:1). The polycyclomerization is not moisture or oxygen sensitive and therefore, no special precautions are necessary before and during the reaction. All the polymers are processible, easily film-forming, and curable into thermosets by heat or irradiation. The hyperbranched polymers can act as fluorescent adhesive materials with large tensile strength.
摘要翻译：通过Huisgen 1,3-偶极环加成合成超支化聚三唑，线性和超支化聚（芳酰基三唑）的方法。聚三唑通过A 2 N + B 3 N 3方法制备，以避免单体制备和储存期间的自聚合。聚合物是发光的并且可以交联以在UV照射时产生良好分辨率的光图案。用荧光显微镜观察白光发射模式。高分子量聚（芳基三唑）（高达26000Da）以高产率（高达92.0％）和高分辨率选择性（1,4和1,5-二取代的1,2,3-三唑的比例等于或大于9：1）。多重环化不是水分或氧气敏感的，因此在反应之前和期间都不需要特别的预防措施。所有的聚合物都是可加工的，易成膜的，并且通过热或照射可固化成热固性材料。超支化聚合物可以作为具有大拉伸强度的荧光粘合剂材料。

5. 发明授权

US10753941B2 Biocompatible nanoparticles with aggregation induced emission characteristics as fluorescent bioprobes and methods of using the same for in vitro and in vivo imaging 有权
公开(公告)号：US10753941B2
公开(公告)日：2020-08-25
申请号：US14342074
申请日：2012-09-03
申请人： Benzhong Tang , Wei Qin , Jianzhao Liu , Sijie Chen , Tsz Kin Kwok , Bin Liu , Kai Li , Dan Ding , Haibin Shi , Jun Long Geng , Jingzhi Sun , Anjun Qin , Qiuli Zhao
发明人： Benzhong Tang , Wei Qin , Jianzhao Liu , Sijie Chen , Tsz Kin Kwok , Bin Liu , Kai Li , Dan Ding , Haibin Shi , Jun Long Geng , Jingzhi Sun , Anjun Qin , Qiuli Zhao
IPC分类号： A61B5/00 , A61B8/00 , A61B10/00 , G01N33/58 , A61K49/00 , C09K11/06 , C12Q1/37 , G01N33/574
摘要： The development of fluorescent bioprobes comprising organic fluorescent compounds that exhibit aggregation induced emission (AIE) properties, methods of producing the same, and their practical applications for in vitro and in vivo bioimaging.

6. 发明授权

US09051598B2 Specific detection of D-glucose by a tetraphenylethene-base fluorescent sensor 有权
标题翻译：通过四苯乙烯基荧光传感器对D-葡萄糖的特异性检测
公开(公告)号：US09051598B2
公开(公告)日：2015-06-09
申请号：US13462183
申请日：2012-05-02
申请人： Benzhong Tang , Yi Liu , Jingzhi Sun , Anjun Qin , Rongrong Hu
发明人： Benzhong Tang , Yi Liu , Jingzhi Sun , Anjun Qin , Rongrong Hu
IPC分类号： G01N21/64 , G01N33/52 , C12Q1/54 , G01N33/66 , G01N33/58
CPC分类号： C12Q1/54 , G01N21/64 , G01N21/6428 , G01N21/6486 , G01N33/52 , G01N33/582 , G01N33/66 , G01N2021/6439 , Y10T436/144444
摘要： A method of detecting the presence or absence of saccharide or saccharide level in a biological or artificial sample comprising contacting the sample with a water-soluble tetraphenylethene-cored probe having multiple functionalities of boronic acid and aggregation induced emission (AIE) characteristics, and detecting fluorescence. A method for detecting pH in a sample solution with a certain pH value comprising contacting the sample solution with a water-soluble tetraphenylethene-cored probe having multiple functionalities of boronic acid and aggregation induced emission (AIE) characteristics, and detecting fluorescence.
摘要翻译：一种检测生物或人造样品中糖或糖含量的存在或不存在的方法，包括使样品与具有多种硼酸功能性和聚集诱导发射（AIE）特征的水溶性四苯乙烯 - 核心探针接触，并检测荧光。一种用于检测具有一定pH值的样品溶液中的pH的方法，包括使样品溶液与具有多种硼酸官能度和聚集诱导发射（AIE）特性的水溶性四苯乙烯 - 核心探针接触，并检测荧光。

7. 发明申请

US20120148958A1 SULFUR-CONTAINING MACROMOLECULES AND METHODS FOR THEIR PREPARATION 有权
标题翻译：含硫的大分子及其制备方法
公开(公告)号：US20120148958A1
公开(公告)日：2012-06-14
申请号：US13391186
申请日：2010-08-06
申请人： Benzhong Tang , Ka wai Jim , Anjun Qin , Wing Yip Lam , Jianzhao Liu
发明人： Benzhong Tang , Ka wai Jim , Anjun Qin , Wing Yip Lam , Jianzhao Liu
IPC分类号： C08F128/04 , G03F7/20
CPC分类号： C08G75/025 , C08G75/045
摘要： A sulfur-containing macromolecule and a method of preparing the sulfur-containing macromolecule comprising a polymerization step are provided, where the sulfur-containing macromolecule contains internal units of formula (I) and the polymerization step is formula (II) wherein n is greater than 1, said precursor comprises alkyne having one or more acetylene groups and thiol having one or more thiol groups; and R is remainder of said thiol excluding said thiol groups, R′ is remainder of said alkyne excluding said acetylene groups, and R and R′ are selected from organic or organometallic groups.
摘要翻译：提供含硫高分子和制备包含聚合步骤的含硫高分子的方法，其中含硫高分子含有式（I）的内部单元，聚合步骤为式（II），其中n大于 1，所述前体包括具有一个或多个乙炔基的炔烃和具有一个或多个硫醇基团的硫醇; 并且R是除所述硫醇基之外的所述硫醇的剩余部分，R'是除所述乙炔基之外的所述炔烃的剩余部分，R和R'选自有机或有机金属基团。

8. 发明申请

US20140328764A1 Biocompatible Nanoparticles with Aggregation Induced Emission Characteristics as Fluorescent Bioprobes and Methods of Using the Same for In Vitro and In Vivo Imaging 审中-公开
标题翻译：具有聚集诱导的排放特性作为荧光生物探针的生物相容纳米颗粒及其在体外和体内成像中的使用方法
公开(公告)号：US20140328764A1
公开(公告)日：2014-11-06
申请号：US14342074
申请日：2012-09-03
申请人： Benzhong Tang , Wei Qin , Jianzhao Liu , Sijie Chen , Tsz Kin Kwok , Bin Liu , Kai Li , Dan Ding , Haibin Shi , Jun Long Geng , Jingzhi Sun , Anjun Qin , Qiuli Zhao
发明人： Benzhong Tang , Wei Qin , Jianzhao Liu , Sijie Chen , Tsz Kin Kwok , Bin Liu , Kai Li , Dan Ding , Haibin Shi , Jun Long Geng , Jingzhi Sun , Anjun Qin , Qiuli Zhao
IPC分类号： G01N33/58 , A61K49/00 , G01N33/574 , C12Q1/37
CPC分类号： G01N33/582 , A61K49/0021 , A61K49/0054 , A61K49/0093 , C09K11/06 , C12Q1/37 , G01N33/574 , G01N2333/96466
摘要： The development of fluorescent bioprobes comprising organic fluorescent compounds that exhibit aggregation induced emission (AIE) properties, methods of producing the same, and their practical applications for in vitro and in vivo bioimaging.
摘要翻译：荧光生物探针的发展包括显示聚集诱导发射（AIE）性质的有机荧光化合物，其生产方法及其在体外和体内生物成像中的实际应用。

9. 发明授权

US08859698B2 Sulfur-containing macromolecules and methods for their preparation 有权
标题翻译：含硫大分子及其制备方法
公开(公告)号：US08859698B2
公开(公告)日：2014-10-14
申请号：US13391186
申请日：2010-08-06
申请人： Benzhong Tang , Ka Wai Jim , Anjun Qin , Wing Yip Lam , Jianzhao Liu
发明人： Benzhong Tang , Ka Wai Jim , Anjun Qin , Wing Yip Lam , Jianzhao Liu
IPC分类号： C08G12/30 , C08G75/04
CPC分类号： C08G75/025 , C08G75/045
摘要： A sulfur-containing macromolecule and a method of preparing the sulfur-containing macromolecule comprising a polymerization step are provided, where the sulfur-containing macromolecule contains internal units of formula (I) and the polymerization step is formula (II) wherein n is greater than 1, said precursor comprises alkyne having one or more acetylene groups and thiol having one or more thiol groups; and R is remainder of said thiol excluding said thiol groups, R′ is remainder of said alkyne excluding said acetylene groups, and R and R′ are selected from organic or organometallic groups.
摘要翻译：提供含硫高分子和制备包含聚合步骤的含硫高分子的方法，其中含硫高分子含有式（I）的内部单元，聚合步骤为式（II），其中n大于 1，所述前体包括具有一个或多个乙炔基的炔烃和具有一个或多个硫醇基团的硫醇; 并且R是除所述硫醇基之外的所述硫醇的剩余部分，R'是除所述乙炔基之外的所述炔烃的剩余部分，R和R'选自有机或有机金属基团。

10. 发明授权

US08524858B2 Preparation of hyperbranched poly(triazole)s by in situ click polymerization and adhesive containing the same 有权
标题翻译：通过原位点击聚合制备超支化聚（三唑），并含有它们的粘合剂
公开(公告)号：US08524858B2
公开(公告)日：2013-09-03
申请号：US12984886
申请日：2011-01-05
申请人： Benzhong Tang , Youhong Tang , Ka Wai Jim , Anjun Qin , Wing Yip Lam , Jie Li
发明人： Benzhong Tang , Youhong Tang , Ka Wai Jim , Anjun Qin , Wing Yip Lam , Jie Li
IPC分类号： C08G73/06 , C08G73/00
CPC分类号： C08G73/08 , C09J5/02 , C09J179/06 , C09J2400/163 , C09J2400/166 , C09J2479/02
摘要： Provided is a high temperature-resistant metal adhesive containing hyperbranched poly(triazole)s synthesized by in situ azide/alkyne click polymerization. Also provided is a method for preparing the same adhesives by in situ click polymerization of azide and alkyne monomers on metal substrates. The method is optimized to get high adhesive strength at room temperature or elevated temperatures by analyzing the effects of monomer ratio, curing temperature and time, and annealing temperature and time. The hyberbranched poly(triazole)s adhesive has comparable or better temperature resistance compared with known high temperature epoxy metal adhesives, and it is the first high temperature metal adhesive using hyperbranched poly(triazole)s prepared by in situ azide/alkyne click polymerization.
摘要翻译：提供含有通过原位叠氮化物/炔烃聚合合成的超支化聚（三唑）的耐高温金属粘合剂。还提供了通过在金属基底上原位点击叠氮化物和炔单体来制备相同粘合剂的方法。该方法通过分析单体比例，固化温度和时间以及退火温度和时间的影响，在室温或高温下得到高粘合强度。与已知的高温环氧金属粘合剂相比，支链聚（三唑）粘合剂具有相当或更好的耐温性，并且是使用通过原位叠氮化物/炔烃聚合制备的超支化聚（三唑）的第一种高温金属粘合剂。

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